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We outline a first version of an ambitious goal: The world's first horizontal (matrix-independent) generic sampling standard. The specific needs and requirements are overwhelming, as all the world's analytical standards follow strict matrix or material type classification pigeonholes, leading to a plethora of analytical standards. One could rightly expect a similar multiplication regarding sampling standards, yet the singular HORIZONTAL is aimed at being truly generic. Also the existing style of standards writing is cumbersome and partly contradictory. The current work is presently being pursued in CEN and European Union standardisation regimens, for which reason full disclosure and publication is not allowed. Respecting this constraint, we unofficially present selected key issues involved in developing HORIZONTAL: The objective and scope of a horizontal sampling standard is to delineate the minimum set of principles and procedures needed to guarantee documented representative sampling for all types of materials. The horizontal standard is designed for two types of use: 1. auditing/assessing/ improving the reliability of an existing sampling procedure, and 2. design and implementation of a new sampling procedure (new lot type). The principles in this standard are all derived from the Theory of Sampling (TOS), but the standard is far from a mere collection of TOS principles. Representativeness is a characteristic of the sampling process, not of samples themselves. For practical purposes, the horizontal standard follows the fundamental distinction between 'stationary lots' (0-D, 2-D, 3-D lots) and 'dynamic lots' (within TOS aka process sampling - including extended, non-moving 1-D lots). TOS' principles of 'correctness' must never be broken at any stage, lest representativeness is irretrievably lost. The horizontal standard is not written in the mandatory fashion for legally binding matrix-specific standards, eg ISO - for the present overarching purpose a different style had to be developed. The standard must be immediately understandable in full, which merits special demands, eg extensive use of didactic illustrations. HORIZONTAL introduces an all-inclusive sampling variability measure, Relative Sampling Variance (RSV) which is for sampling of stationary lots as variographics is for process sampling - RSV is to be used as a quality criterion for any stationary sampling procedure as applied to a specific heterogeneity (lot/material). The target for this standard is all individuals, companies, organisations and regulatory bodies who are responsible for sampling: technicians, process engineers, laboratory personal, academic and industrial scientists as well as project leaders, technical managers/directors and top managers. Based on current R&D we illustrate the principles promulgated by HORIZONTAL with cases from exploration and mining of minerals commodities, a Finnsh 'Autosampler' at work in the mining context (RSV) as well as sampling equipment for use in the cement and mineral commodities industries. This is an ABSTRACT ONLY. No paper was prepared for this presentation.

Mar 1, 2010

The State of Western Australia has a land area of 2 525 000 km2, and is well endowed with minerals and petroleum products. In 1989 - 90 these products were valued at nearly A$10 500 million.

Jan 1, 1992

THIS excellent volumetric method commends itself as a means of estimating the fineness of silver firstly, owing to the large number of possible impurities which do not affect its accuracy (these impurities include Cu-up to 70 % Au, Ph, Zn, Bi, Cd, Fe, Mn, Sb, and As); secondly, the method combines accuracy with speed. The above impurities are the only ones likely to be present in the B. H. A. S. Pty. Ltd. refined silver, and, with the exception of Cu and Au, the others, if present at all, would be well under 0.1 parts per 1000.Briefly stated, the method consists in the solution of the refined silver in HN03 , addition of ferric alum (indicator), and titration with an alkaline (either ammonium or potassium) thiocyanate solution until the brown ferric thiocyanate is formed, and gives a definite tint to the solution. The method is used at the Port Pirie smelters, and the outstanding feature in the method as there applied is the type of burette employed. This burette enables the operator to read 0.01 of a cc. with ease, whereas, with the ordinary burette fitted with a float, 0.05 of a cc., when a number of readings have to be taken, becomes very straining to the eyes. Moreover, waiting for the float to rise, and dislodging air bubbles from it, hinders rapid working.A description of the burette and fittings is appended with fig. 2. DETAILS OF THE METHODSolutions required are:a) Stock Solutions:(1) Ammonium thiocyanate, 40 grm. per litre of water; 30 litres are prepared and placed in a carboy with glass syphon attached.(2) Ferric alum, 250 grnl. per litre; two litres are prepared.

Jan 1, 1922

By D Connelly

The initial results for the cyanide leach gold recoveries were very poor on a high-grade primary sulphide ore of 6.2 g/t Au with no silver. Subsequent mineralogy showed the ore to be a characteristic pyrite, carbonaceous refractory gold ore (double refractory). This was a very disappointing finding. A small scale gravity and flotation test programme was developed to produce a concentrate with the majority of the gold. This also failed with most of the gold remaining in the tailings. An ICP scan also showed variable levels of antimony. A Desktop Study was undertaken with minimal laboratory test work looking at Pressure Oxidation (POX), roasting, ultra-fine grinding, graphite passivation and consideration of any new technologies that might be applicable to this type of ore. The subsequent Study highlighted how difficult these double refractory gold ores are to process and highlighted some recent technology developments may be applicable. CITATION: Connelly, D, 2018. Technology options for processing complex and double refractory gold ore, in Proceedings Complex Orebodies Conference 2018, p 94 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By J Vann, S Dunham, M Job

Two-dimensional (2D) estimation approaches have significant advantages over three-dimensional (3D) approaches when dealing with a narrow vein- or layer-like geometry. The main motivation for 2D estimation is that bias due to non-additivity of grade is avoided. The various aspects of 2D estimation are illustrated by use of a case study from the 1A Shoot Nickel deposit at Leinster, Western Australia. The width of the 1A mineralisation is variable, and so are the angles of drilling intersection. Consequently, the variable of interest (in this case nickel grade) is not suitable for direct kriging because it is defined on non-uniform support. However, grade can also be defined as the ratio of two variables that are suitable for direct kriging: thickness and accumulation. In the 2D approach, tonnage equates to thickness and metal equates to the product of grade and thickness, also called æaccumulationÆ. In the simplest approach we can independently krige accumulation and thickness and derive the grade by the ratio of the two resultant estimates. The thickness and accumulation variables must be in a consistent projection orientation, for example a horizontal projection in the case of steeply inclined mineralisation like 1A. Because the density is not constant across the 1A (and most other) deposits, the issue of density weighting is also discussed. The impact of the correlation between grade and length, or grade and density are important issues in implementation of 2D estimation. The circumstances under which these correlations need to be taken into account (by co-kriging) are reviewed. Finally some comments are made on the final use of the resultant 2D estimate for mine planning purposes.

Jan 1, 2003

By R Grogan

Nautilus Minerals Inc is a sea floor resource exploration and development company focused on developing the Solwara 1 Project, a copper-gold sea floor massive sulfide deposit in the territorial waters of Papua New Guinea, for which it holds a mining lease and associated environment permit.Economies depend upon four key types of capital: built, natural, financial and human. Natural capital consists of the ‘minerals, energy, plants, animals, ecosystems (climatic processes, nutrient cycles and other natural structures and systems) found on Earth that provide a flow of natural goods and services’ (Daly and Farley, 2004). Many ecosystem goods such as fish, fruit and water are already valued and sold in markets; however, some ecosystem services are not amenable to markets and have remained unvalued in traditional accounting methods, even though they provide significant value (such as flood protection, climate stability etc; Batker and Schmidt, 2015).There are now economic methods available to quantify and value natural capital and many non-market ecosystem services. When valued in dollars, these services can be incorporated into a number of economic tools, including benefit-cost analysis, accounting, environmental impact statements, asset management plans and rate of return on investment calculations. Their inclusion ultimately strengthens decision-making. When natural capital assets and ecosystem services are not considered in economic analysis, they are effectively valued at zero. This omission can lead to poor decisions, inefficient capital investments, higher incurred costs and losses due to unexpected events (Batker and Schmidt, 2015).In 2015 Earth Economics was commissioned by Nautilus Minerals Inc to conduct an independent, objective environmental and social benchmarking analysis of the proposed deep seabed Solwara 1 mine with terrestrial copper mines (referred to as ‘the report’). The report represents the first ever natural capital accounting and ecosystem goods and services framework for seabed mining.The report compares the proposed Solwara 1 mine with three terrestrial mines: Bingham Canyon (Utah, USA), Prominent Hill (South Australia, Australia), and Intag (a proposed mine in Intag Province, Ecuador), and provides a natural capital accounting assessment for all four operations.CITATION:Grogan, R, 2016. Natural capital accounting – a sea floor mining application, in Proceedings Life-of-Mine 2016 Conference, pp 2–4 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By N Akizawa, A Tamura, S Arai

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Reaction products between high-temperature hydrothermal solution/uppermost mantle peridotite or lowermost crustal gabbro have been reported along Wadi Fizh of the northern Oman ophiolite; they are named as ‘mantle diopsidite’ and ‘crustal diopsidite’ respectively (Figure 1).The mantle diopsidite contains Cr-rich minerals like chromite, Cr-rich diopside (<2.5 wt per cent Cr2O3) and Cr-bearing grossular (<7.0 wt per cent Cr2O3). The chromites are varied in shape in the mantle diopsidite, euhedral to anhedral chromite grains contain globular inclusions of grossular and chlorite, and film-like chromite veinlets branch off from partially dissolved coarse chromite grains. In the crustal diopsidite, fine chromite grains are included in oscillatory-zoned skeletal uvarovite, especially in its high-Cr zones. The uvarovites are rich in rare earth elements (REEs). Direct laser ablation – inductively coupled plasma – mass spectrometer (LA-ICP-MS) analysis of the primary fluid inclusions detected Na, but not K.Our detailed studies of Wadi Fizh diopsidites clarify that the high-temperature hydrothermal solution dissolves chromite grains at the uppermost mantle section and precipitates hydrothermal chromite at the lowermost crust section. In addition, REEs were mobilised in the hydrothermal solution together with Cr. The hydrothermal solution involved in the diopsidite formation is assumed to have been rich in NaCl, and could mobilise appreciable amounts of Cr and REE.CITATION:Akizawa, N, Arai, S and Tamura, A, 2015. Chromium and rare earth elements mobility by sodium-bearing high-temperature hydrothermal solution – an example from mantle diopsidite and crustal diopsidite, in Proceedings PACRIM 2015 Congress, pp 291–296 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By F R. A Jorgensen, G W. Jensen

A pilot scale experimental investigation of the condensation of zinc vapour from smelter off-gases was performed in conjunction with a mathematical modelling study of the system. The work investigated the feasibility of using the high heat and mass transfer rates associated with a fluidised bed to condense zinc directly from smelter off-gases containing zinc vapour. Of particular interest was whether zinc would revert to zinc oxide during the process of condensation, and whether a zinc fog would form and be carried out of the condenser. A 0.1 m diameter fluidised bed condenser was mounted on the top of a 200 kVA DC electric arc furnace in which mixtures of vapours and gases were generated at 1150 - 1300¦C. The gas/vapour mixtures investigated included Zn/N2, Zn/N2/CO/CO2 and Zn/N2/H2/H2O. Greater than 90 per cent of the zinc was deposited on the zircon sand bed of the condenser, and there was no sign of zinc oxide formation, suggesting that the rate of heat transfer was faster than the reaction rate for zinc oxide formation. There was also no evidence that fog was being formed in the condenser. Using the methods of Kunii and Levenspeil (1991), a mathematical model was developed to predict the behaviour of the fluidised bed condenser. The model enabled the distribution of gas/vapour temperature and bed temperature to be determined as a function of distance from the condenser inlet. Similarly the partial pressure of zinc vapour in the gas mixture, and hence the mass transfer rate of zinc to the particles, was determined. Experimental data allowed validation of the predicted bed and gas/vapour temperatures.

Jan 1, 2000

By T Takayama, R Muroi, M Matsumura

The steel industry occupies 14 per cent of CO2 emissions in Japan, and the sintering process is one of the major emitters. Since most of CO2 released from the sintering process comes from coke fine combustion, replacement of coke fines with biomass char as bonding agent is a potential countermeasure. In order to explore the effective use of biomass char, we chose char made from Palm Kernel Shell (PKS) as a sample. First, the char’s combustion behaviour was examined with varying the char’s particle size by means of admixing the char in alumina ball packed bed placed in an electric furnace. As a result, the finer the PKS char the faster the burning rate and reaching a higher temperature compared to coke fine. In addition, it is also concluded that the optimum size of PKS char was larger than coke fines. Next, the effect of different heat profiles on sinter structure was examined by sintering tablet made of chemical reagents. In this experiment, the chemical composition is designed based on sinter composition. By this sintering test, even at high temperature, rapid cooling is effective to make fine sinter matrix and fine pores, which has possibility for high sinter reducibility. Based on these two experiments, using PKS char as a sinter fine source has the possibility to improve sinter reducibility.

Nov 8, 2021

THE following paragraphs represent an endeavour to describe, briefly the equipment used for the manufacture of sulphuric acid and superphosphates by the Corporation.SULPHURIC ACID PLANTS.Two separate units are in operation, No. I Plant working on sulphur dioxide generated from pyritic ore, No. 2 Plant working on sulphurous gases obtained from the Huntingdon-Heberlein desulphurizing process. The latter plant is unique in being the first installation for the successful use of these gases.

Jan 1, 1918

By L Hussey

Mt Keith concentrator treats low grade disseminated nickel sulfide ore supplied from the adjoining open pit mine. It is a traditional crushing, two-staged closed circuit grinding circuit (SAG & Ball Mills), followed by a complex split-size rougher, scavenger and cleaner flotation circuit. In 2016, 10.5 Mt was milled, at an average head grade of 0.54% Ni, yielding 35 000 nickel metal tonnes in concentrate.Historical analysis of the plant data indicated that of all the nickel lost in the fines rougher circuit tails stream, 25.6% was recoverable in an eight minute laboratory scale flotation test. These results implied that this fine nickel was readily available for recovery in the plant, either through operational improvements or additional flotation capacity. With operation optimisation ongoing, and capital within the business focused elsewhere, plant personnel were challenged to think differently about improving recovery.In 2012, a separate project to improve plant recovery when treating high talc ore was completed. Amongst other vessels, this project saw the installation of two 150 m3 Outotec Cells to the scavenger section of the fines rougher, middlings and scavengers (RMS 1) circuit. Since installation, the operation of these cells resulted in difficulties immediately upstream with instability in the scavenger cells. It was therefore decided that these cells would be better suited to treating the fines rougher circuit tails.The alterations required to divert these flows were minimal, with the capital project totalling $220 000.In the two years since installation, the fines rougher tailings nickel grade has dropped by 9.9%. The scavenger circuit has also seen a 2.8% reduction in tailings nickel grade, and instability issues were immediately resolved. This project serves as a lesson in how existing plant infrastructure may be better utilised to maximise recovery. Although this is especially applicable when capital constrained, such re-appropriation can be considered at any point to maximise return on existing assets. CITATION:Hussey, L, 2017. Repurposing flotation capacity at Mt Keith nickel concentrator, in Proceedings MetPlant 2017, pp 254–258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By D E. Tennant

In the fields of geotechnical engineering and slope management, various software packages are used to assess the behaviour or propensity for a slope to fail. Traditional kinematic analysis calculates the probability of failure of design sectors with respect to dominant structural set orientations. A novel methodology is provided here to view potential hazardous slope behaviour in 3D, allowing engineers to make informed decisions regarding various pit slope geometries. Apparent dips are calculated for every point in space with respect to every slope orientation of the entire pit surface/design, specifically in reference to bench and inter-ramp planar failure mechanisms. Implementing a proactive approach to slope design will not only lead to early mitigation of risk but can also add direct value by enhancing or improving upon slope angles for earlier access to ore. From a safety perspective, identification of unfavourably oriented slope geometries can be dealt with before failure occurs. This methodology relies on a strong understanding of the existing rock mass anisotropy, particularly behind the face, thereby removing some of the uncertainty surrounding pit design as well as presenting engineers with an additional means to manage risk.

Nov 29, 2022

By K Zhao, H Gong, B Li

Health and safety are the first priority for Australian minerals sector. Australia has a global reputation in the mining industry. However, accidents occur every year. Legislation and regulation are important to prevent the accident from occurring, so do the new technologies. It is sad to witness the collision incident persisting and the long called collision avoidance system (CAS) is still not widely used in underground mines. The main reason is that the existing systems are still not advanced enough. The current CASs utilise GPS, infrared, ultrasonic, RFID, Radar, electromagnetic etc have their limitations and disadvantages. For instance, GPS is widely used in a surface mine, but it cannot be applied in underground mine; Infrared and electromagnetic have the false positive problem.

Sep 1, 2024

By E Holloway

The optimisation of an open pit mine can be broadly split into two stages, the first being the ultimate pit optimisation (and subsequent stage designs), and the second being schedule optimisation. Macroeconomic uncertainty clearly impacts on both however interrelationships do also exist. Generally, the opportunity exists for the ultimate pit to be revised during each planning cycle, however when this reprieve is removed the uncertainty for the underlying business increases. As one example, the introduction of an in-pit waste dump can be seen to significantly limit the option to revise the ultimate pit. When in this situation there are two potential risks that present: (i) the long-term price used for the ultimate pit selection is optimistic, and too large of a pit is selected resulting in waste being mined which uncovers material not of a significant value to deliver a profit; (ii) the long-term price used for the ultimate pit selection is pessimistic, too small of an ultimate pit is selected, and ore of realisable economic value left behind. Both of these outcomes are risks and as such can be assessed and quantified. CITATION: Holloway, E, 2018. Incorporating economic variability into a strategic planning framework, in Proceedings Complex Orebodies Conference 2018, pp 88–90 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By T Takayama, M Matsumura, Y Konno

The steel industry accounts for 14 per cent of domestic CO2 emission in Japan, and iron ore sintering process occupies approximately three per cent. While Fe content in iron ore is gradually decreasing. So, the amount of concentrated iron ore will increase in the future. We have focused on magnetite concentrate as sinter materials, because magnetite can be easily magnetically beneficiated. However, it is experienced that blending magnetite ore resulted in increasing Fe2+ component in the iron ore sinter, which results in lower reducibility. Therefore, promoting the oxidation reaction from magnetite to hematite in the sintering process is countermeasure for reducibility. In addition, this promotion causes increase of oxidation heat, which results in high sinter strength and reduction of coke. It is assumed that the oxidation of magnetite tends to proceed in the cooling stage, where the oxygen partial pressure increases after the combustion of fine coke, but there are few studies on the effect of heat profile, especially cooling path. The purpose of this study is to design the effective sintering heat profile to promote oxidation of magnetite ore, especially, to investigate the effect of cooling path on sintered ore microstructure. In this study, magnetite ore and magnetite reagent were respectively mixed with calcium carbonate reagent. Then the mixed samples were pressed and formed into cylindrical tablets for simulating the adhesive layer of a pseudo particle. Through examining influence of maximum temperature and cooking rate on oxidation reaction of magnetite, we confirmed that the oxidation reaction of magnetite is suppressed at above 1350°C for maximum temperature, compared to 1300°C. Sintering at lower temperature is desirable because hematite is stable below 1350°C in the Fe2O3-CaO phase diagram.

Nov 8, 2021

By Pollard D. M

Chalcopyrite samples from two different localities were leached in oxygenated mixed chloride-sulphate lixivants at elevated temperatures and atmospheric pressure. The oxidation of chalcopyrite was found to follow predominantly linear kinetics. The slope of the major region was dependent on stirring rate, oxygen flowrate and chloride concentration while only slightly dependent on the surface area of the sample leached. This region was found to predominate only at low temperatures. The oxidised chalcopyrite releases cuprous and ferric ions into solutions. Chloride ions complex these dissolved ions to effectively move the equilibrium of the leaching reaction to the right. When the level of chloride in solution was below 6 g/l, the unstable cuprous ions were found to reprecipitate with sulphur as covellite. When no chloride was present and the lixivant was a solution of sulphuric acid then ferric sulphates precipitated. The overall leaching reaction occurring in the leaching system is: CuFeS2 + 5H+ + 1.25 02 = Cu 2+ + Fe 3+ + 2S¦ + 2.5H20

Jan 1, 1987

By N Madani

Linear interpolation of geo-related variables is important to different aspects of mining engineering such as long and short-term mine planning. The ore deposit description attained from spatial modeling of blast hole datasets has been widely taken into account, particularly, for short-term mine design and grade control, so as to define the ultimate destination of a mined block. It is approved in practice that making the wrong decision leads to losing a huge amount of money for choosing the destination of a mined block. In the case of complex ore deposits, the issue of estimation of variables in the region is questionable and somehow tedious. Due to this fact, modeling those complications in the co-spatial behavior of the grades in multi-element deposits prompts one to employ enhanced geostatistical techniques. Traditional approaches of this purpose such as polygon, inverse distance weighted and even (co)-kriging approaches, are incapable of reproducing those complexities such as non-linearity, heteroscedasticity and geological constraint that frequently exist among the variables of interest in those deposits. Another difficulty in employing those linear interpolations in grade estimation is smoothing effect, in which the estimated grades are over and under estimated. CITATION: Madani, N, 2018. 3D estimation of variables with complexity in cross-correlation structures, in Proceedings Complex Orebodies Conference 2018, pp 49–52 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By R A. Pakhomov, L V. Krupnov, P V. Malakhov, I M. Dymov

The article presents results of thermodynamic calculations and laboratory studies, focusing on the cobalt behaviour during oxidative smelting of copper-nickel mattes. The compositions of the studied solutions are related to the products formed during the second stage of the converting process of copper-nickel matte at the Nadezhdinsky Metallurgical Plant (NMP) of MMC Norilsk Nickel company. These sulfide products typically contain from 1.5 to 12 wt per cent of iron. The obtained experimental results and thermodynamic calculations indicate that adjusting the CaO ratio to increase the proportion of CaO or complete replacement of SiO2 with fluxes containing CaO leads to a significant increase in cobalt recovery rates in the matte phase (with an iron concentration of 2.5 wt per cent) raising them from 30 per cent to 45 per cent. Meanwhile, the recovery rates of copper and nickel remain constant.

Aug 21, 2024

By M Hassall

There is a plethora of activities that have been, and continue to be, performed to improve the health, safety and well-being of workers involved in resource industry activities. These activities include implementation of risk management systems, performing risk assessments, constructing bow-ties, implementing critical control management systems, undertaking personal, process and functional safety initiatives, implementing psychological and physical health as well as industrial hygiene programs. Despite the significant work that has occurred over the last several decades, unacceptable levels of fatalities, injuries and illnesses continue to persist as evidenced by Safe Work Australia statistics.

Apr 16, 2024

By J H. Kyle

Cyanide is a significant cost in gold processing, as well as an environmentally sensitive issue. It has been suggested that precipitation of cyanide from leach liquors as copper-iron-cyanide compounds such as Cu2Fe(CN)6 may account for part of the total cyanide consumption. This may be especially true for ores that are rich in both copper and iron minerals. Ammonia addition has been shown to decrease the cyanide consumption by copper. Cu2Fe(CN)6.xNH3 precipitates have also been postulated to form during conventional cyanide detoxification processes, using oxidants such as SO2/air, with ammonia arising as a breakdown product from the oxidation of free cyanide. The present work has examined the conditions under which such precipitates may form, particularly in gold plant process and detoxification liquors. Ammonia and pH were found to have a large effect on the extent of precipitation. The compounds that were formed were found to comprise mainly Cu2Fe(CN)6.7H2O, as well as a range of NH3-bearing variants. The stabilities of the various precipitates are important from an environmental perspective. The long-term stability of copper ferrocyanide precipitates in tailings dams may be a problem under alkaline conditions and when some free cyanide is present, elevating the measured total cyanide in solution significantly. Case studies including data from actual plants are also considered, and the importance of these effects is reaffirmed from these results.

Jan 1, 2000