Oxidative Leaching of Chalcopyrite in a Chloride-Sulphate Lixivant

Chalcopyrite samples from two different localities were leached in oxygenated mixed chloride-sulphate lixivants at elevated temperatures and atmospheric pressure. The oxidation of chalcopyrite was found to follow predominantly linear kinetics. The slope of the major region was dependent on stirring rate, oxygen flowrate and chloride concentration while only slightly dependent on the surface area of the sample leached. This region was found to predominate only at low temperatures. The oxidised chalcopyrite releases cuprous and ferric ions into solutions. Chloride ions complex these dissolved ions to effectively move the equilibrium of the leaching reaction to the right. When the level of chloride in solution was below 6 g/l, the unstable cuprous ions were found to reprecipitate with sulphur as covellite. When no chloride was present and the lixivant was a solution of sulphuric acid then ferric sulphates precipitated. The overall leaching reaction occurring in the leaching system is: CuFeS2 + 5H+ + 1.25 02 = Cu 2+ + Fe 3+ + 2S¦ + 2.5H20