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By Joël Kapusta

La pyrométallurgie du cuivre est essentiellement une chaîne de trois étapes successives d’oxydation préférentielle du fer et du soufre et des impuretés moins nobles que le cuivre qui sont contenues dans le concentré de cuivre issu de l’usine de concentration du minerai, aussi appelée concentrateur. La Figure 1 illustre la chaîne complète d’élaboration du cuivre depuis la mine jusqu’au cuivre pur. La voie hydrométallurgique traite le concentré par lixiviation, c.à.d. par dissolution en phase aqueuse à température typiquement inférieure à 100 ou 150⁰C, alors que la voie pyrométallurgique traite le concentré par fusion à température de l’ordre de 1200 à 1300⁰C.

May 2, 2024

By N. Bahrani

Photogrammetry surveys were used to document a footwall slab failure that occurred at a surface coal mine located on the eastern slope of the Rocky Mountains. Photographs taken before and after the failure provided the pre- and post-failure geometry of the slope and the failed slab. A 2D finite element model was constructed using slope profiles. The model contained joint elements that represented the bedding surface upon which the slab slid and the model was used to analyze the footwall slope. The in situ stresses, rock properties and the bedding surface shear strength and stiffness properties are discussed. The process of mining out a valley and exposing a highwall was modelled. As expected, elastic valley rebound occurred in the model, but shear stress and shear displacement reversals along the slip surface were also observed. The modelling results provided new insight into shear strength degradation that occurs when the pit floor approaches and then passes a specific point in the highwall.

Jan 1, 2009

By H. W. Parsons

Several low-temperature, dry chlorination processes for the treatment of sulphide minerals are reviewed, in a chronological order. These processes include the following: the Swinburne-Ashcroft, Baker-Burwell, Maim, Comstock-Wescott (Aldermac) and the Mitterburg Mining Process. Dry chlorination investigations at the Canadian Mines Branch (now CANMET) and the U.S. Bureau of Mines are discussed, as is a proposed process by the South Africa National Institute for Metallurgy. The techniques used in the process are discussed, as are the shortcomings, problems and failures of the methods.

Jan 1, 1978

By Brian L. Beninger

This paper discusses the application of the computer to coal preparation process predictions. In broad terms, the computer is used to perform two main functions. Firstly, the given float-sink analysis is interpolated and extrapolated to cover the entire actual range of raw coal specific gravity. Assumptions based on historical data must be made at times. Secondly, the partition curve, which, from historical data, defines the efficiency of a specific coal washing process, is applied to the washability data in order to determine the expected clean coal yield and quality. The vast amount of numerical work which is required to make a prediction of this type exhibits the need for computer methods in this area.

Jan 1, 1979

By K. G. Baxter, D. G. Dixon

The Sepon process plant utilises an autoclave to oxidize a flotation concentrate containing pyrite, residual copper minerals, and sulphur. The concentrate is produced from the residue of a preceding atmospheric copper leaching circuit. The function of the autoclave is to provide iron and acid for that atmospheric copper leaching circuit. The key issues in the operation of the autoclave are to maximise the production of acid and ferric ions and to avoid scaling issues related to sulphur balling in the autoclave. Scale control in the autoclave was examined using various dispersants and residue recycle without success. Operation of the autoclave at high temperature and high acidity addressed the scale issue through rapid oxidation of the sulphur and produced a ferric sulphate precipitate in the residue that could be re-leached to provide ferric iron. This paper presents the development steps followed, through batch and continuous piloting that resulted in an autoclave circuit design that addressed the above process requirements. Following definition of the process design basis, modelling of the autoclave operation was carried out to assist with engineering design. The model included thermodynamics and kinetics of oxidation of pyrite, elemental sulphur and covellite and also considered gas/liquid mixing, oxygen solubility as a function of temperature and solution composition, ferrous to ferric oxidation, gangue reactions with acid and precipitation/re-dissolution of basic ferric sulphate and alunite.

Jan 1, 2004

By M. Tanaka, T. Oishi, K. Koyama, S. Alam

"A novel hydrometallurgical process for copper recovery from waste printed circuit boards has been proposed, which consists of selective leaching of copper metal as Cu(I) by Cu(II) in ammoniacal alkaline solution, purification, and electrowinning. The distinct feature of this process is much lower power consumption during the electrowinning than that during the conventional one from acidic copper sulfate media, because the deposition of copper metal from Cu(I) at the cathode and the oxidation of Cu(I) to Cu(II) at the anode take place in the present method. In the laboratory-scale tests using waste printed circuit boards, high purity copper which contains 1.1ppm of impurities was obtained in a chloride system. INTRODUCTIONThe recovery of various metals from waste materials is an important issue in order to conserve the environment and metal resources. Copper is used for cables, electric appliances, etc., and is currently a very important material for industries and will continue to be in the future. Among the wastes that contain copper, one of the most complex recycling materials is electronic scrap like printed circuit boards (PCB), which generally contain 10-30% copper as well as plastics, fibreglass and other metals. There are two ways to recover copper, either pyrometallurgical or hydrometallurgical. Hydrometallurgical treatments generally have more flexibilities in the process scale and control. The separation processes tend to become complicated because of the poor selectivity during the leaching in the sulphuric and hydrochloric acid media. On the other hand, the use of ammonia as a complexing agent, gave a higher selectivity for copper leaching (Nigo, Majima, Hirato, Awakura, & Iwai, 1993; Majima, Nigo, Hirato, Awakura, & Iwai, 1993; Zhou, Shinme, & Anezaki, 1995; Koyama, Tanaka, & Lee, 2006) .In this study, recycling process containing leaching, copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) is introduced. Furthermore, copper recovery from a waste printed circuit boards and impurity behaviour was examined in ammonia-ammonium sulfate (sulfate system) and ammonia-ammonium chloride (chloride system) systems."

Jan 1, 2012

By Jean-Marc Lulin

"Depuis 1906, pres de 130 gisements ont ere decouverts dans la inture archeenne polymetallique (Cu, Zn, Au, Ag) du nord-ouest becois. Une etude regionale du developpement du potentiel inier est presentee puis detaillee pour quatre secteurs: RouynDranda, Val d'Or-Malartic, Bousquet-Cadillac et Matagami.L' analyse est conduite a l' aide des parametres suivants: temps, ethodes de decouverte, profondeur des gisements et poids metal. ~~ courbes cumulatives illustrant le nombre de gisements decouverts fonction du temps montrent une forme generale en ""S"" dont les i'iations de pentes correspondent aux variations dans les taux de ~ouverte. Initiation, realisation et stabilisation des cycles de decourte sont ainsi mis en evidence. Deux ""bourns miniers"", de 1922 a ~5 et de 1955 a 1965, rassemblent 72 % des mines identijiees squ' a present.La plupart des mines sont trouvees en subsurface: 90% ont leur fmet entre 0 et 100 metres de profondeur dont 70 % entre 0 et 10 etres. Dans le temps, il y ad' abord recolte par prospection puis par fphysique et enjin, developpement progressif du potentiel en proeur avec des methodes composites. Environ 80% du poids metal extrait de 4 camps miniers, couvrant 8% de Ia surface regionale quelques gros gisements dominent /a production.Ces donnees permettent de proposer une nouvelle approche pour lysed' une region miniere:La distribution de Ia profondeur des gisements en fonction du temps est indicatricede /amaturite d' uncampminieret peut servir a evaluer son potentiel residue/.L' analyse des courbes en ""S"" permet d' extrapoler les taux de succes relies aux differentes methodes et met en relief le role crucial de I' innovation dans I' exploration.ABSTRACTSince 1906, some 130 deposits have been discovered in the Archean polymetallic belt of northwestern Quebec. In this paper, the development of the mining potential is analyzed at the regional scale and for the following mining camps: Rouyn-Noranda, Val d'OrMalartic, Bousquet-Cadillac and Matagami.The analysis is based on the following parameters: time, discovery method, depth and weight of metal extracted. Curves showing the cumulative number of deposits discovered as a function of time are ""S"" shaped with slope variations corresponding to changing discovery rates. Initiation, realization and stabilization of discovery cycles are thus well represented. Two ""mining booms"", 1922 to 1945 and 1955 to 1965, account for 72% of the mines identified to date.Most exploitable orebodies have been found near the surface: 90 %have their top between 0 and 100 meters, including 70% between 0 and 10 meters. Early discoveries were made by prospecting, followed by geophysics while the progressive development of the depth potential is being realized by a combination of methods. Approximately 80 %of the metal extracted comes from four mining camps which cover 8% of the area, but most of the production can be allributed to only a few large deposits. Based on these data, a new approach to the analysis of a mining region is proposed:1) The distribution showing deposit depth versus time is indicative of the maturity of a mining camp and can serve to evaluate its remaining potential.2) The ""S"" curve analysis can be used to extrapolate the success rate of a specific exploration method and also stresses the crucial role of innovation in exploration."

Jan 1, 1990

By Jean-Marc Lulin

"Depuis 1906, près de 130 gisements ont été découverts dans la inture archéenne polymétallique (Cu, Zn, Au, Ag) du nord-ouest québécois. Une étude régionale du développement du potentiel inier est présentée puis détaillée pour quatre secteurs: Rouyn-Dranda, Val d'Or-Malartic, Bousquet-Cadillac et Matagami.L' analyse est conduite a l' aide des paramètres suivants: temps, méthodes de découverte, profondeur des gisements et poids métal. Les courbes cumulatives illustrant le nombre de gisements découverts fonction du temps montrent une forme générale en ""S"" dont les i'iations de pentes correspondent aux variations dans les taux de couverte. Initiation, réalisation et stabilisation des cycles de décourté sont ainsi mis en évidence. Deux ""bourns miniers"", de 1922 à 1945 et de 1955 à 1965, rassemblent 72 % des mines identifiées sqú à présent.La plupart des mines sont trouvées en subsurface: 90% ont leur mmet entre 0 et 100 mètres de profondeur dont 70 % entre 0 et 10 êtres. Dans le temps, il y a d' abord récolte par prospection puis par ophysique et enfin, développement progressif du potentiel en proeur avec des méthodes composites. Environ 80% du poids métal extrait de 4 camps miniers, couvrant 8% de Ia surface régionale quelques gros gisements dominent /a production.Ces données permettent de proposer une nouvelle approche pour analyse d' une région minière:La distribution de Ia profondeur des gisements en fonction du temps est indicatrice de la maturité d' un camp minier et peut servir a évaluer son potentiel résiduel.L’analyse des courbes en ""S"" permet d’extrapoler les taux de succès relies aux différentes méthodes et met en relief le rôle crucial de I' innovation dans I' exploration.ABSTRACTSince 1906, some 130 deposits have been discovered in the Archean polymetallic belt of northwestern Quebec. In this paper, the development of the mining potential is analyzed at the regional scale and for the following mining camps: Rouyn-Noranda, Val d'OrMalartic, Bousquet-Cadillac and Matagami.The analysis is based on the following parameters: time, discovery method, depth and weight of metal extracted. Curves showing the cumulative number of deposits discovered as a function of time are ""S"" shaped with slope variations corresponding to changing discovery rates. Initiation, realization and stabilization of discovery cycles are thus well represented. Two ""mining booms"", 1922 to 1945 and 1955 to 1965, account for 72% of the mines identified to date.Most exploitable orebodies have been found near the surface: 90 %have their top between 0 and 100 meters, including 70% between 0 and 10 meters. Early discoveries were made by prospecting, followed by geophysics while the progressive development of the depth potential is being realized by a combination of methods. Approximately 80 %of the metal extracted comes from four mining camps which cover 8% of the area, but most of the production can be allributed to only a few large deposits. Based on these data, a new approach to the analysis of a mining region is proposed:1) The distribution showing deposit depth versus time is indicative of the maturity of a mining camp and can serve to evaluate its remaining potential.2) The ""S"" curve analysis can be used to extrapolate the success rate of a specific exploration method and also stresses the crucial role of innovation in exploration."

Jan 1, 1989

By Ben Habermann

"The object of the work described in this paper was to increase the understanding of the relation that capillary pressure of a rock, hydro-dynamics, and accumulation of oil in stratigraphie traps have to one an-other. The hydrodynamic oil-water tilt equation is derived by considering the two vector gradients involved: (1) buoyancy of oil in water and (2) hydraulic gradient.Recent theories show the necessity for oil to have a continuons phase in the reservoir rock in order to mi-grate; this fact applies to hydro-static as well as to hydrodynamic conditions. Hydrostatically, the displacement pressure of the rock deter-mines the amount of oil that can be trapped behind a permeability barrier. If the buoyancy of oil in water exceeds the displacement pressure, oil will migrate up-dip; an oil trap will be formed where displacement pressure is greater.In stratigraphie traps the pressure drop caused by moving water is positive when its direction is down-dip, helping accumulation; and it is negative when its direction is up-dip, forcing the oil into the tighter section of the reservoir. Theoretically, pro-vided we have data such as: (1) the displacement pressure of an up-dip permeability pinchout, (2) density difference between the oil and water in place, and (3) the direction and magnitude of the hydrodynamic gradient (if any), the possible extent of a stratigraphie oil accumulation down-dip can be predicted.To test the above theory sample cores from three wells in the Denver Basin were analyzed and the oil column that could be held under hydro-static conditions was calculated. After the hydrodynamic influence was considered, the results were compared with actual field data.The significant fact shown by this investigation is that the calculated oil column in one reservoir very closely approximates the actual extent of the oil column in a well. Also in accordance with the theory, the capillary pressure caused by the buoyancy of the oil column exceeded the measured displacement pressure on core samples from another productive field. For very tight shaly sand and questionable oil shows, the interpretation of data is very critical, as shown by experiments on core samples from a third field."

Jan 1, 1960

By Pritii Tam Wai Yin, Tony Leong, Neetu Bansal, James Vaughan, Amiel Boullemant

Mercury is a toxic element that is associated with many industrial activities including the Bayer process. Mercury is known to enter the Bayer process with the bauxite feed material and has the potential to accumulate as the process solution is recycled. This paper explores the speciation of mercury in Bayer process streams. The process parameters considered are the oxidising-reducing potential, basicity and temperature. The results of a refinery circuit survey are presented and compared with the thermodynamic predictions. Electrochemical measurements on relevant synthetic systems are also included.

Jan 1, 2014

By Guy Demers

"This paper defines the responsibilities and functions of the Maintenance Department, and its organization, physical and human assets, highlighting the unique operating problems. Due to the self-sufficient aspect of the Asbestos Hill Deception Bay project, the Maintenance Department cover-s fields that are numerous and very dissimilar: production, mobile, processing, service, power generation, fire protection, heating, water and sewage disposal equipment. Added to this, buildings, plant and camps, wharves and communications equipment all demand versatility, adaptability and expertise from maintenance personnel. Good maintenance practices are a necessity in this environment and are more critical than at southern locations; that is, high-quality replacement material, complete and well-controlled preventive maintenance, major repairs on a component-replacement basis, updated inventory, efficient training and permanent contacts with suppliers, combined with an equipment improvement program, updated specifications on lubricants, hoses, seals, filters, etc., are mandatory. The seasonal aspect of the operations applies a great deal of pressure on the maintenance team, as the production months do not permit major repairs. Short- and medium range planning and accurate evaluation of equipment conditions highly influence production efficiency. Maintenance control, planning and scheduling do not follow the accepted standard routines, as personnel turnover normally does not permit an accumulation of knowledge of the equipment history and condition by the •individual tradesman."

Jan 1, 1976

By H. W. Wevers

Fatigue failure and accompanying brittle failure occurs frequently in heavy mining equipment. This paper discusses how fracture mechanics can be applied as a tool for crack control and crack management. Information is provided to determine if particular components are prone to brittle failure. By using existing fracture mechanics formulae, an estimation of the critical crack size can then be made. It is explained that for a successful application of fracture mechanics, both the actual engineering stress in the component and the mechanical properties of the applied material must be known. The importance of toughness at low temperatures is quantitatively illustrated by calculating critical crack sizes at room temperature and at below-zero temperatures. Understanding the possibilities of fracture mechanics will also produce a climate in which the purchaser of equipment can more precisely analyze the relative quality of components with respect to crack tolerance and failure prevention. In this manner, communication between the user and manufacturer of equipment may also become more precise and effective, leading to improved design.

Jan 1, 1977

By R. A. Campbell

Pig iron and silicospiegeleisen were produced experimentally from a very low-grade manganiferous iron ore from Steep Rock, Ontario, by a two-stage electric smelting process. The most favourruble operating conditions were determined for each stage. Cement clinker then was made by calcining the slag from the second stage of smelting, with additional limestone and alumina. (This slag would normally be a waste material). The cement clinker produced had the composition of commercial Portland cement, and met the physical test requirements of the Canadian Standards Association Specification A5-1951 for normal Portland cement as well as could be expected for a material produced on .such a small scale.

Jan 1, 1958

By Ernest Davis

WATER power, until developed, produces nothing, but when harnessed it continues to produce, it might be said, indefinitely. Hence the importance of developing all feasible water powers. British Columbia, like the western states of America, is subject to variable meteorological conditions which cause most streams to be erratic in their flow. The wet season, usually commencing in October and continuing to March or April, together with the melting of the snows during the early summer, produces a heavy run-off which diminishes considerably during the later s1.1,mmer months, with the result that storage is essential on practically every stream in order to regulate the flow to obtain a discharge which will meet the requirements of the load of the markets the power is to serve. Storage sites of sufficient capacity to equate the flows are not always present and it follows that, where such a deficiency exists, the difference must usually be met by burning fuel in steam plants. Fortunately, there are within the Province deposits of high-grade coal, suitable for the operation of such auxiliary steam plants. One of the strongest reasons for the development of water powers is the conservation of fuel. All use of coal or oil depletes resources that can never be renewed. Every water power developed means a saving in fuel and, even if at first it does not possess an over-powering financial advantage, it must become of ever increasing value as fuel resources become depleted. However, sight must not be lost of the inter-relation which should exist between the two methods of generating electrical energy, as each makes an admirable supplement to the? other with respect to suitability for carrying different types of load. In general, it can be said that the fixed charges of a water power development are usually high in relation to the operation costs, while those of fuel power plants are usually the reverse, so it is sometimes possible to combine the two methods of generation for the more efficient production of energy.

Jan 1, 1942

By Daniel E. Walsh, P. D. Rao

"A four-inch compound water cyclone (CWC) was tested to evaluate its gold recovery characteristics when processing -4.8 mm run-or-pit, placer material. Neutron activated placer gold particles (840 to 37 microns) were used as radiotracers (/98Au) in a closed circuit ewe test loop to determine concentrator recovery; a procedure believed unique to this study. The effect on gold recovery of gold size and shape, feed pulp density, feed pressure, vortex finder clearance (VFC), ewe cone type, top-size of the feed solids, presence or absence of heavy minerals in the feed, and the quantity of-37 micron slimes in the feed was investigated in over 300 tests.CWC concentration ratio and the top-size of the underflow solids were both affected by cone type, VFC, and feed pressure. Gold recovery was significantly affected by gold size, gold shape, and concentration ratio. These effects are complex, because significant size-concentration ratio and size-shape interactions exist. Radiotracer techniques showed gold particles had a residence time within the ewe of approximately one second. This study suggests ewe gold recovery is a concentration. This work suggests ewe gold recovery is a function of particle size and shape, and the flow rate through the cyclone. CWC cone ""bed density"" is considered important only as a thin, protective layer, which shields coarser gold particles from the entraining currents and facilitates their movement through the CWC.IntroductionCompound water cyclones (CWC), or automedium cyclones, are enhanced gravity concentrators for the beneficiation for slurries of sand, coal, and ground ore (Fig. 1). They are called compound water cyclones because of the compound slopes of their basal cones (Fig. 2) and are operated to suppress classification phenomena in favour of gravity concentration effects. The compound water cyclone is not a new wet concentrator. It was developed in the late 1950s by Dr. Jan Visman through research sponsored by Canada's Department of Energy, Mines, and Resources. Since that time, it has become a common unit in coal washeries for cleaning fine coal. CWCs and other versions of concentrating cyclones have also shown promise for heavy minerals and precious metals recovery."

Jan 1, 1988

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By V. Aprahamian, T. Cheng, M. Tangen, R. Beauprie

The Royal Canadian Mint has implemented significant process additions since 2005. Installation of a whole new highly automated silver refining circuit has allowed recovery of physical silver from gold and silver dorés . To complement this change, a small Top Blown Rotary Converter has been in operation. On the gold refining side, a new hydrometallurgical process to recover precious metals from Miller Chlorination slag has been developed. Finally, new systems have been put in place to improve treatment of waste water, wet and dry fume and dust.

Jan 1, 2011

By Claude A. Jr. Seger

Introduction This paper presents in detailed form the results of settling tests that were published in a few preliminary notes in the April 1949 issue of the Bulletin (p. 166). Carborel is the trade name for sodium carboxymethyl-cellulose and aluminium carboxymethyl-cellulose produced by the reaction of monochloroacetic acid on the alkali cellulose to form an ether. The water-soluble sodium carboxymethyl-cellulose has been known in Europe for several years as sodium cellulose glycolate and has been marketed under several trade names. These cellulose ethers, however, are relatively new in North America, where the name carboxymethyl-cellulose is often abbreviated to C.M.C., or they are referred to as cellulose gum. The particular grade of Carboxel used in the settling tests in the mill of Chesterville Mines, Limited, is the high-viscosity sodium carboxymethyl- cellulose known as Carboxel H.V. It is a white, fluffy powder and is hygroscopic, although not deliquescent. Carboxel solutions in water are colourless, odourless, and resistant to beat and light. They are stable to alkalies, but are precipitated by acids when the pH is reduced below 4.0, and also by solutions of soluble lead, iron, copper, aluminium, and chromium salts. Solutions of Carboxel exhibit the properties of hydrophilic colloids.

Jan 1, 1949

By N. V. Mel'nikov

This paper discusses the reserves of oil, natural gas and coal in the USSR, with particular attention to the future role to be played by coal in supplying the energy fuel resources of the country.

Jan 1, 1972

By Peter M. Power

A microscopic study was made of a series of simultaneous slag and metal samples taken from a low carbon basic open hearth heat. An attempt was made to identify the various micro-constituents found. As the various impurities in the bath are oxidized, the metal structure changes from that of high-phosphorus white cast iron to that of low.-carbon steel. A detailed study of phosphorus distribution is included. The acid run-off slag has an .acicular orthosilicate structure which changes on 'shape-up' to a very basic tri-calcium silicate and calciuim ferrite structure. Many unidentified minor constituents are present in the slags. Though metallography will never replace chemic.al analysis of the bath, the microsopic study of polished slags has some promise of being useful in slag control work.

Jan 1, 1956