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By J. W. Spyker, D. H. Filson, W. H. W. Husband

"Large deposits of sodium sulphate exist in southern Saskatchewan in the brines or muddy crystal beds of alkali Jakes. Currently, more than 300,000 tons per year of sodium sulphate are produced from these lakes and sold as salt cake to the paper industry. Most of the production is obtained from the brines of a limited number of Jakes.The Saskatchewan Research Council was requested to develop a process for recovering sodium sulphate from the muddy crystal beds so that this type of deposit could be exploited in the future. A flowsheet was developed with the aid of phase diagram data and the process was studied on a pilot-plant scale using raw material from three different lakes. Satisfactory yields and product purities were obtained in all cases, and an economic analysis indicated that a 100,000-ton-per-year sodium sulphate plant could produce salt cake at a cost of $12.26 per ton for a rate of return upon investment of 16 per cent at current market prices."

Jan 1, 1966

By M. J. Kovalik

The effect of oxidation by air at temperatures ranging from 200° to 390° C on the change of chemical and physical properties of Pittsburgh-bed coal was studied as a function of processing time and temperature. The goal was to prepare a nonagglomerating fuel from a strongly coking coal for use in continuous carbonizing processes and in fixed-bed gasifiers. The oxidized coal was carbonized in a bench-scale apparatus, and the coke strength was evaluated in a Roga tumbler. Strength of the coke was progressively reduced with time of oxidation until the coking power of the coal was apparently destroyed. Time requirements to obtain an essentially nonagglomerating product were inversely related to processing temperature. Gaseous products released from the coal during oxidation reduced the yield of the desired nonagglomerating product, which decreased with time of oxidation at constant temperature and with increase in processing temperature at equal time. Oxidation at a temperature slightly above the lower limit of the plastic temperature range of Pittsburgh-bed coal was most effective because of the short processing time required and moderate processing losses.

Jan 1, 1963

By F. Peer

In most coal preparation processes, water is a necessary medium, but the presence of water in coal after it has been cleaned has a negative impact on transportation costs, handling and specific energy values. The utilization of super absorbent polymers (SAP) in the nappy application is well known. The concept of utilizing these polymers was investigated for the purposes of dewatering coal and other fines, generated by preparation processes such as flotation. SAPs are granular highly cross-linked synthetic copolymers with excellent water-absorbing properties. The dewatering process is characterized by three main stages: (a) contact of super absorbent polymer with high-moisture fine coal; (b) separation of dewatered fine coal from super absorbent polymer; and (c) regeneration of used super absorbent polymer, by exploiting its response to changes in conditions such as pH or temperature. Preliminary tests showed the separation step to be very difficult. The novel idea of encasing a given amount of polymer in a water permeable cloth solved this problem (of separating the swollen polymer from the dewatered coal). Preliminary tests investigating the effectiveness of the sachets of polymer showed a drastic decrease in the moisture contents of slurries. Furthermore, it was shown that it was possible to regenerate the polymer (still within the sachets) through thermal drying. A full-scale experimental programme was then followed to accurately determine the feasibility of using sachets of SAP. The experimental variables were initial slurry moisture content and polymer dosage. It was observed that the sachets seemed to work fastest and most effectively at high moistures and also at higher dosages of SAP. Regeneration of the polymer was also investigated, using two methods: thermal regeneration and pH-induced regeneration. The experimental variables, for investigating the regeneration process, were method of regeneration and grade of water used. Thermal regeneration at 70°C seemed to work successfully. Although the cost of using thermal energy is still a problem, the safety aspect (fire hazards) has been addressed since the polymer does not ignite when heated, unlike fine coal particles that may do so. The alternative method of regeneration, which exploits the pH-sensitivity of the polymer, was less successful, and further work needs to be conducted.

Jan 1, 2003

By P. R. Pereira

This paper presents a comparison between the simulations of a semi-empirical model and a theoretical model for the prediction of radial stress in rock. The results of the simulations were compared to the results of a field test. The comparison of the radial stress predictions shows that in the semi-empirical model use of the plane wave approximation as the basis for the prediction of the radial stress provides a much better result than the theoretical model. The theoretical model includes the correct elastic wave geometry and theory but fails twice, firstly by considering the charge as a point (unit) energy source therefore; and secondly by using a Delta function with a very sharp rise and decay time to simulate, with no distinction between non-linear and linear zones, the attenuation of the energy per unit volume at the shock wave front as the wave moves away from the borehole. The results of the semi-empirical model were within the same order of magnitude as the results from the field test whereas only one result from the theoretical model came close to the result of the field test. However, even this closer result for the theoretical should be taken with caution as there was no measurement in the field test made at this distance from the borehole. Finally, because of its potential portability, convenience, and cost-effectiveness the theoretical model can be a most valuable tool for mining and civil construction operators in the early design of blasting rounds and of the mining operation itself.

Jan 1, 1993

By K. K. Kelley

"INTRODUCTION The Bureau of Mines nitrogen peroxide process (2) 3/ for extracting manganese from low-grade ores is essentially a two-stage process involving the reversible reactionMnO2 + 2NO2 + 6H2O = Mn (NO3)2 . 6H2O (1).At lower temperatures this reaction proceeds to the rigth and affords a means of dissolving manganece and separating it from unreacted ore. At higher temperatures the reaction proceeds to the left and manganese dioxide is recovered and nitrogen peroxide regenerated for recycling. Evidently, therefore, the energy required for decomposition of manganous nitrate is a matter of practical importance. Similar information for certain other nitrates also is desirable beceuse the nitration step of the process produces appreciable amounts of nitrates of other metals, such as iron, aluminum, magnesium, calcium, and barium, some of which are not broken down in the evaporation and decomposition steps. Thus, a portion of the nitrogen peroxide is not directly available for recycling. Whether or not it is feasible to recover nitrogen peroxide locked in the more-stable nitrates depends partly on the energy required and the conditions necessary for their decomposition.To supply information bearing directly on these subjects, several researches were undertaken at the Pacific Experiment Station: (a) Heats of formation (24, 25, 26) of nitrates of manganese, magnesium, calcium, barium, and aluminum were measured at 298.2° K:; (b) low-temperature specific heats (23), in the range 51° to 298.2° K,, and entropies of nitrates of magnesium, calcium, barium, and aluminumm were determined; and (c) heat contents (21) above 298.2° K. of the nitrates of manganese, magnesium, calcium., and barium were measured. The results of these studies, when correlated by thermodymamic methods, permit evaluation, at any temperature of interest, of the energies required to decomposethe nitrates and furnish information concerning the equilibrium pressure temperature relationships."

Sep 1, 1944

By R. L. Bruening, L. Navarro, Izatt. S. R., R. Adiga, R. M. Izatt, N. E. Izatt, A. Sharma, N. R. Patel, B. V. Rao

Bismuth is a notorious contaminant in the electrolytic refining of Cu that can cause cathodes to fail to meet ASTM International standards and not be suitable for use in Cu rod and other downstream products. Bismuth can significantly decrease electrical conductivity, decrease the mechanical strength of the annealed wire, retard recrystallization, and sometimes induce hot shortness during the hot rolling process in the production of rod. As a result, the control of Bi in the refinery tankhouse must be carefully managed. This paper describes how SuperLig® Molecular Recognition Technology (MRT) is being used for Bi removal at the Birla Copper Dahej Copper refinery. The operation of the SuperLig® MRT Bi removal plant is described and data on Bi removal efficiency are presented. INTRODUCTION Hindalco’s Cu division, Birla Copper, operates one of the largest Cu refineries in the world at Dahej, Gujarat; India. The main feed for this refinery is produced at the company’s smelter. Due to its massive production capacity, this operation mainly relies on imported Cu concentrates resulting in a variety of metals being carried out as impurities in the Cu anodes because pyrometallurgical technologies alone are not enough to remove them to the extent required. Metal impurities found in Cu ores include Fe, Zn, As, Pb, Bi, and Sb. During electrorefining, less noble metals dissolve in the electrolyte gradually increasing their concentrations creating the need for electrolyte control mechanisms that remove these impurities with varying degrees of success (Wang, 2004; Navarro et al., 2013.) Bismuth is one of the most significant impurities in a Cu refinery because it has the lowest ASTM product specification. This situation is critical because the Bi potential is very close to that of Cu making it possible to plate in the Cu cathode directly. Also, Bi can precipitate at high concentrations causing floating slimes and reduction of current efficiency (Ballinas, San Miguel, Munoz, & Gyves, 2003). Production of high purity cathodes from feed stock containing a diverse range of metal impurities becomes a major challenge in the refining of Cu (Izatt et al., 2015). In this work, the purification strategy followed by Birla Copper for the removal of Bi using a separation process based on MRT is presented, outlining the loading and stripping performance of SuperLig®83 and the benefits of using MRT over other lower selectivity methods where hazardous materials are produced instead of high purity products.

Jan 1, 2019

By Boleslaw A. Klosinski

Drilling of a pier hole is accompanied with stress releasing in the surrounding soil and often with loosening of soil at the pier base. In effect the drilled piers are more deformable than driven piles of comparable dimension. The bearing performance of a pier may be considerably improved by properly executed base grouting. Various techniques of base grouting are used; many of them were described by Bruce (1986). The grouting devices are often placed within the pier. Alternatively the soil at or under the base is treated by cement or chemical grout. Preloading of the base subsoil by use of a special grouting cell is considered as the most effective way. Treatment of the ground below pier base with cement or chemical grout may be also useful. It may be performed immediately after the pier construction or during service, as a measure for increasing the pier capacity.

Jan 1, 1995

By E. G. Noble

The effects of hydrogen chloride (HCI) concentration and temperature on the solubility and hydration state of the alkali chlorides LiCI, NaCI, and KCI and the alkaline-earth chlorides, MgCI2, and CaCl2 were investigated by the Bureau of Mines. Saturated aqueous solutions of the chlorides were sparged with HCI gas at temperatures of 20°, 40°, and 60° C. Increased HCI concentration caused decreased salt solubility be-cause of the common ion effect. Aqueous solubilities for the chlorides of Ca, Li, Mg, K, and Na ranged from 42.6, 45.2, 35.2, 25.5, and 26.1 pct, respectively, at 20° C to 56.9, 49.4, 37.6, 31.0, and 27.0 pct, re-spectively, at 60° C. In solutions sparged to HCI saturation, solubili-ties for these chlorides ranged from 22.4, 26.5, 3.0, 1.3, and 0.05 pct, respectively, at 20° C to 53.2, 48.8, 28.3, 2.6, and 0.8 pct, respec-tively, at 60° C. The solubilities of LiCI and CaCl2 in HCI solution were high because HCI solubility is low in these solutions. The chlo-ride salts of Ca, Li, and Mg formed hydrates, which depended on tempera-ture and HCI concentration. Monohydrates for LiCI, tetrahydrates and hexahydrates for MgCI2, and dihydrates, tetrahydrates, and hexahydrates for CaCl2 were obtained.

Jan 1, 1985

By Dr. Peter J. Conroy

The current study is part of the U.S. Department of Energy's (DOE) on-going subsidence research program. The long-term objective of the DOE program is to develop analytical methods of subsidence prediction applicable over a broad range of geologic and mining conditions encountered in the United States. The DOE currently has several contracts in progress to develop a sound data base that can be used in the development of predictive models. Dames & Moore is currently under contract to the DOE to collect and analyze detailed subsidence and hydrologic data from a coal mine employing longwall mining methods in the Eastern Coal Province. Work under Contract No. DE-AC22-80PC 30335 began in October of 1980 and will continue through September of 1984. This paper summarizes the work that has been completed through September of 1981 and presents the results that have been achieved during this period. Technical difficulties encountered during both the installation and monitoring phases are discussed, and recommendations for future work are presented.

Jan 1, 1982

By C Moorhead

The classification of Mineral Resource estimates for reporting in accordance with the JORC Code is a statement of the Competent PersonÆs confidence in the estimate and an attempt to convey that confidence to the various users of the resource estimate. In general the classification process is either largely subjective, relying on the Competent PersonÆs experience, or relies on statistical measures derived from the estimation process. These statistical measures may not necessarily relate to the overall confidence in the resource which must also take account of the confidence in the geological inputs to the estimation. Several authors, including Jackson et al (2003) and Dominy, Noppe and Annels (2004), have addressed methods of including consideration of geological data and its reliability into the classification process. Henry and Parker (2005) have discussed a quantitative measure for classification of Measured and Indicated Resources related to mine production parcels. These methods rely on the availability of sufficient information for the application of geostatistics, data evaluation techniques or repeated interpretation of data to provide an indication of confidence. They are suitable for very advanced projects. In 2005, using a modification of the financial audit æcontrol and quality criteriaÆ principles, then widely accepted within Newcrest Mining Limited (Newcrest), the principal author developed a scheme which categorised the classified resources into æcontrolÆ and æqualityÆ (or risk) categories. Control covers all aspects of the data collection, the geological interpretation, the data analysis and the modelling of tonnage and grade; it is also influenced by the documentation of the estimate. The quality criteria are a subjective measure of risk associated with the estimation of the resource and refer to the risk that the tonnage and grade are not realised and the consequences if decisions are made on the basis of these estimates. By evaluating the generally accepted level of risk attributed to these quality ratings by Competent Persons within Newcrest, a graphical representation of the confidence in the resource ounces was prepared for communication of the expected confidence in the resource statement.

Jan 1, 2009

By J. S. Hansen

In support of its objective to conserve mineral resources by minimizing premature failure of materials, the Bureau of Mines conducted a cooperative study with the U.S. Department of Energy on the erosion and abrasion resistance of hard materials for valves in coal conversion systems. This report describes a newly developed erosion-testing apparatus and presents data on the erosion resistance of over 200 materials. Erosion resistance of most metals was comparatively low. In contrast, ceramics and cermets such as B4C, WC, SiC, Si3N4, and TiB2, when fabricated to minimize porosity, displayed greater than five times the erosion resistance of metals. Coatings such as boron diffused into Mo and WC, chemical-vapor-deposited TiCN, and electrodeposited TiB2 were highly erosion resistant if applied in thicknesses ranging from 60 to 75 µm. Erosion resistance of cemented carbides was inversely related to metal binder content.

Jan 1, 1979

Pilot plants for pressure hydrometallurgy represent special design and project execution challenges unique to the industry and to the pilot- and demonstration-scale. Pilot plant projects have different objectives and shorter timescales than commercial plant projects. Design considerations and strategies, and project execution methods that meet the special needs of pilot plant projects, are discussed. Specific guidance is given for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical process equipment, and for the selection of materials of construction for pilot-scale equipment. The balance between the need for process similarity with future commercial operations and the realities of pilot-scale equipment is also discussed.

Jan 1, 2004

By H. P. LeVan

The aced for reliable reserves of the essential element, manganese, has been a continuing concern of the Federal Government for more than three decades. Because of the increasing vulnerability of outside sources of supply efforts have been intensified to find a means for beneficiating United States domestic deposits. The deposits of most interest would of necessity be near, or have access to, suitable transportation to processing plants. The Georgia manganiferous iron deposits represent some 10 million tons4 of ore readily available to southern iron and steel industries, if a manganese recovery process capable of functioning in the presence of large quantities of iron can be developed. In addition, a successful method for beneficiating the Georgia ore could produce a significant quantity of high-grade iron concentrate. The Differential sulfatization process developed 47 the Bureau of Mines5 seemed to be well suited for this application, particularly because it results in low concentrations of iron in the leach liquors with relatively complete extractions of manganese. In this process, manganese in the presence of iron is preferentially reacted with sulfur dioxide at elevated temperatures and subsequently extracted with water.

Jan 1, 1962

By John C. Stankus

Jennmar Corporation. in an effort to improve mine roof control, has conducted extensive study and research comparing tensioned point anchor resin systems versus the use of non-tensioned fully grouted rehar. Preliminary indications are showing that in thinly laminated, weak strata, tensioned point anchor resin systems are providing more effective roof control than the non-tensioned fully grouted rehar. In this paper two case studies are presented in which tensioned point anchor resin systems were utilized to stabilize and control the mine roof in two different mines. Both mines are alike in many ways, but yet very different in other aspects. However, the mines do share one main common factor. and that being the non-effectiveness of the non-tensioned fully grouted rebar in controlling the thinly lamininated strata in each respective mine.

Jan 1, 1990

By Scott, Turner

MY whole life has been spent in the mining business, PO I naturally tend to address my remarks particularly to the newly-graduated mining and metallurgical engineers among you. To a certain extent, all forms of engineering principles are involved in the training of the mining engineer, and most sorts of engineering are certainly utilized by him, so every one of this graduatins class is concerned with the field I propose to discuss.

Jan 1, 1932

By Frank Haehnig, Kjell-Åke Averstad, Johannes Glückert

"AbstractThe Söderströmstunneln is part of the Citybanan project that is currently under construction in the centre of Stockholm. Main part of the lot Söderströmstunneln is a 300m long immersed tunnel connecting the inner-city islands Södermalm and Riddarholmen. It consists of three tunnel elements that have been immersed in summer 2013. Since the solid bedrock is descending in that area to more then 40m depth, the tunnel elements have been placed and are permanently supported on four pile groups that have been constructed in advance. The common Swedish system of steel core piles has been used to built the pile groups. Drilling and installation of the steel cores piles in free water depth of up to 20m had to be done from a pontoon. The steel core piles are connected with underwater concrete pile caps.IntroductionCitybanan is a new 6km long double track railway tunnel running beneath central Stockholm including two new underground stations Odenplan and Stockholm City. When completed in 2017 commuter trains will have their own tracks through Stockholm, whereas the remaining railway traffic will continue to use the exisiting two tracks (see Fig. 1). This will double the capacity of the railway traffic through Stockholm. The Swedish transport administration Trafikverket is the client for this project. The design and built contract is carried out by the German contractor Züblin Spezialtiefbau GmbH together with their Swedish subsidiary Züblin Scandinavia AS.As the new Citybanan tunnel is in large parts situated below the bedrock level, it can be executed as rocktunnel in the common drill and blast method. Between the two inner-city islands Södermalm and Riddarholmen the tunnel is crossing the Söderström, an arm of the lake Mälaren. Here the bedrock is descending to a deep valley with more then 40m depth. To connect the rock tunnels between these islands a 300m long immersed concrete tunnel supported on pile foundations is currently under construction."

Jan 1, 2014

By John A. Herbst, Xiangjun Qiu

"Prediction of wear on a microscale level in mineral processing equipment turns out to be a challenging undertaking. This is particularly true for cases in which the objective is to use such predictions for wear parts design. The key to obtaining such predictions has turned out to be the use of physics based models along with phenomenological constitutive equations. In this paper, two components of the HFS tool set, one for particles (DEM) and one for slurry (MPF), are used for modeling. These tools are applied to the simulation of wear of SAG/AG shell lifters/plates and wear in slurry pumps. In each case wear predictions are validated with plant measurements.INTRODUCTIONHigh Fidelity Simulation (HFS) has emerged as an important tool set for mineral processing plant equipment design and optimization (Herbst and Potapov, 2003; Herbst and Nordell, 2002; Herbst and Lichter, 2006). This tool set consists of Discrete Element Modeling (DEM) of particle motion, Multi-Phase Flow (MPF) for liquid motion, discrete grain breakage (DGB) for particle fragmentation and discrete grain liberation (DGL) for mineral liberation (Campbell, Potapov and Tsuji, 1997; Ferzinger and Peric, 1997; Potapov and Campbell, 1996; Herbst and Potapov, 2005).Three sample snapshots of basic HFS illustrating the use of each of the various types of mineral processing equipment are shown below.Figure 1 shows a snapshot of a DEM simulation of ball charge motion in a commercial scale Vertimill. DEM simulation involves simultaneous solution of Newton’s Laws of Motion for 400,000 balls."

Jan 1, 2007

By Concentrator Staff

"IntroductionA brief literature search will reveal that the information available concerning rod mills and ball mills is quite extensive. This type of equipment is used to treat every element from antimony to zinc. The size and capacity of individual mills, the number of units employed, and the configuration of the equipment within a concentrator add another dimension to the possible scope of this discussion. It would be impossible to treat this volume of material with any degree of thoroughness.It is the intention in this paper to describe the simplest and generally the most typical circuit wherein a single rod mill and ball mill operate in parallel. Some of the subject matter will not be entirely applicable to every installation. However the principles should be generally relevant to most applications.Typical Circuit DescriptionFigure 1 illustrates the arrangement of the equipment associated with a rod-ball mill circuit.Ore is extracted from a fine ore storage bin (1) the capacity of which is large enough to allow .continuous mill operation independently of the mine and crushing plant production schedules. A number of feeders (2) may be employed to control the flow of ore to one or more feeder conveyor belts (3). In larger tonnage operations several such conveyors are employed at least one of which will be equipped with a variable speed control to allow adjusting of the amount of feed reporting to the rod mill. A rod mill feed conveyor (4) accepts all of the ore from these feeder belts for ultimate transfer to the rod mill. This conveyor is normally equipped with a weightometer (5) to monitor the flow rate of ore to the rod mill and ultimately to allow control of this flow. Typically these conveyor belts would be equipped with feed deficiency switches which would give a remote alarm of the fact that no ore is present on the conveyor. The conveyor belts are protected by underspeed monitors which will provide a remote alarm and automatic shutdown of the conveyor in the C'.'~nt that belt slippage occurs. Finally the belts are protected by monitors which will alarm and shut down a belt if it is not running straight in the idlers."

Jan 1, 1989

By Raymond W. Hiteshue, Sam Friedman, Robert Madden

Experiments were made in a semicontinuous unit to provide engineering data for designing experimental continuous systems . These systems would be used to study the hydrogasification of hvab coal and char (from lowtemperature carbonization ) to high - Btu gas . In experiments at 800 ° C and with a coal residence time of several seconds , yields of hydrocarbon gases increased from about 2,000 scf / ton of maf coal at 250 psig to 7,000 scf at 1,000 psig . With 15 minutes residence time , yields increased from 8,000 scf/ton of maf coal at 250 psig to 17,500 cubic feet at 1,000 psig . In all cases , small quantities of heavy oils were produced along with the gaseous hydrocarbons . Production of oils could be minimized with a corresponding increase in gaseous hydrocarbons by increasing the retention time of the volatiles within the hot zone . Yields of gaseous hydrocarbons from char were slightly greater than from coal under similar conditions . Although the hydrogasification reaction is very pressure dependent , substantial quantities of coal (40 to 60 percent ) could be reacted to gaseous hydrocarbons at pressures as low as 50 psig provided reaction temperatures were increased to 1,200 ° C. It was also demonstrated that a hvab coal could be hydrogasified continuously without incurring agglomeration . This was achieved by dispersing coal in a relatively large reactor with concurrent flow of hydrogen . At 1,000 psig and 800 ° C , it was possible to react about 35 percent of the coal and to produce a gas containing up to 52 percent methane .

Jan 1, 1964

By Brendan Donnelly, Lasitha Piyathilaka, Jung‑Hoon Sul, Sanghyun Jeong, Benjamin Probyn

Premature failure of armoured face conveyor (AFC) chains due to corrosion is a significant proportion of the unplanned downtime experienced on longwall equipment. The AFC chains are constantly in contact with water and wet coal. The premature failure issue of AFC chains has become more prominent since the introduction of longwall top-coal caving with its additional AFC. Reverse osmosis (RO) is a popular water treatment method for reducing salinity and dissolved solids, but its impact on the corrosion of the AFC chains is unclear. This study has been commissioned to investigate the direct effects of RO water on the corrosion of AFC chains. An immersion test was carried out using AFC chain steel submerged in two water samples: untreated dam water and treated water from an RO treatment plant. Elemental analysis was conducted for both water samples, and four corrosion indices were measured for both water samples. The RO water more vigorously dissolves calcium carbonate scales leading to increased corrosion of the AFC chains although the dam water has much higher levels of calcium, chloride, sulphate, sodium, and magnesium. Bicarbonate ions are the main alkaline factor of water that provides the buffering capacity to acids. Decreased alkalinity without balancing other ions in water causes high corrosivity and decreased scaling tendencies.

Oct 16, 2023