Search Documents

By W. P. Yang, L. B. Berger, G. W. Jones

"Any burning carbonaceous material, unless supplied with enough oxygen for complete combustion, will liberate carbon monoxide. Since tobacco in its many different forms consists largely of carbonaceous material, and duo to the conditions under which it is smoked (burned), carbon monoxide should be liberated. That this is true has been shown by Armstrong.***** who found that undiluted smoke from cigars contained in some tests more than 3.00 per cent carbon monoxide, the amount present depending upon the size and closeness of packing of the tobacco during manufacture and on the rate of burning.****** Cigarets gave much less CO, varying from 0.06 to 1.40 per cent. The rate of consumption and carbon content of the tobacco are not g.ven, so that a correlation of the values reported to conditions in closed spaces where people might be assembled are difficult, if not impossible.The Bureau of Mines is interested in the general question of carbon-monoxide hazards from tobacco smoke, mainly with regard to mine ventilation. In non-gaseous mines, especially metal mines, the question arises, whether, if groups of miners are permitted to smoke while working at unventilated faces or entries, would the accumulation of tobacco smoke in these places create an' additional hazards the to carbon-monoxide poisoning. The results should, in addition be of general interest in connection with ventilation of building and inclosed places where people may be assembled and smoking is permitted. The investigation described in this report was made with the above idea in view."

Oct 1, 1923

By J Nell, J Petersen, X C. Goso

The feasibility of increasing the deportment of titanium species and the stability of the pseudobrookite solid solution (M3O5) in a titaniferous slag was investigated, to facilitate the valourisation of titaniferous slags. Thermochemical simulations using FactSage™ software, ver 8.3 (by Thermofact/CRTC and GTT-Technologies), and equilibration-quench experiments were conducted using an appropriate synthetic titaniferous slag composition in an oxygen partial pressure (pO2) ranging from air to 10-16 atm under non-isothermal conditions. The temperature-pressure phase stability diagram for the synthetic slag containing 37.19 per cent TiO2, 19.69 per cent SiO2, 13.12 per cent Al2O3, 16.00 per cent CaO and 14.00 per cent MgO showed that the spinel solid solution (M3O4) was the primary phase until a pO2 of 10-10.5 atm, thereafter M3O5 was the primary phase until a pO2 10-13.2 atm. M3O4 again was the primary phase between a pO2 10-13.2 and 10-16 atm. The changeover of the primary phase coincided with an increase in the liquidus surface. When cooling the slag in a pO2 of 10-16 atm, M3O5 crystallised as a ternary phase that showed a rapid increase in mass while that of the primary M3O4 phase decreased and that of the secondary perovskite (CaTiO3) phase increased at a slower rate. At 1300°C under sub-liquidus conditions, the contents of M3O5, M3O4 and CaTiO3 were about 20 per cent, 15 per cent, and 11 per cent, respectively. Experimental results showed that the Ti3+/Ti4+ mass ratio in the M3O5 phase, ie a measure of the reduction of titanium species, is not considerably sensitive to equilibration temperature in the reviewed range. Slow cooling and minimum/no oxidation during cooling of titaniferous slag would increase the deportment of titanium species to, and the growth and stability of the M3O5 phase.

Jun 19, 2024

By L. S. Hansen

Organized efforts toward the prevention of injuries and occupational diseases have been of comparatively recent origin in the mining industry, dating generally from the beginning of this century. Mining-and particularly underground mining- is more hazardous in many respects than most other major industries, and continual and increasing attention has been given to its health and safety aspects. The importance of the physical well-being of those engaged in mining was recognized by Agricola, who, after describing the hazards encountered in 16th century mining operations, stated that "Some of these evils, as well as certain other things, are the reason why pits are occasionally abandoned." In the past 50 yr particularly, mine managements and labor organizations, separately or collectively, have mounted productive efforts toward the prevention of accidents and industry-associated diseases and illnesses. A statistical study of this period indicates that increasing awareness coupled with the endeavors of all concerned agencies has resulted in decreasing frequency of occurrences of injuries and illnesses. In recent years particularly the mining industry has used the services of safety engineers, industrial hygienists, inspectors, ventilation engineers and other specializing in locating and correcting deficiencies affecting the welfare of employees. Concurrently, the labor movement has incorporated into its organization individuals working in the fields of health and safety, many devoting full time to these responsibilities. Others serve in behalf of their fellow workmen as on-the-job safety representatives. Most authorities agree that accidents are caused by (1) unsafe acts, (2) unsafe conditions and, exceptionally, (3) Acts of God. The "unsafe act" often is cited as the prime cause. but many accidents, and attendant injuries, are the result of a blend of "unsafe acts" and "unsafe conditions," with each chargeable in varying proportions. It therefore is necessary to consider both the physical elements of the mine plant and the training, mental attributes and actions of all personnel involved. Analysis of an accident, if based on hasty reconnaissance and unduly hurried questioning, seldom will disclose more than surface causes and consequently will result in inadequate measures to prevent repetition. Mining involves unavoidable and calculated risks, as in all facets of life. It is most important then that men employed in mining be schooled in the hazards and develop fully the ability to evaluate and minimize risks. The environment, of underground mining often is harsh and strange compared to the more natural surface conditions man has learned to cope with as a part of established life patterns. The miner. therefore, must adapt to unusual situations and conditions and must develop a mental attitude permitting acceptance of change. 3.1-INDUSTRY-AFFILIATED SAFETY AGENCIES L. S. HANSEN There are many organizations primarily interested in health and safety. In addition to industry and labor groups, there are many private and governmental

Jan 1, 1973

By R. E. Krauss

The McLaughlin Mine is a world class epithermal gold deposit located in the coastal thrust fault of Northern California, U.S.A. Homestake adopted a proactive strategy in the permitting of the Mine. Extensive environmental base line studies were undertaken. Engineering and process alternatives were evaluated for environmental impact along with other factors. A unique pressure oxidation process was selected. Screening studies were conducted as a basis for the selection of waste rock and tailings disposal sites. Project engineering and permitting were fast tracked. Construction required eighteen months and the first gold bar was poured in Parch of 1985, six years after the initial discovery. Project facilities are designed and operated so as to minimize environmental impacts. A comprehensive monitering program demonstrates permit compliance. Reclamation of the site is ongoing throughout the Mine?s twenty year life. Non-mined lands are managed to maximize wildlife habitat value.

Jan 1, 1990

By Rich A. Lamb, Paul J. Axtell, Michael K. Muchard

"Since 2010, the Minnesota Department of Transportation (MnDOT) has performed eight full-scale compressive load tests on large-diameter pipe piles at four different project locations across the state. All of the piles were 42-in diameter, open-ended pipes driven to practical refusal on sedimentary bedrock with D125-32 diesel hammers from three separate manufacturers. The rapid load test method in general accordance with ASTM D7383-10 (Statnamic method) was used along with high-strain dynamic testing and subsequent signal matching. Results of these tests indicate that the axial nominal resistance of these piles in compression is not controlled by geotechnical considerations when driven with an appropriately sized hammer and installation criterion. Rather, the predominantly elastic load-deflection behavior of the piles under compressive load suggests the axial nominal compressive resistance is controlled by the structural capacity of the pile. In all instances, the rapid load tests indicated a nominal resistance exceeding that produced by high-strain dynamic tests due to insufficient hammer energy to fully mobilize resistance. In all cases, the hammers used were able to easily install the piles through the soil overburden. Mobilizing a larger hammer simply to demonstrate high-strain dynamic resistance is not economical or practical. This paper presents the subsurface conditions at each location, the ensuing test results, and the ramifications for future projects in Minnesota utilizing large-diameter open-ended pipe piles.INTRODUCTIONThe Minnesota Department of Transportation (MnDOT) has recently performed eight full-scale compressive load tests on large-diameter pipe piles at four different project locations across the state. The four project locations described in this paper where pile load testing was performed are shown in Figure 1 and exist in the southeastern portion of Minnesota. The projects are all major bridges crossing the Mississippi River in three instances and the St. Croix River just above the Mississippi River in the other instance. The first project is the TH 61 Mississippi River crossing in Hasting, MN where two load tests were conducted. The second is the TH 36 St. Croix River crossing in Stillwater, MN where two load tests were performed. The third project is the I-90 Mississippi River crossing in Dresbach, MN where three load tests were conducted. The final project is the TH 43 Mississippi River crossing in Winona, MN where one load test was performed."

Jan 1, 2017

By Sean Gallagher

Bolting large sheets of wire mesh screen (WMS) to the roof of underground mines prevents injuries due to rock falls. However, WMS can be heavy and awkward to lift and transport, and may result in significant spinal loading. Accordingly, six male subjects (mean age =45.8 years + 7.5 SD) were recruited to lift WMS in a laboratory investigation of the biomechanical demands. Biomechanical modeling was used to estimate external moments about L5-S1 for sixteen lifting tasks, using two sizes of WMS. Full-size WMS involved a two-person lift, while half-size WMS involved a one-person lift. Lifts were performed under 168 cm and 213 cm vertical space. Restriction in vertical space increased the maximum L5-S1 extensor moment from 254 to 274 Nm and right lateral bending moment from 195 to 251 Nm. Lifting full sheets of screen (as opposed to half sheets) resulted in an average 33 Nm increase in L5-S1 extensor moment. The L5-S1 extensor moment was increased by an average of 44 Nm (18%) when lifting screens positioned flat on the floor compared to an upright position. Relevance to industry: Large flexible materials are commonly lifted in industrial work environments, and may involve the efforts of two or more workers. The current study examines the low back loading associated with lifting large flexible screens and presents recommendations to reduce spine loading.

Jan 1, 2009

By Greg Rasmussen

"Huckleberry Mines Ltd is an open pit porphyry copper-molybdenum mining operation located 120 km south of Houston, British Columbia with a 18,000 tpd milling facility. Huckleberry Mines is owned 60% by Princeton Mining Corporation, the operator, and 40% by Japanese partners.The Huckleberry deposit is one of several porphyry systems located in the Tahts a district of the intermontane belt of British Columbia. The principal economic minerals are chalcopyrite and molybdenite. The ore deposit is split into two ore deposits, the Main Zone, consisting of24,241,000 tonnes of mineable reserves grading 0.484 %Cu and 0.013 %Mo, and the East Zone, consisting of 66, 131,500 tonnes of mineable reserves grading 0.523 %Cu and 0.014 %Mo.The milling begins with gyratory crushing. This sizes the product down to 100% passing 6 inches. This product is discharged onto a stockpile by a stationary conveyor. The stockpile was designed for a capacity of 144,000 tonnes with a live capacity of 20,000 tonnes. Two apron feeders draw the ore from the bottom of the stockpile and discharge onto a SAG mill feed conveyor which in turn feeds a grinding circuit consisting of one 32' x 15' SAG mill and two 30' x 16.5' ball mills. The grinding cyclone overflow feeds bulk flotation at 55 -65% minus 200 mesh.The bulk flotation uses conventional rougher and column flotation methods to float a bulk concentrate recovering 92.6% copper on the East Zone and 95% copper on the Main Zone with 75% recovery molybdenum on both zones. The bulk concentrate feeds the bulk thickener which produces a density of 60 %solids. This in turn feeds the molybdenum circuit, which separates the copper and molybdenum, by depressing the copper then using conventional rougher and column flotation produces a copper concentrate of 27 %Cu and 0.02 %Mo, and a molybdenum concentrate containing 1.5 %Cu and 54 %Mo at 67% recovery. These concentrates are separately thickened, filtered, dried, and shipped to the smelter for processing."

Jan 1, 1998

By X. Goso

Laboratory-scale tests were conducted at Mintek for the production of titanium powder from particulate Kroll sponge by the hydrogenation-dehydrogenation (HDH) process. The aim of this work was to produce titanium powder for powder metallurgical consolidations. The work involved the production of titanium powder at optimized conditions, which included hydrogenation in a horizontal tube furnace at 600°C for 2 hours, milling using planetary and roller mills, and dehydrogenation in a vacuumed retort fitted in a muffle furnace running at 700°C for 36 hours. The titanium powder produced in this project matched the elemental specifications of commercially available titanium powder, except for high carbon content. Nevertheless, the powder has been tested further in mechanical alloying and has been found suitable for the production of powder metallurgical compacts. Keywords Powder metallurgy, titanium components, HDH process, ball milling.

Jan 1, 2011

By Michelle Mangione, John Kuyt, Zili Li, Michael Mooney

"Twin bored tunnels are commonly used for a variety of road and tunnel projects throughout the world.A major component of these twin tunnel projects is the construction of connecting cross passages that provide emergency access between tunnels and space for tunnel service equipment. Cross passages can present significant geotechnical risk and technical challenges to a project – support systems must be considered for redistributing loads around the mainline tunnel openings and supporting new loading resulting from excavation activities. Additionally, cross passages pose risks to construction schedule and cost because of their sequencing at the end of construction, so mitigation of schedule overruns can be critical. By observing field instrumentation data records from completed projects, a better understanding of the force development in each temporary structure can be achieved with indication of which structures are the most critical to support ground loads.This article discusses the data obtained during the Brisbane Airport Link construction project, a road tunnel located in Brisbane, Australia. Strain gauge instrumentation data from the precast segmental lining and propped opening steel sets is presented with relation to the construction sequence and local geology. Interpretations and conclusions based on the observed trends are proposed, with several key mechanisms affecting the loading and unloading identified.Brisbane Airport Link project overview. The Brisbane Airport Link project in Brisbane, Australia, connects central Brisbane to the airport located northeast of the downtown with more than 7 km (4 miles) of twin-bore road tunnels, two lanes each, with several caverns, interchanges and access ramps constructed along the alignment to connect to other key routes in the city. The project was executed under a public-private partnership (P3) scheme, funded and operated by the consortium BrisConnections. The main contractors were a joint venture of John Holland and Theiss, while the design was carried out by Arup and Parsons Brinckerhoff.Construction of the tunnels was conducted using a combination of 17 roadheaders and two 12.5-m (41-ft) double-shield Herrenknecht tunnel boring machines (TBM) (Harding & Francis, 2013). The TBMs were used in earth pressure balance- (EPB) type closed mode for the initial portion of their drive, starting at the northeast end of the alignment. Tunneling started in soft ground, weathered rock, and mixed face conditions initially, progressing to competent sedimentary rocks as the drive continued. Support was accomplished using a 12.1-m (39.8-ft) diameter steel fiber reinforced concrete (SFRC) segmental lining installed behind the TBMs in nine segments + one key arrangement. The innovative design of these segments is detailed in the paper by Harding and Francis (Harding & Francis, 2013). Ancillary roads and underground interchange caverns were constructed by sequential excavation techniques using roadheaders, accounting for nearly half of the total underground excavations."

Mar 1, 2017

By David E. Fogelson

One model each of three different makes of portable displacement seismographs was calibrated on a shaking table capable of 5,000 pounds of force, Calibration tests were conducted in the frequency range of 5 to 200 c.p,s, and in the amplitude range of 0,002 to 0.05 inch peak-to-peak, The seismographs were tested under two mounting conditions: (1) The feet of the instrument were bolted to the shaking table, and (2) the feet were resting on emery cloth affixed to the table, The results of these tests show that, in the frequency range of 5 to 40 c.p,s, and for vibration levels less than 0.2 g, the magnification for all three instruments is constant with input level but varies slightly with frequency. For vibration levels greater than 0.4 g. and for frequencies greater than 40 c.p.s., the magnification of all three instruments shows large variations with frequency and amplitude of table motion.

Jan 1, 1962

By Mech B

This paper gives a general description of mining practice at The Zinc Corporation Ltd., Broken Hill, New South Wales.The basic mining methods are those which have been common in Broken Hill for many years and have been well described in previous Proceedings. The main object of this paper is to indicate developments which have occurred in recent years and to describe changes in layout, mining methods and equipment which are taking place at present.The following headings have been adopted: History Geology and general characteristics of the orebodies, Geology, The lead lode, The zinc lode, General characteristics, Ore reserves, General mining method, Exploration and diamond drilling, Shafts and shaft sinking, Main shaft, Old main shaft, Block 5 shaft, New upcast airway, Development, Level interval, Level layout, Driving and crosscutting, Winzing, Rising, and Stope preparation.

Jan 1, 1946

By Woodcock J. T, Sparrow G. J, MacRae C. M

The external urfaces and interiors (as polished sections) of particles of coconut hell and extruded peat activated carbons taken from everal Australian carbon-in-pulp operations were examined with an optical micro cope, a scanning electron microscope, and an electron microprobe.Calcium carbonate (calcite) precipitated from the pulp was the major inorganic material on the external surfaces of the carbon particle, but several ore minerals, including quartz, hematite, pyrite, arsenopyrite, and clay minerals were also identified, along with trona, gypsum, a nickel cyanide, and a magnesium salt. Sections of carbon particles showed that calcite was virtually the only introduced inorganic material inside the carbons.It was distributed in the pores and cracks throughout the coconut shell carbon particles but tended to be concentrated in the outer layers of the extruded peat carbon particles. The mechanism of calcite formation and deposition is uncertain. Gold X-ray dot maps showed that gold was distributed through to the centre of coconut shell carbons and to a depth of at least 500 µm in extruded peat carbons. The distribution of gold within the carbon particles was similar to that of calcite.

Jan 1, 1988

By P. Mark. Hawley

Development of Barrick Gold?s Pierina Gold Mine in north-central Peru requires construction of a waste dump for disposal of non-ore grade materials stripped from the open pit to expose the ore. The waste dump site is located near the open pit in a U-shaped valley that is underlain by thin colluvial and morainal soils with locally thick peats and glaciolacustrine deposits. Bedrock underlying the site consists of variably weathered volcanics. The site is subject to moderately high seasonal rainfall and significant seismicity. The geotechnical quality of the waste rock is highly variable, ranging from low quality, degradable, soil-like materials containing appreciable quantities of silt and clay, to high quality, hard, durable, blocky waste rock. A hybrid dump design concept was developed that requires in-pit segregation of high and low quality waste, and selective placement of materials in the dump to maximize stability and enhance internal and subsurface drainage. The design includes a rock drain beneath the dump along the axis of the valley and a series of connected finger drains. Extensive peripheral diversions and stormwater control measures to inhibit infiltration of precipitation are also included. This paper discusses the unique challenges presented by the site and waste materials, the design methodology and stability analyses, and planned monitoring systems.

May 1, 2002

By S. Plaatjie, L. Linzer, M. S. D. Manzi, M. Sihoyiya

Fiber-Optic Sensing and UAV-Platform Techniques for Innovative Mineral Exploration (FUTURE) is a joint European Union and South African consortium project funded under ERA-NET Cofund ERA-MIN3. The project aims to develop cost-effective and novel seismic methods to image geological structures ahead of the mine face, ultimately leading to improved decision-making and safer mining practices. In this study we present results from numerical simulations conducted at South Deep Gold Mine for active in-mine seismic surveys. The study uses a finite differencing code known as WAVE3D, which models models the propagation of a seismic wave generated by stress pertubations that are applied to a defined grid. The numerical simulation model included two major ore bodies (Black Reef and Ventersdorp Contact Reef) and mine tunnels. The model was constrained using laboratory physical property measurements from underground borehole samples such as seismic velocities (e.g., compressional and shear waves) and bulk densities. Two case studies were created, one modelled the active shots and receivers on surface, and the other modelled the shots at depth (in a mine tunnel at ~4000 m depth) with receivers on surface. In both cases, the objective was to investigate the wavefield propagation through the rockmass between the mine tunnel and surface. The simulated wavefield produced by the source located along the mine tunnel was successfully recorded on surface. The surface-recorded wavefield exhibits clear one-way P-wave arrival times at approximately 450 ms to 500 ms, which can be used to calculate the surface-tunnel P-wave refraction tomogram. The results from the study were used to constrain the design, and for the acquisition and processing of the real surface and in-mine seismic surveys acquired under the FUTURE project.

Jan 12, 2025

By A. R. Farkoosh, K. Korgiopoulos, McGill University, O. Rodop, L. A. Villegas Armenta

"New generation of Al-Mg-Si alloys with thermally stable dispersoids that prevent recrystallization and grain growth during hot deformation are currently used in automotive components requiring good formability. Alloy chemistry controls the phase formation especially age-hardening precipitates, dispersoids, and primary intermetallic which have pronounced effect on grain structure, strength and formability. In this work, thermodynamic calculations have been used to predict the effects of varying levels of Si (0.5-1.5wt%), Mg (0.5-1.5wt%) and Mn (0.1-2.5wt%) on phase selection. Thermodynamic calculations have been performed in equilibrium and non-equilibrium conditions via the FactSage™ software using the FTlite database. Selected compositions have been cast, heat treated, extruded and characterized through scanning electron microscopy with energy dispersive spectroscopy and electron channeling contrast imaging techniques. The calculations showed that at the hot deformation temperature of ~540 oC, exceeding certain Mg and Si levels would lead to retained *-Mg2Si intermetallics and Si particles at the grain boundaries in addition to a-Al-(Mn,Fe)-Si. It was found that retained *-Mg2Si phase which adversely affects formability can be avoided for Si+2Mg levels lower than 2.3wt%. FactSage calculations also showed that increasing Mn from 0.5wt% to 1wt% leads to an increase in the amount of dispersoids (from 1wt% to 2wt%) that can potentially slow down recrystallization and grain growth during hot deformation and improve formability. Calculations at room temperature also show that for an alloy with 0.7wt% Mg, excess Si beyond 0.7 wt% promotes the precipitation of Si clusters in the Al matrix that accelerate natural age-hardening. Results were confirmed by experimental investigation.INTRODUCTIONAluminum alloy 6082 (Al-Mg-Si) is used in the automotive industry because of its high strength, and good weldability (I. J. Polmear, 2006). The alloy is age-hardenable through the precipitation of ß-Mg2Si and its precursors, and the recrystallization is usually inhibited by Mn- and Cr-containing dispersoids formed through high temperature heat treatments (I. Polmear & Couper, 1988). However, it is known that minor changes in alloy chemistry (Mg/Si ratio) can have significant influences on the ductility and formability of these alloys by altering phase selection and the resultant microstructure (Gupta, Lloyd, & Court, 2001; McQueen & Celliers, 1997; Zajac, Hutchinson, Johansson, & Gullman, 1994). For automotive applications where wrought alloys (usually extrusions) are cold-formed to produce suspension components, the chemistry of the alloys and the extruded structure are of crucial importance as they determine the formability at room temperature (Asensio-Lozano, Suárez-Peña, & Vander Voort, 2014). In this study, thermodynamic calculations along with experimental investigations were carried out on the Al-Mg-Si system to understand their phase formation and precipitation hardening as a function of alloy composition."

Jan 1, 2016

By Lon Santis, Gregory M. Rumbaugh, Christopher Mark

This paper examines the relevant theory, experience, and past practices relating to development mining near gas or oil wells. It addresses setback distance for both coal and stone room-and-pillar mining. This study also involved a review of accident reports involving well interceptions and downhole well surveys. It provides technical considerations for decisions regarding safe setback distances for development mining throughout the United States. The study’s scope is limited to mining near active or inactive (i.e., non-producing, abandoned or inadequately plugged) wells with known surface locations.

Jun 25, 2024

By J. J. Baz-Dresch

"The Cannon Mine, a joint venture between Asamera Minerals (the operator) and Breakwater Resources, is located in the centre of Washington state at the eastern base of the Cascade Mountains. The mine complex is located three blocks south of the city limits of Wenatchee, part of an urban area with a total population of 47 000. The closest residence is 350 feet from the mine portal.The B-Neath zone is a narrow, high-grade, downward extension of the southern tail of the mine's main ore body, the B-North zone. It also underlies the northernmost portion of the B-West zone (Fig . I) . The ore is usually reasonably competent but completely surrounded by very weak rock consisting of shear zone and unsilicified sandstones and siltstones.The zone has maximum dimensions of 420 ft in thickness, 500 ft in length , and 200 ft in width . The economic reserves extend from the 70-ft elevation (elevation above sea level) to the 630-ft elevation and consist of about 1.3 million tons of geologic reserves (proven and probable) at an average grade of 0.33 ounces per ton.Acquisition and ExplorationInitial DiscoveryThe initial discovery of the B-Neath zone was made by Tenneco Minerals during July through September, 1984. Their 22-hole surface drilling program consisted of 18 200 ft of drilling. Tenneco Minerals had acquired the 91/2 acre lease from United Mining Corporation.Asamera Minerals subsequently purchased Tenneco's lease in July, 1985; Tenneco retained a royalty position which was later purchased by Echo Bay Mining.Follow-up drilling by Asamera Minerals consisted of both surface and underground drilling. Eight surface holes (7200 ft) were drilled commencing in December, 1985. Following evaluation of the geologic data, an access drift was driven on strike along the top of the ore zone on the 500 level. Diamond drilling from this platform consisted of 17 200 ft in 79 holes."

Jan 1, 1990

By P. den Hoed, R. I. Rambiyana

"Four sulphide minerals - pyrite (FeS2), pyrrhotite (Fe1-xS), pentlandite ([Ni,Fe]9S8), and chalcopyrite (CuFeS2) - contain the base metals and most of the iron in concentrates of platinum group metals (PGMs). In the pyrometallurgical processing of PGM concentrates these sulphides form a matte during smelting, and iron and sulphur are removed from the matte during the converting process. This paper discusses the roasting of Merensky concentrate in air before smelting, with the purpose of reducing the matte load to the converter.Roasting tests were conducted in a bench-scale rotary kiln at temperatures from 350°C to 700°C. The concentrate tested contained 17.4% sulphur and consisted of 23% pyrrhotite, 16% pentlandite, 11% chalcopyrite, and 2% pyrite. The particles were fine (d50 = 22 µm), and all the sulphide particles were liberated. Roasting in air at 550°C and 650°C for 20 minutes removed respectively 60% and 70% of the sulphur. The iron in the sulphides was oxidized to Fe3O4 (magnetite) at temperatures below 500°C and to Fe2O3 (haematite) at temperatures above 550°C. At 700°C the bed sintered and copper oxides formed. At temperatures below 450°C oxidation was incomplete: pyrrhotite remained and only 30% of the sulphur was removed. Smelting tests were conducted to assess matte fall and the deportment of copper and nickel to matte. It was evident that roasting resulted in lower matte falls (a drop of approximately 60%) compared with matte falls from unroasted concentrate. The iron and sulphur levels in the matte were reduced to below 3.5% and 22% respectively.This paper also briefly describes the mechanisms by which pyrrhotite, chalcopyrite, and pentlandite are oxidized during roasting. For chalcopyrite, the mechanism proceeds through an intermediate solid solution phase, which extends from Cu1.02Fe1.04S2 to Cu2.04Fe0.72S2 to a copper-rich solid solution of bornite (Cu4Fe1.4S4-Cu2S). The oxidation of pentlandite proceeds through a monosulphide solid solution (Ni0.39Fe0.53S-Ni0.74Fe0.15S) to a solid solution of heazlewoodite ([Ni,Fe]3}xS2). These mechanisms are explored in relation to chemical thermodynamics and microstructures."

Jan 1, 2015

By James J. Scott

Eleven workshops were held in various locations throughout the country in an attempt to reach the many diverse groups working in various mineral commodity areas and special ties. These meetings were held between March 1, 1974 and June 25, 1975. They were held under the auspices of the Bureau of Mines Contract to the University of Missouri-Rolla which was designed to help define Bureau research and development priorities. At each workshop a summary of current Bureau research and development was presented and the attendees were asked to present their ideas on what Research and Development programs should be undertaken to meet their needs locally. Participants included representatives of federal and state agencies, educational institutions, mining companies, equipment companies and other interested parties. The workshops covered under this report include lead mining in Missouri, limestone mining, coal mining both surface and underground in the midwest and in the Rocky Mountain area, iron mining in Minnesota, two top management meetings on institutional problems and, finally, a special two-day meeting on roof control.

Jan 1, 1977

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015