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By Benjamin W. Haynes

The Bureau of Mines conducted research to provide technical information needed to devise waste management plans for the processing of manganese nodules. Studies included summary descriptions of Pacific manganese nodules, process options and flowsheets, methods for characterizing nodules and their tailings, and results of analyses of laboratory and pilot-plant generated tailings. This information is the result of a cooperative research effort of the Bureau of Mines and the National Oceanic and Atmospheric Administration (NOAA), with NOAA providing funding and the Bureau conducting the research. A summary of the extensive literature review is provided for manganese nodule mineralogy, chemistry, processing techniques, and methods of analyses. Characterizations and analyses of laboratory-generated tailings and slags are given, as well as the results of the leaching studies on these waste materials. Leachability was determined by three standard leachate tests- the Environmental Protection Agency (EPA) extraction procedure (EP) toxicity test, the American Society for Testing and Materials shake extraction test, and the U.S. Army Corps of Engineers-EPA seawater elutriant test. While the wastes generated in the laboratory may not be entirely representative of those to be generated in full-scale plants, results of these studies provide a positive indication that commercial recovery of cobalt, copper, manganese, and nickel from manganese nodules would be environmentally acceptable.

Jan 1, 1985

By T. Oberthür

The Great Dyke of Zimbabwe constitutes the world?s second largest reserve of platinum group elements (PGE) after the Bushveld Complex in neighbouring South Africa. Within the Great Dyke, economic concentrations of PGE are restricted to sulphide disseminations of the Main Sulphide Zone (MSZ), which are currently mined at the Ngezi, Unki, and Mimosa mines. Near-surface oxidized MSZ ores have a large potential. Their total resources are in the range of ca. 160 ? 250 Mt; however, all previous attempts to extract the PGE from this ore type proved uneconomic due to low PGE recoveries (<< 50 per cent) achieved by conventional metallurgical methods. Within the ores of pristine, sulphide-bearing MSZ, the PGE are bimodally distributed. Platinum occurs mainly in the form of discrete platinum group mineral (PGM) grains (mainly bismuthotellurides, sulphides, and arsenides), whereas approximately 80 per cent of the Pd (and some Rh) is hosted in pentlandite. Within the oxidized MSZ ores, the PGE are polymodally distributed. Whereas arsenide- and sulphide-PGMs, making up ca. 25 per cent of the original Pt content of the ore, largely remain stable (relict PGMs), the remaining PGMs are disintegrated. The base metal sulphides are destroyed, partly releasing their base metal and PGE contents, and are replaced by iron oxides or hydroxides. Unspecified amounts of the PGE are redistributed and either form secondary PGMs, are found in chemically and mineralogically ill-defined (Pt/Pd)-oxides or hydroxides, or in iron-hydroxides, Mn?Co-hydroxides, and in secondary silicates. The problematic processing of oxidized MSZ ores is attributable to their complex nature and polymodal distribution of the PGE, prohibiting a significant upgrading of the ores by conventional metallurgical methods. Therefore, only bulk leaching methods are viable for ore treatment, and novel metallurgical methods have to be developed for the processing of these ores. Our ongoing work aims at locating the PGE in their mineralogical form in order to understand the mineralogical balance of the PGE in the ores and thereby facilitate the evaluation of metallurgical options for their recovery. A short overview on options and recent advances regarding the recovery of the PGE from oxidized ores is given.

Jan 1, 2012

By Rachel Bauer, Jacob Henderson, Dr. Catherine Johnson

Capital Quarries in Owensville, Missouri faces several challenges when designing a blast that allows for ease of movement while maintaining controlled throw and compliant air over pressure. The primary challenge is the nearest non-owned structure (NNOS) is a residential home located 250 feet from the quarry. Another challenge is a production bench which is 100 feet tall and separated from the NNOS by Pennsylvanian fire clay that filters out high frequency waves from the blast. Material from the blast must also be less than 5 inches in order to be processed by the crusher in the quarry. To provide as much relief as possible, production shots will consist of a single row with the minimum required burden. To design the shot, signature hole analysis was used to determine the optimal timing between powder columns. Electronic detonators provided an accurately timed shot to minimize the amplitude of the vibrations while maximizing the frequencies. Boretraking and 3D profiling with Renishaw laser profiler and Strayos drone photogrammetry provided an accurate burden measurement. Powder factor was kept at 1.3 tons/lb using bulk emulsion. The boreholes were split into 5 powder columns with the top of the hole firing first in order to blast to floor grade. The resulting shot produced good fragmentation and shot to floor grade. Seismograph readings showed air over pressure vibrations within legal limits. Due to this success, multiple shots will be designed using the process described.

Feb 6, 2023

By A Karrech, C Schrank, O Gaede, I Canbulat

Strain-based failure criteria have several advantages over stress-based failure criteria: they can account for elastic and inelastic strains; they utilise direct, observable effects instead of inferred effects (strain gauges versus stress estimates) and they model complete stress-strain curves, including prepeak, non-linear elasticity and post-peak strain weakening. In this study, a strain-based failure criterion derived from thermodynamic first principles utilising the concepts of continuum damage mechanics is presented. Furthermore, implementation of this failure criterion into a finite element simulation is demonstrated and applied to the stability of underground mining coal pillars.In numerical studies, pillar strength is usually expressed in terms of critical stresses or stress-based failure criteria where scaling with pillar width and height is common. Previous publications have employed the finite element method for pillar stability analysis using stress-based failure criterion, such as Mohr-Coulomb and Hoek-Brown, or stress-based scalar damage models.A novel constitutive material model, which takes into consideration anisotropy as well as elastic strain and damage as state variables, has been developed and is presented in this paper. The damage threshold and its evolution are strain-controlled, and coupling of the state variables is achieved through the damage-induced degradation of the elasticity tensor. This material model is implemented into the finite element software Abaqus and can be applied to 3D problems.Initial results show that this new material model is capable of describing the non-linear behaviour of geomaterials commonly observed before peak strength is reached as well as post-peak strain softening. Furthermore, it is demonstrated that the model can account for directional dependency of failure behaviour (ie anisotropy) and has the potential to be expanded to environmental controls such as temperature or moisture.CITATION:Gaede, O, Schrank, C, Canbulat, I and Karrech, A, 2014. A strain-based failure criterion for pillar stability analysis, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 393–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By Priscilla Danielle de Oliveira Lopes Costa

Na indústria aeronáutica, fadiga é um dos processos mais importantes quando se considera o dano e a falha das estruturas de uma aeronave. Adicionalmente, os materiais compósitos apresentam altas resistência e rigidez específicas. No entanto, os mecanismos de dano de um material compósito são complexos. Como consequência, o objetivo deste trabalho é identificar as propriedades à fadiga de materiais compósitos de fibras de carbono e resina epóxi, com configuração de lâminas 0°/90°/±45º e caracterizar os mecanismos de dano quando estes são submetidos à fadiga. Para tanto, nos corpos de prova foram realizados ensaios de fadiga em uma máquina universal de ensaios MTS, em controle por tensão com frequência de 10 Hz com carregamentos máximos de 6000, 5000, 4000 e 3000 N e R = 0,1 (tração-tração). O compósito em estudo demonstrou boa resistência à fadiga por controle de tensão, a vida infinita é de aproximadamente 48,5% da resistência à tração. O número de ciclos a fadiga depende da amplitude de tensão, assim como da tensão média, sendo que quanto menor a carga aplicada menor a amplitude de tensão (e a tensão média) e maior o número de ciclos a fratura. A fractografia após os ensaios caracterizou os mecanismos de dano durante o processo de fadiga, sendo que fratura na matriz, fratura das fibras e descolamento fibra/matriz são os mecanismos de falha dominantes durante a fadiga, através de análise por microscopia eletrônica de varredura.

Aug 7, 2018

By M. Akram

Stability assessment of entry roofs is an essential precursor to all underground design. Both multi-seam interaction and longwall mining can subject entries to radical changes in the surrounding stress field. Such loading changes frequently produce instability and failure in the roof, floor and pillars. Roofs are shown to be vulnerable to stress-induced failures, particularly when the load is unsymmetrical. To predict the effects of changes in stress field, roof failure conditions under increasing loads were studied using finite element analysis and body loaded photoelastic models. A large range of geologic conditions were evaluated and incorporated into the model using Monte Carlo methods. Entry analysis using the model showed the roof to be particularly vulnerable to shear with the location of the failure site changing to meet loading and geologic conditions. Results were correlated with field data to determine stress levels at which failure could be expected to occur. Based on this research a roof stability model SESAME was constructed for roof stability evaluation under specified loading conditions.

Jan 1, 1993

By Hugh P. Godard, K. Winslow

"AbstractA number of panels of various aluminum alloys in different combinations and secured by steel and three types of aluminum rivets were exposed underground at two locations in a Northern Ontario gold mine for two years and then examined to determine the extent of corrosion. The results indicate Alcan 65S-T to possess considerable advantages over Alcan 178-T, which has been employed in the construction of light skips and cages with considerable success for almost twenty years. Information on the behaviour of these alloys when used with steel rivets and in mixed combinations with themselves was obtained.IntroductionBy the complete substitution of aluminum alloys for steel in the fabrication of mining skips and cages, their weight can be reduced as much as 50 per cent. Lesser savings are possible though its savings are possible through its plates, doors, reinforcing members, etc. Reduced weight leads to economy through increased hoisting efficiency.For a new installation, the basis of design is the rate of production, which thus fixes the live load to be hoisted per trip. A lighter skip permits the use of a lighter rope and a smaller hoist. In deep shafts with high-speed hoists operated in balance, the power required for accelerating is considerable. The hoist size is determined by the weight of skip, load, and rope plus the force required to accelerate or decelerate these three elements A light skip may result in a considerably lighter rope. This is important because, even though the skip can be completely balanced this is not true of the rope. Partial balancing is possible, but conical hoist drums or other devices for this purpose are costly; thus a smaller rope results in a smaller hoist, with consequent general reduction in cost of the whole installation. A reduction in power consumption is also obtained as a result of keeping to a minimum the amount of unbalanced load and the weight of all moving parts which must be accelerated."

Jan 1, 1950

By Gilles Recher, Jörg Riechers, Albert Lueghamer

"INTRODUCTIONIn view of a global trend towards urbanization, more and more trunk sewers and combined sewer overflow tunnels (CSO) with medium to large diameters and the corresponding link sewers are currently built and under design. Shielded tunnel boring machines using segmental lining as tunnel support represent an efficient solution for construction of new wastewater and supply tunnels. Especially in the field of sewers, the durability of concrete structures both exposed to any groundwater present on its exterior and to aggressive waste water as well as gases on its interior is a key requirement. Despite thorough research on segmental lining and mechanized tunneling machinery, conventional thermoplastic liners show comparatively minimal progress in terms of practical advancements. This is in contrast with the development of the latest segment embedded high density polyethylene (HDPE) system. Based on experiences achieved, this paper discusses the latest development of an integral protective lining system in respect of material characteristics and its adaptability to both project and customers’ demands. Reviewed performances, as the bondage behavior of the embedded HDPE system at axial stress loads due to acting thrust cylinders during ring build as well as the ability to drain pressurized water behind the embedded membrane, tested at full scale segments, are also presented. The paper is round off by presenting first details of sewer projects endeavoring to utilize this cutting-edge solution for an integral concrete protection, which will be commenced beginning of 2016.CASE HISTORIES ENCOURAGE ADVANCEMENTS Past experience has shown that unprotected concrete surfaces as well as chemical based linings such as coatings, sprayed linings and cured in-place-systems cannot reach the desired life times. Also the fact that in deep tunnel sewer system hardly maintenance is possible, a durable and maintenance free system is required which only can be reached by applying mechanical anchored HDPE (CPL)."

Jan 1, 2016

By H. B. Jensen

STUDY of the thermal-solution process was begun by treating crushed oil shale in a small autoclave at temperatures of 700° to 950° F. The effect of temperature, reaction time, type of solvent, and richness of shale upon the amount of organic matter that was removed from the oil shale was thus determined. Following this orientation work a semicontinuous, bench-scale apparatus was built so that heated solvent could be pumped through a bed of shale under elevated pressure, thus removing the converted organic matter from the spent shale. After some operating experience had been gained, a continuous unit was constructed. This permitted treating a slurry of shale oil and pulverized oil shale at about 300 p. s. i. and temperatures of 750° to 850° F. for various retention times. Considerable cracking and polymerization of the shale oil were found to take place during the process. In an attempt to prevent this, a study was made of extraction of the shale in batch-type autoclaves under high partial pressures of hydrogen at total gas pressures of as much as 4,300 p. s. i. at 850° F. The thermal-solution process was found to convert over 90 percent of the organic matter in oil shale to oil and gas. The highest yields of gas and oil obtained without hydrogen pressure were equivalent to 119 weight-percent of those obtained from the same shale by Fischer assay. With a high partial pressure of hydrogen, yields equivalent to 126 weight-percent of Fischer assay were obtained. However, the oil produced by thermal solution has a higher boiling range than that obtained by other retorting methods, particularly so if the thermal-solution process is used without a high partial pressure of hydrogen. Nondistillable oil (all benzene-soluble material that would not distill under 2 mm. Hg absolute pressure without cracking) equivalent to over 100 percent of the organic matter in the shale was obtained without hydrogen pressure in the system. When the process was carried out under hydrogen pressure, the yield of nondistillable oil amounted to 60 to 70 weight-percent of the organic matter. Part of this heavy material is formed partly by polymerization and condensation of the shale-oil solvent used. These reactions, as well as cracking of the solvent to form gas and a carbonaceous deposit on the shale, are unfavorable features of the process.

Jan 1, 1953

By Slawomir Bock

One of the fundamental issues having a great influence on the safety of operations performed in underground mines is the support of workings which should assure their stability in a given geological setting and mining-technical conditions during the life of their use. The process of designing and planning support for roadways may use analytical and empirical, as well as numerical methods. In view of the rapid increase in the data processing capacity of computers and the development of more and more enhanced software for numerical modeling, it seems to be advantageous to use numerical methods in searching for design solutions ? especially in the case of non-typical mining and geological conditions and in cases that need to take into consideration a great number of factors. The assessment of rock mass quality is of basic significance in designing mine supports. Fractures, dividing the rock mass into blocks, have an essential influence on the stability of the rock mass and underground construction. This paper presents examples of the fundamental underground investigations on the rock mass conducted by the Department of Extraction Technologies and Mining Supports of the Central Mining Institute in Poland, such as: penetrometric tests, introscopic examination, laboratory testing of rock samples and ground penetrating radar. Moreover, this contribution also presents examples of applications of three-dimensional numerical modeling for the purposes of stress-strain analysis of the rock mass around mine workings and computer-aided support design by means of FLAC3D (developed by Itasca) and Cosmos/M (developed by Structural Research and Analysis Corporation).

Jan 1, 2009

By Clark D. Harrison

This paper compares the ash slagging potential of Illinois No. 6 Seam coal: as raw coal; as commercially cleaned coal processed in a baum-jig plant; and as coal cleaned to a reduced ash specification at the Electric Power Research Institute&apos;s Coal Cleaning Test Facility. The comparison is based on: ? ASTM ash fusibility data ? A slagging index ? Gravity fractionation analyses of critical mineral matter compounds ? Comparative pilot combustion tests. The first three grounds of comparison are laboratory data; and the final comparison involves burning approximately 15 tons of each coal at CONOCO&apos;s 1.5 MBtu/hr (440 KW) test combustor. The evidence of these .four comparisons indicates that lowering the ash specification of coal before combustion can significantly improve the ash slagging characteristics of Illinois 90. 6 Seam coal.

Jan 1, 1984

By Marcos Meyer

A pelotização é um processo de aglomeração com objetivo de agregar valor aos finos de minérios de ferro (pellet feed). A partir de 2010, a mina de Brucutu situada no Quadrilátero Ferriferro (QF) passa a ser a maior fornecedora de matéria prima para as plantas de Tubarão / Vitória-ES. O estudo avaliou a performance industrial de duas misturas com alta participação de minério de Brucutu, acima do padrão utilizado na usina de pelotização. Os minérios compostos nas misturas foram caracterizados por análise química, física, mineralógica e microestrutural. O desempenho operacional mostrou superior à mistura padrão utilizada para a produção de pelotas para redução direta, permanecendo com os parâmetros de qualidade consoantes com as especificações do produto final. O conhecimento das características geometalúrgicas destas misturas com minério de Brucutu em maior escala foi de suma importância para adequar o processo e custo das principais operações unitárias da planta envolvida (moagem e forno).

Aug 1, 2018

By William C. Morel, Sidney Katell

This report covers the period January 1964 through December 1964; it is a continuation of the series that began with the publica- tion of Information Circular 7516 in October 1949. Also, it is the sixth in a series of reports prepared under a cooperative agreement between the Bureau of Mines and the American Association of Cost Engin- eers. The agreement provides for the publication of an annual cost bibliography with the work load involved in the preparation shared equally. The abstracted articles, concerned with all facets of cost engineering in the field of chemical and petroleum plants and related subjects, are from the following sources: 1. American Association of Cost Engineers Bulletin. 2. Bureau of Mines Information Circulars. 3. Bureau of Mines Reports of Investigations. 4. Chemical Engineering. 5. Chemical Engineering Progress. 6. Chemical Week. 7. Coal Age. 8. Coal--Today and Tomorrow. 9. Cost Engineering. 10. Hydrocarbon Processing and Petroleum Refiner. 11. Industrial and Engineering Chemistry. 12. Nucleonics. 13. 011 and Gas Journal. 14. Petroleum Management. 15. World Oil.

Jan 1, 1965

By Alei Leite Alcantara Domingues

A microscopia óptica é uma ferramenta importante para o entendimento dos processos envolvidos na produção do minério de ferro e seus aglomerados. Nos laboratórios em que esse tipo de análise é feita, tem-se geralmente um microscópio de luz refletida e um operador treinado que leva diversas horas para concluir uma única amostra. Nesse trabalho serão mostrados exemplos de resultados de minérios de ferro, sínter e pelotas obtidos em um sistema de microscopia óptica automática com análise de imagens. No estudo do minério de ferro foram determinados a composição mineralógica quantitativa, morfologia das partículas e tamanho dos cristais. Na microscopia de sínter foram determinados a quantificação de fases, porosidade, textura, recristalização de hematita e morfologia das ferritas. Nas pelotas produzidas com minério de ferro foram feitas análises de quantificação de fases, distribuição e quantificação dos poros e evolução microestrutural dos grãos. A implantação de um sistema de microscopia óptica automática com análise de imagens permite que análises sejam feitas em menor tempo, com maior reprodutibilidade possibilitando que a técnica seja implantada em áreas de produção que exijam respostas mais rápidas.

Oct 30, 2017

By Daniel G. Di Canio

A computer based accident cost indicator model (ACIM) for estimating tangible costs of occupational injuries, illnesses, and fatalities in the U.S. mining industry is described. Studies performed to expand the scope of the ACIM to all mining sectors are presented. Validation of ACIM cost element estimation algorithms with actual costs of mining-related injuries and illnesses are presented. A study of the effect of a fatal accident on production in surface coal and metal/nonmetal mines is presented. The study is based on a sample of 15 fatalities in underground and surface mines. Evidence of significant long- term decline in postfatality production at 6 of 8 underground samples is presented. The average loss is shown to be 1.8% of annual mine production. A study of accident costs in U.S. mining from 1975 through 1981 using the ACIM is presented. The study shows that total annual costs increased from $180,000,000 in 1975 to $379,000,000 in 1981, a 15% annual increase after adjusting for inflation, with mining companies bearing 45% of the total and expected wage losses to mining families accounting for 42%. The study shows total costs of $12,400 per accident and $674,000 per fatal accident for 1981.

Jan 1, 1983

By R. C. Gilmore

Computational fluid dynamics (CFD) has been used to model gas compositions in underground longwall coal mine gobs to study oxygen ingress and the development of potentially explosive methane-air mixtures that may form in the gob. The scenarios studied involve various headgate and tailgate ventilation and inertization schemes and controls. In a project sponsored by the National Institute for Occupational Safety and Health (NIOSH), researchers at Colorado School of Mines have used an innovative meshing approach, allowing easy adaptation of the CFD model to adjust to a variety of bleeder and bleederless mining geometries, with gob porosity and permeability scalable over a wide range. This paper presents the methodology of the meshing and scaling approach along with recommendations for using CFD modeling in longwall gob ventilation applications. The new meshing technique was utilized to evaluate the function of a back return in a progressively sealed gob. The back return was successful in maintaining sufficient oxygen concentrations in the tailgate corner of the longwall face.

Feb 23, 2014

By A. E. M. Warner

In co Limited has long and extensive experience in converting nickel-copper primary smelting mattes over a broad range of nickel/copper weight ratios and combined nickel-copper-cobalt contents. At the Copper Cliff Smelter, the composition of the converter product matte has to meet the requirements of the matte separation process; at the Thompson Smelter, converter matte of a different composition is cast into anodes for nickel electrorefining; and in Soroako, Indonesia, a very low copper product matte is granulated for the Japanese market. Recently, Inco has conducted pilot plant testing of three possible nickel-copper matte continuous converting routes, namely flash converting, oxygen top blowing-nitrogen bottom stirring, and tuyere blowing. This test work has generated substantial new information on nickel-copper matte converting chemistry. This overview paper reviews the metallurgy of nickel-copper matte converting, in particular the behaviour of cobalt and the operating conditions required to meet the iron and sulfur specifications of the product matte. The relevant thermodynamic information is used to discuss the industrial data.

Jan 1, 2003

By A Fern, A Hawkes, o, T Vincent

The modern workplace has changed dramatically in recent years with an increased emphasis on the psychological well-being of employees. While adhering to a certain standard of psychosocial safety at work is now not only a moral, but legal obligation in Australia, it begs the question: how can organisations begin to ensure psychosocial safety? A positive psychosocial safety climate is one where employees feel they are psychologically safe, feel supported in their work and are not exposed to work-related stressors that can negatively affect their mental health. Such a climate can help boost productivity and create a more positive working environment. This presentation will provide a twopronged approach to understanding and managing psychosocial safety: pairing a traditional risk assessment with climate measurement. Risk assessments can provide several benefits, including identifying and characterising work-related hazards, identifying the nature and severity of the risks to employees and prioritising necessary interventions for reducing or preventing psychosocial harm in the workplace. However, these assessments can have certain limitations, especially when it comes to capturing some of the less obvious causes of psychosocial harm. Climate measurement can provide valuable insights into employees’ perceptions of the work environment, identify areas of concern that may not have been identified in the risk assessment and help to guide organisational changes that will enhance employees’ psychosocial well-being over time. It will also be argued that climate should be assessed from a broad perspective exploring general, physical, social and psychological aspects of safety climate. This presentation will explore why conducting risk assessments in conjunction with detailed climate measurements is integral to protecting the psychosocial safety of employees in the workplace and demonstrate why employers should view the two approaches as complementary and interconnected. Best practice recommendations will be provided for the risk assessment, climate measurement and psychosocial interventions

Apr 16, 2024

By Jaroslav Briancin, Katarína Gáborová, María Florencia Márquez-Zavalía, Marcela Achimovičová, Ol’ga Šestinová, Pavel Škácha

Naumannite (Ag,Se), a silver selenide mineral, was first discovered in 1828. This study investigates the structure, morphology, chemical composition, and leaching kinetics of naumannite. Mechanical activation in a planetary ball mill increased its specific surface area, enhancing the leaching rate of silver in nitric acid (HNO3). The study found that mechanical activation significantly improves silver recovery.

Jul 1, 2023

By Edward J. Felten

THE oxidation resistance of chromium and Fe-Cr alloys is increased by small additions of yttrium or other rare earth metals.1,2 In addition, the presence of the additives increases the resistance of these alloys to spalling of the external oxide above 1000°C. This ability to prevent spalling appears to be related to the formation of an internal oxide in alloys containing yttrium or the other rare earth metals. The internal oxide is found in the form of a filamentary growth concentrated in the grain boundaries of the unoxidized metal. In alloys containing yttrium this internal oxide was found to be either Y2O3 Or YCrO3.&apos; In an earlier report,&apos; the growth of the external oxide was found to be controlled by diffusion through the oxide layer. Thermal balance studies were used to establish the kinetics of external oxide formation. In this related study the rate of growth of the internal filamentary oxide has also been studied. The results obtained indicate that the growth of the internal oxide is also diffusion controlled. Internal oxidation appears to occur in at least two ways. Using copper alloys containing small amounts of silicon, Rhines 3 found that between 600" and 1000oC a subscale was formed which consisted of particles of silica dispersed in the metallic matrix. The conditions requisite to internal oxidation as suggested by Rhines are: 1) a solubility of oxygen in the alloy, 2) the ability of oxygen to diffuse at an appreciable rate into the alloy, 3) the possibility of the formation by the alloying element of an oxide more stable than the oxide of the host metal, and 4) a relatively low solubility of this oxide in the metal. These conditions are fulfilled for a number of other copper alloys.3-5 Furthermore, the relationship between the depth to which the internal oxide is formed and the oxidation time follows the simple parabolic law.6 The activation energy for copper containing small amounts of silicon, germanium, iron, or manganese as calculated from Rhines data6 is about 48 kcal per mole. In some cases the internal oxide is found segregated at the grain boundaries, especially near the the surface. Observations of this type of oxide formation have been reported by stead,7 Rhines,* and Lustman. Evans" cites these cases as examples of the simultaneous movement of anions and cations during oxidation. Furthermore, Evans states that the presence of a minor constituent with a high

Jan 1, 1962