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By D. Mohapatra

Extraction of Al(III) from aqueous sulfuric acid solutions into organic Cyanex 272®-carbon tetrachloride systems was investigated from a multi-component mixture containing aluminum, cobalt and nickel. Al(III) extraction efficiency was quantitative with 1.0 M Cyanex 272® in two stages at an aqueous: organic (A:O) phase ratio of 1:1 and an equilibrium pH of 3.2. The stripping of Al(III) from the loaded organic (LO) with different acids indicated sulfuric acid to be the best stripping agent. More than 99% stripping of Al(III) from the LO was achieved using 2 M H2SO4 at an A:O phase ratio of 1:1 in a single stage. The stoichiometry of the extracted species of Al(III) was determined by the slope analysis method. The extraction reaction proceeded via the cation exchange mechanism and the extracted species was assumed to be AlA3?3HA, where HA refers to the dimeric and A the anionic form of the extractant, Cyanex 272®. The extraction of Al(III) was studied in the presence of various ions to ascertain the tolerance limit of individual ions.

Jan 1, 2008

By A. J. Hyett

Due to the ongoing revolution in electronics and communications more cost-effective geotechnical instruments can be manufactured using digital technology. This new generation of digital instruments have embedded microcontrollers that provide highly accurate and reliable measurement of geotechnical behaviour in real world units that can be immediately interpreted. Digital measurements can be transmitted across existing mine-wide wireless communication networks, interfaced directly with infra-red enabled PDA?s or PC?s, and parsed to memory by low-cost data-loggers.

Oct 1, 2004

By M. Radwan, S. Shimada, S. Z. El-Tawil, K. A. El-Barawy, Y. Miyamoto

This study presents the results of synthesizing monolithic siliconoxynitride, Si2N2O, ceramic from a mixture composed of reclaimed silicon and natural desert sand by using the nitriding combustion synthesis method. Single-phase Si2N2O powder was prepared by the combustion of a mixture composed of silicon and pulverized sand in 3 MPa nitrogen gas. The combustion reaction completed in 2 min and the combustion temperature reached 1577°C.The as-synthesized Si2N2O powder is agglomerate of fine particles with sizes < 5 µm and has various morphologies; rod-like and irregular crystals, irregular kinking, hollow crystals and grown pseudo-hexagonal prismatic crystals. Porous Si2N2O compacts (24.5–47.1% porosities) were fabricated from the synthesized Si2N2O powder at different calcia-alumina additives (5–20 wt%) by normal sintering at 1500°C for 1 hr in N2atmosphere.They showed superior oxidation-resistance at high temperatures up to 1500°C in an oxidizing atmosphere of Ar/O2/H2O(70/20/10 kPa).Near-full dense Si2N2O compacts were also successfully fabricated from the synthesized Si2N2O powder with 5 wt% oxide additives by using the spark plasma sintering at 1600°C.DenseSi2N2O had good mechanical properties (18.7 GPa Vickers hardness, 3.3 MPa.m1/2fracture toughness and 363 MPa strength) and excellent chemical and oxidation resistance.

Jan 1, 2004

By Pierre L. Labelle

Non electric Dual Delay initiators have revolutionized many aspects of underground mining. The units are used in all types of underground blasting operations. Some operations, due to the complexity and variety of their blasts, have extremely large inventories of conventional non electric products. The Dual Delay system has drastically reduced these inventories and has added an important element of versatility to blast designs.

Jan 1, 1994

By J. M. Richards

For most of the 20th century optical petrography has been the primary petrological and mineralogical tool used to characterize coal. The development of quantitative SEM-based techniques, e.g. QEMSCAN®, for coal began only about a decade ago. The application of these techniques for coal lagged behind other commodities, but they are currently being developed with the aim to provide ?one complete analysis? for coal. Quantitative SEM-based techniques are supplemented by quantitative X-ray diffraction (XRD). Recent indications are that these more modern techniques cannot replace the ?standard? petrographic and chemical evaluations, but rather complement them where and when required. The great advantage of quantitative SEM-based techniques is that they are very rapid, with the result that large volumes of samples can be processed on a routine basis. This is ideal for coal type identification, since the results can be used in the creation of ?intelligent? composites. This can lead to the more speedy evaluation of coal deposits by reducing the number of samples on which detailed metallurgical and characterization test work is required, without an increase in the overall statistical error of the resource model. Coal petrography, however, remains important for the prediction of the coking characteristics of certain coals and coal products. As a consequence it is therefore important that any coal laboratory be able to produce data with confidence. This requires strict quality control and assurance protocols that adhere to international standards. Keywords coal petrography, coking strength, scanning electron microscopy, QEMSCAN®.

Nov 1, 2013

By G. Paquet, E. Godin

"Since the mid fifty's, worlwide pellet production capacity has constantly risen (Fig. 1, Ref. 1 l. There was however at that time no real incentive to decrease production costs but only to produce as many pellets as possible. State of things changed with the iron and steel market recession, starting in 1975, and is currently leading producers to improve pellet quality and to reduce fuel and power consumption.At the Port-Cartier pellet plant, the energy needed for the induration of pellets ranks first in overall operating costs. An important step was made when starting admixing coke breeze in 1980. Oil prices justified the use of coke breeze as a direct replacement in terms of dollar/ton, however, while gaining expertise in using solid fuel a significant decrease in energy consumption was observed (Fig. 2, Ref. 2).In 1985, the ""Centre de Recherches minérales"" was commissioned to undertake research work to investigate the effects of further increasing coke addition to the pellet mix. The positive results of that work led to a 1,5% coke addition plant trial during the fall of 1985. Both laboratory and industrial results are discussed in this paper."

Jan 1, 1986

By Adil Aledresse, Louis Mercier, Laxman Amaratunga

"The development of high capacity adsorbents with uniform porosity denoted, MP-HMS (Mercaptopropyl – Hexagonal Mesoporous Structure) using nanotechnology, and their ability to extract gold from solution, is presented. The preparation of highly effective heavy metal ion adsorbents by the incorporation of thiol moieties into the pore channels of mesoporous silica molecular sieves has been the subject of many nanotechnology research investigations. The unique feature of these nanoporous adsorbents is their ability to adsorb gold ions from ultra-low concentration solutions like mine effluent as well as from leached solutions in gold mills. The preliminary studies from laboratory simulated gold solutions show that the adsorption capacities of these materials are also among the highest reported. MP-HMS has shown the capability to adsorb 370 mg gold per one gram of the nanomaterials from Tetrachloroaurate solution (up to 37% of their weight). Experimental studies indicated that the maximum adsorption of gold (as high as 99.9% recovery). The current studies will be extended to investigate the interaction of ionic gold complexes with nanomaterials. Future development of this work may lead to either to replace the conventional CIP/CIL processes or use nanomaterials in tandem with the former, suggesting plausible use of mesoporous material in pulp, MIP or in leach, MIL, as a novel gold extraction process.INTRODUCTIONGold typically occurs at very low concentrations in ores less than 10 g/t or 0.001% (mass basis). At these concentrations the use of aqueous chemical (hydrometallurgical) extraction processes is the only economically viable method of extracting the gold from the ore. Typical hydrometallurgical gold recovery involves a leaching step followed by the separation of the gold bearing solution from the residues, or adsorption of the gold onto activated carbon adsorbent. After elution from the activated carbon the gold is further concentrated by precipitation or electrodeposition."

Jan 1, 2008

By W. A. Hockings, D. W. Fuerstenau, A. L. Mular

This paper briefly describes a simple air pycno-meter and its use for rapid determination of the composition of mixtures of solid particles. Research on such problems as the pelletizing of solids, the mixing of solid particles, and the comminution of mixtures can be simplified by means of this analytical tool. THEORY OF OPERATION Liquid pycnometers1 are commonly employed to measure volumes. These devices are time consuming and sometimes give inconsistent results. The liquid used in the pycnometer may have an undesired influence on the material to be measured; moreover, complete displacement of air by the liquid is seldom

Jan 1, 1963

By A. A. Bilgin

The prevention of acid mine drainage (AMD) in situ is more attractive than down-gradient treatment alternatives that do not involve source control. AMD source control can be achieved by shifting the microbial activity in the sulfidic rock from pyrite oxidation to anaerobic heterotrophic activity. This is achieved by adding biodegradable organic carbon amendments to the sulfidic rock. This technique was applied to an abandoned coal mine pool in Pennsylvania. The pool had a pH of 3.0 to 3.5. Following treatment, near-neutral pH and decreased effluent heavy metal concentrations were achieved. In situ bioremediation by the enhancement of bacterial iron and sulfate reduction is a promising technology for AMD prevention.

Jan 1, 2007

By Peter Fischer

Between 45,000 and 50,000 claims for subsidence are submitted each year to the German hard coal industry. In order to improve the service to claimants a quality management was established in 2005. This paper describes the process now used for handling these claims. A quality check has also been carried out by way of a customer survey, which was performed by an independent research agency. The results of the survey are presented in this paper. In Germany, research into mining subsidence mainly involves the prediction of ground movements caused by deep mining operations. Special areas of research are subsidence reducing aspects of the extraction panel planning, especially from the point of view of mining dynamics, as well as securing and restoration measures. This work seeks to prevent or minimize mining-induced damages close to the surface, for instance, buildings or infrastructure installations (such as pipelines), or underground mine openings (e.g. shafts). Roof collapses and surface fractures caused by shallow mine workings of an earlier era currently constitute a special area of investigation.

Jan 1, 2006

By James A. Finch, Stéphanie Somot

"The self-heating facility developed at the Noranda Technology Centre [Rosenblum and coworkers, 2001; 1995] has now been established in the Department of Mining, Metals and Materials Engineering at McGill University. A research program into mechanisms has been initiated (with support now from four industrial partners under Camiro). The first investigation is into the role of pyrrhotite (Po), the most commonly suspected mineral to trigger self-heating. Following a standard experimental protocol, self-heating was assessed on samples of Po mixed with sand as an inert material. With increasing Po content, self heating progressively increased but, interestingly, the samples visually appeared less and less oxidized. A high Po content, it was hypothesized, may give a more reducing environment favouring formation of H2S. The presence of this gas could be significant as it has a high exothermic heat of reaction with oxygen. The system was modified to test the hypothesis by including copper pieces and copper sulphate to react with (and therefore reveal) the gas as copper sulphide. Evidence is presented in support of H2S production, which to our knowledge has not been shown before and introduces a potentially important avenue of investigation into self-heating mechanisms.INTRODUCTIONSelf-heating of sulphide minerals poses potential environmental and safety hazards in mining of ores, and storage and transport of concentrates. While some conditions are known to be critical, the reactions remain poorly understood making self-heating difficult to predict and control.A major advance in measurement was introduced by Rosenblum and co-workers [Rosenblum et al., 2001; Rosenblum and Spira 1995]. A self-heating assessment method was developed and applied to various sulphide-bearing materials The method is based upon automated calorimetric cells with data acquisition, now available to McGill researchers and which have been used for the study reported here."

Jan 1, 2006

By Stephen Iverson

The National Institute for Occupational Safety and Health (NIOSH) is currently performing research to help mine operators minimize the amount of loose or damaged rock surrounding a blasted opening. Improperly designed blast rounds can result in excessive wall rock damage that may reduce the rock mass competency and increase ground support requirements. Unnecessary blast damage can cause many safety and operational concerns including an increased potential for injury from rock falls and other hazards resulting from sub-optimal blast designs. This paper focuses on the ground control and safety implications of blast damage in underground mines. A reduction in rock quality due to blasting can increase the amount of ground support required. Case study data collected by NIOSH in underground metal mines during standard drill and blast production rounds included blast vibration monitoring, detailed three-dimensional laser scanning of the as-built excavation, and geotechnical mapping of development headings.

Jan 1, 2007

By Wesley Schmutzler

The Deep Mixing Method (DMM) was employed to raise and support the LPV (Lake Pontchartrain and Vicinity) -111 Levee in New Orleans. Even using innovative technologies, the tight schedule to achieve the 100 year elevation by June 1, 2011 was a daunting endeavor. The size and scope of DMM proposed for LPV-111 was on a scale never attempted outside of Japan. Over 1.65 million cubic yards of DMM was installed. LPV-111 is adjacent to the Bayou Sauvage Wildlife Refuge, which is the largest urban National Wildlife refuge in the United States. By utilizing DMM to control settlement and improve stability of the taller levee, side slopes were steepened from the conventional 1V:4H to 1V:2.85H, thus avoiding encroachment into the Bayou Sauvage and reducing the amount of clay needed for the completed levee. The COE utilized Early Contractor Involvement (ECI) for this contract. The ECI process allowed for input from the DMM contractor, TREVIICOS South, in order to optimize equipment resources and material requirements. This paper gives an overview of the extensive DMM requirements for LPV-111 and explains the benefits of the ECI process.

By Gennaro Di Lauro, Laura Meraviglia, Demostenes Efstratiadis, Danilo Coppe

This paper presentation regards the European Union’s project “I.C.E.A. - Identification Colors of Explosives and Blasting Accessories (Agreement number – HOME/2010/ISEC/AG/071 – 30 – CE – 0447240/00-11), submitted under the call for proposal “ISEC 2010 ACTION GRANT” of the “Prevention and Fight against Crime” Program of European Commission. The main objective of the project is to simplify counter-terrorism security measures and the procedures for visual identification of blasting devices.

Jan 1, 2015

By J. D. Miller, C. L. Lin

In the processing industries, it is well known that particle shape is an important factor which determines the behavior of particulate systems. For example, system properties of technological significance including rheology, suspension stability, agglomeration, packing, permeability…etc, are affected by particle shape. In this regard, characterization and analysis of particle shape is essential for more detailed understanding and improved development of particulate processes. In general, it is clear that the behavior of these systems depends on the statistical characteristics of particle shape. Remarkably few techniques exist to predict the mechanical and hydrodynamic behavior of an irregularly shaped particle or a population of irregularly shaped particles for that matter. The lack of models and correlations can be attributed to the wide variety and complexity of particle shapes, the difficulty of defining shape descriptors suitable for modeling, the limitations of measuring shape, and the lack of classifying techniques to characterize particle shape. In this paper, we present information on how 3D particle shape can be measured, characterized, and analyzed using cone-beam X-ray microtomography (XMT).

Jan 1, 2005

By A. B. Cron, R. MacPhail, L. Melis, K. Armstong

"Mt. Milligan is a porphyry gold/copper deposit in north-central British Columbia. Diluted and mineable drill-indicated reserves total 449 million tons at an average grade of 0.013 oz gold/ton and 0.19% copper. Large-scale commercial development of the deposit will make Mt. Milligan Canada's third largest gold mine.Metallurgical investigations for the Mt. Milligan project were done in three phases: scoping tests in the first half of 1989; bench-scale work from October 1989 to April 1990; and a pilot plant program in May and June 1990. Various process alternatives for the recovery of gold and copper are described and results are presented. Net smelter return evaluations led to the selection of optimum process conditions for maximizing revenue from gold/copper flotation concentrates.The selected flotation circuit and basic design criteria are described. Forecast average recoveries over the presently-defined 20-year project life are 75.2% for gold and 90.5% for copper in a copper concentrate averaging 17.6% copper and 1.0 oz gold/ton. 1.0 PROJECT LOCATIONThe Mt. Milligan porphyry gold/copper deposit is located in northcentral British Columbia, 150 km north of Prince George, British Columbia. The site is at an elevation of 1,100 m in an area of logged, gently-rolling topography. Nearby communities include MacKenzie and Fort St. James. Climate in the area is moderate and there is direct road access to the property. A location map is presented in Figure 1-1."

Jan 1, 1991

By H. S. Rathor

NTPC (National Thermal Power Corporation), a multi-unit organization, is generating 26% of India’s total power. This power is produced from its 14 coal based stations and 7 gas based stations. NTPC is entering into the business of power-distribution, power-trading, setting up of coal mines and diversification in non-conventional energy sector as well. For achieving the goal of the country “Power for All” NTPC has taken a giant stride by entering into Hydro Power generation which is also the cheapest and the cleanest renewable source of energy. In its pursuit for excellence, 800 MW Koldam Hydro Power Project is NTPC’s first venture in hydro sector. In Koldam, hydropower potential will be harnessed by constructing a 163m high earth and rock fill dam in a narrow gorge at upstream end of Bhakra reservoir. The river diversion is envisaged through two parallel, 14m finished diameter ‘horseshoe’ tunnels of length 901m and 934m at village Kian on the right bank, where the river forms a 180° loop. The diversion tunnels are designed to accommodate a flood of 6500m3/sec, taking into account the maximum probable discharge of 200 years return period. The tunnels pass through dolomite and limestone rock formations. The excavation of tunnels was done with drill and blast method. The excavation was attempted from both inlet and outlet faces. During geological investigation a rock fault was located at the outlet area. The location of the fault was such that it was passing through the edge of the Tunnel-1portal and around 30m away from the face of the Tunnel-2 portal. The quality of the rock at Inlet was also poor. To save the portals from slips, excavation of the tunnels was planned to start after the completion of the open excavation and its support system both at inlet and outlet. The tunnel excavation at inlet was envisaged by approaching the tunnels’ portal by constructing a road through 540EL bench and meeting the inlet portals on the upstream end, which would have been ready by mid2003, only after completion of the open excavation and its support system. To save time and cost, it was felt necessary to modify the planning by starting the tunnel excavation simultaneously along with open works both at inlet and outlet. The excavation at the inlet face of the tunnels started in December 2002 after rerouting the approach road to inlet portals through haulage road on the downstream and similarly Tunnel-1 at the outlet was started in the low cover area before completion of open area works. Thus the tunnel—heading excavation was started nearly 06 months early with the change of methodology.

Jan 1, 2005

By S. R. Noble, F. R. Harris, E. T. C. Spooner

"The Logtung deposit discovered in 1976, is an example of large tonnage (162 million tonnes), low grade (0.13% WO3 and 0.052% MoS;) W(scheelite)-Mo mineralization related to multiple felsic intrusions. Because mineralization is predominantly fracture-controlled (> 95 %) rather than disseminated, Log tung is not a skarn deposit. Metamorphism of the Logtung country rocks (interbedded calcareous shale and graphitic quartizite) to a series of competent reaction skarns (quartz-diopside-garnet calc-silicate, biotite quartzite and wollastonite-vesuvianite calc-silicate) clearly precedes W-Mo mineralization. Hence mineralization was related to permeability created by hydraulic fracturing and not replacement processes.Logtung shows a theme of several phases of mineralization (4) related to multiple intrusions (>2) which is similar to that of the Climax and Urad-Henderson Mo systems. The earliest quartzmolybdoscheelite vein system, which consists of a typical ""porphyrystyle"" crackle-breccia of thin (0.5 mm to 4 mm) quartz-garnetdiopside- molybdoscheelite veins, is related to a high Si02 (approx. 76%), seriate-porphyritic monzogranite stock (approx. 2 km by 0.5 to 1 km) of Cretaceous age (118 ±2 Ma [2u]; Stewart, 1983). Later quartz-pyrite scheelite (fluorite-KINa-feldspars-molybdenite) veins, with prominent green, hornblende-bearing alteration selvages, and quartz-molybdenite (-pyrite-jluorite-scheelite) veins are related to a quartz-feldspar-spessartine-rich garnet porphyritic felsic dike complex approximately 500 m across. Both intrusive phases have anomalously high Wand Mo concentrations of about 100 ppm and 50 ppm respectively, which Stewart (1983) attributes to a primary enrichment. The final stage of mineralization consists of a prominent 4.5 km by 1 km zone of 1 em to 1 m wide polymetallic sheeted veins centred on the felsic dike complex. The system is zoned from quartz scheelite-molybdenite-pyrite-blue-green beryl-jluoritebismuthinite veins in the core to Pb-Zn-Ag veins with abundant arsenopyrite and minor Sn (approx. 0.1%) in the northeast. The focus of recurrent intrusive and hydrothermal activity was located above a flank or nose of the monzogranite stock.The distribution of WO3 and MoS2 grades within the approximately 750 m (across) by 300m (evaluation depth) mineralized zone is a result of the variable superimposition of the four separate vein systems each with different W:Mo ratios. Well-defined Wand Mo ore, shells such as those at Climax, Henderson and Mt. Emmons did not develop at Logtung. The upper surface of the mineralized zone, as shown by the 0.03% MoS2 contour defines an elongate dome with an apical region approximately coincident with the felsic dike complex. Hydrothermal alteration occurs as well-defined vein selvages, and not as pervasive zones.The Logtung deposit shows many similarities to porphyry Mo deposits in the western Cordillera and may be identified as a porphyry W(scheelite)-Mo deposit, with a W:·Mo ratio of 3.3:1. The principal reasons are: (1) mineralization is spatially associated with porphyritic granitic intrusions and (2) much of the scheelite and molybdenite occurs in typical ""porphyry-style"" vein stockworks"

Jan 1, 1995

Ferrochrome is the major chromium source for stainless steel production, and submerged-arc furnaces (SAF) are most commonly utilised to smelt chromite ores into ferrochrome by using suitable carbonaceous reductants such as coke. Because of the complexity of feed structure and electrical-thermal-chemical interactions, there exist large gradients and wide distributions of temperature, mineralogy and other process variables in the furnace. This leads to various zones in the furnace, and different reduction mechanisms. Control of the furnace is thus often difficult due to the complicated physical and chemical situations in the furnace. The temperature profile in the submerged arc furnace has a great influence on the reduction rate and the production efficiency. Therefore, the energy generation through electrical arcs submerged in the solid feed and its distribution within the packed bed play an important role. In the present paper, an overall process model is illustrated to simulate inter-linked transport processes of fluid flow, heat transfer and reduction kinetics within the submerged arc furnace. The application of reaction kinetic data to simulate the chromite pellet/lumpy ore reduction with CO gas is presented and further adjusted to provide a submodel for a flow and heat transfer simulation for the packed bed by using computational fluid dynamics (CFD) technique. The comprehensive process model is aimed to simulate materials and gas flow, temperature and energy distribution throughout the furnace system. A preliminary model for gas flow and temperature distribution for the upper part of a 20 MW furnace (the packed bed) for high carbon ferrochrome production has been developed under simplified conditions. The integration of the reaction kinetic model into process simulation, and the future vision for a more comprehensive process modelling are discussed. It is expected that better understanding of the furnace insights through process modelling will help process optimisation and furnace control.

Jan 1, 2004

By T. Lindstad, S. Gaal, S. Hansen, S. Prytz

The SINTEF SiO-reactivity test, developed by Tuset and Raaness in the 1970?s, is a recognised method of characterising the ?reactivity? of carbonaceous reactants, used in the ferrosilicon and silicon metal industries. Recently, the test has been updated, which has resulted in the development of an extended and improved SINTEF SiO reactivity test. This has included updating the test reactor, control system, data-logging, handling and preparation of carbonaceous materials to be tested and measurement procedure. The scientific basis has been re-assessed, resulting in a new interpretation of the test results. The repeatability of the test has improved significantly, especially through system automation. In the ?old? test, the kinetics of the reaction: SiO(g) + 2C(s) = SiC(s) + CO(g) for a specific carbonaceous material was characterised solely by the ?R10? parameter, the volume of SiO(g) which passes un-reacted through the coke-bed as the concentration of CO in the outlet gas decreases from 18 to 10%. As both the kinetics and obtainable conversion of SiO to SiC for a reductant is of importance to the ferroalloy producer, the new SINTEF SiO reactivity test ranks carbon materials both according to degree of conversion and reaction rate. From research carried out on the test in the past couple of years at SINTEF and NTNU, it has also become clear that some of the reactions taking place in the test reactor are more complex than previously assumed. As an example, it was previously assumed that the condensation reaction of SiO gas in the condensation chamber of the test reactor can be described as: 2 SiO(g) = Si(l,s) + SiO2(s). However, it has been established that the side-reaction: CO(g) + 2Si(l) = SiC(s) + SiO(g) causes approximately 10% of the total volume of CO to react to SiC and SiO2 in the condensation chamber. This means that some back-reaction i.e., the reverse SiO-generator reaction 3SiO(g) + CO(g) = 2SiO2 + SiC also takes place in the condensation chamber. In the new SINTEF test, the %CO versus time curves are therefore corrected in order to describe the effect of the reaction between SiO(g) and C(s) studied i.e., SiO(g) + 2C(s) = SiC(s) + CO(g). A correction-formula for this purpose is presented.

Jan 1, 2007