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By P. C. Miller

The paper reports laboratory results from the bioleaching of chalcopyrite ores and concentrates using a mixed moderate thermophile culture. Copper dissolution in excess of 95% was achieved in all cases with the majority of tests indicating copper dissolution in excess of 98%. Aspects of downstream processing are discussed in relation to iron rejection by precipitation. The laboratory results indicate the need for careful control of the pH value to prevent co-precipitation of the copper with iron. A comparison of capital and operating costs is given indicating potential differences between the use of toll smelting and bacterial leaching on site. A discussion is given highlighting the sensitive cost areas of these two process routes.

Jan 1, 1997

By R. D. Irwin, W. M. Mullins, E. A. Medina

"Various stability criteria are introduced and thermo-kinetic models for metallurgical processes are used as concrete examples for evaluation. Kinetic criteria for the process of dynamic recrystallization are proposed. These criteria are compared to the non-equilibrium thermodynamic approaches discussed in the literature. The application of macroscopic stability criteria to materials processing is then discussed.IntroductionThe mechanical behavior of metals at elevated temperature is very well predicted by any of several empirical constitutive relations. Typical is the power-law (or Swift's) form,Equationwhere r-is the stress, y is the strain and m, n , t0, y0 and Q are material constants. This form has been used with some success in the metals processing area [1]. In general, though, all of the empirical constitutive equations are static, failing to account for any dynamical properties of the system they seek to describe.The physics of warm deformation is qualitatively well understood. An example is power-law creep, where the dominant mechanism is assumed to be lattice diffusion limited climb of dislocations, which allows the strain-rate to be determined by the applied stress through"

Jan 1, 1997

By Chuck Edwards

"The development of two large, high-grade uranium projects has been proposed for northern Saskatchewan. The projects are now under review by a joint federal/provincial panel. The McArthur River project is owned by the McArthur River joint venture (Cameco Corporation 53.991 %, Uranerz Exploration and Mining Limited 29.775%, Cogema Resources Inc. 16.234%) and operated by Cameco. Cameco proposes to mill the McArthur River ore at the existing Key Lake mill. The Cigar Lake project is owned by the Cigar Lake joint venture (Cameco Corporation 48.75%, Cogema Resources Inc. 36.375%, Idemitsu Uranium Exploration Canada Ltd. 12.875%, Korea Electric Power Corporation 2.000%). The Cigar Lake joint venture proposes that Cameco operate the Cigar Lake mine for the owners, and that Cogema mill the ore at their McClean Lake mill, now under construction. Proposed systems provide safe mining and ore handling, and allow the milling of McArthur River ore at Key Lake and Cigar Lake ore at McClean Lake. This avoids the disturbance of new sites for milling and tailings disposal.The McArthur River and Cigar Lake deposits are the largest known high-grade uranium deposits in the world. The ore grades at McArthur River and Cigar Lake are at least 100 times those that are mined elsewhere. It is proposed to mine these deposits using remote underground mining methods, to crush and grind the ore underground, to pump a thickened ore slurry to surface, and to transport it in special containers by truck to the mills.During all mining and processing stages the ore is fully contained. Radon emission is controlled by positive ventilation of all process vessels, with the process ventilation backed up by the primary mine ventilation system. Radiation is controlled by heavy steel pipe and vessel walls, concrete walls and sometimes lead sheeting."

Jan 1, 1997

By G J. Corbett, P Magner, M McKenzie

Structures formed during ductile deformation have been reactivated during the later brittle mineralisation process. Two generations of folding are classified as: early recumbent megascopic FI folds and FI shears which transpose the hinge regions, and later upright F2 folds. S1 is folded about F2 folds which contain axial planar S2 crenulation cleavage. Vergence relationships between S1 and bedding indicate that many of the mineralised structures occupy sites of FI folds which have acted as plumbing systems for later gold mineralisation (eg Blackwater mine). The Globe-Progress gold mineralisation is localised by a major jog formed by sinistral strike-slip movement on two FI fault segments and mineralisation also occurs in smaller jogs along strike (eg Sir Francis Drake, Happy Valley-Merrijigs, Cumberland).   The lodes of ribbon quartz which exploit the FI shears and local bedding planes, are inferred to have mostly formed after the peak of metamorphism, possibly related to the emplacement of Carboniferous granites. This was followed by a sequence of vein deposition and wallrock alteration which consists of quartz-As/Fe sulphides ? carbonate - stibnite ¦ trace base metal sulphides and Bi-sulphosalts ? illitic clay/sericite-chlorite. Gold at Globe-Progress is mainly encapsulated in arsenopyrite. At Blackwater, free high fineness gold occurs in partings in lode quartz with late sericite-chlorite. The above sequence of events is comparable to that encountered in many intrusion-related gold systems throughout the Southwest Pacific region. There is a spatial relationship between gold mineralisation and dykes variably described as diabase, dolerite or lamprophyre. Alkaline rocks occur in many Pacific rim and older goldfields and may possibly be related to a magmatic source for gold mineralisation.

Jan 1, 1997

By Jr. Watts, B. K. Cantrell, K. L. Bickel, J. F. McDonald

"A field trial was conducted at an underground gold mine to evaluate diesel fuel derived from soybean oil (soy-methyl-esters or “biodiesel”) as an alternative to commercial, low-sulphur, number 2 diesel fuel (D2). A 2.7 m3, 18-ton load-haul-dump (LHD) unit, powered by a naturally aspirated, indirect injection (pre-chamber), 100 kW diesel engine was used as the test vehicle. The LHD was equipped with a diesel oxidation catalyst. The LHD operated satisfactorily on the biodiesel fuel. Operators observed a slight decrease in power and an absence of black smoke.Diesel particulate matter (DPM) concentrations were monitored for a six-week period while the LHD was operated with either the biodiesel fuel or the D2 fuel. DPM concentrations were measured in the mining section’s clean air intake, exhaust and on the LHD. Reduction in DPM emissions was determined from the measured difference in DPM concentrations between the clean air intake and the exhaust. The biodiesel fuel reduced energyspecific DPM emissions approximately 75%, from 3.6 ± 1.8 g/kW-hr to 0.86 ± 0.27 g/kWhr. Time-weighted average DPM exposure, measured near the LHD operator, was reduced from 0.67 ± 0.13 mg/sm3 to 0.28 ± 0.12 mg/sm3, or approximately 58%, when the biodiesel fuel was used. IntroductionDiesel exhaust consists of noxious gases and diesel particulate matter (DPM). Recent attention has focussed on the potential carcinogenicity of DPM and the potential health impact on miners. The National Institute for Occupational Safety and Health (NIOSH) recommended that whole diesel exhaust be regarded as a “potential occupational carcinogen”, and that reductions in workplace exposure would reduce cancer risks (NIOSH, 1988). The International Agency for Research on Cancer (IARC) declared that “diesel engine exhaust is probably carcinogenic to humans” (IARC, 1989)."

Jan 1, 1997

By Stephen L. Chryssoulis

"""Preg-robbing"" of gold by carbonaceous matter during the cyanidation of certain types of carbonaceous gold ores is well documented. Recent studies established that ""preg-robbing"" of gold is not limited to carbonaceous matter. Gold sorbed on the surface of pyrite grains was detected and quantified by TOF-LIMS (Time of Flight Laser Ionization Mass Spectrometry). Crystallites of pyrite from a number of ores from different geological environments have been shown to have gold on their surface apparently sorbed from the ore forming solutions. Surface gold accounts for significant fractions of the gold head assay. Preg-robbing of gold by pyrite from pregnant cyanide solutions was also documented, and accounts for significant losses to tailings. Preventative measures are discussed.1.0 IntroductionThe detection and subsequent quantification of gold sorbed on the surface of pyrite particulates came about during routine determinations of the deportment of gold employing the comprehensive mineralogical approach (Chryssoulis and Cabri, 1990). In some pyritic gold ores it was discovered that the sum of the various forms in which gold ""conventionally"" occurs, was short of the gold assay. The mineralogical procedure used involves the independent determination of each fraction of gold, in other words there is no form of gold which is calculated ""by difference"". The systematic shortfall after having added the forms of gold listed in Table 1 led to the inquiry for the 'missing' gold and its discovery on the surface of pyrite grains, such as crystal facets and fractured surfaces.Preg-robbing of gold by pyrite from pregnant solutions was first described by Lloyd. In his studies, preg-robbing was measured by changes in the solutions/solids gold assays. This paper describes the first application of a direct measurement method for surface gold on pyrite particles from untreated and processed samples, its impact on gold deportment and processing. The advantage of the direct measurement lies in the absence of interference from other forms of gold, leading to more accurate and precise determinations of this unconventional form of gold."

Jan 1, 1997

By I. J. Moon

The reduction behavior of hematite by H2 and H2-CO gas mixtures was investigated to elucidate the reduction mechanism at 800-950 °C. The hematite compacts were made by Cold Isostatic Pressing to produce compacts of uniform shape and size. The compacts were sintered at 1000° C for 30min, and showed a contraction of 29%. Mercury pressure porosimeter was used for measuring the total porosity, pore size distribution and pore surface area of the compacts. Reduction was measured by means of weight-loss technique using Cahn Balance (Model : TG-171, capacity log, accuracy f 10pg). Microscopic examination and X-ray analysis were used to correlate the structure of reduced compacts with the mechanisms of reduction. Neither chemical reaction control nor diffusion control is adequate in describing the complete course of reduction of the hematite compact. The reduction of hematite compacts was initially controlled by the chemical reaction at oxidelmetal interface. The reaction goes through a transition phase .where it is undergoing a mixed control, followed by the diffusion control towards the end of the reduction. The values of apparent activation energies for chemical reaction control were 3.48-8.43 kcal/mol depending on the gas compositions.

Jan 1, 1997

By Michael F. Roach, Joseph K. Cavey, Gary E. Taylor

A rigorous horizontal drilling and chemical grouting program was specified beneath the Hollywood Freeway (U.S. Route 101) section of Los Angeles Metrorail Contract C-311.Twin 6.67-m (22-ft.) diameter starter tunnels were to be conventionally mined through amixed alluvial and bedrock face consisting of silty sand, gravel, and weathered sandstone and siltstone of the Topanga Group. The contact between the alluvium and bedrock dipped toward the Crossover Excavation where the horizontal drilling and grouting operations were performed. The intent of this grouting program was to stabilize the mixed face to minimize ground loss and surface settlement, and to reduce groundwater inflow into the tunnel headings. Given the highly variable mixed face conditions, horizontal drilling up to 86 m (284 ft.) resulted in upward trending trajectories which likely followed the bedrock contact. Chemical grouting was performed in a primary, secondary and tertiary, three dimensional sequence. Evaluation of the primary and secondary grouting parameters indicated where tertiary grouting was required. Grouting pressures induced a small rock failure at the tunnel heading as well as increased stresses on the tiebacks of the excavation.

Jan 1, 1997

By Rudy Tenbergen, Dick Farmery, Jim Naylor

"Paste backfill has replaced cemented rock fill as one of the components to improve ground · control and mine safety at the Macassa Operation of Kinross Gold Corporation in Kirkland Lake, Ontario. It is the first operation to utilize "" flash thickening ""of very fine gold tailings to a paste consistency in the ""Paste Production and Storage Mechanism"", a joint technical development of Inco and GL&V. The tailings paste is mixed with alluvial sand to produce an engineered quality paste backfill. The development leading up to the decision to proceed with this novel technology is discussed, as well as commissioning of the backfill operation.IntroductionThe occurrence of a major rockburst on November 23, 1993 prompted a review of mining and backfill procedures at the Macassa No 3 shaft . This shaft is some 7238 ft deep and lies in a mining belt that is prone to seismic events. The recommendations were to change the mining from underhand cut and fill to mechanized long hole stopping and to look at alternatives to the rockfill backfill system in place. The Macassa cemented rock backfill operation, while producing the desired fill stiffness had drawbacks as compared to paste fill. With paste fill, placement rates are faster, more openings can be filled, it is less expensive and less prone to the occurrences of compensable incidents.Macassa mining personnel visited the Sudbury operations of Inco in 1993, where development on paste backfill was in progress. As some of the R&D was taking place with funding from the Premier's Council Technology Fund of the Ministry of Trade and Technology of the Province of Ontario , Inco personnel at that time did some feasibility and conceptual consulting on the use of paste fill for the industry. Inco had developed the use of alluvial sand paste fill, an engineered blend of alluvial sand and tailings fines and was doing development work to eliminate the ""conventional"" way of producing paste from mill tailing by thickening and filtration. This latter development work was taking place with GL&V Ontario. That work led to the filing of a joint Inca/ GL&V patent application for the PPSM, the Paste Production and Storage Mechanism with all marketing rights being held by GL&V."

Jan 1, 1997

By Michael L. Maniocha

Most magnesia (MgO), whether of natural or synthetic origin, is used in the dead-burned or periclase form as refractory linings for the production of steel. Continued research in refractory science, combined with good refractory maintenance and improvements in steel-making processes, have resulted in decreased use of magnesia. To make up for this loss of business, producers of synthetic magnesia have started to manufacture a variety of magnesium-based chemicals that are used in many industries. There are three primary methods of producing MgO. The first involves the calcination of naturally occurring minerals species. Most of the magnesia produced by this method uses the rhombohedra1 carbonate mineral magnesite, MgCO,. To a lesser extent, the mineral brucite, Mg(OH), is calcined to magnesia. Magnesia produced by the calcination of minerals is called natural magnesia. The second production method uses magnesium-rich brines, or sea water reacting with lime or calcined dolomite to produce magnesium hydroxide. The magnesium hydroxide is subsequently calcined to magnesia. Material produced in this way is called synthetic magnesia. The third major method of production uses saline lake brines to produce magnesium chloride. Magnesium chloride brine is sprayed into a reactor where it thermally decomposes into MgO and HCl. The magnesia is purified by slaking to magnesium hydroxide followed by calcination. Magnesia produced in this manner is also know as synthetic magnesia (Duncan and McKracken, 1994). The degree to which the magnesium minerals or the synthetically prepared magnesium hydroxide is calcined governs the physical properties of the resulting MgO. It is the physical properties that dictate the end use for the product. The terms used to describe magnesia vary along with the degree of calcination. Table 1 summarizes the terminology used when discussing the various forms of magnesium oxide.

Jan 1, 1997

By Felicia F. Peng

Employing the combination of two types of polyelectrolyte might become necessary to enhance both settling rate of the flocs and water clarity of fine particle suspension in high capacity thickening process. The sequence of addition, mixing, type and dosage of polymer affect the overall performance and capacity of a thickening process. For the sedimentation of copper flotation tailings, the cylinder test results showed that two different techniques may be used to achieve the required performance including high settling rate of flocs, underflow density and overflow water clarity, by either adjusting pH prior to anionic polyelectrolyte flocculation, or using a combination of polymer flocculant and coagulant (dual polymer system). The dynamic thickening testing results showed that only the approach using a dual polymer system is able to meet the required performance. The effects of polyelectrolyte dosage, the sequence and numbers of polyelectrolyte addition, feed concentration, bed level and rake speed on the settling rate, underflow solid, and water clarity were studied in cylinder test and a laboratory dynamic thickening unit with various conditions related to the thickening process. The dynamic test is especially valuable in evaluating the addition and mixing of polymers. The results were evaluated quantitatively, using total suspended solids in supernatant, underflow density and capacity per unit settling area per unit time as the measure of effectiveness. The objective of this study is to quantify and explain some of the parameters involved in the sedimentation of copper flotation tailings.

Jan 1, 1997

By Harry L. Siebert

A major Arizona highway project is jeopardizing site safety and security because of the lane rental policy. One million cubic yards of rock must be fragmented to provide two additional lanes parallel to the existing roadway. Traffic is stopped during blasting operations.

Jan 1, 1997

By David R. Ziegler

The concept and facts concerning "threshold blast damage" are not considered "general knowledge". Perhaps because of a lack of knowledge, understanding, and experience of blasting effects, property owners and lay-persons may attribute a wide range of common cosmetic conditions to "blasting damage".

Jan 1, 1997

By B. R. Stewart

The exclusion of coal fly ash from regulation as a hazardous waste has led to increased interest in returning ash to the coalfields for co-disposal. A multi-year column study used coal refuse with high potential acidity (4% total-S), and two alkaline ashes in various bulk-blends. The unamended refuse acidified rapidly, producing acidic (pH 1.7) leachates, high in dissolved metals. Treatments blended with sufficiently high amounts (20 to 33%) of alkaline ash produced alkaline (PH >8.4) leachates with low metal levels, while lower ash blending rates acidified over time to produce metalliferous leachates. Examination of solid materials indicated that pyrite oxidation was occurring to some extent in all treatments. A regression equation (r = 0.95) was developed to estimate time to net acid release for mixtures of these materials. Ash alkalinity and refuse potential acidity must be balanced to insure water quality for co-disposal environments, or the ash materials should be isolated away from acidic drainage waters.

Jan 1, 1997

By T. I. Urbancic, C-I. Trifu

"ABSTRACTSeveral case studies are presented on the use of seismic techniques to map active structures, evaluate changes in stress levels, and identify the conditions leading to large magnitude seismic events and the generation of rock-bursts in Canadian mines. The results suggest that microseismicity can be used to identify the orientation of active fractures; define regions of relatively high and low stress, and those most likely to host a rockburst; determine the role of local stress on observed shear failures; and identify the path of stress transfer associated with the remote triggering of rockbursts. Additionally, the conditions leading to rock-bursts can be characterized by a significant increase in the clustering of microseismic events along the fault plane orientation of an impending event, and an increase in the effective stress levels. It is concluded that the analysis of microseismicity provides the means for remotely monitoring rock mass behaviour as a result of mining."

Jan 1, 1997

Allis Mineral Systems' Grate- Kiln system can economically convert low-grade iron ore into high- grade iron-ore pellets suitable as feed material for blast furnaces for making steel. These pellets can also be fed to a direct reduction process for making sponge iron. The Grate- Car system combines the company's [ ] Grate-Kiln system for iron-ore pelletizing and Accar system for iron- ore reduction. The Grate-Car system consists of a traveling grate, a ported rotary kiln and a rotary cooler that are coupled in series. This system eliminates the pelletizing plant's rotary kiln and annular cooler. It reduces the need for some auxiliary equipment. This results in lower capital cost and lower energy consumption. The traveling grate provides that static bed handling necessary for heat hardening pellets before their discharge into the kiln. The ported kiln provides the reducing atmosphere with a more precise means of controlling the kiln axial temperature profile than conventional rotary kilns.

Jan 1, 1997

By N. T. Rempe

The underground voids that result from mining provide opportunities for deep geologic waste disposal (DGWD). Such disposal could solve many environmental problems. DGWD takes careful planning, technology transfer and true partnership between waste generators and mine/repository operators. The US government is now planning on using specially mined excavations to dispose of radiotoxic and mixed waste. Using the experience gained from the domestic projects that are now in preparation and from foreign repositories that are now in operation, US mines can claim their rightful share of the growing market for DGWD.

Jan 1, 1997

By Edward J. Cording, William H. Hansmire

INTRODUCTION The Washington Metro, a rapid transit system that will serve the District of Columbia, Virginia, and Maryland, has been under construction for about two years. Construction of the Metro by the Washington Metropolitan Area Transit Authority involves a large amount of cut and cover, soil tunnel, and rock tunnel construction. To aid initial construction and improve future designs, performance observations were undertaken on tunnels in the initial construction phase. The University of Illinois Department of Civil Engineering was engaged to carry out a comprehensive program of field observations and measurements for this purpose. One part of the program was on the first soft ground tunnel constructed in the system. The tunnel is a 2200-ft (670 m) twin-bore section, designated Contract A-2, in downtown Washington. Two objectives of this program were to determine the relationship of construction procedure to settlements and to observe the pattern of soil movement around the tunnel as an aid in evaluating underpinning criteria for nearby structures. A test section, consisting t three instrument lines located across the tunnel path, was established prior to mining in Lafayette Park to measure in detail both vertical and lateral soil displacements as the tunnel was mined through the section. The site was selected because it is free from surface structures and access for installation and reading of the instruments was convenient. Load and distortion measurements on the lining were also made within the test section; observations of construction procedure were maintained throughout construction.

Jan 1, 1997

By Ralph Harris, Qi Xia

"Gold cyanidation rates are known to be limited by the rate of oxygen dissolution in the cyanidation tanks. The effect of solids loading on the oxygen dissolution rates is not obvious and the results of previous studies are ambiguous. The present paper presents an analysis of oxygen dissolution rates using a ""spent"" commercial gold slurry diluted to various levels of solids loading. It was found, in an 170 litre stirred tank reactor using an inverted cone sparger, that under certain high loading conditions, there was a decrease of as much as 50 %, i.e., there was a halving of the rate of oxygen dissolution as compared to that in clean water. In particular, it was observed that, due to gas flooding of the impeller, there was a drop in kLa even with an increase of gas velocity. Gas holdup reached a maximum value of only 1.7 %. The total power consumption was between 0.06- 0 .10 kw/m3 within the range of gas velocity before flooding occurred. The decrease in oxygen dissolution rate with increased solids loadings is believed to be mainly due to the increase in the apparent viscosity which reduced the turbulence and shearing effect and resulted in larger bubbles and hence reduced the reaction area a. The interrelations between solids loading, gas holdup, flow pattern, power consumption, and liquid mass transfer coefficient are discussed.IntroductionThe reactors generally used in gold cyanidation are Stirred Tank Reactors (STR). Compared with other types of reactors like fluidized bed reactor and column reactor, STR is of particular importance due to its wide application in industry. It is reported that the stirred tank reactor is used for more than 50 % of the world's chemical production (Xu and McGrath, 1996)."

Jan 1, 1997

By William S. Heckman

a. When to use: high surcharges, vertical capacity required, limit noise and eliminate vibrations, low headroom, eliminate vibration induced settlements. b. Advantages: eliminates impact noise and vibrations, high section modulus if required, vertical load bearing capacity; corrosion resistant, easy to apply facing for use as a permanent wall, adapts to complex wall layouts, would allow top- down construction, very high uplift resistance. c. Disadvantages: spoil disposal, not water tight, cannot penetrate rock and most obstructions, soil can erode between the piles if surface water and ground water are not controlled, hard to install reinforcing beams over 409 long; subject to high negative skin friction loads, high grout takes in rubble and organic soils. e. Relative cost to other systems: 30% to 50% more expensive than driven soldier piles and lagging except when surcharge loads are involved, or the pile cannot be driven due to noise and vibrations. About the same cost as a sheet pile system. Very competitive if high vertical load must be supported by the wall.

Jan 1, 1997