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By Peter Duniam, Stephen John Brace

2000 HIGH-TECH SEMINAR Blasting Technology, Instrumentation and Explosives Applications Orlando,Florida,USA July24-27,200O. Objectives:- After completing this session 1. Explain safety issues 2. Do simple initiation design 3. Describe how the system works 4. Demonstrate scanning, hookup, testing and firing 5. Describe hot to do a post blast check 6. Explain how to treat misfired detonators

Jan 1, 2000

By Fiona J. Stevens McFadden, Gregory J. Hardie, Mark P. Taylor, William Uru

"Over 20 million tonnes of installed aluminium smelting capacity exists worldwide, with smelter energy con.sumption in the range 14-17 kWh/kg aluminium. In terms of the reduction cell technology itself, the lowest sustained energy consumption is just below 13DC kWh/kg, or 50% energy efficient.For 15 years Comalco Aluminium Ltd. in Australia has been engaged in developing and testing reduction cells that use a refractory hard cathode, composed of a TiBif carbon composite coating over a carbon cathode. This technology has the potential to reduce energy consumption significantly while simultaneously increasing the life of the cells, which is currently limited by wear rate of the conventional carbon cathodes used throughout the worldIntroductionThe successful development of an aluminium wettable cathode technology affords the opportunity to the cell designer and smelter operator to fundamentally change the physical operating characteristics of the Hall-Heroult process. With this revolutionary capability in hand, published papers and patents have indicated that the technology may be exploited in a wide variety of ways to improve the economic performance of aluminium smelting process. Comalco has been developing refractory hard cathode technology for more than 15 years and has been exploring a number of ways that the technology may be commercially applied in a smelter operation [l]."

Jan 1, 2000

Zircon producers are often required to lower impurity levels to meet customer specifications as most of these impurities adversely effect the end use. For example, zircon sand in foundry applications needs to be free of any surface impurities (eg clay, gibbsite and goethite) which otherwise could cause sintering or fusion between cast metal and the zircon mould. Light coloured ceramic grade zircon, typically low in iron oxides and titania, is preferred in ceramics applications. The presence of impurities in zircon sands is a problem in the magnetic and electrostatic separation stages of their concentration. Previous work (Aral et al, 1997) showed that impurities in zircon sand concentrates occurred in the form of stains on grain surfaces, discrete gangue minerals and in the mineral grains. The gangue minerals such as rutile, garnet, xenotime, monazite, spinels, ilmenite, and aluminium silicates in the concentrate in some cases (Aral et al, 1997) contribute significantly to the impurity content of the concentrate. A careful hand picking of the impurity grains from a Western Australian zircon sand showed that the impurity content of the concentrate could be lowered significantly as a result of the removal of the surface stained grains and gangue minerals. The hand-picked ædirtyÆ fraction, comprised about eight per cent by weight of the concentrate, and consisted mostly of iron-oxide/hydroxide-stained zircon, silica grains and rutile, and occasionally ilmenite, monazite, gahnite and other (unidentified) coloured grains. The chemical analysis of the remaining æcleanÆ fraction showed that the major impurities (Fe and Ti) were reduced significantly (Table 1). The reduction in the uranium content was about 30 per cent. The other measured impurities, P, Mg, Al, Th, and Ca remained mostly unchanged as shown in Table 1. The contribution of ilmenite to the overall iron content of æcleanÆ zircon was insignificant as it comprised about 0.1 per cent weight of the æcleanÆ zircon. Rutile was the major source of titanium contamination (about one per cent by weight). Recent work (Aral and Calle, 1999) on zircon sand concentrates from the Murray Basin showed that, under the electron microprobe, the bulk of the impurities occurred in the dark back scattered electron (BSE) regions of the zoned zircon grains. The impurity contents of the light BSE regions and unblemished (unzoned) grains were low. The impurity content in zoned zircons has been investigated on single, relatively large, crystals (McLaren, Gerald and Williams, 1994; Smith et al, 1991; Romans, Brown and White, 1975). These studies generally aimed to investigate the incorporation of U in zircon as zircon is used extensively for U-Pb geochronology owing to its relatively high content of uranium. Smith et al (1991) identified a striking difference in composition between the areas of lower (dark BSE) and higher (light BSE) average atomic number in the zoned zircon. Their work showed in particular that the zones of lower atomic numbers contained very significant amounts of trace metals such as Y, REE, Nb, U, Al, Fe, Ca, Ba and, by difference H2O. In this paper the impurity distribution in zoned zircon grains was investigated on statistically significant number of grains before and after a leach treatment. The distribution of impurities was also measured in unblemished areas to compare the results.

Jan 1, 2000

By Steve Kral

The mining industry in Colorado faces the same problems the industry faces throughout the United States and the world — record low commodity prices and increasing regulatory and environmental restrictions that seemed designed to curtail mining activities. Despite those obstacles, the mining industry in Colorado still contributes about $8 billion annually to the state’s economy in the form of base and precious metals, industrial minerals, coal and associated service businesses and jobs. So the 300 attendees at the102nd National Western Mining Conference felt reason-ably positive about the industry in their state. The meeting is the Colorado Mining Association’s annual conference and was held at the Broadmoor Hotel in Colorado Springs in November. The theme was “Mining in the New Millennium — Achievement + Innovation = Survival.” Experts from Colorado’s mining industry and abroad discussed the challenges faced by the mining industry as it enters the new millennium. They offered insights into how the industry will operate during the early years of the 21st century and how it will survive low prices and increased regulatory restrictions.

Jan 1, 2000

By Heikki Laurila, Sirkka-Liisa Jämsä-Jounela, Jarkko Karesvuori

"Artificial Intelligence includes excellent tools for the control and supervision of industrial processes. Several thousand industrial applications have been reported worldwide. Recently, the designers of the A1 systems have begun to hybridize the intelligent techniques, expert systems, fuzzy logic and neural networks, to enhance the capability of the A1 systems. Expert systems have proved to be ideal candidates especially for the control of mineral processes.As successful case projects, an expert system based on on-line classification of the feed type using neural data analysis is described in this paper. The essential feature of this expert system is the classification of different feed types and their distinct control strategies at the plant. In addition to the classification, the expert system has a database containing information about how to handle the determined feed type. This self-leaming database scans historical process data to suggest the best treatment for the ore type under processing. The system has been tested in the Outokumpu Finnmines Oy, Hitura mine. Other projects have been reported to be in progress.INTRODUCTIONIn the past ten years considerable researches have been done in the application of artificial intelligent methods in process industry. The technologies of fuzzy logic, neural networks and expert systems have received several thousand applications worldwide: monitoring and analysis of process operations, fault diagnosis, supervisory control, feedback control and scheduling and planning of operations. Recently, the designers of these systems have begun to hybridize these intelligent techniques to enhance the current capability of expert system. Complex signal processing, neural networks, fuzzy logic and rule-based systems are also implemented to develop new so-called smart or intelligent sensors, actuators or components. Field buses are playing a more and more important role in automation systems and in imbedded systems. The development of field buses has allowed the distribution of smart components over networks."

Jan 1, 2000

By Philip J. H. Ball

The new application and development of grout jacking processes has combined, over the last decade in particular, to provide a method by which the effects of new underground construction on superficial structures can be controlled to acceptable levels. This paper sets out the basic principles, processes and limitations of compensation grouting. It describes key elements of the philosophy and design and details the control systems required to perform satisfactorily. To illustrate the application, a case history is described for the construction of a shaft and tunnel within and beneath the prestigious structure of Harrods in London.

Jan 1, 2000

By A G. Grice

WMC Resources Pty Ltd û Copper Uranium Division operates the large underground Olympic Dam Mine at Roxby Downs, South Australia. These operations mine and process the ore to produce refined copper, uranium oxide, gold and silver. In mid-1996, the company committed to the Olympic Dam Expansion Project (OEP) to expand production from 3.0 million tonnes per annum of ore (85 000 tonnes per annum of copper metal) to over 9.0 million tonnes per annum of ore (over 200 000 tonnes per annum of copper metal). Along with the increase in the ore production capacity of the underground mine and the surface ore handling and processing facilities, expansion of the backfill system was required. The target backfill placement rate was 2.0 million cubic metres of backfill per annum which was to be predominantly delivered as cemented aggregate fill (CAF). This paper discusses the engineering activities undertaken to assess and change the method of designing the required strength of fill exposures. In addition, the operational changes that were introduced to achieve the required fill quantities and the mix designs to meet the specified strengths, including the use of alternate binders, are discussed. This work resulted in a large increase in the fill placement rate and a reduction in the overall unit cost of fill.

Jan 1, 2000

By Brian Fulcher

In April 1997, Kiewit/Parsons Brinckerhoff (K/PB) completed the 7,600-m (25,000-ft) primary access tunnel for the Yucca Mountain, NV proposed high-level nuclear waste site. K/PB then began boring an exploratory east-west cross drift tunnel at the site. The 2,681-m (8,796-linear ft)East-West Cross Drift Tunnel was excavated through volcanic tuffs having zones of incompetent rock using a rebuilt Robbins 5-m (16.4-ft)hard-rock tunnel boring machine(TBM) with a special arrangement of supporting equipment. This portion of the Yucca Mountain project was completed in eight months.

Jan 1, 2000

By J. H. Ahn, J. K. Yoon, Jung-Eui Lee

"A concentration change during grade transition operation in steel thin slab casting is predicted with computer simulation, water model and plant trial. Fluid flow and mixing patterns in various tundish levels and flow rates were analyzed through three-dimensional mathematical modeling. Comparing with water model experiments, a simple, efficient and accurate computational model has been suggested to predict the concentration profile at outlet of tundish. Based on the model, mixing in/below the mold was analyzed considering EMBR. The predicted concentration profiles show good agreements with the measured values. It is found that the lower vortices in the mold are suppressed by the electromagnetic field and the plug-like flow region develops which decreases the intermixing of two different grades of steel and shortens the length of transition region.1. IntroductionContinuous casting is the primary mode of production of semifinished steel products as it offers tremendous advantages in terms of energy savings, increased yield and higher productivity over the traditional ingot casting process. Efforts have to be made constantly to improve the quality of the cast product, reduce costs and thus increase the competitiveness of the steel manufacturer. One way of reducing costs is to reduce the amount of intermixed steel during the grade transition operation.Several different procedures exist to handle the casting of dissimilar grades for the conventional slab casting. Each procedure has its own merits and demerits. In order to choose the best method for a particular operation, there are a lot of researches. In the case of present continuous thin slab casting of POSCO mini mill, the only possible method is to change ladle during the grade transition. Due to the high casting speed (3.8m/min-4.4m/min) it is impossible to change the tundish and due to the thin thickness of slab it is also impossible to insert grade separator."

Jan 1, 2000

By Brian Stump, David Anderson, D. Craig Pearson, Robert Martin

Mining explosions designed to move, bulk or fracture rock are often composed of a number of explosions arranged in a complex spatial and temporal pattern. The effects of the explosions are strongly dependent upon the design and implementation of this blasting pattern. This paper describes the collection, combination and visual display of multiple types of data from these explosions for the purposes of understanding the relationships between the blast design, implementation, and observations. Data sets consist of three-component ground motion, acoustic, video and high speed film, three-dimensional topography, geological and geophysical properties, design blast pattern and timing, and velocity of detonation in the explosive for individual borehole detonation times. The explosions studied include simple single-fired contained explosions, ones designed to bulk and fracture rocks and those that cast material.

Jan 1, 2000

Open pit mining at Bingham Canyon commenced in 1904 and about two billion tonnes of ore have been extracted since then. There remain just under one billion tonnes of ore in the pit and this will be mined by 2015. Because the porphyry system extends below the ultimate pit limits, Kennecott Utah Copper Corporation initiated a study in 1997 to determine the viability of underground mining. The study was initiated at that time because the results were to be used to compare the economics of a further pit expansion to that of an underground mine. If a pit expansion was viable then overburden removal would have to start in the near future. This paper is a summary of the work that was carried out for the underground study. Block cave mining was determined to be the most appropriate method to mine the deposit. Two block cave areas have been planned with a total production rate of 72 500 tpd. Additional sources of ore will come from skarn orebodies that are associated with the porphyry deposit. The geology of the deposits is described together with the geotechnical techniques that were used to characterise the rock in the absence of more detailed data that are normally available. A general description of the mine plan is given along with the reasons for selecting the particular methodology used. The study was completed at the end of 1998 and demonstrated the viability of underground mining at Bingham Canyon. Funds have been approved for further drilling and technical studies, which will lead up to a feasibility study in 2004/5.

Jan 1, 2000

By Tadafumi Adschiri

"Supercritical water can provide an unique reaction atmosphere for synthesizing metal oxide nanoparticles. Due to the drastic change of properties of water around the critical point, including density, dielectric constant and ionic product, the reaction phase with O 2 or H2 gas and the reaction rate and equilibrium can be varied to synthesize new materials or define particle morphologies. In this work, hydrothermal crystallization experiments are performed with several types of flow apparatus that allow convenient manipulation of variables such as temperature, pressure, and residence time. Key features in the flow modes and material preparation are discussed. The proposed supercritical hydrothermal synthesis method has the following desirable features: i) nanoparticles can be produced, ii) morphology of the produced particles can be controlled with small changes in pressure or temperature, and iii) a reducing or oxidizing atmosphere can be applied by introducing oxygen or hydrogen or other gases. An overview of this method is given for functional material synthesis of significant industrial interest including barium hexaferrite magnetic particles, YAO/Tb phosphor fine particles and lithium cobalt fine crystals.IntroductionHydrothermal crystallization, a method of metal oxide formation from metal salt solutions, is typically used at temperatures ranging from 373 K to 473 K. We are developing a new process for hydrothermal crystallizations that uses temperatures in the range of 673 K to 723 K, which is just above the critical temperature of water1 • 8 • In this work, we refer to this process as supercritical hydrothermal synthesis. The supercritical state of water allows one to vary reaction rate and reaction equilibrium by shifting the dielectric constant and solvent density with pressure and temperature. From of our research on material production in supercritical water, we have identified the following specific features of the supercritical hydrothermal synthesis method: (i) ultrafine particles can be produced, (ii) morphology of the produced particles can be controlled to some extent with pressure and/or temperature, and (iii) a homogeneous reducing or oxidizing atmospheres can be provided by introducing gases, such as O 2, H2, H2O 2• and so on.1"

Jan 1, 2000

By Nagahiro Saito, Takashi Nishimura, Takamichi Ichikawa, Akio Fuwa

"Yttria-stabilized zircohia (YSZ) has high potential to be used as solid-oxide fuel cell (SOFC) electrolyte. However, the high efficiency of SOFC has not been yet achieved due to the high internal resistance of bulk electrolyte. The resistance becomes lower with the decrease in the electrolyte thickness. Thus, the decrease in electrolyte thickness leads to lower internal resistance. . The aim of this study is as follows: (a) to prepare the thin films of YSZ by inductively-coupled RF plasma-enhanced metal organic chemical vapor deposition (PEMOCVD) process using Zr(t-OC4H9)4,Y(DPMh and oxygeil, and (b) to reveal the relationship between the structural characterizations and the process parameters.1. IntroductionYttia-stabilized zirconia (YSZ) has, been widely used as not only heat-resistant materials but also the components in automotive oxygen sensors, electrolytes of solid-oxide fuel cell (SOFC)(1)(2) and the buffer layers for the high-temperature superconductor because of its low thermal conductivity, good mechanical properties and high ionic conductivity. However, it is said that the internal resistance of the bulk electrolyte is too high to be appropriate as a solid electrolyte for high-efficient SOFC. The authors believe that the thin YSZ electrolyte can give a high performance to characteristics SOFC, since the internal resistance becomes lower with the decrease of electrolyte thickness. Thus the process technology to prepare YSZ thin films is desirable and must be established.In recent years, the YSZ thin films have been reported by chemical vapor deposition (CVD), thermal CVD using metal chlorides (MC) of ZrCl4 and YC(3)(4), thermal CVD using metal organic compounds (MO)(5)(10) Zr(t-OC4H9)4 and Y(C11H19O2)(11) and plasma-enhanced (PE) CVD using MO. Here, these methods are called MCCVD, MOCVD and PEMOCVD. MCCVD has two disadvantages; a large quantity of chlorinated impurities in deposited films and high processing temperature (> 1273K). This high processing temperature leads to damage of substrates in particular, so the application of this technology is limited. On the other hands, the processing temperature by MOCVD becomes and is lower. Unfortunately, the accurate vapor pressures of these metal organic compounds have not been, known so: that it is difficult to control the composition and the film thickness by MOCVD method well. Moreover, the large amount of carbonic compounds in the films prepared by MOCVD method is produced. However, plasma-effect has been reported to decrease large amount of the carbonic impurities by PEMOCVD. However, PEMOCVD has many reaction parameters in plasma processing; the geometry of experimental apparatus, radio frequency, electronic power input and so on. Thus, the general understanding about the relationship among reaction parameters, the composition and crystal structure of thin deposit film by this method has not yet been established."

Jan 1, 2000

The geotechnical factors controlling the design of the open pit slopes of the Pasminco Century Mine near Lawn Hill, Queensland are presented below. Pasminco Century is a stratiform shale hosted zinc deposit in the Lawn Hill Formation that is overlain in part by the Thorntonia Limestone Formation. Both the mineralisation and overburden is located within a competent rock mass such that intact rock strength and discontinuity spacing is generally sufficient to prevent large-scale slope failure by breakage through the rock mass. Rather, overall slope stability issues are dominated by the major discontinuities within the rock mass. The deposit is located in a structurally complex regime, it consists of a synclinal basin which is truncated by easterly striking normal faults through its centre and northern and southern limits and by an unconformity on its eastern and western margins. Deposit geometry and slope stability is further complicated by small-scale folding, a pattern of northeast and southeast striking subvertical faults and north easterly dipping thrust faults with their associated fault emplaced blocks of Lawn Hill Formation in the overburden. The large size of the deposit requires a staged mining approach with the excavation of both final pit walls around the external sides of each stage and interim pit walls along the internal boundaries between adjacent stages. The deposit geometry and major discontinuities control not only the final pit wall design but also interim wall location and orientation, excavation sequence and in some stages the excavation schedule. Two and three-dimensional limit equilibrium stability analyses were conducted using both deterministic and probabilistic approaches to determine appropriate pit wall design criteria and to select a suitable excavation sequence and schedule.

Jan 1, 2000

By Michael Mann

Two house trailers and a modem modular house, all pillar-supported with cantilevered perimeters, were monitored for structural response to vibrations from surface coal mine blasts. Due to the large blast site distances, peak particle velocities measured in the ground beside the houses did not exceed 0.32 ips, and airblasts did not exceed 106 dB. However, the structures responded significantly to the ground vibrations, with maximum high-comer amplification factors as high as 8.5 in the horizontal directions. Vertical structural responses were as high as 10 times the vertical peak particle velocities in the ground, but appeared to be driven more by horizontal ground motions. No measurable airblast responses were observed. The natural frequencies of the structures ranged from 5 to 10 Hz.

Jan 1, 2000

By Neal Schwartz, Robert De Saro, Richard Rosenthal, Ed Kear

"A Stack Melter has been installed and is currently operating at Lexington Die Casting. The Stack Melter consists of a 1 meter (3 foot) diameter refractory tube, 2 meters (7 feet) high. Specification ingots are continuously fed to the top of the melter and piled to nearly the top. A burner fires through the scrap which melts the lower portion and preheats the upper portion. As the lower portion is melted, it is drawn out and the upper preheated scrap falls to a lower level where it in tum melts. The molten metal is fed to one of two holding furnaces for eventual delivery to a casting machine.The Stack Melter's energy use is approximately 2900 joules/g (1,250 Btu/lbm), resulting in an overall energy savings of about 58%. This energy savings is brought about primarily because the flue gases preheat the scrap and the flue gas temperature is dropped to well under 528°C (1000°F)."

Jan 1, 2000

By Hideki Minoura

"Two novel electrochemical techniques for the preparation of highly crystallized CdS film have been presented. One is cathodization of a conductive substrate in an acidic chemical bath containing cadmium salt and thioacetamide, where electroreduction of proton at small current densities induces a growth of highly crystallized CdS thin films, whose growth is not disturbed by the reactions in the solution phase. The other technique is electoreduction of aqueous Cd2+— SCN complex. An advantage of this technique lies in no formation of solid particles in the bulk, of the bath.IntroductionIn recent years much attention has been paid to materials preparation by solution processing because of its advantages in lowering the cost as well as the stress to the environment, as compared to the conventional gas phase techniques which unavoidably require high temperature and/or vacuum. We have been trying to explore novel techniques for preparing functionalized compound semiconductors by aqueous solution process. Semiconductors which we have been mainly focusing on are CdS and ZnO, which are important semiconductors finding applications in various devices. In the present paper, some of the techniques that we have recently established for the preparation of highly crystallized CdS will be presented.Methods of the CdS film processing in solution phase (wet process), which have been reported so far can be divided into two major groups; one is chemical bath deposition (CBD) in alkaline solution containing Cd2+ and thiourea 1)4) and the other is electrodeposition (ED) in acidic solution containing Cd2+ and thiosulfate ions - 5)-8) or organic solutions containing dissolved sulfur 9)-11)."

Jan 1, 2000

By R. Q. Honaker, D. P. Patil, A. Sirkeci

Due to increased production of fine coal during mining during this century and inefficient fine coal recovery technologies, a vast reserve of high quality coal currently exists in refuse ponds. A novel fine coal circuit consisting of a hindered-bed classifier, an enhanced gravity concentrator and a flotation column has been evaluated for the recovery of fine coal from refuse ponds. The treatment of a pond derived from Pittsburgh No. 8 seam coal resulted in the production of a premium fuel containing less than 5% ash and a calorific value of about 30,173kJ/kg with 60% mass yield. The results from the treatment of two refuse pond materials will be presented in this publication.

Jan 1, 2000

By Kiyoshi Shibata, Jun-ichi Hayashi

"Steel making technology poses strong potentials for environmental protection in three direction. One is pollution control on steel making process itself. Japanese steel industry has cut down various type of emission drastically since 1970's. Secondary, those process technology can be applied to reduce environmental burden in other industrial sectors. One of the successful examples is municipal waste treatment facility. Thirdly, development of high performance steel products, such as high strength steel for automobile body, can contribute to improve environmental performance during their use, based on the concept of life cycle assessment. Some examples of the successful development and future task is discussed.IntroductionsStack and smoke used to be a symbol of energy intensive industry such as steel making. But, scenery of steel works and its surroundings have been completely changed, and steel products have been changing, as well. The steel making industry consumes huge quantities of energy and resources. Variety of technical development have been carried out to reduce the pollutant release. The steel industry in Japan has been making direct and indirect contributions to reducing of various kinds of environmental impacts through development of high-performance process and products: Its potential technical capability accumulated in steel making is fundamental and essential infrastructure for the vein systems of our society. In this paper, the activity of steel making industry for better environment is discussed"

Jan 1, 2000

By W. J. van Niekerk

Ballast Nedam is in Surinam constructing two bridges that will improve communications in the coastal region. The bridges will cross the Coppenam and Surinam rivers and will be founded on open-ended steel piles over 60 meters in length. The majority of piles are inclined and support prefabricated concrete girders forming the roadway. In most locations the stratum is consolidated cohesive layers extending to a depth in excess of 60 meters. For this reason, before pile driving operations commenced, it was decided that a number of test loads would be carried out determine the capacity of the piles. Loading tests were carried out on specially installed piles as well as on piles that would be used as working piles to support the structure. Working piles were dynamically tested using Pile Driving Analysis (PDA) equipment. This decision was based on the inclination of the piles, the cohesive nature of the soil and the increase of strength after the piles are driven. A good insight has been obtained into the real strength of the soil by comparing dynamic and static loading tests on vertical test piles. This made it possible to determine the required length of pile.

Jan 1, 2000