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By Kevin Ashley

Because toxicities may differ for Cr(VI) compounds of varying solubility, some countries and organizations have promulgated different occupational exposure limits (OELs) for soluble and insoluble hexavalent chromium (Cr(VI)) compounds, and analytical methods are needed to determine these species in workplace air samples. To address this need, international standard methods ASTM D6832 and ISO 16740 have been published that describe sequential extraction techniques for soluble and insoluble Cr(VI) in samples collected from occupational settings. However, no published performance data were previously available for these Cr(VI) sequential extraction procedures. In this work, the sequential extraction methods outlined in the relevant international standards were investigated. The procedures tested involved the use of either deionized water or an ammonium sulfate/ ammonium hydroxide buffer solution to target soluble Cr(VI) species. This was followed by extraction in a sodium carbonate/sodium hydroxide buffer solution to dissolve insoluble Cr(VI) compounds. Three-step sequential extraction with (1) water, (2) sulfate buffer and (3) carbonate buffer was also investigated. Sequential extractions were carried out on spiked samples of soluble, sparingly soluble and insoluble Cr(VI) compounds, and analyses were then generally carried out by using the diphenylcarbazide method. Similar experiments were performed on paint pigment samples and on airborne particulate ?lter samples collected from stainless steel welding. Potential interferences from soluble and insoluble Cr(III) compounds, as well as from Fe(II), were investigated. Interferences from Cr(III) species were generally absent, while the presence of Fe(II) resulted in low Cr(VI) recoveries. Two-step sequential extraction of spiked samples with (?rst) either water or sulfate buffer, and then carbonate buffer, yielded quantitative recoveries of soluble Cr(VI) and insoluble Cr(VI), respectively. Three-step sequential extraction gave excessively high recoveries of soluble Cr(VI), low recoveries of sparingly soluble Cr(VI), and quantitative recoveries of insoluble Cr(VI). Experiments on paint pigment samples using two-step extraction with water and carbonate buffer yielded varying percentages of relative fractions of soluble and insoluble Cr(VI). Sequential extractions of stainless steel welding fume air ?lter samples demonstrated the predominance of soluble Cr(VI) compounds in such samples. The performance data obtained in this work support the Cr(VI) sequential extraction procedures described in the international standards.

Jan 1, 2009

By k. Osei-Boakye

This paper presents the calibration of a real-time aerosol monitor, the TSI DustTrak?, to the NIOSH 5040 method being used by the Mine Safety and Health Administration (MSHA) for compliance enforcement evaluation. The standard NIOSH 5040 instrument for compliance evaluation of diesel particulate matter (DPM) has an inherent time lag of up to two weeks for laboratory processing of sample results. Therefore, providing the underground mines with a means of quantifying DPM conditions in real-time, will enable them to efficiently and effectively manage DPM levels to ensure compliance with the regulated limit.

Jan 1, 2009

The roasting of sulphide ores and concentrates is often the first step in the production of metals or chemicals. In many processes, the production of sulphuric acid is viewed as a by-product, while in some plants production is an important economic factor. Regardless of the purpose, a pyrite roasting plant consists of mainly three plant sections: roasting, gas cleaning and sulphuric acid. With the addition of air, the pyrite concentrates are transformed into solid oxides and gaseous sulphur dioxide at temperatures of 600 - 1000° C. After cleaning and cooling, the sulphur dioxide in the roasting gas is further processed to sulphuric acid. Two types of reactors are used depending on the application: stationary or circulating fluid bed . For over 60 years, Outotec has progressively been developing the principle of fluidised bed technology in several different reactor types for a multitude of process applications. The versatility of the fluidised bed reactor system has manifested itself in the treatment of minerals, including solid fuels, and for metallurgical processes both in the ferrous and non-ferrous fields. Process applications have included roasting, calcining, combustion and charring of coals, as well as off-gas treatment. This paper provides a summary of the pyrite roasting technology currently used along with a simple cost comparison of pyrite roasting and sulphur burning processes.

Jan 1, 2009

By Viviane Tavares

The liquid crystal display (LCD) are currently known by its vast application in electro ? electronic devices, amongst them can be detached the devices of TV, laptops, electronic date, calculators and even though the mobile telephones (mobiles). The mobiles are changed more frequent of the TV for example, this happens due to the technology advance. With the constantly mobile exchange, the batteries, printed circuit board and liquid crystal display accumulation its become an environmental problem. To minimize the environmental impacts caused by mobile telephones residues are considered the segregation process of the LCDs main components, to goal to recover the recycle material. This process involves the use of treatment ore techniques with disc, hammers and balls mills. The process with best efficiency (about 98%) of LCD glass release was the hammers mill. The glass recovered can be used in the glass recycling and the sand substitution in the production of concrete blocks.

Jan 1, 2009

By D. J. Hutchinson, M. Lato, M. Diederichs

Light Detection and Ranging (LiDAR)-based applications for geomechanical purposes have recently proven to be a highly reliable and accurate form of remote analysis and documentation. The ability to remotely collect, process and evaluate rockmasses for structural geomechanical applications has benefits ranging from safety to efficiency, and provides a permanent record that can be assessed before and after an excavation has been completed. With the collaboration of Queen’s University and Rio Tinto, the Iron Ore Company of Canada (IOC) mines in Labrador City, Newfoundland and Labrador, evaluated the practical application of the I-Site 4400 LiDAR equipment, in conjunction with the Vulcan geotechnical module for geomechanical purposes. The project provided a comparative analysis between conventional hand-mapping and digital analysis. The analysis indicates that digital mapping could be employed as an active tool within the general geotechnical workflow, where results would be used in pit wall and rockmass support designs. As well, the field work enabled the generation of effective operational guidelines and protocols to maximize scanning efficiency.

Jan 1, 2009

Operations and maintenance departments have had a long-standing adversarial relationship. The widespread evolution and adoption of modern management techniques, such as reliability centered maintenance (RCM) and Lean, however, has driven interest in working co-operatively to optimize overall plant performance. Mining and minerals operations have long adopted RCM in maintenance and are now adopting Lean throughout organizations. Such modern management initiatives explicitly call for co-operation between the two disciplines of maintenance and production and many advances have been made in terms of people and methodology. One area that has lagged behind in supporting these developments, however, is information systems. Enterprise asset management (EAM) systems in maintenance and newer manufacturing execution systems (MES) in operations have not been truly integrated in the needed ways. Complicated plants, different software architectures, continually changing conditions and many other variables have led to systems problems, which have contributed to the maintenance/operations divide. Master data synchronization (the plant tree) and integrated reporting of real-time data with transactional data are just two of the issues that are being solved by new approaches in information technology, including web services and service orientated architectures. New technologies are coming on-stream to enable the final bridging of the gap.

Jan 1, 2009

By Valérie Léveillé

As new legislation drives to lower SO2 emissions from metallurgical plants, plant managers face the challenge of keeping their costs under control. The Cansolv® SO2 Scrubbing System has been broadly adopted in the non-ferrous industry as a cost effective solution for smelter operators to meet the new SO2 emissions targets. The Cansolv® SO2 Scrubbing System is an amine-based regenerable process that selectively absorbs SO2 from a variety of gases, including dilute smelter gases, such as furnace and converter gases. The system produces a pure, water-saturated SO2 byproduct stream, which can then be directed to the front end of a sulfuric acid plant for conversion to sulfuric acid. When deployed in a smelter complex, the Cansolv® SO2 Scrubbing System may also be used to process acid plant tail gas, allowing single absorption sulfuric acid plants to achieve emissions an order of magnitude lower than that of a double absorption acid plant with a lower capital investment. Depending on inlet gas temperature SO2 emissions in the treated gas can be controlled to as low as 55 mg/Nm3. This paper will describe some of the applications where customers have or are planning to use the Cansolv® SO2 Scrubbing System and what as well as which features and cost advantages for the treatment of smelter gases were key to the technology choice.

Jan 1, 2009

By V. T. McLemore

Petrographic analysis of rocks is traditionally performed with optical microscopy using thin sections and point counting. However, this does not provide accurate mineral proportions for sedimentary, volcanic, and soil-like material, because rock fragments, groundmass, and matrix are not identified as specific minerals. In addition, groundmass phases in volcanic rocks can be too fine to identify individually, and making thin sections of intact soil-like material is difficult because much of the material is not well cemented. ModAn is a normative calculation that estimates modes ??by applying Gaussian elimination and multiple linear regression techniques to simultaneous mass balance equations? (Paktunc, 2001) and allows location-specific mineral compositions to be used. One of the features of ModAn that makes it appropriate for this study is that it can model one of several sulfide minerals. Mineral compositions for Questa minerals were determined from electron microprobe analysis and entered into ModAn. Then by combining and normalizing results, bulk quantitative mineralogy can be determined using ModAn, petrographic observations, electron microprobe analysis, clay mineral analysis, and the whole-rock chemistry of the sample.

Jan 1, 2009

"Standing 92 stories high and just over 1,362 ft tall, Chicago’s Trump International Hotel and Tower is perfectly positioned at the center of one of the world’s most impressive skylines.The Tower serves as a link between its famous predecessors, Willis Tower (formerly, the Sears Tower) to the south and the John Hancock Building to the north. Originally planned to be the world’s tallest building, the project was scaled back when the developers started questioning the need for super-tall buildings after the September 11, 2001 terrorist attacks. In its River North neighborhood, Trump Tower dominates the skyline as a symbol of Chicago’s last great building boom, standing triumphantly over other high-profile projects that have been postponed due to current economic realities.It is often said that the three most important factors in real estate are location, location and location. This maxim was not forgotten by The Trump Organization when the site was selected for the International Hotel and Tower. Located two blocks west of Michigan Avenue and Chicago’s famed Magnificent Mile, the site is bound by the historic Wrigley Building to the east, Wabash Avenue to the north and west, and the Chicago River to the south. The building’s position along a bend in the Chicago River allows visitors and residents unobstructed views to the mouth of the Chicago River and Lake Michigan. Site ChallengesUnderneath the site there are approximately 10 to 20 ft of sand and urban fill underlain by soft Chicago blue clay. At 75 ft in depth, the soft clay transitions into Chicago hardpan, a very hard till that was consolidated by the glaciers over 10,000 years ago. Below the hardpan, the till turns granular with cobbles, boulders and water under pressure. Bedrock is about 100 ft below existing grade and has a weathered surface with fractures and clay seams. Unweathered limestone bedrock is sound and hard with unconfined compressive strengths of 10,000 to 20,000 psi."

Jan 1, 2009

By J Lea, D C. Kettlewell

The Carina iron ore deposit lies 105 km northeast of Southern Cross, WA. The area designated the Yilgarn Iron Ore Project (YIOP) is comprised of five prospects along an east-southeast trending greenstone belt that extends from the Helena-Aurora Ranges in the northwest to the Yendilberrin Hills in the southeast, over a strike length of approximately 40 km. The YIOP project encompasses the previously identified iron deposits of Bungalbin, Bungalbin East and Mt Walton. The Carina deposit was discovered by Polaris Metals NL in May 2007. The Carina deposit is located within and parallel to the structurally complex northwest trending Mount Dimer shear zone. The volcanosedimentary Archaean-aged greenstone sequence consists of ultramafic and mafic lavas and flows with interbedded sediments dominated by chert and banded iron formation (BIF). Supergene enrichment processes formed a goethite orebody replacement of BIF sequences within a doubly plunging synclinal fold structure. Mineralised outcrops dominated by goethite form a low ridge 1500 m long, up to 90 m wide and drilled to over 200 m in depth. In the vicinity of the Carina deposit, iron occurrences have been identified over at least a 12 km strike length and the exploration potential of the area is identified as 30 - 40 Mt. Polaris Metals began exploration in the area in 2006. Target generation in the area used existing state geological survey maps and regional magnetic survey data to focus on BIF occurrences associated with major structures. Early field investigations resulted in the identification of a large outcrop of predominantly goethite mineralisation at Carina. Detailed geological and structural mapping was completed, followed by close-spaced reverse circulation and diamond drilling. The mineralisation is predominantly goethite with specular and coarse platy haematite localised along structures that cut the goethite mineralisation. Mineralised zones are moderately vuggy and larger cavities occur in proximity to fault zones that transect the orebody. A capping by a thin veneer up to 9 m thick of canga or ferricrete occurs in places. By December 2008, 178 reverse circulation and 11 diamond drill holes (seven surface holes, four tails) were completed. The current JORC-compliant resource estimate is based on assays from 72 RC drill holes and using a 55 per cent Fe cut-off stands as an Inferred Resource of 27.9 Mt at 58.6 per cent Fe, 1.3 per cent Al2O3, 3.7 per cent SiO2, 0.09 per cent P, and 10.1 per cent LOI. Assaying has recently been completed and will be incorporated into a new updated resource later in 2009.

Jan 1, 2009

By Mike Muchard

A design phase load test program was performed at the Broadway Viaduct bridge site to evaluate load carrying capacity and constructability of post grouted drilled shafts. The program included construction, instrumentation, post grouting and load testing of three drilled shafts. Two shafts included sleeve port and plate base grouting apparatus and were post grouted. The third shaft was un-grouted and served as a control shaft for comparison of the un-grouted end bearing. The shafts were 5 feet in diameter with the control shaft at 55 feet in length and post grouted shafts at 55 and 66 feet. SPT borings at the centerline of each test shaft defined geotechnical conditions at each shaft. Test shafts were instrumented with strain gages and concrete integrity was evaluated with crosshole sonic logging. Instrumentation and data acquisition was used during the post grouting operation to fully capture the shaft behavior. Finally, Statnamic load testing was performed on all three shafts to their ultimate capacity. The fine to coarse sandy soils in which the shafts were tipped in were well suited to improvement from post grouting. Grout pressures of 660 psi were achieved with 0.08 inch or less of upward shaft movement. Subsequent Statnamic load tests showed 183 to 192 percent greater end bearing in the post grouted shafts as compared to the un-grouted shaft. The overall result showed a potential savings of approximately 9 feet to 35 feet of drilled shaft length in addition to the increased quality assurance from post grouting.

Jan 1, 2009

By Kenneth Gavin

Design practice for piles installed in Irish glacial till has developed in an ad-hoc manner, based on the results of un-instrumented load tests. This had led to designers using similar design parameters for both CFA and displacement piles. To address the concerns of industry a series of instrumented pile tests were performed by two Irish Universities. These tests summarized herein, revealed that CFA piles develop higher shaft resistance than piles driven in glacial till. However, they exhibit low base stiffness and the end bearing resistance that can be mobilized at acceptable pile settlement is low. The use of simple non-linear elastic design approaches to predict the load-displacement response is considered. The methods are used to predict the capacity of two large diameter CFA piles installed in glacial till. While the predictions were reasonably accurate at predicting the initial load-displacement of the piles, significant creep settlement developed at higher load levels. The cause of the creep settlement was investigated through the use of plate load tests and the consequences for pile design are discussed.

Jan 1, 2009

By M. I. Brasileiro

The use of experimental design to the study of mixtures has found a wide range of applications, even in laboratory scale or in industrial development works. The aim of this work was to maximize granite sawing waste content in ceramic tiles using experimental design. Based on the raw materials, specific formulations were developed using the experimental design. The raw materials were mixed and sample bodies were produced using uniaxial pressing. The sample bodies were fired and characterized in terms of water absorption, mechanical strength and X-ray diffraction. Regression models were adjusted relating the water absorption and mechanical strength with the amount of raw materials. The results showed that the methodology of experimental design maximize the content of wastes incorporated in ceramic tiles formulations. Formulations containing up to 40% of waste can be used for the production of ceramic tiles.

Jan 1, 2009

By R. G. Gürtunca

The future of the United States (US) mining industry will be affected greatly by recent coal mining disasters. These have resulted in new legislation which will have an impact on mining economic costs as well safety and health of miners. This paper discusses the changes that new legislation and regulations are making to the industry and current research that is producing technologies to make mining safer and will likely impact the future of mining.

Jan 1, 2009

By Larry Southwick

This Peirce-Smith Converting Centennial symposium is celebrating the contributions of two men, William Peirce and E.A.C. Smith, in advancing technology allowing the copper industry to realize its full potential. However, theirs is representative of a larger story: New, simpler technology releasing the stranglehold of older, more complicated technology, new developments in vessel configuration and design finding alternate routes around dead ends in operability, advances in technique and concepts removing roadblocks of cycle time and capacity, and overall innovation opening up vast new reserves around the world to those companies willing to embrace those improvements. Our story is also one of personalities, stubborn smeltermen versus the innovators, those inside the industry versus those from outside. It is a story of an initial borrowing from the steel industry, but also Peirce and Smith, from the refining end of the copper business, taking the ideas of Baggaley from Pittsburgh’s steel and airbrake industry, who built on what Hollway, Manhès and David, Douglas, and others had done in smelter tests, further to compete with the previous primacy and closely held expertise of the copper smeltermen in Wales. These advances have been well recorded in photographs taken over the last 150 years. A number were submitted especially for this symposium. Many others were published in the mining and metallurgy press of the times. Several mining schools also retained copies of photos either taken during field trips, or donated to the school by alumni and operating companies. This presentation will provide a selection and discussion from these sources of “converters in action”, describing the various designs, operations and developments depicted. The focus here will be on the first roughly 60 years of copper converter development, from Bessemer’s days at the dawn of this new idea, up to and slightly past the time of initial adoption of Peirce and Smith’s designs.

Jan 1, 2009

By N. T. Lowe

The National Institute for Occupational Safety and Health (NIOSH), Spokane Research Laboratory (SRL), investigated a means to evaluate the potential impact of surface conditions above underground mines on emergency response activities. Recent events have highlighted the need to conduct critical emergency operations on the surface above underground work areas. Accessibility and usability of the surface, such as the ability to drill holes or deploy seismic monitoring or through the earth communications systems, are an important consideration for emergency response planning. This paper identifies critical surface conditions such as: surface waters, valley fill, highways, railroads and significant structures that must be considered in emergency response planning and in the conduct of emergency operations as they relate specifically to the seismic detection of trapped underground miners. Results of case studies indicate a need to consider the impact surface conditions may have on emergency response capabilities.

Jan 1, 2009

A mineralogical study was conducted on the feed (3.51 g/t Au and ~90 g/t Ag) and four leach residue samples (assaying 0.09 to 0.19 g/t Au and 30.0 to 61.5 g/t Ag) from the Pinos Altos silver-gold deposit in Mexico to determine the cause for gold and silver losses. A comprehensive mineralogical and analytical approach including fire assay, gravity pre-concentration, ore microscopy, mineral liberation analyser (MLA) and electron microprobe was used for the current study. Results showed that gold and silver lost in the leach residues occurred mainly as inclusions in quartz and silicates (accounting for over 80% for Au and 92% for Ag of the head assays, respectively), with a minor amount in iron oxide and other minerals. The amount of liberated gold and silver is negligible. Results also showed that gold and silver particles in leach residues are mainly ranged from 1 µm to 5 µm in size, which implies that ultrafine grinding is required to improve the recoveries of these two metals. Keywords: mineralogy, gold deportment, silver deportment, silver-gold ore, leach residue, recovery improvement.

Jan 1, 2009

By Timothy D. Stark

Jet grouting has increasingly become one of the ground improvement technologies used to address seepage concerns and to provide strength improvement of soils. The technique of jet grouting uses high pressure/velocity jet fluids to erode the existing soil and then to mix the cuttings with cement slurry to form soilcrete. Excess slurry or spoil is ejected to the surface. If the native soil is not completely mixed with slurry, the resulting columns will have soil inclusions which can reduce the strength of the column and/or increase the permeability of the column. A jet grout test program at Tuttle Creek Dam shows that the completed large diameter columns contain perhaps 40 to 50% or more of native soil that was not broken up and mixed during the jet grout process. The test program included excavation of full-scale columns to a depth of 35 ft (10.7 m) for visual inspection and testing. Additionally, six of the columns were cut or sectioned to investigate the interior of the columns. The observed inclusions include significant amounts of both fine grained (silts and clays) and coarse grained (fine sands and sands) soils. Evidence suggests at least two explanations: (1) fine grained soils can be difficult to erode and break up into small enough particles that can be ejected to the surface, especially if at low natural water content, and (2) when large diameter columns are being excavated, the excavated roof of the cylindrical cavity may be unstable and may collapse. With this roof instability large slabs of material can break off, fall into the slurry and escape the cutting and mixing action of the rotating jets. This paper describes the Tuttle Creek Dam test program, inclusions observed in the completed columns, and suggests potential causes of the inclusions.

Jan 1, 2009

By Özgür Bezgin

This paper presents observations on the installation of drilled shafts from two construction projects and an academic study with experimental and analytical parts. The construction projects involved the use of pressurized drilling methods. The experimental part of the academic study involved the use of the auger drilling method. The analytical part of the academic study investigated the effect of drilling methods on the soil-structure interaction and the behavior of drilled shafts under lateral loads. The concept of ?free-length? is introduced for the lateral load design of pressure-drilled shafts that are thought to be fully embedded within a soil media. The academic part of the study presented herein was conducted in Rutgers, the State University of New Jersey.

Jan 1, 2009

By Andy Hudson, Stuart Brashear, David Lilly

Because of greatly increased timing accuracy, electronic detonator systems are a well-known and widely accepted major tool to control and reduce ground vibration. At a Southeastern quarry the authors found that the use of electronic detonators improved the reliability of the well known cubed root scaled distance equation for determining air blast. In addition, the authors noticed significant correlations between selected major peak particle velocity frequencies and air blast magnitudes. The major peak particle velocity frequency alone is a close approximation to air blast magnitudes. This relationship is not as significant or not always evident when standard pyrotechnic initiation systems are used.

Jan 1, 2009