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By Julian Johnson

The effect of changing redox potential (Eh) on the high temperature sulfuric acid leaching of Western Australian dry-land nickel laterite ores has been investigated. In particular, the effect of added reductant (sulfur, sodium sulfite) or oxidant (potassium chromate) on Eh, leaching kinetics, metal extractions, acid utilisation and leach residues has been determined. Three separate ores - nonhonitic ores from Murrin Mumn and Bulong, and limonitic ore from Cawse - were used in the study. Sulfur addition varied from 0 to 7.8 kg/t ore. The total acid loading was kept constant at 430 kg/t (Murrin Murrin ore) and 330 kglt (Cawse ore), whilst acid loading for Bulong ore was varied according to the presence of either reductant or oxidant. The extraction of both nickel and cobalt from limonite ore remained unaffected when small amounts of sulfkr were added, but addition of even small amounts of reductant to nontronitic ore decreased both nickel and cobalt extraction. Increased manganese and iron dissolution were observed as the levels of reductant increased, accompanied by a decrease in chromium dissolution. As the iron dissolution increased, free acidity decreased, with a subsequent decrease in nickel extraction. In contrast, addition of oxidant lead to reduced iron and manganese dissolution and slower extraction of nickel and cobalt. Keywords: Limonite, Nonhonite, Eh, Nickel Extraction

Jan 1, 2004

By L. G. Wang

The stability of foams and froth plays an important role in flotation, in which small amounts of relatively weak non-ionic surfactants (frothers) are used to produce air bubbles and foams. In the present work, factors affecting the stability of the foams produced in the presence of common frothers, such as n-pentanol, n-octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG), have been studied. We used the thin film pressure balance (TFPB) technique of Schelud-ko-Exerowa type to measure the equilibrium film thicknesses. The results were used to determine the contributions from the various surface forces to the disjoining pressures in the thin lamellae (foam) films formed between air bubbles. In addition, we used a model developed by Wang and Yoon (Colloids and Surfaces A: Physicochem. Eng. Aspects, 2006) to calculate the elasticities of the lamellae films at the critical thicknesses at which films rupture. The surface forces and elasticity da-ta were then compared with the foam stabilities in the presence of the various flotation frothers. It was found that foam stabilities are controlled by both film elasticity and surface forces, the relative contributions of which change with frother type and concentration. In general, surface forces play a more important role at relatively low frother concentrations, while elasticity plays a more important role at higher concentrations. At the frother additions usually employed in the mining industry, MIBC relies on surface forces while PPG-400 relies on film elasticity in producing stable foams. The former is capable of dampening the hydrophobic force, which is a major attractive force destabilizing lamellae films, while the latter is capable of reducing surface tensions at low concentrations.

Jan 1, 2014

By C. Peña, C. A. Zaror, M. Bustamante, M. Vega

The goal of this paper is to present the carbon footprint of Chilean cathodic copper, as a function of the electricity generation mix, ore grade, and process efficiency. Ore grades and acid leach-solvent extraction-electrowinning (LX-SX-EW) yields in the range 0.5-1.0% and 60-80%, respectively, were considered here. Additionally, electricity supply from two Chilean suppliers, SING (1.0 ton CO2/MWh) and SIC (0.4 ton CO2/MWh) was assessed. Simulation results show that oxide plants located in northern Chile, served by the SING network, feature carbon footprint within 4.3 - 11.4 MWh I ton cathodic copper, as compared with 3.5 - 9.3 MWh I ton copper in plants served by SIC. The footprint was found to increase as ore wade and process yields decrease.

Jan 1, 2011

By P. G. H. Pistorius, D. S. Konadu, G. Lubbe

The aim of this investigation was to determine whether the composition of a shielded-metal arc-welding electrode coating affected the low-temperature impact toughness of austenitic stainless-steel weld metal. It is generally accepted that increases in the δ-ferrite and nitrogen contents result in a decrease in toughness at low temperatures. Weld metal from electrodes with a basic coating also generally exhibit better toughness than those from rutile (acidic) electrodes. An increase in basicity was expected to decrease the number and size of inclusions, which in turn provides a tougher weld metal. Three commonly available potassium–rutile E308L electrodes were used, complying with the E308L-16 and E308L-17 specifications. Analysis of the electrode coatings showed very similar chemistry and basicity. Significant differences in the inclusion contents of the weld metals were observed: the E308L-17 weld metal had a lower inclusion content (1.4% by volume) than the E308L-16 weld metal (3.7%). The former had higher impact toughness at all temperatures, despite a slightly higher nitrogen content. Regression analysis confirmed that the inclusion content had a significant effect on the impact toughness at all temperatures.

Jul 2, 2022

By Antonio Kodsy, Lutful Khan

A research was carried out to test the possibility of reducing the pullout resistance of metal sheet piles driven in clay soils using Electrokinetic (EK) conditioning. The hypothesis was applying an electric gradient for a certain period of time should reduce the adhesion between the clay soil and the sheet piles. Tests were conducted on bench scale thin stainless-steel metal plates embedded in pure kaolinite clay, and mixtures of kaolinite clay and sand. The pullout resistances were determined after 20, 40, and 60 minutes residence times of steel plates in the soils before and after EK conditioning under an electric gradient of 1500 V/m. In kaolinite clay, the pullout resistance showed linear reduction with the duration of EK conditioning and about 60 % reduction in pullout resistance was observed after 60 minutes EK conditioning. For the kaolinite-sand mixtures, the pullout resistances were reduced by about 70% and 80% for 20% and 30% sand contents respectively after 20 minutes EK conditioning and showed no significant improvement with the increase in conditioning duration. It was concluded that the proposed electrokinetic conditioning process could potentially reduce the pullout resistance of metal plates embedded in clay and clayey soils. SHEET PILE WALLS Sheet pile walls are typically used at waterfronts as retaining structures or during the construction phase to shore the soil and avoid collapse of the excavations. When used as permanent structures, sheet pile walls are not removed after the completion of the project. However, as temporary support, they are extracted after the completion of the project and reused. In pure clay soils the extraction processes often becomes a challenge requiring very large pullout forces which could damage the sheet piles. There is a research need for developing an efficient method of sheet pile extraction from clay soils addressing the issue of pullout force reduction. However, very few researches have been conducted regarding the extraction techniques of sheet piles and their economic effect on the cost of a project. In this study a novel method for reducing the pullout resistance of sheet piles in clayey soils using electrokinetic conditioning was explored. The hypothesis of this research is that the electrokinetic process in soil/water system, specifically electrophoresis and electroosmosis, could be used to loosen the sheet pile walls embedded in cohesive soil and hence reduce the required force of extraction. The aim of this study was to test this hypothesis through laboratory tests carried out on steel plates embedded in cohesive soil samples. The pullout forces of the steel plates before and after varied duration of electrokinetic (EK) conditioning were evaluated and compared. The process was also investigated for clay-sand mixtures.

Jan 1, 2019

By Nina Panteleeva, Elena Afonina, Stanislav Titkov, Jury Buksha

"Flotation processing of water-soluble minerals (potassium ores, sedimentary salts of salt lakes) is currently the main method for production of potassium fertilizers and concentrated carnallite which is the initial product for production of metallic magnesium. Flotation of sylvite (KCl) and halite (NaCl) is carried out in the electrolyte solutions: KCl-NaCl-H2O and KCl-NaCl-MgCl2-H2O. The report presents the results of studies of the effect of concentration and the electrolyte type on the size of air bubbles in a flotation cell in comparison with the floatability of mineral constituents of potash ores. The floatability in electrolytes of various compositions has been studied: - of sylvite (KCl) by alkylamines, - of halite (NaCl) by alkylmorpholines, - of silicate-carbonate slimes contained in the ore by ethoxylated surfactants. The reagent modes (regimes) activating the flotation desliming of potash ores have been developed."

Jan 1, 2014

By Norimasa Yamasaki, Masao Kurosaki

"The effects of plating conditions on the crystal orientation of electrodeposited zinc were investigated by varying elecyrolyte flow rate and current density. Precipitation of the Zn (00 • 2) basal plane is promoted at lower current density and higher flow velocity. Effect of the flow velocity on the mass transport was evaluated based on the polarization measurement in which Cu was used as the tracer. As a result, it has been clarified that the crystal orientation of electrodeposited zinc can be uniquely arranged by the overvoltage (iU0.5) that can be simply calculated by considering -the current density and boundary layer thickness. At the same time, the electrode potential during electrodeposition that can be calculated by using a model based on the competitive reactions of hydrogen reduction 'and zinc reduction exhibits an extremely good correlation with the crystal orientation of electrodeposited zinc.Introduction Electrogalvanized steel sheet has better surface properties than hot-dip galvanized steel sheet, and is used in home electric appliance and automobile applications. Factors such as crystal morphology, crystal orientation and surface roughness have a large influence on its appliance, formability and corrosion resistance [1-3].Electrolysis, condition, bath composition and alloying elements are reported as factors that affect the crystal orientation of the electrogalvanized coating. Factors that can be controlled on time in the production site are electrolysis condition that-is current density and plating solution flow velocity.Some studies[4-6] report that the crystal- orientation of the Zn(00 • 2) plane is increased by promoting, the mass transfer of zinc ions in the plating solution or decreasing the concentration overvoltage, but did not investigate in detail the plating solution flow conditions in the plating cell nor quantitatively determine the effects of both current density and plating solution flow conditions on the crystal orientation of ' electrodeposited zinc."

Jan 1, 2000

By S. -H. Kim

This work investigated the effect of the concentration of CO2 and lead contamination on the forest ecosystem. Changes of the plant growth, lead concentration in soil, plant, and soil microbial community caused by CO2 concentration (380 ppm and 760 ppm) and lead contamination (500 mg/kg) were measured. Plant growth was inhibited by 50% due to lead contamination. Particularly, shoot growth was inhibited more than the root. However, the root elongation was not affected by the CO2 concentration increase. The diversity of microbial population with AWCD (Average Well Color Development) and PCA (Principle Component Analysis) showed that the lead contamination has an effect com-pared to CO2 concentration. The Shannon index calculated from DGGE profiles was high in soil with Pinus densiflora, while the effect of CO2 concentration was not significant (P<0.5). The similarity of microbial community from each treatment showed that lead has an effect on plant growth and microbial community rather than the CO2 concentration.

Jan 1, 2006

By Guillermo Krstulovich

Pillar strength is a fundamental variable in the design of room and pillar mining. A number of researchers have investigated the strength of mine pillars by loading cubical, cylindrical and rectangular model pillars to failure in a compression testing machine (1). Several of these researchers have observed an increase in the compressive strength of model pillar with an increase in friction at the platen-specimen interface (2, 3, 4, 5). It has been postulated that the friction prevents lateral expansion of the specimen, thereby exerting a confining pressure at the interface. Seldenrath and Gramberg in their work with cylindrical specimens of limestone and marble noted that the effect of clamping the ends of the specimens, i.e., to restrict lateral movement of the specimen face, was to increase the compressive strength about 10% for marble and from 50-75% for the limestone, as compared to the same type of specimens when tested with the end planes free (6). No attempt was made to determine the confining pressure exerted by the clamps. In recent years, Bureau of Mines has conducted an extensive study, similar to Seldenrath and Gramberg&apos;s, with dog bone specimens. The confining pressure exerted by the clamps was determined and an increase in the compressive strength with increasing confining pressure noted (7, 8).

Jan 1, 1970

By Evangelos Petrakis, Kostas Komnitsas

This study investigates the evolution of dimensional properties of grinding products, namely, the mass, the surface area, the length, and the number of particle distributions with the energy input in a ball mill. The size analysis of the mill products enables the calculation of the mass distribution of each material at predetermined size classes and then the determination of the other dimensional properties by taking into consideration the geometry of the particles. Based on the distribution of dimensional properties, an effort was made to determine whether the grinding products are fractal in nature. The effect of material type and grinding conditions on the relationship between the dimensional properties and the specific energy input was also investigated. Special importance was assigned to the study of the specific surface area and the surface area production rate, both during the initial grinding stages and at higher energy levels. The determination of the surface area production rate allows the identification of the grinding limit and the maximum specific surface area which could theoretically be achieved. This approach has as ultimate objective the maximization of energy efficiency and subsequently the minimization of the high grinding cost.

By Evangelos Petrakis, Kostas Komnitsas

This study investigates the evolution of dimensional properties of grinding products, namely, the mass, the surface area, the length, and the number of particle distributions with the energy input in a ball mill. The size analysis of the mill products enables the calculation of the mass distribution of each material at predetermined size classes and then the determination of the other dimensional properties by taking into consideration the geometry of the particles. Based on the distribution of dimensional properties, an effort was made to determine whether the grinding products are fractal in nature. The effect of material type and grinding conditions on the relationship between the dimensional properties and the specific energy input was also investigated. Special importance was assigned to the study of the specific surface area and the surface area production rate, both during the initial grinding stages and at higher energy levels. The determination of the surface area production rate allows the identification of the grinding limit and the maximum specific surface area which could theoretically be achieved. This approach has as ultimate objective the maximization of energy efficiency and subsequently the minimization of the high grinding cost.

By Hasan Ozturk

Laboratory testing examined the effect of a variety of intrinsic rock properties and environment conditions that influence the adhesive bond between rock and thin spray-on liners. The liner materials used for these tests were Tekflex, provided by Fosroc, Castonite, provided by Rohms and Haas Co., Rockweb provided by Spray-on Plastics, and CS 1251 2K, provided by Master Builders. Some of the variables examined include: rock strength (tensile/compressive strength) rock mineralogy, rock surface roughness (grain size, fracture/joint roughness), and surface contamination (oil, water or dust). Under optimal conditions, adhesive strengths reaching at least 3 MPa can be achieved. Where the rock surface is contaminated with dust or the rock is weak in tension, it may be difficult to reach adhesion strengths of 1 to 1.5 MPa.

May 1, 2004

By S. Rajeswari, D. Gopi

"Pitting corrosion inhibition of 304 stainless steel (SS) in groundwater with a ternary inhibitor mixture (phosphonic acid + bivalent cation + various surfactants) was studied with different environmental variables such as temperature, pH, dissolved oxygen and chloride ions. Critical pitting potential and corrosion potential were calculated for these test media using electrochemical techniques. Under the tested condition, the localized corrosion resistance of 304 SS was determined and the results are discussed. IntroductionPitting corrosion of metals and alloys is a major cause of failure in chemical processing desalination plants, scrubber for flue gas desulphurization (FGD) plants, water storage tanks and pipelines, petroleum refineries, etc.Heat exchangers and condensers in inland thermal and nuclear powerplants utilize groundwater as a coolant, but materials of construction are generally prone to localized corrosion.Localized corrosion attack can be initiated when the passive film on the metal is disrupted. The presence of certain aggressive anions such as chlorides (Cl-) can migrate to the actively corroding area and stabilize pitting corrosion. Attention has been focussed on improving the resistance of stainless steel against localizedcorrosion in aqueous environments.One of the most accepted methods of avoiding corrosion is by the addition of chemicals (inhibitors). Over the past two decades, some phosphonic acids have been explored due to their good corrosion inhibition efficiency and low toxicity (Fang et al., 1993; Karman et al., 1998; Rajendran et al., 1998; Gopi and Rajeswari, 2000a). Bivalent cations like Zn2+ are often applied as additives to inhibit the metal dissolution (Sekine and Hirakawa, 1986; Aruna Bahadur, 1998)."

Jan 1, 2003

By Martin Langenderfer, Catherine Johnson, Phillip Mulligan, Kelly Williams

The physical geometry of a charge has a direct correlation to the geometry of the shock wave. This relationship appears strongest within the boundaries of the visible fireball. As the shock wave propagates outward past the limits of the fireball, the theory states that the geometry of the shock wave should even out and become more spherical. This paper investigates pressure vs. time at two distances, one ‘Near Field’ at the extent of the fireball and one ‘Far Field.' The two Fields were instrumented with three free-Field pressure probes from PCB oriented at 0, 45, and 90 degrees to the front face of the charge, in the same horizontal plane as the charge. This orientation allows for the comparison of the shock wave from the face and vertices of the charge. All the pressure sensors were connected to a Data Acquisition System (DAS) recording at 2 million samples per second (2MS/s). Two high-speed cameras, a Phantom and an MREL Ranger II, recorded the detonations for qualitative examination of the fireball, and the shock wave. Three charge geometries were used and compared to the shock propagation of a sphere. The other geometries tested are cylinders, cubes, and tetrahedrons. Charges were made from a PETN based sheet explosive. In the Near Field, a lower pressure is observed along charge vertices with highest pressures from each face. In the Far Field, vertices record a higher pressure, possibly due to the shock waves from the adjacent faces intersecting, indicating that shock pressures do not always even out in the Far Field. This paper will describe the methodology and findings of this experiment and attempt to determine causality for trends in the data gathered.

Jan 1, 2018

By Beattie T. A

The ability of explosives to fragment rock has been assessed in small scale trials at the Granite Rock quarry, Baimsdale, Victoria. Three 65 mm diameter holes were fired simultaneously in a five metre bench, and the rock collected, screened and weighed. The mass of fines increased as the explosive strength increased in the series 30(10 ANFOPS

Jan 1, 1990

By SMF Hossaini

With the aim of a clearer understanding of the applicability of existing empirical equations for blast induced ground vibration, an investigation has been conducted on three mostly applied forms of such equations. The effect of explosive type on the applicability of these equations has been assessed by analysing 44 sets of data produced by using two types of explosives, namely ANFO and slurry explosive, in an open pit coal mine. The analysis of the data has revealed that the type of explosive affects the applicability of the criteria of the three equations. All three criteria have better correlation with the data of shots in which ANFO was used than the shots with slurry explosive. However, the applicability of one of the criteria is reduced, by far, only by replacing ANFO with slurry explosive for the same ground conditions. It was also found that one of the parameters of these criteria (i.e. “k”) is significantly sensitive to the type of explosive in all the three equations. The degree of influence to the values of “k” obtained by the variation of explosive from ANFO to slurry explosive in the three equations is 76.3%, 811% and 39%. This implies that “k” is not only dependant on ground conditions, as stated in most previous publications, but is also strongly a function of the type of explosive.

Jan 1, 2004

By W. G. Miller, J. D. Scott, D. C. Sego

An overall study was conducted to evaluate the properties and processes influencing the rate and magnitude of consolidation for oil sands fine tailings produced using different extraction processes. As part of this overall study, consolidation tests using slurry consolidometers were carried out for caustic and non-caustic fine tailings. The influence of a change in bitumen extraction process (caustic versus non-caustic) on consolidation properties, namely compressibility and hydraulic conductivity, was determined, as was the effect of adding a coagulant (calcium sulphate [CaSO4]) to caustic fine tailings. For fine tailings originating from two different oil sands ores (Ore A and Ore B), results were presented in terms of variation in average void ratio with time (settlement), void ratio with effective stress (compressibility), hydraulic conductivity with void ratio and coefficient of compressibility and hydraulic conductivity with sodium adsorption ratio. Findings indicated that chemical characteristics of fine tailings (water chemistry, degree of dispersion) do not have a significant impact on their compressibility behaviour and have only a small influence at high void ratio (low effective stress). The biggest advantage of non-caustic fine tailings and treating caustic fine tailings with coagulant is an increased initial settlement rate and slightly increased hydraulic conductivity at higher void ratios. Thereafter, compressibility and hydraulic conductivity is governed by effective stress.

Jan 1, 2010

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT: As part of an overall study of properties and processes influencing consolidation of oil sands fine tailings resulting from different extraction processes, self-weight consolidation tests were per-formed. Fourteen 2 m and 1 m high standpipe tests were instrumented to monitor the rate and magnitude of consolidation of seven fine tailings materials. Tests provided valuable information about the variation of consolidation related to differences in fine tailings material properties that result from a change in bitu-men extraction process (caustic versus non-caustic). In addition, the effect of adding a coagulant to caustic fine tailings was measured. Test results are presented and discussed in terms of consolidation rate long-term volume decrease, compressibility, and downward drainage. Non-caustic fine tailings had fasterinitial consolidation, which is important in tailings ponds for reducing storage capacity and returning decant water at a faster rate to the extraction plant. Similar results were obtained for caustic fine tailings with a coagulant addition. However, long-term settlement of the different fine tailings appears to con-verge to a similar value over time because it is then governed by effective stress.

Jan 1, 2011

By W. G. Miller

An overall study was conducted to evaluate the properties and processes influencing the rate and magnitude of consolidation for oil sands fine tailings produced using different extraction processes. As part of this overall study, consolidation tests using slurry consolidometers were carried out for caustic and non-caustic fine tailings. The influence of a change in bitumen extraction process (caustic versus non-caustic) on consolidation properties, namely compressibility and hydraulic conductivity, was determined, as was the effect of adding a coagulant (calcium sulphate [CaSO4]) to caustic fine tailings. For fine tailings originating from two different oil sands ores (Ore A and Ore B), results were presented in terms of variation in average void ratio with time (settlement), void ratio with effective stress (compressibility), hydraulic conductivity with void ratio and coefficient of compressibility and hydraulic conductivity with sodium adsorption ratio. Findings indicated that chemical characteristics of fine tailings (water chemistry, degree of dispersion) do not have a significant impact on their compressibility behaviour and have only a small influence at high void ratio (low effective stress). The biggest advantage of non-caustic fine tailings and treating caustic fine tailings with coagulant is an increased initial settlement rate and slightly increased hydraulic conductivity at higher void ratios. Thereafter, compressibility and hydraulic conductivity is governed by effective stress.

Aug 1, 2010

By Panfeng Gou

In order to solve the problems of supporting the roof of the gateroads affected by a fault, the movement characteristics of roof strata must be fully understood. In this paper, a plane stress physical simulation model was constructed to study roof strata displacement and deformation of gateroads driven in the hanging wall of the fault after the coals in the footwall were extracted. The results indicated that, due to the effect of fault, vertical cracks, orienting parallel to the dip of the fault, occurred in the horizontal direction of the model within the areas affected by the fault. The roof strata are discontinuous. On the other hand, non-uniform subsidence of roof strata occurred due to the bedding plane separation in the vertical direction. Roof strata, especially the lower roof strata, dip toward the fault. Failure of the surrounding strata is not symmetrical with the roof and floor close to the fault being deformed severely. In the selection of type of supports for the gateroads, the U-shaped steel supports are superior to roof bolting.

Jan 1, 2006