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By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By Z. Zhang, M. -Y. Liu, X. -G. Chen, F. Breton

"The microstructures of AlSi10Mg foundry alloy in permanent mould (PM) and high pressure vacuum die (HPVD) castings were analyzed and compared. The as-cast microstructures of two castings mainly consisted of eutectic silicon particles, primary Mg2Si and Fe-rich intermetallic phases. The surface layer in HPVD castings, which has a unique feature and different structures, was carefully characterized. The dimension variation of microstructural phases along the cross section in PM samples is less than that in HPVD samples, although the size of microstructural phases in PM samples was much larger than that in HPVD samples. The mechanical properties of PM and HPVD samples were evaluated on as-cast and T6-treated conditions. The tensile properties of HPVD castings are remarkable better than those of PM castings on the as-cast condition. The T6 heat treatment greatly improves the tensile strength of PM castings while it has limited impact on the tensile strength of HPVD castings.INTRODUCTION The AlSi10Mg alloys are widely applied to the high pressure die casting (HPD) and high pressure vacuum die casting (HPVD). In the HPD process, the melt is injected into the die cavity under a high speed (30–50 m/s in the gate velocity for aluminum alloys), and solidified under a high pressure (up to 200 MPa in the cavity) and with a high cooling rate (up to ~103 Ks–1) (Gourlay, Laukli & Dahle, 2007; Ji, Wang, Watson & Fan, 2013). This results in a unique microstructure feature that is different to other casting processes under gravity. One major concern in HPD castings is porosity due to trapped air in the cavity (Ji et al., 2013), which seriously restricts the application of a heat treatment on the improvement of mechanical prosperities because of the formation of blisters on casting surfaces. For the process improvement, the high pressure vacuum die casting was developed in 1980s (Uchida, 2009). In this process, the melt is injected into the die cavity under reduced pressure (vacuum), which greatly reduces gas porosity in castings due to effectively avoiding the trapped air. Consequently, HPVD castings are heat-treatable without the formation of blisters on castings surface during heat treatment. The HPVD process has been widely applied to produce high quality structural castings in recent years attributed to reliable vacuum system development (Uchida, 2009). However, the microstructure features of HPVD castings are not systemically characterized yet."

Jan 1, 2018

By R. G. S. Mussi

An inclined cooling plate is utilized as a modification in the compocasting process of magnesium alloy and the mechanical properties of the composites obtained are studied in this work. Based on crystal separation theory, molten AZ91D is poured onto an inclined plate in order to produce solidification nuclei inside the fluid metal, and is mechanically stirred while reinforcement is added. Particulate SiC was utilized as reinforcement in quantities varying from 0 to 15%vol. Dispersion of the reinforcement was observed by macro and microstructure analysis. SiC was properly mixed into matrix until 15%vol., and Vickers hardness tests were carried out for the composites produced. Results obtained for hardness were shown to increase with reinforcement addition and comparable to those of traditional compocasting. Utilization of Inclined Cooling Plate produced good inclusion and homogenization of SiC through an AZ91D matrix, at lower temperatures and shorter times than traditional compocasting.

Jan 1, 2006

By Sangjian Zhang, Zhu Xiao, Lairong Xiao, Rushi Chen, Mei Fang, Zhou Li

The copper-graphite metal matrix composites were fabricated by two different production methods: directly sintering with copper and graphite (Cu-Gr composite), and in-situ sintering with cuprous copper and graphite (Cu2O-Gr composite). During the in-situ reaction sintering, a redox reaction occurs at the interface of the Cu2O particles and Gr particles, resulting in the improved physical and mechanical properties of Cu2O-Gr composites. Compared with Cu-Gr composite, Cu2O-Gr composite has a higher compression strength at any given graphite content due to the improved interface bonding and uniformly distributed fine graphite particles in the matrix. Increasing graphite content decreases the mechanical properties of the copper-graphite composites. The compression strength of Cu2O-Gr composite is 50-100 MPa higher than that of Cu-Gr composite. INTRODUCTION Copper-graphite composites have been widely used in industry due to their low density, relatively high strength and hardness, good thermal and electrical conductivity, arc ablation resistance and self- lubrication ability (Grandin & Wiklund, 2018; Han & Xu, 1999; Huang et al., 2017). Electric sliding contact friction pair in the high-speed railway system and motor brush in electric contact components have a very high demand on electrical conductivity and self-lubrication ability of materials. The electric devices need to bear both mechanical load and high electric current. Copper-graphite composites with good mechanical, electric and self-lubrication properties are the best candidates for application in multifunctional electric sliding contact frication components. The relative sliding speed of friction pair is developing towards 100 m/s or even faster, which can withstand the electric flow of more than 800 A, and it is often accompanied with vibration and impact (Guo & Ding, 2008). Conventional wear-resistant materials can no longer meet the current requirements and this promotes the development of copper- graphite composites with excellent comprehensive properties (Ding, Chen, Zhu, Zhang, & Zhou, 2009; Yasar, Canakci, & Arslan, 2007). There are many ways to fabricate copper-graphite composites, mainly including powder metallurgy method, liquid immersion infiltration method, rapid sintering method and electrodeposition method (Kalin & Poljanec, 2018; Kim, Lee, & Han, 2014; Liu et al., 2018; Wang et al., 2018). Each method has its own advantages and disadvantages, and the powder metallurgy method is the most commonly used one due to its simple process, high economic benefit, and industrial production applicability. The common steps of the powder metallurgy method are as follows (Samal, Parihar, & Chaira, 2013): firstly mixing the copper (copper alloy) powders and graphite with a certain ratio, following by die-forming, and then sintering at the high temperature with or without pressure. The advantage of copper-graphite composites is that the graphite distributed in the copper matrix uniformly and it can form a carbon diaphragm preventing the wear of the composite (Fu & He, 2010). However, the bonding strength of the interface between the copper matrix and the graphite is relative low as the combination between them is mechanical interlocking but not metallurgical bonding (Ma et al., 2008). It is meaningful to develop new fabrication technology of copper-graphite composites with better interface bonding, which could provide guidance for the design of copper-graphite composites with excellent comprehensive properties.

Jan 1, 2019

By S. Xu

Magnesium alloy AM50 is of interest to automotive cradle application because of it excellent castability and good ductility. In this work, microstructure and mechanical properties of both low pressure die cast (LPDC) and high pressure die cast (HPDC) AM50 test bars are characterized. Microstructure was examined using optical microscope, scanning electron microscope (SEM) and transmission electron microscope (TEM). Phase identifications were performed using energy dispersive x-ray spectrometer (EDS) and TEM diffraction. It has been found that LPDC produces much coarser microstructure than HPDC. At the same time, the HPDC samples are more heterogeneous in microstructure and composition close to grain boundaries. Particles with various dimensions and morphologies of two different intermetallic phases, Mg17A112 and A18Mn5, were found in all the samples. Mechanical tests were performed under conditions similar to those related to an engine cradle application. LPDC samples show lower strength but better creep resistance than HPDC mainly due to the difference in grain sizes and grain boundary microstructure between LPDC and HPDC. Creep curves are well described by the empirical Andrade equation. Tensile-compressive yield and creep asymmetries were found in AM50, i.e. better deformation resistance in tension than in compression. The average yield asymmetry ratio for all the samples is 0.87. Microstructural examinations on the samples tested in tension, compression and creep showed that the deformation mechanisms in AM50 were slip plus twining at temperatures up to 125°C. The examinations indicate the important role of twining in the asymmetry phenomenon. The creep results indicate that dynamic precipitation of the Mg17A112 phase during testing is not the mechanism directly responsible for the creep asymmetry in AM50.

Jan 1, 2004

By K. Izumi

Ultra-grain refinement and high strengthening of metals by accumulative roll bonding (ARB) was widely reported. However, applications of ARB to magnesium alloys were rather limited. In this study, Mg-9%Li-1%Y sheets were applied to ARB at room temperature. Six 0.5 mm thick sheets were stacked and reduced into 0.5 mm thick by four passes. The procedure was repeated up to three cycles, so that the equivalent strain of 6.2 was applied. The sheets show dual phase structure with a (hcp) and ß (bcc). Grains elongates to the rolling direction with increasing number of ARB cycles. After three cycles, fragmented a grains with average size of about 300 nm are uniformly distributed. After the first cycle, the ultimate tensile strength increases to 180 MPa from 133 MPa, while the elongation decreases, however, still high (26%). The tensile strength slightly decreases by the second cycle and does not change at the third cycle. Meanwhile the elongation increases by the second cycle and the sheets show 41% of the elongation after the third cycle.

Jan 1, 2006

By C. Y. Lim, H. W. Kim, M. S. Kim, J. H. Cho, Y. S. Lee

Al - 5.5 wt% Mg - 0.3 wt% Cu alloy strip was successfully fabricated by horizontal-type twinroll casting (TRC). For producing sound strips with no surface defect, the casting was conducted at various roll rotation speed, and the sound strip could be obtained at relatively low casting speed (3 rpm). The cast strip was homogenized at 450 °C for 10 hours, and then cold rolled with a reduction rate of 78%, followed by a final annealing at 450 °C for 1 hour. The annealed sheets showed good mechanical properties with approximately 330 MPa in tensile strength and 27 % in elongation, but exhibited strong anisotropy depending on the tensile directions. For the homogenized sheets, warm rolling was also conducted at 200, 300, and 400 °C. The tensile test results of the warm-rolled sheets showed that the rolling at medium temperature (300 °C) was proper to fabricate the sheets with relatively good mechanical properties and low anisotropy.

Jan 1, 2014

By Guojun Wang, Zejun Chen, Wenchang Liu

Al/Mg/Ti laminated metal composite sheet (LMCS) can combine the merits of each of metal components, and obtain excellent performances. It incorporates the advantages of high strength, light weight, easy melt and atomization, and good space adaptability to substitute for the bumper Al sheet of Whipple shield structure for space debris shield. The Al/Mg/Ti LMCS was fabricated by hot roll bonding technology in a certain sequence. The manufacturing process and parameters were analyzed and studied, including the first rolling reduction, roll boding temperature and stacking structure of each metal. The microstructure of dissimilar metals and bonding interface were characterized and analyzed. The optimized manufacturing procedures and parameters were presented based on the microstructure and mechanical properties of LMCS. The research results offer some guides and references for controlling the shape of bonding interface, optimizing the annealing process, improving the mechanical properties of Al/Mg/Ti LMCS.

Jan 1, 2015

By A. Singh

Two alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho have been processed by direct extrusion at 300°C and 200/230°C to produce various microstructures containing icosahedral quasicrystalline phase with different grain sizes. The alloys were mechanically tested in tension and compression. The mechanical properties were related to the grain size and microstructures studied by transmission electron microscopy. The extruded alloys showed a mixture of nano-sized icosahedral and monoclinic Mg4Zn7 phase, as well as icosahedral phase particles a few hundred nanometers in size distributed in the matrix. Coarse icosahedral phase particles several micron in size also remained after extrusion. The alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho extruded at the same temperature of 300°C produced very different grain sizes of 15 and 3 µm, respectively. The alloy Mg96.9Zn2.7Ho0.4 extruded at 200°C and Mg93Zn6Ho extruded at 230°C produced grain sizes of 0.7 µm and 1.5 µm, respectively. Both the alloys showed yield stresses of about 300 MPa in both tension and compression with elongations of about 18%. Hall-Petch parameters are calculated for the alloys.

Jan 1, 2006

By Sandeep Singh Sandhu, Karanvir Singh Ghuman, Manjit Singh

"Cobalt based super alloy stellite 6 was weld cladded on AISI 304 L stainless steel using SMAW process in order to improve the wear resistance for tyre crusher blades. Microstructure characterization and micro hardness testing was performed on stellite 6 cladding. The suitable parameters viz. 80 Amp current with arc weaving technique was selected by performing bead on plate experiment were further used for depositing multipass multilayer cladding to achieve full filler chemistry at the top surface. Further GTAW process was used for re-melting the top surface of the cladding. Comparative evaluation of the claddings showed that TIG re-melting resulted in increased microhardness and wear resistance in comparison to as cladded specimens even with lesser deposition of material. It was observed that TIG re-melting improved the hardness from 603 HV0.5 kg to 712 HV0.5 kg. Micro structures of stellite 6 contained cobalt solid solution matrix along with inter dendrite chromium carbides which resulted in the increased micro hardness values. Pin on disc abrasion tests were carried out at room temperature and the worn out surfaces were characterized using SEM and EDS.INTRODUCTIONThe crusher blades are used in many industries for crushing various types of material and its wider applications in tyre rubber crushing mills, metal-powder crushers industries etc. Most of the crusher blades are damaged by the wear and impact loading conditions. It is because of metal to metal abrasion and the temperature also plays a vital role in blunting the cutting edges of these blades. The wear is the major cause which leads to loss of material and thus the productivity that can never be recovered (Kotechi et al., 1992). The wear can be reduced by coating of various super alloys which could reduce the behavior of metal degradation even in aggressive environments. Cladding of cheaper low alloyed material with expensive superalloys to enhance the performance of components at low cost has been investigated by many scholars (Deng et al., 2010, Kennametal, 2007, Lolla et al., 2014, Singhet al., 2014, J.N et al., 2003, Ramkumar et al., 2012). Many researchers have reported that cladding is an application of build-up deposits of specialized alloys to resist abrasion, high temperature corrosion and impact loadings. Cladding is used for providing required mechanical strength properties as well as inhibition of oxidation and other corrosive degradation. Coatings are used to protect the heat affected areas like tubes of fluidized bed combustor etc. (Kirchbner et al., 2008, Wang et al., 1994, Hocking et al., 1993, Ananthapadmanabhan et al., 1991, Staia et al., 2001). Coating techniques are widely used for the protection of turbine engine and boiler tubes against high temperature corrosion attack, power generation equipment, chemical process equipment, aircraft engines, pulp and paper processing equipment, bridges, rollers and concrete reinforcements, orthopedics and dental, land-based and marine turbines, ships. Coatings of stellite 6 are widely used in steam turbine blades and boiler tubes for power generation because of an excellent combination of impact, wear and other properties. It can maintain its properties even at high temperature and in harsh environments (Kobayashiet al., 1999, Alam et al., 2009, Munehru et al., 2009). The loading and unloading conditions experienced by the material may induce the surface cracks which lead to its breakage and leaving large pits in the surface (Meng et al., 1995). Many researchers have reported that the properties of cladded layers can be increased by various techniques such as controlling the current variations, dilution, heat input, laser and other re-melting processes, addition of special alloying elements, speed of weldingetc(C.M Anaet al., 2002, Kumaret al., 1999, Luo et al., 2012, et al., Madadi et al., 2011, Shin et al., 2003, Kuzucu et al., 1997, Sudha et al., 2008, Sawant et al., 2017, Houdkova et al., 2016, Ciubo"

Jan 1, 2017

By R. Boom, L. Holappa

In the present paper, microstructure changes of solid-state reduction of industrial chromite pellets and lumpy ore were investigated with SEM/EPMA. To simulate the reactions in the packed bed zone of the Submerged Arc Furnace (SAF), carbon monoxide was used as the reducing agent, with the presence of graphite in proximity to chromite. The experiments were carried out at 1500 °C. Scanning electron microscopy was used to observe and analyse the structure and composition changes of the chromite samples. It was found that reduction of lumpy ore generally took place slower than that of pellet. In all samples, chromite reduction proceeded faster in the outer part of the sample than in the centre part. The reaction mechanism is discussed on the basis of experimental results and earlier investigations. The possibilities to optimize the FeCr production process are also discussed.

Jan 1, 2007

By O. F. Ochonogor

Laser metal deposition (LMD) is an additive manufacturing technique whereby a stream of metal powder is consolidated by a focused laser beam on the surface of a substrate or engineering component. The interaction zone between the laser beam and powder particles is scanned superficially, generating tracks of deposited material. The tracks are overlapped in a deposition strategy in accordance with slices of a CAD model. Successive layers of material are built up to fabricate a near net shape part. In this work, the technique is used to fabricate metal matrix composites (MMCs) by using an elementally blended feedstock combining metal and ceramic powders in the melt pool, which melt and solidify to create the required morphology. Ti6Al4V + TiC MMCs were produced with 10, 20, and 30 vol.% reinforcing ceramic, and Zr + TiC MMCs were fabricated with 10, 20, and 30 vol.% TiC. The deposited thin walls were analysed using optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), and indentation testing. In both systems, the analysis revealed the presence of partially melted TiC particles embedded in the metal matrix along with fine dendrites of re-solidified ceramic. The dendritic structures in the Ti-based composites were confirmed as TiC, whereas in the Zr-based composite the Zr metal reacts with theTiC to form ZrC, leaving Ti in solid solution. Both the MMCs show an increase in microhardness with increasing ceramic (carbide)content, reaching a peak HV0.1 value of 500 in the Zr- based MMC and HV0.1 of 550 in the Ti based MMC.

Jan 1, 2012

By S. Yue, P. Vo, M. Jahazi

The flow behaviour and microstructure development of a near-alpha titanium alloy during beta working has been investigated. Typical cogging conditions were simulated through compression testing of IMI834 at temperatures of 1025°C-1100°C, strain rates of 0.01 s-1 - 1 s-1 and post-deformation heat treatments up to 4h. Using a synthesis of available literature models, a finite element model has been developed and validated through quantitative measures of flow stress-strain data and beta grain characteristics. Flow behaviour was analyzed through a self-consistent method while the microstructure development was considered with regard to the kinetics of beta recrystallization. Deformation at beta or high alpha/beta working temperatures (T>l025°C) produced minor flow softening with complete grain refinement achieved through metadynamic recrystallization.

Jan 1, 2006

By G. Avramovic-Cingara, H. J. McQueen

The microstructure of commercially pure aluminum was investigated by using polarized optical microscopy (POM), orientation imaging microscopy (OIM), and transmission electron microscopy (TEM) techniques. Specimens were deformed in torsion at 400°C and equivalent strain rate of 0.1 s-1, to various strains of 0.2, 0.5, 1, 4, and 6. The results indicate that POM can usefully reveal grain and subgrain structures over a large field in aluminum. TEM is most suitable to study dislocation substructure and evolution of subgrains. While TEM microscopy and OIM are capable of resolving individual subgrains, OIM can not reliably distinguish subgrains with small misorientations, particularly in samples with low strain. On the other hand, the OIM technique is very useful in the analysis of many regions surrounded by high, medium, and low angle boundaries (HAB, MAB, LAB). Various misorientation maps were studied using different data processing methods. The analysis revealed that the subgrain size is relatively insensitive to strain. The fraction of low LAB ( < 5°) decreased and HAB (>15°) increased conversely with increasing strain, whereas MAB (5-15°) remained stable. The development of an increasingly bimodal grain boundary misorientation distribution is consistent with the predominance of dynamic recovery (DRV) in the evolution of microstructure, combined with geometrical dynamic recrystallization (gDRX), now called grain-refining DRV.

Jan 1, 2006

By K. Matsuura, M. Ohno, T. Tokunaga

"Recently, weight saving of automobiles has been strongly required to solve the global environmental problems. Mg alloys are one of the promising candidates as a new material for automobile components. However, the application of the Mg alloys is limited due to their poor corrosion resistance. In the authors’ preliminary study, an Al/Mg/Al clad sheet was fabricated by hot extrusion and subsequent hot forging. The clad sheet exhibited a high corrosion resistance and excellent super plasticity. More specifically, the elongation of the clad sheet was as high as 550%.Importantly, despite that the elongation of Al itself was only 40%without cladding with Mg, the ductility of Al was greatly improved in the form of the clad sheet. In the present study, in order to clarify the mechanism of the superplastic deformation of the Al part in the clad sheet, the microstructure evolution of the Al during the tensile de formation is investigated. The tensile tests were conducted at a temperature of 573 K and at a strain rateof1.0×10-3s-1. The Al exhibited fiber-type texture at the beginning of the tensile deformation, and brass-type texture after the elongation of 50%.INTRODUCTIONMg alloys have been gaining attention because of their excellent properties e.g. light weight, good recyclability and high electromagnetic shielding. However, their practical applications have been limited due to their poor corrosion resistance. In the authors’ previous study, in order to solve this problem, Al coating on Mg alloy by hot extrusion has been proposed, and the Al-coated Mg alloy plate was fabricated(Tokunaga, Matsuura, &Ohno,2012). The plate was hot-rolled and an Al/Mg/Al clad sheet was fabricated. No cracks or debondings were observed at the Al/Mg interface. The sheet exhibited a high corrosion resistance in a comparable level as pure Al. Also, the sheet exhibited a large and uniform elongation of 550%in a tensile test at a temperature of 573 K and at a strain rate of 1.0×10-3s-1without any breakings or debondings of the Al part(Tokunaga, Matsuura, &Ohno,2014).Mg alloys have been known to exhibit a superplastic characteristic when the grain size is small. However, it is known that the pure Al does not generally exhibit the super plasticity. As mentioned above, the Al-coated Mg alloy sheet exhibited 550% of elongation in the authors’ previous study (Tokunagaet al., 2014). However, the pure Al itself showed only 40% of elongation, while the Mg alloy itself exhibited 800% of elongation. Thus, it has been demonstrated that the pure Al was super plastically elongated when it was bonded with the Mg alloy. Generally, deformation mechanism of the super plasticity of the Mg alloy is known as a grain boundary sliding. On the other hand, the mechanism of the superplastic elongation of the pure Al is still unclear. The purpose of the present study is investigation of the deformation behavior of the Al part in the Al/Mg/Al clad sheet during tensile de formation."

Jan 1, 2018

By L. A. Matthews

The embrittlement of the Ti-6Al-4V alloy by hydrogen dosing at elevated temperature has been investigated. Metal coupons were subjected to isothermal treatments in a partial hydrogen atmosphere in the temperature range from 650ºC?950ºC and the degree of embrittlement after treatment was determined by drop-weight impact testing. Embrittlement was found to be inversely related to reaction temperature as a result of the combined effects of greater hydrogen absorption and titanium hydride precipitation at the lower isothermal temperatures. Keywords Titanium, hydrogen embrittlement, impact energy

Jan 1, 2011

By Timothy W. Skszek, Adrian S. Sabau, Hebi Yin, Xiaoping Niu

The microstructure evolution during solution treatment plays an important role in mechanical properties of heat-treated aluminum alloys. In this paper, models were reviewed that can predict the microstructure evolution during the solutionizing process of the aging heat treatment of aluminum alloys. The dissolution ofMg2Si particles has been modeled as a diffusion process of Mg in the a-Al matrix. The evolution of volumetric fraction of fragmented silicon as a function of time and temperature was also considered. The growth and coarsening of silicon particles during the heat treatment was considered. It was found that constitutive equations and required property data for most of the phenomena that need to be considered are available. Several model parameters that need to be obtained from material characterization were identified. Pending the availability of these model parameters, this comprehensive model can be used to describe the microstructure evolution of aluminum alloys in order to optimize the solutionizing heat treatment for energy savings.

Jan 1, 2013

By Kathie Mcgregor, Muhamad Firdaus, Nathan A. S. Webster, Yvonne Durandet, W. John Rankin, M. Akbar Rhamdhani

There is a growing interest in recycling/recovery of rare earth elements from permanent magnets. A number of processing techniques are currently being developed but are highly sensitive to the oxidation state of the material. The oxidation microstructure of NdFeB magnets is studied at high temperatures (773-1173 K) to understand oxide formation mechanisms and support the development of viable recycling strategies.

Mar 1, 2017

By M. A. Neri

A lead-free solder alloy Sn-57.5Bi-0.5Ag has been developed by mechanical alloying and foundry processes, and has great potential as a lead-free solder system, to low temperature applications. The mechanical alloying powders show a microstructure different to the microstructure obtained by the foundry process for the same alloy. Its melting point of 142°C is slightly higher than that of eutectic tin- bismuth solder. Examination of the microstructure revealed that eutectic microstructure is refined by the mechanical alloying process Ag additions. The lamellar structure of tin-bismuth gradually disappeared with the process of mechanical alloying, while intermetallic compounds AgaSn phase was formed. The Cu-Sn intermetallic compound layer formed at solder-copper interface is the Cu6Sn5 phase. Keywords: Lead-free solder, Microstructure. Mechanical alloying

Jan 1, 2003

By Kan Song, Lin Liu, Hengzhi Fu, Jun Zhang, Haijun Su, Xiaojiao Jia

"Al2O3/YAG/ZrO2 eutectic in situ composite has been regarded as new generation of high temperature structural material due to its excellent performance even close to its melting point. The directionally solidified Al2O3/YAG/ZrO2 eutectic ceramics are prepared by recently developed Laser Floating Zone Melting (LFZM) apparatus in which a splitter mirror is used to obtain two beams with the same quality from one CO2 laser. With the two laser beams irradiate the sample from opposite directions, the sample is zone melted. The apparatus configuration and the solidification processing are described in detail. The solid/liquid interface morphology is studied and the mechanism of microstructure formation especially the characteristic of eutectic cellular is discussed. It is shown that YAG and ZrO2 phases play a leading role during the ternary eutectic growth. Meanwhile, the relationship between the solidification microstructure and the processing parameters are investigated.IntroductionAl2O3/YAG/ZrO2 ternary eutectic in situ composite, due to its excellent high temperature mechanical properties, is now considered to be a promising candidate material as a replacement of nickel based super alloy for new generation aero space engine turbine blade [1]. They exhibit flexural strength of 360-500 MPa from room temperature to 2073K in air atmosphere [2]. The compression creep strength at 1873K is 433MPa with the strain rate of 104/s [3]. However, because of the high melting point and complex physical properties, there remain still many difficulties for its application. One of the bottlenecks is the poor understanding of the relationship between microstructure and solidification conditions."

Jan 1, 2012