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By Oliver Bowles

In 1943 the Bureau of Mines began a review of trends in consumption and prices of the more important nonmetallic minerals. The first report covering building materials4/ appeared in December of that year. The present paper, which deals with chemical raw materials and fertilizers, is the second of the series. The 34 years from 1910 to 1943, for which statistics are presented herein, comprise periods of uneventful peace, unparalleled prosperity, industrial depression almost to the point of stagnation, and two wars of world proportions.

Jan 1, 1945

By Frank E. Cash

The iron-ore ranges in the Lake Superior district are the liarquette in Michigan, Menominee and Gogebic in Michigan end Wisconsin, and the Vermilion, Mesabi, and Cuvuna in Minnesota. These ranges produce about 85 percent of the iron ore mined in the United States. Accident experience in connection with this production is better than that of the regions producing the remaining 15 percent. Production and shipments vary slightly from year to year but closely approximate each other over a period of years. During the 4-year period 1940 to 1943, inclusive, 323,667,599 long tons of iron ore was shipped from the Lake Superior district.4/ Michigan and Wisconsin shipped 65,386,608 tons, or 20.2 percent of the total, and employed approximately 15,000 men; Minnesota shipped 258,280,991 tons, or 79.8 percent of the total, and employed approximately 10,000 men. The tons produced per man employed is much, greater in Minnesota than in Michigan and Wisconsin owing to the large open-cut production in Minnesota.

Jan 1, 1945

By A. C. Fieldner

The past full year of war has increased greatly the demand for virtually all kinds of fuel, and the Bureau of Mines research and service facilities have been extended to meet these unprecedented requirements. Liquid fuels, such as aviation and motor gasolines, are fundamental to modern warfare. Bituminous coal and anthracite are needed, not only to servo the expanded industrial program for which coal normally is used but also to replace natural gas, wherever possible, and fuel oil in the Eastern States, New England, and the Pacific Northwest. Railroad transportation with energy derived from coal is replacing much of the motor-vehicle transportation that has been stopped or curtailed to conserve rubber. Pulverized coal hoe been sound to be a satisfactory and cheaper substitute for fuel oil in metallurgical heating furnaces. Celloidal fuel - a mixture of coal dust and oil - may offer a partial substitution for curtain coal-burning equipment. Several industrial experiments have been made with this type of fuel. The expansion of the steel industry in connection with the war program has required a corresponding increase in the production of metallurgical coke and its associated byproducts - light oil, tar, ammonium sulfate, and surplus gas. If the war is of long duration and new reserves of petroleum are not discovered, wartime trends from fuel oil to coal probably will not be reversed.

Jan 1, 1945

During the interval 1929-41, geophysical exploration in Russia made considerable progress, as reflected in publications. The greater part of these publications was available during the preparation of Geophysical Abstracts and Ms been abstracted in them. The rest was not received and remained unaccounted for. A considerable portion of these lading publications are now listed in bibliographic form, in view of their interest to geophysicists. All publications entered in the bibliography are in Russian. 1. GRAVITATIONAL METHODS 1. Abakelia, M. S. The Organization of Gravitational Observatories in Transcaucasia. Problemy Sovetskoi Geologi, Moscow, vol. 6, No. 5, 1936, pp. 452-454.

Jan 1, 1945

Geophysical Abstracts 1 - 86 wore issued in mimeographed form by the Bureau of Mines; Abstracts 87 - 111 were published in bulletins of the Geological Survey; Abstracts 112 - 119 were issued in mimeographed form by the Bureau of Mines as Information it ion Circulars 7256, 7257, 7267, 7273, 7285, 7292, 7303, and 7310. 1. GRAVITATIONAL METHODS 7786. Barton, D. C.3/ Case Histories and Quantitative Calculations in Gravimotric Prospecting. Am. Inst. Min. and Meat. Eng., New York, Tech. Pub. 1760, 1944, 49 pp.

Jan 1, 1945

By W. J. Kroll

The production of beryllium metal and its alloys is one of the most difficult tasks in metallurgy. In this report we shall examine the progress made in this work- in the last 15 years; taking into account the outstanding publications, including; those of the patent literature, and the information obtained during our 20 years? experience with this metal. The difficulties experienced' in producing elementary beryllium derive from the physical nature as well as from the chemical behavior of the metal and its compounds. Its oxygen affinity is about the same as that of calcium and a little higher than that of magnesium. Its chlorine affinity is much lower than that of magnesium, about equal that, of manganese, and little higher than that of aluminum. The sulfur and nitrogen affinity is probably almost the same as that of calcium for these elements, and beryllium carbide is probably more stable than aluminum carbide, A14C3. The intermetallic affinity of beryllium may be given in descending order, as follows: Nickel - copper - iron. It forms eutectics with -aluminum and silicon as well as with silver. It does not alloy with magnesium and only partly with calcium. Its oxide melts at 2,570° C., but CaO and BaO form readily fusible eutectics with BeO(65).3/ No igneous solvents are known for BeO, which behaves id this regard like Mgo. The beryllium silicate is a strong compound, the aluminete much less so; however, CaO easily displaces Be in the heated mixtures. The Anhydrous chloride hydrolyzes, and it cannot be made from aqueous liquors. It sublimes at 488° C, and melts at 405° C., The fluoride, which, is very Soluble in water, hydrolyzes also, but a kind of oxyfluoride of the approximate formula 2 BeO?5 BeF2 can be made from solutions by dessication. The fluoride melts at 800° C, and boils above 1,100° C. It forms very stable double fluorides with alkalifluorides, which have very low melting points and are fairly soluble in water. They are more stable than the analogous fluosilicates and the sodium fluoaluminate cryolite.

Jan 1, 1945

By W. J. Kroll

Despite the fact that barium minerals are plentiful and widely distributed in nature, this element is one that we do not yet know how to prepare cheaply in metallic form. This is due to its chemical activity, as evidenced by its great affinity for fluorine, chlorine, oxygen, nitrogen, hydrogen, and sulfur. Furthermore, it forms a very stable subchloride and subfluoride, which prevents isolation of the metal by fusion electrolysis from a halide bath. A good survey of the metallurgy of barium calcium, arid strontium has been made recently in Light Metals (54,55).3/ Metallic magnesium (46), calcium (83), barium, and strontium (27) reduce each other's oxides. Proof of this can be found in the activation of BaO after reduction with Mg, which leads to the formation of so-called "Maquenne" mixtures (58) used for absorbing gases. However, it is impossible to extract the reduced metal- from the residue, a fact that Guntz (25) attributed to the formation of barium suboxide. There is no necessity for presuming the formation of such a compound, as it has boon established that in the reduction there is always formed an alloy of the alkaline-earth metal with the magnesium, which is capable of producing hydrogen when brought into contact with water. The reduction of alkaline earth-metal oxides with aluminum was observed by Mallet (57) in 1877, but recent investigations have shown that the end product of the reaction is an alloy of aluminum with the alkaline earth metal (1,2). Silicon also has been suggested as a reducing agent, and the results obtained are the same (84,85).

Jan 1, 1945

By D. Harrington

The greatly extended use of the underground trolley-locomotive system for hauling coal without doubt was one of the most important factors in the rapid progress of coal mining and the increased production of coal in American coal mines during the period 1910-20. Much of the superior efficiency of production of our underground coal and metal lines should also be credited to the trolley locomotive system. The trend to mechanization of mines during the past 15 years, mere particularly the past 5 years, with higher production per man employed and greatly accelerated advancement of working places, has required increased use of trolley locomotives, necessitating larger equipment, higher speeds, and more 'frequent turn over of pit cars. This is re¬flected in increased size of locomotives and the use of larger mine ears (some with a capacity up to or over 10 tons); moreover, heavier rails and larger-size trolley wires have boon or ought to have boon installed. Trolley-locomotive haulage has proved to be rapid; economical, efficient, and productive; nevertheless; in spite of these advantages, so-many hazardous features and, unsafe conditions are involved and the price paid in life and property is so high as to justify the statement that the system should be scrapped if it cannot be operated under reasonably safe conditions. Since bare trolloy wires were introduced into underground mines, they have boon responsible for the death of hundreds of diners, property damage totaling millions of dollars, an indeterminate loss of tonnage through the abandonment of mines or parts of mines, and loss of time after disasters caused by fires or explosions originated by the trolley haulage system.

Jan 1, 1945

By Sara J. Davenport

Hydrogen sulfite has been listed (1)3/ as a possible hazard in 50 occupations, many of which are in the mineral industries. The effects of its occurrence in the petroleum industry made themselves felt more than two decades ago, resulting in a comprehensive study (2) of the toxic gases from Mexican and other high-sulfur petroleum products. The mining industry, likewise, has had cause to guard against this gas. Enough hydrogen sulfide has been found in coal and some noncoal mines during normal operations to cause severe eye irritation, some serious illness, end even fatalities. It is usually a product of the decomposition of sulfur compounds and may be produced by burning explosives containing sulfur; the gas in harmful qauntities is formed by the use of block blasting powder or by the use of dynamite in blasting sulfide ores. Hydrogen sulfide is readily soluble in water, and enough may be released from water streams in coal and noncoal mining to cause fatal poisoning it is found sometimes in stagnant water underground, particularly where ventilation currents are absent, and great care must be exercised when accumulations of such waters are disturbed, as exposure to comparatively low concentrations of the gas evolved therefrom has caused fatal accidents.

Jan 1, 1945

By D. Harrington

Although the explosion-fatality record for the fiscal year 1944 showed considerable improvement over those of the preceding 4 years, it is still fur from creditable, and the coal-mining industry and agencies interested in the prevention of coal-mine accidents should not be satisfied until accidents from explosions and fires are eliminated. In view of present knowledge of the methods of preventing explosions and fires, such disasters are inexcusable and discredit the mining industry. Despite this knowledge, far too many coal¬mine operators and employees continue to follow procedures that have resulted in disasters in the past. Included in the appendix to this circular are a number of safety measures designed to prevent coal-mine explosions and fires and metal-mine fires. Their adoption is essential if explosions and fires are to be prevented, as certainly they should be. An epidemic of disastrous mine fires of electrical origin during the past 2 years emphasizes the need for better methods of protection of underground electrical circuits. At present, committees of mining-electrical engineers, electrical-equipment manufacturers' representatives, and others are cooperating with the Bureau of Mines seeking means to solve this problem.

Jan 1, 1945

By Carlton E. Brown

This report contains information on the cells or containers used to hold a known small depth (usually 1 mm. or less) of the dust-containing liquid from impinger, 5/6/ filter-paper,7/ and other samples collected from the air while the particles revealed by a microscope (equipped with a 16-mm., 0.25- or 0.50-N. A. objective and ordinarily used with axial light-field illumination) are counted in order to obtain an index of the concentration of dust in the sampled air. Information is given on such subjects as the kinds of cells available, kinds used, actual depths of cells, and construction of simple, inexpensive cells. ACKNOWLEDGMENTS The interest, encouragement, and assistance received from H. H. Schrenk, chief chemist of the Health Division, in the preparation of this report are gratefully acknowledged, as 'is all other assistance received.

Jan 1, 1945

The revised inspection standards or recommendations herein have been prepared for use in Federal inspection of bituminous-coal and lignite mines. They succeed a compilation of similar standards published as Bureau of Mines Information Circular 7268 in December 1943 and employed as a guide in Federal inspections since that time. Important alterations and additions have been made because of changes in mining, practice and temporary shortages of some safety equipment; moreover, several previous standards have been found not generally applicable and have accordingly been deleted. Mining methods and equipment continue to change, and new hazards and new safeguards are introduced. Consequently, these standards are subject to revision from time to time. Questions from the coal-mining industry regarding these standards and suggestions as to changes and additions thereto will be welcomed and considered carefully when the next revision is made. Many constructive criticisms from the mining industry have been considered in preparing this edition.

Jan 1, 1945

By D. H. Platt

Bauxite, the principal source of aluminum, has been mined from deposits in Saline and Pulaski Counties, Ark., since 1899; war needs have greatly stimulated production. Many of the ore deposits are basin-shaped and either outcrop or are covered by a shallow-depth overburden at their peripheries; these are mined by stripping and open-pit methods. When stripping becomes economically impracticable, incline shafts or slopes are sunk on the dips of the deposits, and underground mining is done on the retreat, using a room-and-pillar method.

Jan 1, 1945

By Claude W. Sill

In the course of a series of investigations on vanadium deposits of the western United States, the Bureau of Mines collected many hundreds of samples for chemical analysis. As uranium is often associated with these vanadium minerals, they were also analyzed for uranium, which was pound to be absent in a large percentage of the samples. Since the usual methods for determining uranium are laborious and time-consuming it is very desirable to have some simple qualitative test that can be applied prior to a quantitative analysis to determine whether uranium is present or absent and thus save the time and expense of applying the quantitative analysis to the large proportion of samples containing no uranium. To be acceptable, the test should be specific for cranium, sensitive enough to detect small amounts of uranium, and. simple enough to make it worthwhile to apply. The available methods for detecting uranium lacked one or more of the desired characteristics. Eventually, however, a method was worked out that satisfied all the requirements. This method is probably more specific and sensitive than the usual qualitative methods for uranium, and its simplicity and speed of application make it ideal for testing samples prior to quantitative analysis.

Jan 1, 1945

Geophysical Abstracts 1 - 86 were issued in mimeographed form by the Bureau of Mines; Abstracts 87 - 111 were published in bulletins of the Geological Survey; Abstracts 112 - 120 were issued in mimeographed form by the Bureau of Mines as Information Circulars 7256, 7257; 7267,`7273; 7285, 7292, 7303, 7310, and 7324. 1. GRAVITATIONAL METHODS 7933. Ansel, E. A Eine Untersuchung zum Problem der Isostasie (An Investigation Regarding the Problem of Isostasy). Gerlands Beitr. Geophys., Leipzig, vol. 59, 1942, pp. 16-26.

Jan 1, 1945

By A. B. Needham

Graphite is a raw .material of considerable importance in both waxy and peace. Two types of graphite, classified according to particle size as flake and fines, are used, but the former is in much greater demand. The principal wartime use of graphite is in the manufacture of crucibles for melting brass and special alloys of copper and steel. Other uses in both peace and war are as lubricants, for foundry facings, and in paints, electrodes, batteries, motor and generator brushes, and a variety of other commodities. . This paper describes the operations of the Southwestern Graphite Co. of Los Angeles, Calif., which produces both flake and fine graphite from a property in Burnet County, Tex.

Jan 1, 1946

By Irving Kabik

Chlorates and perchlorates, when mixed with certain reducing materials, may give a detonating explosive of considerable power. Concerning explosive chlorate mixtures, Guttman3/ states that they "have at all times fascinated inventors on account of the large amount of oxygen stored up in potassium chlorate, which can be given off so readily. When Lavoiser and Berthollet tried to make a chlorate powder in a stamp mill in 1788, they made a great show of it, and even two ladies were present. Unfortunately, after a certain amount of pounding the powder exploded and killed an official and the daughter of the Government commissary, who assisted at the experiments.***. It is interesting to observe how the same old mixtures are proposed over and over again with slight alterations only, in order to qualify for a patent. Potassium chlorate with some carbonaceous matter like charcoal, sugar, starch, glycerin, flour, or sometimes a vegetable or mineral oil and the like occurs again and again." Sprengel explosives, in which some of the undesirable sensitivity of the chlorate was minimized by coating the crystals with a liquid reducing agent, received some attention after a patent was issued to Dr. Herman Sprengel in England in 1871.4/ A somewhat similar explosive, known as Rack-a-

Jan 1, 1945

By W. J. Kroll

This report on the bibliography of zirconium has been confined to those publications and patents that appear to be useful in the commercial development of the metal, both the malleable and the nonmalleable. The methods of production have been stressed and special attention has been given to the alloys. Compounds of importance, like the oxide and chloride, for the manufacture of the metal or of the alloys have been considered. The use of the oxide in refractories anal in the glass and porcelain industries has been omitted. The present survey is critical; that is to say, an attempt has been made to evaluate the effectiveness of suggestions made in the literature. The exhaustive work of Marden and Richy, Bureau of Mines Bulletin 186, published in 1921, has been taken as a base to start from with the intention of bringing the subject up to date with material published in the last 24 years. During this time there was considerable 'advance in the preparation of the metal and Its alloys, and in the development of new uses. On the other hand, there was little progress in the methods of decomposing the ores, so that the chapter on this latter phase is necessarily short.

Jan 1, 1946

By S. H. Ash

The paramount responsibility of Government is to protect the general welfare. One of the chief functions of the Bureau of Mines is to investigate and publicize methods of increasing safety and efficiency in mining operations. In an industrial civilization, energy resources constitute the foundation of a sound economic structure (14).4/ Coal is only one source of energy, but it provides more than half the energy consumed in the United States.

Jan 1, 1946

By Henry P. Wheeler

As recently as 1915, helium was available only in very small quantities at a cost equivalent to $2,500 per cubic foot. It was a laboratory curiocity, and its properties were of interest to a limited number of scientists (11).3/ During the past 30 years, however, helium has grown from a plaything of scientists to a factor of importance in the prosecution of the recent war. Navy blimps filled with nonflammable helium proved to be more than a match for German submarines operating in the Atlantic. American bombers were able to fly unheard-of distances to drop bombs on Tokyo, Nagoya, Yokahama, and other Japanese cities because they had been made lighter with magnesium, arc-welded in a helium atmosphere. The Army utilized helium-filled radio-sonde balloons to obtain vital information concerning weather conditions affecting D-day invasions and other military maneuvers.

Jan 1, 1946