Search Documents

By Ralph W. Edie

"IntroductionTHIS PAPER deals with chemical and mineralogical changes in wall-rocks associated with pitchblende mineralization in the Gold-fields area of Saskatchewan. The localities at which the rock specimens studied were collected, and descriptions of the various rock-types referred to, are given in a previous paper by the author (5).The geological field work upon which this paper is based was carried out while the writer was employed by the Eldorado Mining and Refining Company during the summers of 1948, 1949 and 1950. The laboratory work§ consisted largely of quantitative spectrographic analyses for both major and minor elements, supplemented by an examination of 250 thin sections of both altered and unaltered rocks.Character of the AlterationHydrothermal alteration, with associated pitchbende mineralization, is widespread in the Goldfields area of Saskatchewan. The most intense alteration is restricted to the immediate vicinity of fault or breccia zones, but large areas are affected to a minor extent.In detail, the relationship between alteration and pitchblende mineralization is complex, as individual veins do not in general have separate alteration halos. Pitchblende generally occurs in gash-like calcite veins or stringers in wide, fractured zones associated with faulting. Large, lenticular and tabular masses of slightly to intensely altered rock occur in the same wide fracture zones as the mineralized veins. However, vein deposition appears to be-long to a later fracturing period, after hydrothermal alteration was more or: less completed. Generally, the veins transect and are confined to highly altered rock, but on the other hand many highly altered zones intersected in diamond drill-core are barren of mineralized veins."

Jan 1, 1953

By Jeanne B. Percival, Paul Ramaekers, Charles W. Jefferson, Pat A. Hunt, Eric G. Potter, Katherine E. Venance, William Davis, Sean A. Bosman

"A 10-cm thick clay-rich layer near the top of the Manitou Falls Formation of the Athabasca Group is unusual in its breccia texture, alteration, and detrital mineral composition relative to the adjacent overlying and underlying sedimentary beds. This layer is composed of angular quartz grains set in an illite >> kaolinite + dickite matrix. Deformed clay-rich fragments within the layer have very similar mineral assemblages. The presence of euhedral accessory minerals including Ti-oxides and aluminophosphatesulphate minerals points to a diagenetic/hydrothermal origin. The presence of individual grains of Kfeldspar and amphibole is unusual relative to the typical Athabasca quartz arenite; originally, these minerals were probably included in detrital quartz and subsequently liberated during fracturing. The textures and alteration characteristics suggest that this layer is a hydraulically-fractured unit, which has experienced hydrothermal fluid alteration - a possible pathway distally related to uranium mineralization Une couche argileuse de 10 cm d’epaisseur pres du sommet de la Formation de Manitou Falls du Groupe d'Athabasca est remarquable par sa texture brechique, son alteration et la composition de ses mineraux detritiques qui different de ceux des couches sedimentaires sus- et sous-jacente. Cette couche est composee de grains de quartz angulaires dans une matrice composee d’illite >> kaolinite + dickite. Des fragments deformes riches en argile dans cette couche presentent des assemblages mineraux tres similaires. La presence de mineraux accessoires idiomorphes dont des oxydes de titane et des aluminophosphates-sulphates suggere que ces derniers ont une origine diagenetique / hydrothermale. La presence de grains de feldspath-K et d'amphibole est inhabituelle comparativement aux arenites quartziques typiques de l’Athabasca; initialement, ces mineraux constituaient probablement des inclusions dans le quartz detritique qui ont ete subsequemment liberees pendant la fracturation. Les textures et les caracteristiques de l'alteration suggerent que cette unite a subi une fracturation hydraulique et a ete alteree par un fluide hydrothermal - possiblement en lien avec les effets distaux de mise en place de la mineralisation en l'uranium."

Jan 1, 2013

By J L. Mauk

Gladstone Hill, a volcanic-hosted low-sulfidation epithermal prospect in the Coromandel Peninsula, is less than 1 km from the world-class Martha Hill Au-Ag deposit. Gold-silver-bearing quartz veins occur in Late Miocene andesitic volcanic rocks of the Waipupu Formation that are extensively altered. The occurrence, spatial distribution and temporal relationships of hydrothermal minerals have been determined along two cross sections that transect the Amaranth, Gladstone, Cowshed and Moonlight veins. Quartz and pyrite are ubiquitous along these sections. Adularia and chlorite are widespread, but both are scarce in wall rocks adjacent to the Moonlight and Cowshed veins. By contrast, rare hydrothermal albite and epidote are restricted to wall rocks surrounding the Amaranth vein. Illite, which replaces adularia, is widespread and grades laterally eastwards into a zone of interstratified illite-smectite that envelops the Moonlight and Cowshed veins. During late-stage hydrothermal activity, rare calcite formed at depth and uncommon kaolinite and alunite formed at shallow levels. The overall clay mineral zonation with illite grading eastward into interstratified illite-smectite reflects paleothermal gradients of >220¦C to -170¦C towards the margin. The alteration assemblage of quartz, adularia, chlorite, albite, epidote, illite, interstratified illite-smectite and pyrite reflects formation from a near-neutral to weakly alkaline pH chloride water that contained low concentrations of CO2, Late calcite formed from very local descending steam-heated CO2rich water, whereas the rare assemblage of kaolinite and alunite formed from shallow steam-heated acid-sulfate water. Analysis of the available data indicates that the Martha Hill deposit and the Gladstone Hill area formed within a single large geothermal system. We infer that the Martha Hill deposit formed in the main upflow zone, whereas the Gladstone Hill area may have formed adjacent to this upflow zone.

Jan 1, 2001

By R L. Braithwaite

Mesothermal quartz lodes in Paleozoic Greenland Group metasediments of the Reefton area have produced 67 t of gold up to 1951, and recent exploration has identified new gold resources in several deposits, including the largest past producers, Blackwater and Globe Progress. The metasediments consist of alternating sandstone and argillite, metamorphosed to lower greenschist facies and hydrothermally altered near the quartz lodes. We examined and sampled drill core from four prospects, Globe Progress, General Gordon, Merrijigs and Blackwater, to determine the mineralogical and geochemical characteristics of hydrothermal alteration in the sandstone units. The sandstones are feldspathic litharenites averaging Q65, FlO and R25, with detrital grains of quartz, feldspar, rock fragments, muscovite, biotite (mostly altered to chlorite), and trace quantities of graphite, apatite, zircon, tourmaline and titanite. Hydrothermal alteration has developed a secondary mineral assemblage of K-mica (muscovite, sericite and illite), carbonate, chlorite, pyrite, arsenopyrite and limonite. The abundance of secondary chlorite is greater at Blackwater than at the other locations studied. Features in the sediments associated with increasing hydrothermal alteration towards quartz lodes include, the development and increasing intensity of colour bleaching and carbonate spotting, increasing quantities of disseminated pyrite and arsenopyrite, and the appearance and increasing quantity and size of thin carbonate, quartz and sulphide veins. This is accompanied by increasing concentrations of sulphur, arsenic and antimony as shown in assays, and of volatiles (loss on ignition) and iron as seen in XRF analyses. We were unable to identify consistent trends in the behaviour of potassium, sodium, and calcium that are exhibited by similar mesothermal quartz lode deposits inVictoria, Australia.

Jan 1, 1998

By D Mnller, J L. Mauk

The Oblaga Cu-Au skarn deposit and porphyry prospect is located in the south-eastern edge of the Gobi Desert in western Inner Mongolia. The deposit occurs within metamorphosed middle Paleozoic volcanic, plutonic and sedimentary rocks.   Ivanhoe geologists recognise eight main rock types in the area. Calcareous sediments include conglomerate, interlayered siltstone-sandstone, and limestone. Covering the calcareous sediments is a slab of thrusted biotite granite, and above it is rhyodacitic lithic tuff which, in places, is overlain by alluvial sediments. Various plutonic rocks and related intrusion breccias have intruded these units. Monzodiorite, quartz-monzonite and monzonite tend to form thin, high-angle intrusions and the youngest andesitic intrusions are generally wider and subhorizontal.   The Oblaga Cu-Au skarn, which occurs in the calcareous sediments, shows typical prograde and retrograde mineralogy. Petrographic studies show that prograde skarn minerals have been overprinted by retrograde skarn minerals, and original host rock minerals have been texturally obliterated and completely replaced. The mineralogy of the Oblaga skarn deposit is very similar to other Cu-Au skarn deposits worldwide.   Sericitic and minor chloritic alteration occurs throughout the study area and may relate to porphyry-style mineralisation. Generally, this alteration is not intense and most rocks have retained their original texture. Geochemical analyses suggest that K-metasomatism is not widespread at Oblaga. XRD analyses suggest an upward and outward transition from sericitic to chloritic alteration.   Comparisons between Oblaga and other porphyry Cu-Au deposits worldwide show that Oblaga has very similar characteristics to deposits that have undergone sericitic alteration. However, Oblaga is special because it also has relatively intense chloritic alteration, which is uncommon in other porphyry Cu deposits described in the literature.

Jan 1, 2005

By Y Miyoshi, J Ishibashi

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Sea floor hydrothermal activity in the Okinawa Trough is considered a modern analog to ancient Kuroko-type volcanogenic massive sulfide (VMS) deposits. Recent scientific drilling projects at active hydrothermal fields have enabled us to conduct comparative studies on hydrothermal clay minerals between ancient and modern systems. Zonal distributions of clay minerals below the sea floor of an active hydrothermal field have been revealed, which is represented by the distinctive assemblage of clay minerals. Zone 1 consists mainly of montmorillonite and sometimes of kaolinite; Zone 2 consists of chlorite and chlorite-smectite mixed-layer mineral; and Zone 3 is represented by the co-occurrence of illite and chlorite, from shallow to deep. This zonal distribution is likely to be in accordance with that reported previously for the Kuroko-type ore deposit. Similarities are also recognised in chemical compositions of illite and chlorite, which are both abundant clay minerals in the vicinity of the ore deposit. While illite would be formed by interaction with the hydrothermal ore fluid, the formation of Mg-rich chlorite is attributed to Mg metasomatism caused by the involvement of sea water. Further studies, especially focusing on interactions between fluid and solid phases, would significantly promote our understanding of dynamic processes for the formation of VMS depositsCITATION:Ishibashi, J and Miyoshi, Y, 2015. Hydrothermal alteration process in active sea floor hydrothermal systems in the Okinawa trough, from a viewpoint of a modern analogue for the Kuroko-type volcanogenic massive sulfide deposits , in Proceedings PACRIM 2015 Congress, pp 481–486 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By S G. Hagemann, M E. Barley

The Mt Tom Price deposit is a world-class high-grade hematite deposit in the Hamersley Province of Western Australia with an original resource of 900 Mt of almost pure hematite, averaging 63.9 wt per cent Fe. Petrological and geochemical studies at both the Southern Ridge and the North deposit at Mt Tom Price have identified three hypogene alteration zones between unmineralised BIF and high-grade iron ore: distal magnetite-siderite-stilpnomelane; intermediate hematite-magnetite-ankerite-talc-chlorite; and proximal martite-microplaty hematite-magnetite-apatite alteration zones.Fluid inclusions trapped in siderite within the distal magnetite-siderite- stilpnomelane alteration zone at the North deposit revealed primary high salinity (25.5 eq wt per cent NaCl-CaCl2) inclusions that homogenised between 107¦ and 142¦C into liquid. Fluid inclusions trapped in ankerite within ankerite-microplaty hematite veins in the intermediate hematite-ankerite-magnetite-talc-chlorite alteration zone at the North deposit revealed mostly H2O-CaCl2 pseudosecondary and secondary inclusions with salinities of 22.4 - 25.4 eq wt per cent and 22.9 - 25.9 eq wt per cent CaCl2, respectively. Pseudosecondary inclusions homogenised between 153¦ and 449¦C and secondary inclusions homogenised between 103¦ and 157¦C. Fluid inclusions trapped in apatite within talc-microplaty hematite veins in the intermediate hematite-magnetite-talc-chlorite-apatite alteration zone at Southern Ridge revealed that primary, medium salinity (7.0 - 9.0 eq wt per cent NaCl) inclusions homogenised between 181¦ and 257¦C and primary high salinity (22.8 - 25.9 eq wt per cent CaCl2) fluid inclusions homogenised between 118¦ and 257¦C into liquid. Microthermometric analysis of quartz from quartz-hematite veins from the Southern Batter Fault, Southern Ridge show a complex fluid inclusion history. Primary fluid inclusions consist of: low- and high-salinity H2O-NaCI inclusions trapped at temperatures of approximately 140¦ to 230¦C; vapour-rich inclusions of unknown compositions; and æcomplexÆ salt-rich (Ca, Mg, K and Na inclusions).Secondary inclusions consist of medium-salinity fluid inclusions trapped at temperatures of about 140¦ to 280¦C.A two-stage hydrothermal model is proposed for the formation of both the Southern Ridge and North deposits. Early 1a hypogene alteration involved the release of hydrothermal NaCl-CaCl2-rich (25.5 eq wt per cent) basinal brines (110¦ - 150¦C) from the underlying Wittenoom Formation and directed upward along normal faults and focused within the silica-rich rocks of the Dales Gorge Member, by the shales of the underlying Mt McRae Shale Member and overlying Whaleback Formation. Within the Dales Gorge Member hydrothermal basinal brines migrated laterally within large-scale folds with permeability controlled by shale bands and the NW trending dolerite dyke sets. Fluid rock reactions transformed unmineralised BIF to magnetite-siderite-iron silicate BIF, with subsequent desilification of the chert bands. Stage 1b hypogene involved an increase in temperature of the hydrothermal, CaCl2-rich saline (24 eq wt per cent) basinal brines (250¦ - 300¦C) resulting in formation of hematite-ankerite-magnetite-talc-chlorite alteration and the crystallisation of microplaty hematite. Late stage 1c hypogene alteration involved the interaction of low-temperature (~120¦C) basinal brines with the hematite-ankerite-magnetite mineral assemblage. At the Southern Ridge deposit this process was very intense (ie high fluid flux), therefore resulting in the almost total removal of ankerite and resulting in the increased porosity of the ore. Stage 2 supergene enrichment in the Tertiary resulted in the removal of residual ankerite and apatite and the weathering of the shale bands to clay.

Jan 1, 2005

By D Chappell

Coromandel Peninsula gold mineralisation has an epithermal style which involves extensive alteration of host rocks and addition of pyrite over large volumes of rock. These altered rocks therefore have high potential for generating acid rock drainage. Natural acid groundwater discharges occur in altered rocks, but not in propylitically altered rock. There is little calcite available in mineralised rocks to neutralise this acid. In contrast, the mesothermal veins of the Otago Schist cause little alteration of the host rock, and that alteration has similar mineralogy to the host rock. Calcite is a common mineral in host and mineralised zones, and sulphides are generally subordinate. Hence acidification of Otago rocks is unlikely. This lack of acidification in Otago facilitates arsenic mobility in solution, up to hundreds of ppm. Arsenic is insoluble under acidic conditions in the Coromandel. Base metals are soluble under acidic conditions of the Coromandel, but they are immobilised by adsorption on to the widespread clay minerals where the solutions are neutralised. Base metals are generally immobile in Otago, but when they are mobilised, adsorption is less effectiveas an attenuation mechanism because clay minerals are rare.

Jan 1, 1998

By Joon H. Jang

At a selected pH, hydrothermal oxidation of chalcopyrite was carried out under controlled F+,, at elevated pressures and temperatures (172-200°C) by balancing the rate of oxygen injection against the rate of consumption. Chalcopyrite was converted to covellite (CuS) and digenite (CU1.8S) with rejection of iron and sulfur to the solution. Covellite forms in the first stage, followed by nucleation and growth of digenite in the second stage. The effects of rapid and slow injection of stoichiometric quantities of oxygen are compared. Both the covellite and digenite form a porous layer occupying the same volume as the original chalcopyrite grain. An electrochemical kinetic model is presented to correlate the observed results.

Jan 1, 1993

By Masahiro Yoshimura, Sergiy Korablov

"Hydi-othermal corrosion ofTiN, TlAlN and CrN PVD films (3 µm thick) deposited on SUS-304 substrate was studied in 100MPa water in 20-950°C temperature range up , to 750h. The beginning temperature of their reaction was determined as 200°c for TiN and TiAlN and 500°C for CrN films, which are quite low in comparison with that of air oxidation of those powders. Very thin oxide scales. of TinO; n-I homologous series phases were formed above 300°C. TiO2 anatare. is observed for TIN and TiAlN films at 400°C. The· feature of hydrothermal corrosion of CrN films seems to be CrNxOy phase formation.Distinguishable weight changes were observed at higher temperature than 700°C for TiN, 750°C for· TiAlN and 800°C for CrN respectively. Hydrothermal corrosion kinetics .was constructed to calculate the activation energy of hydrothermal corrosions. On the base of obtained data, hydrothermal corrosion resistance was as follows: TiN – TiAlN - CrN. Facetted oxide crystals were formed at higher temperature than 500°C for TiN, TiAlN and 850°C forCrN.IntroductionThe metallic nitride (TiN; TiAlN, CrN) PVD films have high hardness, strength and wear resistance. Therefore these films are widely used in industry for wear resistij.nce application such as cutting tools and die molds. Their performances depend on not only the mechanical properties but also corrosion resistance of coated films. High temperature oxidation of metalliq nitride and nitride films was well studied [1-5]. However there are no reliable data concerning the .corrosion resistance of coated nitride materials. In high-temperature and high-pressure water. There are a few reports on hydrothermal corrosion of nitride films [6,7]. The increase of corrosion resistance of CVD films was observed in following succession TiC - TiCNO - TiCN - TiN at 300-680°C temperature interval and I 00 MPa pressure water according to data of the first report. Kawana et al. [7] have reported about excellent corrosion resistance of CrN films under 290°C and 8, 6 MPa water during I 000 h in the circulating type experimental loop. The films thickness was about 7-10 µm in both cases. However it remains unclear the chemical state of the surface species and especially in-depth distribution, oxide scale thickness and its growth, and defects formation in the oxide film."

Jan 1, 2000

By D O. Hayba

Metal-rich slurries discharged from excess-enthalpy geothermal wells at Kawerau (NZ) indicate that an efficient ore precipitation mechanism operates in some feedzones. In our conceptual model, which takes into account the relative permeabilities of liquid and gas phases in boiling fluids, a metal-precipitating liquid phase is effectively immobilised along boiling fronts, leading to the formation of highly concentrated ore. Chemical equilibrium and heat/mass transport modelling demonstrate the general applicability of this conceptual model to hydrothermal eruption environments.

Jan 1, 1995

By Hayba DO

Metal-rich slurries discharged from excess-enthalpy geothermal wells at Kawerau (NZ) indicate that an efficient ore precipitation mechanism operates in some feedzones. In our conceptual model, which takes into account the relative permeabilities of liquid and gas phases in boiling fluids, a metal-precipitating liquid phase is effectively immobilised along boiling fronts, leading to the formation of highly concentrated ore. Chemical equilibrium and heat/mass transport modeling demonstrate the general applicability of this conceptual model to hydrothermal eruption environments.

Jan 1, 1995

By Needham RS

Hydrothermal mineral deposits are the dominant mineral deposit type in the Cullen Mineral Field, and have been important sources of tin, tungsten gold, silver-lead, zinc and copper. The deposits are mostly in north to northwest-trend- ing shear zones, and are confined to Early Proterozoic contact metamorphosed metasediments or synorogenic to postorogenic granitoids. The distribution of the vein-type deposits with- in the contact aureole defines a district-scale metal zonation of uranium closest to granitoid, through tungsten, copper, tin, silver-lead to gold with increasing distance from granitoid contacts. This zonation probably reflects de- creasing temperatures within the contact aureole during granitoid emplacement, and at the time of generation of a variety of metal-bearing fluids. A magmatic source for some of the metals is indicated by the positive spatial relationship between uranium, tungsten, copper and silver-lead deposits and granitoids abundant in those metals. There is little evidence for any such relation- ship for tin and gold deposits, except for an association of some tin deposits with tin-enriched mafic rocks. Most of the granitoids with anomalous metal values are late stage highly fractionated leuco- granitic phases forming younger plutons peripheral to the main body of the Cullen Batholith, They probably form cusps connected to the main body at shallow depths.

Jan 1, 1984

By D Craw, J Becker

Post-metamorphic structural evolution of Otago Schist resulted in a pattern of northwest and northeast striking faults and fractures cutting the basement rocks. These faults have been reactivated several times since Mesozoic metamorphism. Gold-bearing quartz veins which have been exploited sporadically over the past 130 years are almost invariably hosted by northwest striking structures, and most exploration has been focussed on these structures. There is evidence for hydrothermal activity and mineralisation along some of the northeast striking structures, although there has been very little work done on these structures. Our study is attempting to characterise the hydrothermal processes in the northeast structures, in comparison to the northwest structures, in order to see if further detailed exploration is warranted. There is evidence for both normal and reverse senses of movement on northeast striking faults, and some of the faults have evidence for early ductile deformation overprinted by later brittle structures. Northeast striking structures host stibnite mineralisation in places, and faults are locally silicified or extensively impregnated with ankeritic carbonate. Sulphides are rare in veins, but do occur in some hydrothermally altered host rocks. Hydrothermal haematite accompanies extensive silicification along the Manuherikia fault zone near Alexandra. Anomalous gold concentrations occur in some hydrothennal zones, and in downslope sediments in some localities.

Jan 1, 1998

By Peter A. Rona

The recent discovery of the first black smoker-type hydrothermal venting and massive sulfide mineral deposits at a site in the rift valley of the slow-spreading Mid-Atlantic Ridge near latitude 26°N, longitude 45°W (Rona et al., 1986, Nature, 321: 33-37), demonstrates that a complete series of hydrothermal mineral deposit types exists at slow-spreading oceanic ridges (half-rate = 2 cm/y), similar to the series previously known at faster-spreading oceanic ridges (half-rate > 2 cm/y). The largest hydrothermal mineral deposit known at a seafloor spreading center is a stratiform massive sulfide body with bulk dry weight of about 100 x 106 metric tons in the Atlantis II Deep at the slow-spreading axis of the Red Sea. This observation invalidates the concept that size of a hydrothermal deposit is directly proportional to rate of seafloor spreading. Instead, the occurrence, grade and size of a hydrothermal deposit formed at a seafloor spreading center is controlled by anomalous chemical and physical conditions which may occur at extremely localized sites at the full range of spreading rates. The basic hydrothermal process involving subseafloor hydrothermal convection driven by magmatic heat sources appears to be similar at slow- and faster-spreading centers. However, differences exist in the periodicity of magmatic cycles that energize hydrothermal circulation (104 y at slow-spreading centers; 103 y at faster-spreading centers); in the distribution of hydrothermal sites along a spreading axis (estimated 100 km along slow-spreading centers; 10 km along faster-spreading centers); and in residence time

Jan 1, 1986

By Ryo Sasai, Takeshi Itakura, Haruki Imaizumi, Hideaki Itoh

"Emission of industrial wastewater containing harmful oxoanions is one of the serious problems on account of its toxicity and the environmental pollution, especially caused by boric, phosphinic, arsenic and antimonic species. In this study, we developed a novel treatment technique of such polluted-water by hydrothermal mineralization. The treatment is “Geomimetic” method for precipitating oxoanions in aqueous media as natural ore resources by using hydrothermal treatment with calcium salts mineralizer. The treatment made it possible not only to detoxify the polluted-water, but also to recover the calcium minerals such as Ca2B2O5·H2O, Ca5(AsO4)3(OH), etc. Concentration of each ion in treated-water was lower than that of effluent standard in Japan. Moreover, the residual concentration of each ion was independent of the initial concentration, but it depends only on the solubility of the formed mineral under hydrothermal condition. Therefore, the hydrothermal treatment could be recommended as one of the treatment techniques of polluted-water.IntroductionVarious oxoanions such as boron and arsenic oxo-anions have high toxicity against human health and the environment. They are important resources, however, for plating or advanced material manufacturing industries[1-3], from which the wastewater containing these oxoanions is generated every day. An appropriate treatment is often required for industrial wastewaters to attain national effluent standards of Japan (NESJ, B: 10 mg/dm3, As: 0.1 mg/dm3). On the other hand, there is no production of arsenic and boric resources in Japan, and they are expected to be recycled. Therefore, the establishment of a system for the removal and recycling of arsenic and boron from wastewaters is of global significance.Several methods to remove them from aqueous media have been already reported by using adsorption[4], electro-coagulation[5], membrane separation[6-8] and biological techniques[9]. However, these methods have the following problems because of their stability in water. (1) Removal yield is low, especially for tri-valent arsenite ion (AsIIIO3 3-) and borate ion. (2) The applicable concentration range is narrow. In addition, the used adsorbents or collected residues after treatments are sill hazardous wastes, so that they must be treated by a proper method. But, it is very difficult to convert them to recyclable resources at most industrial plants. These problems are caused by the difficulty to recover these oxoanions as stable solid precipitates with low solubility in water. The establishment of recycling system of these hazardous compounds will be one of the world-important issues, especially, in Japan, which is poor in natural resources. On the other hand, compounds that contain high arsenic concentrations and are insoluble in water, are often found in natural minerals, for example, as haidinglite (Ca(AsO3OH)·(H2O) or Johnbaumite (Ca5(AsO4)3(OH)). This fact suggests that nature has an ability to produce insoluble As-bearing minerals. Similar phenomena can be found in case of boron, antimony, etc."

Jan 1, 2008

By V. Yahorava

Mintek has developed a non-destructive Resin-in-Leach method for the recovery of Rare Earth Elements (REE) from phosphogypsum (PG) waste dumps. However, PG from different sources was found to be highly variable in terms of REE recovery and physical properties. Development of a pre-treatment process was initiated to improve the robustness of the current REE recovery process in order to render it effective for any type of PG. Extensive research into the mineralogy of REE associations with PG revealed that the majority of REE are trapped inside phosphogypsum clusters which inhibits their recovery. Hydrothermal treatment of PG-containing slurry was found to result in re-crystallisation of gypsum with the release of REE phases encapsulated in it. This process was tested on various PG samples and subsequent REE recoveries improved from 5 to 80%. This approach carries a large potential for unlocking value associated with gypsum dumps worldwide.

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By R. Weideman, M. Le Roux, F. B. Waanders, Q. P. Campbell, E. Fosso-Kankeu, D. Moyakhe

"*Paper written on project work carried out in partial fulfilment of B.Eng (Chemical Engineering) degreeSynopsisSpent coffee grounds were transformed into biochar using a hydrothermal method. Some of the biochar product was pre-treated through surfactant impregnation with sodium dodecyl sulphate (SDS) to enhance its adsorption capacity. The non-treated(NT) and pre-treated(PT) biochars were characterized using FTIR spectroscopy and SEM-EDS analyses, which revealed that the products had the potential for adsorption of heavy metals from solution and confirmed the successful impregnation of biochar with SDS surfactant. The two adsorbents were then used for the removal of cadmium from solution and the adsorption behavior and capacity determined through adsorption isotherm, kinetic, and thermodynamic studies. It was found that the cadmium was adsorbed in several concentric layers on the surface of the adsorbents through a chemisorption mechanism. The PT biochar was identified as a superior adsorbent, with a capacity of qe = 10.67 mg/g compared to the NT biochar with qe = 4.82 mg/g. The adsorption of cadmium onto the PT biochar was further determined to be spontaneous and endothermic. It was therefore concluded that the PT biochar shows potential as an adsorbent and could be considered for implementation in the treatment of metal-polluted effluents. IntroductionCoal mining operations are notorious for producing large amounts of waste tailings, which are disposed of in the form of a slurry on tailings dams. This inadvertently contributes towards environmental problems (Jin, Mansour, and Thomas, 2017). Heavy metals are one of the most common pollutants that originate from solid mine waste disposal facilities, and these can leach into groundwater supplies, contaminating them and rendering the water unsuited for human consumption (Salomons, 1995). Cadmium occurs in conjunction with metalliferous ores and can cause severe damage to agricultural soils and drinking water supplies in the vicinity of mining sites (Dudka et al., 1995). It has a tendency to migrate into the surrounding vegetation, which in turn can cause harm to humans and animals when consumed (Marquez et al., 2018)."

Jul 1, 2019

By Yves Fouquet

Results of the two main drilling operations on hydrothermal fields demonstrate that the two dimensional submersible operations need to be followed by drilling expeditions to study the third dimension of hydrothermal systems and understand hydrothermal and ore forming processes. Two types of environments were drilled recently in basaltic environment on slow spreading ridge, and on a sedimented ridge. Similar work has still to be done and targets to be discussed in other environments such as back-arc basins for felsic rocks environments and slow spreading ridges for ultramafic rock environments.

Jan 1, 2011