Hydrothermal and Host Rock Controls on Environmental Geochemistry: Comparison Between Coromandel and Otago

Coromandel Peninsula gold mineralisation has an epithermal style which involves extensive alteration of host rocks and addition of pyrite over large volumes of rock. These altered rocks therefore have high potential for generating acid rock drainage. Natural acid groundwater discharges occur in altered rocks, but not in propylitically altered rock. There is little calcite available in mineralised rocks to neutralise this acid. In contrast, the mesothermal veins of the Otago Schist cause little alteration of the host rock, and that alteration has similar mineralogy to the host rock. Calcite is a common mineral in host and mineralised zones, and sulphides are generally subordinate. Hence acidification of Otago rocks is unlikely. This lack of acidification in Otago facilitates arsenic mobility in solution, up to hundreds of ppm. Arsenic is insoluble under acidic conditions in the Coromandel. Base metals are soluble under acidic conditions of the Coromandel, but they are immobilised by adsorption on to the widespread clay minerals where the solutions are neutralised. Base metals are generally immobile in Otago, but when they are mobilised, adsorption is less effectiveas an attenuation mechanism because clay minerals are rare.