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By J. Fletcher Smoak

Consumption of abrasive materials in the United States in 1981 was approximately $340 million, of which 37 % was industrial diamond (natural and synthetic), 39% manufactured abrasives, and 24% natural abrasives. Production and shipments of natural abrasives, excluding emery and industrial diamond, decreased in quantity 9% and 7%, respectively, when compared with that of 1980. Emery showed the largest change in output, decreasing 30% in quantity and 20% in value. Production of nonmetallic .manufactured abrasives material plus shipments of metallic abrasives material decreased 5% in quantity but increased 4% in value. Nonmetallic manufactured abrasives consisted of aluminum oxide (fused) and crude silicon carbide produced in the United States and Canada and accounted for 63% of the value of all manufactured abrasives. Metallic abrasives shipments included chilled and annealed iron shot and grit, steel shot and grit, plus cut wire, aluminum, and stainless steel shot and equaled 37 % of the value of all manufactured abrasives.

Jan 1, 1982

By I. F. Avery

The productive capacity of natural-gasoline and cycling plants in the United States on January 1, 1958, was 48.8 million gallons per day, according to the Bureau of Mines biennial survey. This represented an increase of 2.4 million gallons per day during the 2-year period since the last survey. In the previous 2-year period, capacity had increased 7.5 million gallons per day. The major increase in operating capacity occurred in Texas and New Mexico. In New Mexico, capacity increased 43 percent. The total number of plants decreased from 600 on January 1, 1956, to 584 on January 1, 1958. The number of operating plants decreased from 571 to 558. Five new plants were completed in Colorado, increasing the number of operating plants from 7 to 12.

Jan 1, 1958

By John R. McWilliams

The technological and economic pattern of the U. S. mining industry has undergone a rapid and continuing change since World War II. To provide realistic up-to-date cost data and to disseminate knowledge of technical developments, the Federal Bureau of Mines, with the cooperation of individual mining companies, is presenting a series of mining methods and costs reports similar to those it issued before 1939. Shaft sinking has always played an important part in mine development and [ration] and is an appropriate subject for this series of reports. Shafts [are] especially important in areas such as the Coeur d'Alene district of Idaho, where every major mine is served by one or more shafts and shaft sinking is in progress at one mine or and her almost continuously.

Jan 1, 1960

By G. W. Jones

In a previous report results were given and a method outlined whereby from a knowledge of the composition of the natural gas and of the inflammability limits of the individual constituents composing the natural gas, the limits of inflammability of natural gas and air mixtures could be closely calculated. This method is based on the application of Le Chatelier's law as modified by Coward, Carpenter and Payman, to apply to a mixture of any number of combustible gases. This law must not be used indiscriminately, because many exceptions have been found. For example, when ethylene, acetylene, hydrogen sulphide, or chlorinated hydrocarbons are present the law may not hold. For a discussion of the rally exceptions which have been found, reference should be made to a report by Coward and Jones. Before this method can be used the inflammable limits of the individual constituents must be known. Also, the composition of the complex combustible mixture, and representative mixtures besides, must be tested both experimentally and by calculation to prove whether Le Chatelier's law may be applied.

Jan 1, 1933

By Norma Golumbic

The primary purpose of the Bergius (hydrogenation of coal) and Fischer-Tropsch (hydrogenation of carbon monoxide) processes is the production of synthetic liquid fuels. This objective is of importance in insuring an adequate supply of motor fuels and lubricating oils in the United States. In the urgency of the basic research and process development work on synthetic liquid fuels, the possibilities for the production of synthetic chemicals inherent in these processes have hitherto received little attention in this country. However, the by-products, as well as the primary products, from the Bergius and Fischer-Tropsch processes are rich source materials for organic chemicals. The overhead oil from liquid-phase hydrogenation of coal, for example, contains benzene, toluene, xylene, cyclohexane, methylcyclohexane, aromatic solvents, about 20 percent tar acids (largely phenol, cresols, and xylenols), and 3 percent nitrogen bases. Wax, alcohols, and acids are by--products of the Fischer-Tropsch synthesis. In addition, techniques have been developed which make possible the production of aliphatic hydrocarbons, alcohols, acids, aldehydes, and other oxygenated organic compounds. These chemicals are more valuable on a unit basis than gasoline. Because of continued rapid expansion of the plastic, resin, lacquer, and solvent industries, larger amounts of many of these chemicals will be needed in the near future.

Jan 1, 1949

IN 1949 the Government Printing Office issued Bureau of Mines Bulletin 468 3 and previously (in 1948) Bulletin 467 4 as part of the program under the Synthetic Liquid Fuels Act of April 5, 1944 (30 U. S. C., 321-325, and amendments). The two bulletins, relating to oil shale and its products, were published to present abstracts of all patents in this field from 1845 to 1945 5 or before the Synthetic Liquid Fuels Act was passed. Also, as part of this program, bulletins were published on patents relating to the pressure hydrogenation of coal e and the Fischer-Tropsch synthesis.7 The Synthetic Liquid Fuels Act was not extended beyond April 1955, but it inspired much increased activity in the field of oil-shale research, and many patent applications were filed. It is the purpose of this bulletin to abstract the patents issued in the United States, the United Kingdom, and Europe from 1946 to 1956, inclusive. A few older patents omitted in the previous bulletins have been included.

Jan 1, 1959

By George J. Conroy

This Bureau of Mines report summarizes the results of a study of mine inspection records covering 2,200 mining installations over a 3-year period ending December 1974. Tables show the relative frequency of violations of certain provisions of the Coal Mine Health and Safety Act of 1969 in particular areas of concern, such as circuit breakers, grounding, and permissibility. Examples of past use of the data and analyses are presented.

Jan 1, 1976

By Carl H. Beal

The oil industry in the United States is further advanced than in any other country, because of American initiative and the development of industries dependent in some way on petroleum or its products. For this reason the output has constantly increased (fig. 1), and as a result this country has produced more than half of the total output of the world. Trw total past output of the world is approximately 7,000,000,000 barrels of 42 gallons each; of this the United States produced about 4,000,000,000 barrels, or about 57 per cent. The limit of production in this country is being approached, however, and although new fields undoubtedly await discovery, the yearly outpnt must inevitably decline, because the maintenance of a given output each year necessitates the drilling of an increasing number of wells. Such an increase becomes impossible after a certain point is reached, not only because of a lack of acreage to be drilled, but because of the great number of wells that will ultimately have to be drilled. According to figure 1, the daily production per well each year has increased during the last few years. However, this increase is abnormal, being caused by the new pools brought in. Although such a condition may continue for several years, the average production per well will finally begin to decrease on account of the lack of new pools to make up for the normal decline in production of the old ones.

Jan 1, 1919

By James Westfield

This report covers the calendar year 1953 and has been prepared and submitted in accordance with the provisions of Sec. 106(a) and Sec. 212(c) of the Federal Coal Mine Safety Act (66 Stat. 692; 30 U.S.C. Secs. 451-483). During this first full calendar year of operations under the Federal Coal Mine Safety Act, the coal-mining industry of the United States attained the best injury records in its history - improving the former best records (made in 1952) by 91 fatal and 10,020 nonfatal injuries. Whereas, the mandatory provisions of the act were intended and designed to prevent major mine disasters, apparently the effects have reached beyond the scope thereof in reducing mine accidents generally.

Jan 1, 1954

By Robert L. Montgomery

Heats of solution of samarium (III) oxide and chloride in hydrochloric acid and of samarium (III) oxide, sulfate, and hydrated sulfate in sulfuric acid were measured. The heats of solution of this hygroscopic oxide are larger than those from the literature, probably because of more complete removal of water in the present study. From the literature value for the heat of combustion of samarium, the heats of formation of samarium (III) chloride and sulfate are -244.18 ± 0.41 and -928.5 ± 1.6 kcal./mole, respectively. The heat of hydration of the sulfate is -34.7 ± 1.0 kcal./mole. The heats of formation of other samarium com-pounds have been recalculated, using the new data.

Jan 1, 1959

By D. C. Dahlin

To identify and characterize potential domestic chromium resources, the Bureau of Mines investigated podifom chromite deposits along the Border Ranges Fault in southern Alaska. Part 1 of this two-part report describes an extensive field investigation and preliminary resource evaluation studies by the Bureau's Alaska Field Operations Center. This paper, part 2, describes the mineralogy of 38 samples that were collected from low-grade deposits in the Chugach Mountains, on the Kenai Peninsula, and on Kodiak Island, and presents the results of laboratory batch beneficiation tests designed to concentrate the chromite. The samples are peridotites and chromites that consist primarily of variable amounts of chromite, olivine, and serpentine. They were beneficiated by a sequence of grinding, sizing, and gravity concentration operations. Twenty-four high-chromium or marginal high-chromium chromite concentrates, six high-iron or marginal high-iron chromite concentrates, and five submarginal concentrates were produced with chromium recoveries that ranged from 37 to 95 pct. Three very low-grade samples were not beneficiated. These results indicate that several of the de- posits may be significant chromium resources, Potential precious metals association with the chromite was also investigated. Analysis of these samples indicates that the chromite deposits are not good platinum sources.

Jan 1, 1985

By Roy L. Wilfong

The linear expansion of high-purity oxides of yttrium, cerium, samarium, europium, and dysprosium was determined by the interferometric method for the temperature range 25° to 1,000° C. Single-crystal magnesium oxide and single-crystal aluminum oxide were used as reference materials. The bulk density and crystal form of the nonreference materials also were determined. The coefficients of linear expansion in the range 25° to 1,000° C were found to be 8.10 x 10-6 for yttria, 12.10 x 10-6 for ceria, 10.81 x 10'6 for samaria (monoclinic), 10.35 x 10-6 for europia (monoclinic), and 8.13 x 10-6 for dysprosia, each given in centimeters per centimeter per degree Centigrade. A detailed investigation of the interferometric technique for measuring thermal expansion in this temperature range was made. The interferometer was found to be a precise tool but only when adequate precautions were taken. These precautions are described.

Jan 1, 1963

By Henry C. Meeves

The nonpegmatitic sources of beryllium in Arizona, Colorado, New Mexico, Utah, and four adjacent states investigated by the Bureau of Mines are described. The investigations included 155 properties from which over 6,200 rock samples were collected; more than 5,500 samples were analyzed by the nuclear beryllium-detection technique. Twenty-four of the properties examined had rock containing more than 0.10 percent BeO. Many of the beryllium determinations were made in the field with portable detection instruments by direct scanning of outcrops and by testing samples of rock brought to the instrument. The large domestic resources of low-grade nonpegmatitic beryllium ore in Utah, which were discovered by private enterprise and which respond favorably to small-scale treatment processes, may come into commercial use and thus reduce the dependence of the United States on imported beryl.

Jan 1, 1966

By Robert J. Evans

The Bureau of Mines is sponsoring a variety of long-term, high-risk research to advance state-of-the-art technology in U.S. underground coal mining. This report reviews the status of many Bureau projects that support fundamental underground coal mining operations; the project areas include cutting coal from the solid (extraction), hauling coal from the face (transport), and activities that sustain daily operations (logistics). Innovative equipment and technology have been developed, with these major objectives: to significantly improve coal mine productivity, to further advance coal recovery and personal safety within the mining industry, and to reduce the time needed to develop longwall panels. The majority of the prototype equipment covered in this report either has undergone or will undergo comprehensive evaluation at Bureau surface test facilities so that performance and reliability can be improved before the equipment is tested and evaluated in a working section underground.

Jan 1, 1988

By Oliver C. Ralston, Dorsey A. Lyon

Volatilization in retorts has been, until recently, the only commercial process of producing spelter, hence the zinc mine operators have had to meet the terms of the zinc smelters in regard to the following requirements: (1) Minimum percentage of zinc the ore must contain; (2) the chemical combination of the zinc in the ore; (3) the proportion present of those elements that interfere with the suceessful recovery of the zinc when the ore is retorted. In consequence of these requirements, only a comparatively small proportion of the zinc ores mined can be shipped directly to the smelters.

Jan 1, 1919

By Thomas G. Chapman

The four major steps in the production of marketable copper are mining, concentrating, smelting, and refining. In a few cases, however, leaching takes the place of concentrating, smelting, and refining, and in others ores are smelted without being concentrated. Copper ores have been milled since the early days of mining in the United States. Except in the Michigan district, most copper ores went direct to the smelter until the so-called porphyry mines were developed. At present, although considerable leaching and direct-smelting ores are produced, the bulk of the copper ore mined is concentrated. Improved methods of concentration have kept pace with the increased tonnages of ores milled.

Jan 1, 1936

By W. W. Fowkes

The Federal Bureau of Mines examined a low-temperature tar obtained from a small-scale commercial unit for carbonizing North Dakota lignite for products that might be important to the economic processing of the tar. Tie tar may be divided into three distinct parts: (1) Tar acids, 45 volume-percent; (2) tar bases, 1 volume percent; and (3) neutral compounds, 54 volume-percent. It has a boiling range of approximately 150° to 380° C. (the decomposition temperature) and yields 18 weight-percent as hard pitch. The tar distillate up to 365° C. may be separated as: (1) Tar acids, 48 volume-percent; (2) tar bases, 1 volume-percent; and (3) hydrocarbons, 51 volume-percent. The tar-acid distillate, boiling to approximately 265° C., was characterized in some detail; the neutral fractions and the tar bases were less thoroughly examined. In general, as might be expected of a primary low-temperature tar, the lower boiling fractions are less in quantity compared with the usual high-temperature tar. The homologous series of each major class appears to be rather complete, although some components are present in very small amounts. The tar is quite unstable thermally, and might be more conveniently processed by extraction methods rather than by distillation procedures. The neutral fraction of the tar is highly aromatic, and might be considered as base stock for the production of liquid fuels.

Jan 1, 1961

By Robert A. Clifton

This Bureau of Mines report discusses the mineralogy of zeolites, the properties that make them commercially valuable, the conditions of formation of both natural and synthetic zeolites, and present and potential markets.

Jan 1, 1987

By V. F. Parry

[Approximatel~r 7-1/2 illion tOlls of subb1tnminous coals are mined an-nuall in Colorado, Wyo~ing, and Montana, of which 50 percent probably reaches dome ,-tic conswno:os. r:L'he moi s t'_re of the se subbi t1.Uninous coal sis high, averae;:t.:ug about 25 :!,)ercent \-Then they are :nined. T'ne coals are non-caking d ~~ack to a vari ble degree when exposed to nornal atmospheric conditions. ~hey a~e gpod domestic fuels, are considered to be smokeless in most furn~ces, and have been used. f, r f!1an: y ars in hand-fired domestic furnaces in hich tnc practice i~ to e~ploy large lureps for efficient com-]

Jan 1, 1941

By Clarence Hall, Spencer P. Howell

Among the more important factors involved in the use of high explosives in blasting operations is the means employed to bring about the detonation of the charge. When flame is applied to high explosives many of them may burn if not confined; but all of them when burning under certain conditions of confinement may detonate. Detonation may also be effected by mechanical means, such as frictional impact caused by a blow or by rubbing between surfaces. By this means, however, the full effect of the explosive charge may not be developed, so that a partial detonation, often accompanied by the burning of the explosive, results. When nitroglycerin was first used it was fired by the application of flame, but considerable difficulty was experienced in exploding it with certainty and in obtaining uniform resl'llts. In 1864 Allred Noble, a Swedish engineer, discovered that nitroglycerin could be surely and completely detonated by exploding in contact with it a small quantity of an initiatory explosive. Mercury fulminate was the substance then found capable of producing the best results There are many other fulminates and other substances that will produce complete detonation of commercial" high" explosives, but detonators or electric detonators containing mercury fulminate as the characteristic ingredient are still almost exclusively used in this country. The term" detonator" is used in the publications of the Bureau of Mines to designate what the miner calls a "blasting cap "-a copper capsule containing a small quantity of some detonating compound that is ignited by a fuse. The term" electric detonator" is applied to a blasting cap that is similar except for being ignited by means of a small wire which is heated to incandescence or fused by the passage of an electric current. One of the conditions prescribed by the Bureau of Mines for a permissible explosive a is that it shall be :fired by a detonator, or preferably an electric detonator, having a charge equivalent to that of the standard detonator used at the Pittsburgh testing station. A further requirement is that this charge shall consist by weight of 90 parts of mercury fulminate and 10 parts of potassium chlorate (or their equivalents). At the request of a manufacturer of permissible explosives, an investigation was undertaken by the bureau to determine the relative strength of detonators and electric detonators having different compositions. The tests of electric detonators herein reported were conducted by H. F. Braddock, junior chemist; J. W. Koster, J. E. Tiffany, junior mining engineers; and A. S. Crossfield, junior explosives chemist, at the Pittsburgh testing station of the bureau. Similar tests of detonators were not conducted because it was believed that the results would not show sufficient variation to warrant such tests. It is hoped that the conclusions drawn from the tests made will be of service to those using explosives by enabling them to select the grade of detonator or electric detonator that will insure the most effective results. The conclusions are given in this bulletin, which is published by the Bureau of Mines as one of a series of publications dealing with the testing of explosives and the precautions that should be taken to increase safety and efficiency in the use of explosives in mining operations. The results of tho experiments described in this bulletin show that the average percentage of failures of explosives to detonate was increased more than 20 per cent when the lower grades of electric detonators were used instead of No. 6 electric detonators, and was increased more than 50 per cent when these lower grades were used instead of No. 8 electric detonators. It is noteworthy, however, that when sensitive explosives, such as 40 per cent strength ammonia dynamite (p. 33), were tested under conditions ideal for detonation, the same energy was developed irrespective of the electric detonator used. When tests were made with a less sensitive explosive, such as a 40 per cent strength ammonia dynamite containing nitrosubstitution compounds (p. 32), the energy developed increased with the grade of the electric detonator used. For example, the average efficiency of four different explosives was increased 10.4 per cent when a No.6 electric detonator was used instead of a No.4 electric detonator, and 14.9 per cent when aN 0.8 electric detonator was used (see tabulation onp.45). The results of the tests emphasize the importance of using explosives in a fresh condition, but as fresh explosives can not always be had in mining work, strong detonators should be used in order to offset any deterioration of explosives from age.

Jan 1, 1913