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By C. F., Christopher

The purpose of any steel-making process is to convert the two raw materials iron and scrap into steel. The chemical analysis of the steel is set within certain limits which involve the physical proper- ties desired by the consumer. In addition to tensile properties a large number of other properties are at the present time desired, such as impact resistance, grain size regulation, specific degrees of hardenability, resistance to creep at high temperatures, resistance to expansion on heat treatment, the ability of the product to undergo extreme amounts of cold deformation without failure, and many other properties which are not directly related to the specified chemical analysis. Variations in many of the properties of plain-carbon steels are due to elements and compounds not included in the ordinary "five element"§ composition. Such variations result primarily from variations in oxidation of the metal in the furnace and from the deoxidation method employed. The steel-making problem therefore resolves itself into two distinct sections: (I) the elimination of certain elements from the charge (the iron and scrap entering the furnace) and the addition of materials to meet the chemical specifications for the heat; (2) the manipulation of the slag and metal and the process of deoxidation to give certain desired properties in the steel entirely apart from the chemical analysis specified. Each of 'these two ends must be attained

Jan 1, 1957

By Charles G. Maier

"INTRODUCTION The use of thermodynamic calculations to answer practical problems in metallurgy, especially those that are relatively difficult to test experimentally, is rapidly becoming a conventional method of procedure. Nevertheless, these methods cannot he applied effectively until the fundamental thermodynamic constants used for them have become available either by direct experiment or by recalculation of data already existing in more or less undigested form.In an attempt to collect such data far the compounds of lead and the antimony group the incentive has been to make a preliminary survey that will disclose the gaps or questionable phases of available information and to collect data that may be used to answer certain rather practical problems presented by operating metallurgists.This report comprises three sections; the first gives the basis of selection of the constants which may now be given or estimated, and the later sections discuss the application of the figures obtained to two of the more interesting problems.The reader will discover that many of the quantities involve critical study of a number of more or less discordant observations. Although certain data could be rejected on the basis of thermodynamic comparisons, it must not be overlooked that many of the figures are the results of rational estimates rather than exact experiment. The use of thermodynamic methods to control and partly authenticate such estimates is one of its most valuable characteristics for the practising metallurgist or chemist, who cannot check by direct experiment each property of the materials which he converts to usable form.Nevertheless, while it is definitely possible in certain instances that the final figure selected for the heat or free energy of a process or substance may be in error by as much as a few hundred to a few thousand calories per formula weight, questionable figures are usually revealed by the thermodynamic calculations made. When quantities of such degree of accuracy are, and they often must be, used for estimating an unknown reaction, the result often gives no more than the order of magnitude of the desired quantities. Yet even in these extreme cases the answer is far more reliable and valuable than an unordered guess or a conclusion based on incorrect data."

Dec 1, 1934

By W. R. Dengler

Dynatec Mining Limited contracted to sink a lS00 metre (4960 ft.) concrete lined shaft for Falconbridge Nickel Mines in Sudbury, Ontario, Canada. The shaft is 6.3 metres (20.S ft.) in diameter inside the concrete lining and is equipped with steel furnishings. Dynatec used the owner supplied 4.6 metre (l5 ft.) diameter double-drum hoist to sink the shaft with 12.S tonne buckets for muck removal and 4 cubic metre concrete buckets for concrete placement. One of the unique features of the shaft sinking operation is the use of a four-boom electric hydraulic drill jumbo permanently mounted in the shaft sinking stage. This paper will describe the performance obtained with the electric hydraulic drilling equipment and the high capacity muck removal and concreting equipment.

Jan 1, 1992

By Keith L. Harris

The performance of the world economy improved significantly in 1984. Real world output!/ grew 4.3% (compared with 2.6% in 19831, the highest since the 4.4% increase recorded in 1978 (table 1). The output of industrial nations rose 4.9%, while that of the developing nations rose 3.7%. The United States and Japan had the largest increases in output of the major industrial nations, with respective increases of 6.8% and 5.8% (table 2). The components of real output with the most significant growth in the industrial countries were gross fixed investment (9.2%), consumer expenditure (3.1%), and public consumption (2.5%) (table 1). Industrial output, as measured by industrial production indices, has returned to about the 1980 level for most of the major industrial nations (table 2). Exceptions to this were industrial production in Japan and the United States; Japan's industrial production rose steadily throughout the 5-yr period and is now more than 16% above the 1980 level, and the industrial production index for the United States reached 11 1.2 (1980=100.0). Real total domestic demand grew at 8.7% in the United States, more than double the rate of Japan, which, at 4.0%, had the second-largest growth. Average demand for all industrial countries was up 5.1%. During 1984 the U.S. dollar showed great strength on international markets, contributing to large current-dollar negative net exports of goods and services and even larger negative net exports of the merchandise sector. While growing U.S. imports helped spread the benefits of the recovery, they also led to a widening of current account imbalances and growing trade tensions throughout the world.3/, 4/

Jan 1, 1985

By AIME AIME

T HE 133rd meeting of the A. I. M. E., opening in New York on Feb. 15, promises to be as successful technically and socially as any in the past. The papers submitted for the various technical sessions are unusually excellent and insure something of interest to every group. Tentative programs have already been issued, and a concise resume of the various sessions, arranged chronologically, appears on page 48. Among the many interesting technical sessions arranged, attention is directed to those of the Petroleum Division, embracing the Symposium on Production that has come to be an annual feature, and new ones on refining practice, transportation and economics. The Institute of Metals program is similarly comprehensive. It includes 15 papers, 8 on copper, 4 on aluminum and its alloys, and one each on magnesium, lead, and fatigue of metals. The Coal Committee offers as a leading contribution its report, prepared under the direction of H. N. Eavenson, giving a new analysis of the capacity of the mines and a comparison of coal with other industries. This will be supplemented by a number of other papers of especial interest to operating men, among which are "Data on Use of Loading Machines in Bituminous Mines," by Graham Bright; "Evaluation of Coal," by R. H. Sweetser; "Selection of Coals for the Manufacture of Coke," by H. J. Rose; and "Relation of Origin and State of Carbonization of Coal to Problems of Low Temperature Carbonization," by S. W. Parr. The Iron and Steel Committee has scheduled seven papers, and there will be a special session on open-hearth practice, in which will be presented the first results of the two conferences, held by the sub- committee at Pittsburgh and Cleveland. A symposium on molding sands will be a special feature of the session on non-metallics.

Jan 1, 1926

By D Connelly

Silver and gold bearing ore from the Troy Resources NL Casposo Gold-Silver Project, located within the San Juan Province of Argentina contains a complex mix of gold, silver, electrum and silver sulphides in the ore. Casposo is a typical low sulphidation epithermal style gold–silver deposit where mineralisation is hosted within rhyolite – andesite flows and breccias. Veins are typically banded quartz–chalcedony colloform - crustiform banded with quartz - carbonate infill. Mineralisation is associated with an assemblage consisting of quartz, chalcedony, adularia, calcite, illite, sericite and trace sulphides. Gold and silver occur as electrum, native silver, sulfosalts and silver sulphides. This paper presents a case study that describes the process selection, development and engineering of a tailored process plant for the recovery of gold and silver from this ore.The original feasibility study, modelling, metallurgical testwork and engineering studies are outlined. The final flowsheet was based on minimising capital cost, operability, recovery and minimising technical risk.The process flowsheet uses the traditional Merrill Crowe route because of the high silver to gold ratio in the feed and achieves maximum gold and silver recovery while providing a common facility for future ore body treatment.

Aug 8, 2011

By S. Sinha, S. Ganguly

"In an opencast mine explosives are used for fragmentation of rock. Inefficient use of explosive energy in an opencast operation produces excessive ground vibration, which is measured by peak particle velocity (PPV). To mitigate ground vibration, it is essential to develop a model to predict PPV. At present empirical models are used. These models are based on only a few input variables, hence they fail to take into account the effects of the myriad factors that cause ground vibration. Due to lack of explicit knowledge about the complex mine blasting system the scope of application of mathematical and statistical modeling techniques is limited. The artificial neural network (ANN) technique is a learning algorithm that can remove some of these limitations and can be applied to predict PPV. In this paper an ANN model is developed for prediction of blast vibration using 248 data records collected from three coal mines with diverse geomining conditions. The correlation coefficient between measured PPV and model output was found to be 0.96 and the average error percentage 11.85. The ANN model output was compared with the output of three empirical models that are widely used for prediction of PPV. The correlation coefficient between the PPV predicted by an empirical model and measured PPV data was 0.63 and the relative error percentage 38.47. This result demonstrates the superiority of the ANN model compared to empirical blast models. By using site-specific structural discontinuities as input the model performance can be further improved. Sensitivity analysis and 3D plotting were used to gain further knowledge about blast-induced ground vibration. IntroductionIn an opencast coal mine explosives are used for fragmentation of coal and overburden. If the explosive energy is not fully utilized it causes blast-induced ground vibration, which may damage nearby structures. Ground vibration is expressed as peak particle velocity (PPV). During different stages of mine planning and operation, it is necessary to use a ground vibration prediction model for blasthole design. Selection of the modelling technique is crucial. Mathematical and statistical modelling techniques have limited application because of the lack of explicit knowledge about the complex mine blasting system. Vogiatzi (2002) highlighted the problem of multicollinearity in case of statistical modeling techniques. Mutalib et al. (2013) stated that mathematical models are unable to capture the nonlinear relationship between several blasting-related parameters due to the complexity of the model input data. However, the difficulty involved in modelling complex blast vibration problems can be removed by adopting an alternative soft computing modelling approach. One of the soft computing techniques is the artificial neural network (ANN). Ragam and Nimaje (2018) developed an ANN model for predicting PPV using six input variables. Kosti et al. (2013) stated that the conventional predictors fail to provide acceptable prediction accuracy. They showed that a neural network model with four mine blast parameters as input could make significantly more accurate on-site predictions. Sayadi et al., (2013), using a database from Teheran Cement Company limestone mines, found that a neural network resulted in maximum accuracy and minimum error. Khandelwal and Singh (2009) developed an ANN model using 150 data records from an Indian coal mine with site-specific rock characteristics and geomining setting. Khandewal and Singh (2007) built a ground vibration prediction model for a magnesite mine using four prediction variables with 20 data records. Kamali and Ataei (2010) predicted PPV in the structure of the Karoun III power plant and dam using an ANN. El Hafiz et al. (2010) evaluated ground vibration predictors using data from a single-station seismograph at a limestone quarry in Egypt."

Feb 1, 2019

By G R. Ballantyne, M S. Powell

A comprehensive Australia-wide survey of comminution energy consumption at copper and gold mines was presented by the authors at the 11th AusIMM Mill Operators’ Conference 2012. The database has been extended to include major overseas mines and used to benchmark comminution energy consumption across the industry. The mines included in this study now represent 15 and 24 per cent of the total global gold and copper production respectively, and almost all Australian production. The comminution energy intensity per unit of saleable metal has been presented in a graphical form similar to a cost curve used in economics. The graphical method has been developed to assess the competitive advantage that can be achieved by reducing comminution energy intensity.This benchmarking tool has been applied to three published case studies to assess its applicability. The first case study indicated that a large reduction in size-specific energy (kWh/t -75 µm) was achievable by converting standard semi-autogenous and ball mill circuits to include high pressure grinding roll and stirred mills. The second case study investigated the metal-specific energy reduction historically achieved by Bougainville with the addition of a preconcentration screening plant. The final case study was conducted by Barrick Gold Corporation and involved incremental efficiency upgrades at three of its gold mines: Cortez, Cowal and Mara North. The application of the benchmarking tool to each of these case studies successfully demonstrated the scale and competitive advantage that was achieved by reducing energy intensity.CITATION:Ballantyne, G R and Powell, M S, 2014. Benchmarking comminution energy consumption for improved efficiency, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 95–100 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

As the chief field of the gold dredging industry in Otago is the district traversed by the Molyneux River (called above Cromwell the Clutha) and its tributaries, a brief reference to the geology of that region and the origin of its alluvial gold will not be out of place. The prevailing rocks are metamorphic schists, chiefly mica and quartz schists, pr.obably of Silurian age. Though these rocks do not contain many payable quartz reefs, gold appears to be distributed in small quantities all through them,chiefly associated with the quartz lamime and lenses. The river drift, however, contains numerous pebbles of quartzite, quartzoze conglomerate, and fme-grained slate. Seeing that these rocks are hardly known to occur in situ within the watershedof the Molyneux River, though Devonian and carboniferous rocks of similar character occur to the north-east and south-west, it seems probable that the schists were at one time overlaid by carboniferous and Devonian rocks, and that these have been removed by denuding agencies. Be this as it may, it is certain that the schists themselves have been greatly eroded by the action both of water and of ice, and that the resulting drifts have themselves, in many cases, been sorted and re-assorted by the same agents.Consequently the drifts are very varied in character and often developed on a grand scale. In geological age they vary from Early Tertiary (though some may be older) to Recent.

Jan 1, 1903

By Xiang Li, Xibing Li

It is paramount that the stability of rock slopes be correctly accounted for under diverse operating and environmental conditions. Owing to different sources of uncertainty entailed in such stability problems, conventional deterministic approach through the calculation of a factor of safety (FOS) cannot reflect quantified uncertainties explicitly and sufficiently. Thus it is highly desirable to invoke the reliability approach to consider uncertainties in a systematic manner. Nowadays, the current design standards have an increasing tendency to ensure rock slope stability by pre-defining a target reliability index (or target probability of failure), viz., the reliability level of a rock slope is pre-set as a target to be satisfied. In such a situation and considering the fact that the FOS used as an indicator of slope performance still has a very wide acceptance, we focus on proposing an inverse-reliability-based methodology which aims at developing a two-fold indicator strategy, i.e., using the FOS and reliability together to deal with slope stability problems. The basic idea behind it is to utilize a so-called inverse first-order reliability method (IFORM) to directly calibrate the FOS provided the target reliability index has been given. In this way, the calibration scheme relating the FOS can be rationally done by not only incorporating uncertainties, but also satisfying a desired level of the prescribed reliability. Based on this, to make the IFORM computationally feasible and also reduce its computational cost, we introduce the response surface method (RSM) to generate a surrogate for the FOS-based limit state function (LSF), considering the lengthy and complicated form of the FOS in some recognized methods (e.g., within the framework of limit equilibrium). Distinguished from the existing RSMs that potential inadequacies may arise, we present an RSM based on a hybrid approach combining support vector machine (SVM; used as a regression technique) and uniform design (UD; pertaining to experimental design). Using a representative example of rock slope stability problem, we demonstrate the feasibility and validity of the developed methodology, during which the associated sensitivity study and further discussion are also performed. By dint of such a methodology, we can establish a link between the conventional deterministic approach and the reliability approach, where a logical and realistic framework is provided, for cases achieving the specified reliability, to assist in selecting the FOS which remains adequate for rock slope stability even in the face of uncertainty.

Jan 1, 2015

By D Cork, R Peet

"Methane is a signifi cant greenhouse gas. Methane is released from coal seams during the mining process, both in surface and underground operations. This uncontrolled release is termed æfugitive emissionsÆ and in underground mines is transferred to the atmosphere in ventilation air, known as ventilation air methane (VAM). The global VAM emissions are over 369 Mt of CO2-e/a (Butler, 2011; US EPA, 2010). Coal mines may abate this VAM or consider abatement should there be a price on carbon. These fugitive emissions are heading towards ten per cent of AustraliaÆs emissions by 2020 (Department of Climate Change, 2011).There are safety issues involved in VAM destruction. Due to the nature of coal, and coalextraction, unpredicted methane spikes above the lower-explosive-limit (LEL) can occur in theventilation air; for example outburst events or ventilation failure. This could lead to a mine fi re ifthe mine ventilation air was connected to a VAM abatement plant and the risks are left unmitigated.CorkyÆs is working with the mining industry to directly address these safety issues. CorkyÆs calltheir technology VAM RAB, which stands for ventilation air methane regenerative afterburner(VAM RAB). VAM RAB utilises the principles of a thermal oxidiser.This paper discusses fi ve independent layers of protection (ILPs) to fi rst stop methane reachingthe thermal oxidiser and secondly prevent the fl ame front from burning away from the VAMRAB. The test work completed or contemplated includes safety integrity level (SIL) assignmentto various vents, barriers and door systems to prevent a fl ammable mixture reaching the VAMRAB, proven rapid response methane monitoring sourced from the petrochemical industry, anddefl agration experiments to test the eff ectiveness of the passive geometry and active engineeringcontrols. These experiments and SIL assessments indicate that it is possible to safely connect theVAM RAB to a working coal mine.Further work is required to upscale the pilot safety work. Refi nement to the design is possible;for example improvement to safety duct controls once trialled at demonstration scale plus thermalenergy capture for power generation or other applications to provide heat. Nevertheless, thispaper shows how safety issues can be managed by a multilayer of protection approach usingvents, barriers and doors, and appropriate thermal oxidiser geometry."

Jun 1, 2012

By I T. Ross

In the last 50 years there have been tremendous improvements in equipment used in development on underground mines. Compressed air powered jacklegs have been replaced by high powered electro-hydraulic drifters on sophisticated drill jumbos and load haul dump units have taken over from small shovels and rail cars.Despite the increase in power applied in key parts of the development cycle, average advance rates have fallen and costs have increased. The factor that is most often regarded as the main contributor to slowing advance rates is increased support requirements. Whilst there is no denying that the drive to improve safety has resulted in the requirement for more bolting and the installation of a skin support (mesh or shotcrete), this is not the only factor.Within the industry as a whole, many of the basic principles of development appear to have been lost over time. This paper looks at a historical case study and discusses some of the features of old development cycles that are no longer in use. This highlights some of the basics that appear to have been forgotten. These may be indicators to what may provide improvements in the conventional drill and blast development cycle.CITATION:Ross, I T, 2014. Development – back to basics, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 67–74 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By Matthew Geary, Stephen J. Marino, Jordan A. Schreiner

"INTRODUCTION Project Overview The Southeast Collector (SeC) is a new 15km long 3.0m internal diameter wastewater tunnel designed by Hatch Mott MacDonald (HMM) that twins the existing 2.6m diameter York-Durham Sewage System (YDSS) tunnel. Both sewage tunnels are located north of the City of Toronto in Ontario, Canada. The SeC provides much needed conveyance capacity for the rapidly growing York Region population, supporting development until 2036 and increasing sewage system security (Hatch Mott MacDonald and AECOM 2011). Construction of the SeC will also permit flows of the twinned section of the YDSS to be bypassed in order to clean, inspect and carry out any essential maintenance within the YDSS tunnel. Although owned and operated by York Region, the SeC spans two regional municipalities beginning upstream from the intersection of Ninth Line and Rouge Bank Drive in the City of Markham in York Region to the downstream Finch Avenue and Valley Farm Road intersection in the City of Pickering in Durham Region. See Figure 1 for the SeC and YDSS alignment. The project includes 19 shafts and chambers with depths ranging from 8 to 48m in addition to seven facilities supporting the operation and maintenance of the sewer. The construction contract was awarded to Strabag Inc. in July 2011 for $291M CAD. Construction Management services were provided by a joint venture team of Hatch Mott MacDonald and AECOM. Existing York-Durham Sewage System The YDSS tunnel was completed in 1979 and was constructed using an open shielded TBM with ribs and lagging temporary support, followed by installation of a 380mm thick unreinforced cast-in-place (CIP) concrete final lining. The YDSS sewer system has numerous connections that accumulate flows from various urban areas within York Region. The section of the YDSS twinned by the SeC flows under gravity conditions and had been putting a strain on the municipality’s potential for population and development growth having reached its maximum capacity of 420 ML/d. According to the York Region’s Water and Wastewater Master Plan, the existing YDSS would not have been able to handle wet weather flows past 2016 (Genivar and XCG Consultants 2009). The dependability of this section of the YDSS is also of concern because it is the main and critical connection between the sewer systems upstream and the downstream Duffin Creek Water Pollution Control Plant (WPCP)."

Jan 1, 2016

By Peter Waggitt

Northern Australia has been home to uranium mining for over 70 years, more or less continuously. In the early days, post World War 2, there was little effort made to remediate workings at the end of operations. The three “campaigns” of uranium mining (1951-55; 1960-70; and 1979-present) are all now in various stages of remediation. This includes not only the large legacy site at Rum Jungle but also smaller fields like the South Alligator Valley, as well as contemporary works at Nabarlek and the ongoing closure at Ranger– Australia’s longest operating uranium mine. This paper briefly describes some of the past remediation activities before providing an update on the Ranger closure programme and future timetable.

Jan 1, 2020

By S. Kenzap, V. Kazakidis

Risk assessment is an essential component of mine feasibility studies. However, it is often challenging to identify the appropriate analysis and derive the required input data. The uniqueness of a mining project and the associated technical issues require customization of the risk assessment approach to meet both requirements and characteristics. The uncertainty driving the operating risk in mine feasibility studies and its assessment through Monte Carlo simulation as a component of a cash flow analysis are discussed in this paper. The paper introduces the use of the analytic hierarchy process for derivation of qualitative input and conducts quantification of the three main sources of operating performance delays, equipment, ground and schedule problems, in a cash flow simulation. A methodology for the assessment of operating risk in mine feasibility studies is presented.

Jan 1, 2011

By M. Kinne

Catalyst preparation/ characterization Slightly modified DP (~Schumacher et al. Catal. Lett. 89, 109, 2003) CeO2 HAS 15 from Rhodia calcined in air for~ 2h BET: ~188m2/g, particles size: 5.7nm (TEM, XRD) + HAuCl4 at pH of 6.5-7, (>95% of the Au was deposited) ? Au/CeO2 (2.6wt% Au, ICP-AES) A new conditioning procedure was applied, including heating at low temperature in N2 and H2/N2 mixtures) Patent DE 10205873A1. Very small Au particles <2nm, for CO oxidation catalyst as Au/TiO2, Au/Fe2O3, and Au/Co2O3 Here Au particles size <3.5nm (XRD) Summary ? CO is nearly exclusively adsorbed on the Au particles ? Positive reaction orders of 0.5 are found for CO and H2O ? Ea= 40kJ/mol ? The catalyst is very active and stable ? During WGS reaction huge amounts of formates are formed and cover the surface ? The activity of the catalyst seems to be correlated with the formate species.

Oct 1, 2003

By J. P. Schde

The authors deal with nickel production and usage patterns, nickel&apos;s first-use and end-use, examples of nickel applications in modern technology, e.g., energy generation and conservation, environmental protection, the oil and gas industry, construction and machinery, food production, conservation and distribution, consumer durables and the like. A special section of the paper is devoted to new applications of nickel in the electronic industry, modern corrosion control and the building and construction industries. The need to defend traditional markets for nickel while striving to find new applications, is also stressed.

Jan 1, 1988

By R. A. Plumbridge

The Honourable Mr Molefe, Premier of the North- West Province; Or Scot-Russel, Chairman of the CMMI&apos;s XV Congress; Mr Loton, Chairman of the CMMI; distinguished guests, ladies and gentlemen. At the outset may I express my sincere appreciation to the organisers of this Congress for their kind invitation to me to participate in the plenary session. May I also thank the CMMI for inviting me to be their fifth distinguished lecturer. This is a signal honour and one which is sincerely appreciated by my Group and myself. The subject of gold is a very emotive one. It conjures up different images in the minds of a wide variety of people. For many of us it is very simply the ultimate metal. In ancient times gold was sought after and treasured; it was the chosen metal for adornment and many of the best preserved artefacts of that time were hand-fashioned from gold which had been won by primitive mining techniques. Gold&apos;s rarity and its value was recognised by those who fashioned the earliest gold coins thus underlining gold&apos;s special place as a store of value.

Jan 1, 1994

By S. D. Cramer

Corrosion research is being conducted by the Federal Bureau of Mines to determine suitable construction materials for geothermal resource recovery plants. As part of this research, the corrosion resistance of 31 iron-nickel-, aluminum-, copper-, titanium-, and molybdenum-base alloys was characterized and evaluated in laboratory corrosion studies in low-and high-salinity geobrines representative of those found in the Imperial Valley, Calif. General, crevice, pitting, weld, and stress corrosion were measured at 105° and 232° C in deaerated brines and brines containing dissolved 02, C02, and CH4 General corrosion rates in deaerated brines at 105° and 232° C were usually below 5 mpy for the alloys tested except carbon steel, the low-alloy steels, Monel 400, 70-30 cupronickel, and the aluminum-base alloys. Dissolving carbon dioxide and methane in the brines at 2320 did not markedly alter these results. However, the introduction of oxygen, which can enter the brine during process operations, seriously degraded the corrosion resistance of many alloys by increasing the incidence of stress corrosion cracking, crevice corrosion and, except for the titanium-base alloys, pitting. In deaerated brine at 2320 C, the general corrosion rates for carbon steel and the low-alloy steels were relatively unaffected by pH in the range of 6.1 to 3.0. However, general corrosion rates increased sharply below pH 3.0. In deaerated brine at 232° C, welds in several iron-, nickel-, and titanium-base alloys corroded at rates comparable to the general corrosion rates of the alloys, but the addition of oxygen to the brine increased corrosion rates for welds in Inconel 625 and E-Brite 26-1. Alloys exhibiting good corrosion resistance in the deaerated Salton Sea KGRA-type brine at 232° C were E-Brite 26-1, Inconel 625, Hastelloy S, Hastelloy G, Hastelloy C-276, TiCode-12, Ti-0.2Pd, Ti-2Ni, Ti-1.7W, and TZM. The alloys most resistant to corrosion in oxygenated Salton Sea KGRA-type brine at 232° C were the titanium-base alloys. These alloys appear the most suitable for use in the construction of geothermal resource recovery plants. Carbon steel and the low-alloy steels are unsatisfactory for high-temperature, high-salinity brines and alternative low-cost materials with improved corrosion resistance should be sought.

Jan 1, 1980

By Bo Björkman

A controlled dust generation whereby the dust generated would be enriched with specific metals would considerably facilitate the possibilities of recovering metals from such dusts. A basic understanding of the dust forming mechanisms is of fundamental importance to achieve a controlled dust generation. The present study deals with dust formation in a copper converting process. Dust samples collected from various places in the gas cleaning system were characterised for chemical and mineralogical composition using chemical analysis as well as microprobe analysis. Thermodynamic calculations were used to predict the formation of chemically formed dust at various temperatures and amounts of leakage air to the gas system. The results show that a separation of mechanically formed dust. e.g . Si0:2. Cu and chemically formed dust. e.g .? Ph, Zn, As, Bi. could, to some extent, be obtained due to their different particle sizes. A selective condensation of Pb, Zn and As at various temperatures could. according to thermodynamic calculations, he possible at high temperature. A selective condensation of metals requires an airtight gas cleaning system or a gas cleaning system with a limited amount of leakage air in order to maintain the desired temperature level.

Jan 1, 1996