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By Francis Breton, Daniel Larouche, Pierre Heugue, Rémi Martinez

"Nowadays, in order to fit environmental restrictions, automotive markets are demanding cast aluminum alloys working at high temperature (180–300°C). New generations of alloys are required for higher strength components in engine downsizing or start-stop systems which lead to higher loading and higher specific power and stretch current materials to their limits. Recently, transition metals, such as zirconium and vanadium, have been added as alloying elements into an AlSi7Cu3.5Mg0.1 alloy to improve physical, mechanical, thermodynamic properties with the aim of increasing service life of parts. In such alloys, the best mechanical properties are associated with the formation of precipitates through an optimum heat treatment sequence, including: solutionizing, quenching and artificial aging. This study is focused on the modified AlSi7Cu3.5Mg0.1 cast alloy with Mn, Zr and V additions for high temperature application. The characterization of the cast alloy in this study, firstly, helps to evaluate and understand its performance both chemically and structurally according to their physical state: as-cast or as-quenched. Comparison of precipitation kinetics between a binary Al-3.5%wt.Cu alloy and the AlSi7Cu3.5Mg0.1 (Mn, Zr, V) alloy has been characterized by differential scanning calorimetry, TEM observations and micro-hardness testing. The Kissinger analysis was applied to extract activation energies from non-isothermal DSC runs conducted at different stationary heating rates. The study focuses on the impact of the chemical composition such as Si content on the kinetics parameters.INTRODUCTION Pure metal Aluminum shows poor mechanical properties and its malleability is high, that is why alloying elements are added to the mixture before casting to improve physical, mechanical and thermodynamic properties (Javidani, 2015); such as Silicon (Si) for casting properties (castability, cold crack capability, wear resistance, shrinkage behavior), Magnesium (Mg) and Copper (Cu) to generate precipitation hardening systems. Aluminum hypoeutectic alloys (<12% Silicon) with Cu, Mg additions used in the automotive industry for manufacturing mechanical parts (Larouche & Javidani, 2014) are mostly subject, after casting, to precipitation hardening heat treatment (Mohamed & Samuel, 2012) according to specifications and associated standards. The best mechanical properties are associated with the formation of precipitates through an optimum heat treatment sequence, generally including: solutionizing, water quenching and artificial aging (Manente & Timelli, 2011). Hypoeutectic aluminum-copper alloy with amount of Cu around 1 to 4.5wt% is an elementary case for precipitation in heat treatable aluminum alloys. Researchers essentially focused their work on the full precipitation sequence of binary Al-Cu alloy during aging which is presented below."

Jan 1, 2018

By B. Meddings, O. J. I. Evans

"This paper is mainly concerned with the present and probable future role of hydrometallurgy in the production of base metals.The economic and technological bases of the hydro-metallurgical plants built and operative in the mid-fifties are compared to those in production in the mid-sixties. The trends observed are extrapolated and some estimates made concerning the probable size and type of hydrometallurgical plants which will be operative in the mid-seventies.The impact of emerging socio-economic factors such as pollution control and the market demand for specialized metal products which favour hydrometallurgical recovery processes are also discussed."

Jan 1, 1971

By A. R. Farkoosh, K. Korgiopoulos, McGill University, O. Rodop, L. A. Villegas Armenta

"New generation of Al-Mg-Si alloys with thermally stable dispersoids that prevent recrystallization and grain growth during hot deformation are currently used in automotive components requiring good formability. Alloy chemistry controls the phase formation especially age-hardening precipitates, dispersoids, and primary intermetallic which have pronounced effect on grain structure, strength and formability. In this work, thermodynamic calculations have been used to predict the effects of varying levels of Si (0.5-1.5wt%), Mg (0.5-1.5wt%) and Mn (0.1-2.5wt%) on phase selection. Thermodynamic calculations have been performed in equilibrium and non-equilibrium conditions via the FactSage™ software using the FTlite database. Selected compositions have been cast, heat treated, extruded and characterized through scanning electron microscopy with energy dispersive spectroscopy and electron channeling contrast imaging techniques. The calculations showed that at the hot deformation temperature of ~540 oC, exceeding certain Mg and Si levels would lead to retained *-Mg2Si intermetallics and Si particles at the grain boundaries in addition to a-Al-(Mn,Fe)-Si. It was found that retained *-Mg2Si phase which adversely affects formability can be avoided for Si+2Mg levels lower than 2.3wt%. FactSage calculations also showed that increasing Mn from 0.5wt% to 1wt% leads to an increase in the amount of dispersoids (from 1wt% to 2wt%) that can potentially slow down recrystallization and grain growth during hot deformation and improve formability. Calculations at room temperature also show that for an alloy with 0.7wt% Mg, excess Si beyond 0.7 wt% promotes the precipitation of Si clusters in the Al matrix that accelerate natural age-hardening. Results were confirmed by experimental investigation.INTRODUCTIONAluminum alloy 6082 (Al-Mg-Si) is used in the automotive industry because of its high strength, and good weldability (I. J. Polmear, 2006). The alloy is age-hardenable through the precipitation of ß-Mg2Si and its precursors, and the recrystallization is usually inhibited by Mn- and Cr-containing dispersoids formed through high temperature heat treatments (I. Polmear & Couper, 1988). However, it is known that minor changes in alloy chemistry (Mg/Si ratio) can have significant influences on the ductility and formability of these alloys by altering phase selection and the resultant microstructure (Gupta, Lloyd, & Court, 2001; McQueen & Celliers, 1997; Zajac, Hutchinson, Johansson, & Gullman, 1994). For automotive applications where wrought alloys (usually extrusions) are cold-formed to produce suspension components, the chemistry of the alloys and the extruded structure are of crucial importance as they determine the formability at room temperature (Asensio-Lozano, Suárez-Peña, & Vander Voort, 2014). In this study, thermodynamic calculations along with experimental investigations were carried out on the Al-Mg-Si system to understand their phase formation and precipitation hardening as a function of alloy composition."

Jan 1, 2016

By Waldemar W. Koczkodaj, William O. MacKasey

Abstract - A consistency-driven pairwise comparisons method for mineral potential assessment is presented, using a simplified case of volcanic-associated massive sulfide type deposits as an example. Geological, geochemical, and geophysical criteria are considered on two levels: local and regional. The local geological criteria are subdivided into stratigraphy, lithology, alteration and/or mineralization, and structure. The concept of geomerit index and a procedure for computing this index are introduced. The method of consistency-driven pairwise comparisons can be combined with other quantitative and qualitative assessment methods, enhancing them by incorporation of nonmeasurable geological criteria (e.g., stratigraphy or lithology) and by computation of weights. The consistency-driven approach allows experts to refine at-times subjective judgments concerning exploration and land-use planning, and contributes to the improvement of mineral-potential assessments.

Jan 1, 1997

By Waldemar W. Koczkodaj, William O. MacKasey

A consistency-driven pairwise comparisons method for mineral potential assessment is presented, using a simpli?ed case of volcanic-associated massive sul?de type deposits as an example. Geological, geochemical, and geophysical criteria are considered on two levels: local and regional. The local geological criteria are subdivided into stratigraphy, lithology, alteration and/or mineralization, and structure. The concept of geomerit index and a procedure for computing this index are introduced. The method of consistency-driven pairwise comparisons can be combined with other quantitative and qualitative assessment methods, enhancing them by incorporation of non-measurable geological criteria (e.g., stratigraphy or lithology) and by computation of weights. The consistency-driven approach allows experts to re?ne at-times subjective judgments concerning exploration and land-use planning, and contributes to the improvement of mineral-potential assessments.

Jan 1, 1997

By R. W. Coburn

The results of field experiments on wells which required stimulation indicated that engineered well-completions will cause an increase in ultimate recovery at reduced costs. Techniques and tools have been developed which can be used to establish well conditions most conducive to successful stimulation. Cementing, perforating and treating are bound together so completely that the success of one phase is completely dependent on the .effectiveness of the preceding phase. A method of determining the efficiency or effectiveness of any given well-stimulation treatment has been derived. Pressure behaviour during a treatment can be analyzed to yield the total percentage of the formation which has been treated.

Jan 1, 1960

By Robert Macdonald, William Coombe, John F. Lewry

Gold occurrences have been known in the La Ronge Domain for many year . Mineable reserves have more recently been outlined and there is every prospect of a major gold camp being established in the domain within this decade. The La Ronge Domain lies in the Lower Proterozoic 'Trans-Hudson Orogen' and is part of a collage of Early Proterozoic crust comprising volcanoplutonic arcs, batholiths, associated volcaniclastics and volcanogenic sediments lying between the Superior Craton to the outheast and the reworked Archean basement/Aphebian cover terrain to the northwest. The domain has several lithostructural subdivisions, the most important of whjch , from a gold exploration point of view, is the Central Metavolcanic Belt. This belt is composed dominantly of a range of metavolcanic rocks and gabbroic to granitic intrusives, which geochemically resemble younger subduction-generated 'primitive' arcs developed on oceanic crust. U-Pb zircon geochronology indicates that the arc volcarusm and pre- to late-kjnematic plutonism occurred about 1890 Ma to 1850 Ma ago. The belt has an attained grade of upper greenschist to amphibolite facies and is relatively undeformed , though high strain zones occur locally. Most gold occurrences in the La Ronge Domain have been found in the Star-Waddy Lakes area of the Central Metavolcanic Belt, and in the Sulprude-MacKay Lakes area to the south which is interpreted as a tectonically dismembered part of the main belt. Both tratiformand vein-type gold occurrences are present in the domain; vein-type predominate and form nearly 90 per cent of the occurrences. The stratiform-type occurrences show a regional lithological a sociation with iron-rich sediments within proximal felsic volcanjc sequences. Some vein-type occurrences appear related to brittle fracturing associated with intrusive emplacement (the magmatic-hydrothermal "syn:' and "subvolcanic" veins) and faulting. However, most of the vein-type occurrences exhibit a spatial association with regionalscale ductile shear and other high strain zones, and were probably formed by metamorphichydrothermal processes.

Jan 1, 1986

By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By A. Deneys

This paper reviews industrial gases used in primary copper production. Copper smelting industrial gas demand has steadily increased since the first commercial oxygenconcentrate smelting in 1952 [1]. In copper production oxygen for smelting is the dominant industrial gas use followed by oxygen for converting. Nitrogen is finding increased use in copper smelters. Nitrogen is used for porous plugs for copper converting and anode refining [2-5]. Nitrogen can be used for concentrate drying [6,7] and is also used in some Ni-Cu smelters as a coolant in Peirce-Smith converting [8,9]. Industrial gas supply options of cryogenic or adsorbent based on-site plant or cryogenic liquid delivery are detailed.

Jan 1, 2007

By R. D. Parker

Location The Frood ore-body is expressed on surface as a prominent gossan ridge, with a total length of approximately two miles. The original Frood (the old No. 3 mine of the Canadian Copper Company) is at the southwest end of this gossan; adjoining it on the northeast is the Frood Extension (until 1929 the property of i:he Mond Nickel Company), while at the extreme northeast end is the Stobie mine. The first two of these divisions of the ridge form the Frood mine as it is known today.? This lies in lots 6 and 7 of the sixth concession, township of McKim, and is two and a half miles north of the city of Sudbury. The general elevation is 1,000 feet above sea level. The Ore-Body The Frood-Stobie parallel offset(l), as its name implies, has no connection in the field with the main mass of the Sudbury nickel eruptive-a norite. It lies one mile to the southeast of that body, and, in general, parallels it in strike. The ore occurs as a more or less tabular structure in what is known locally as the Sudbury series. They are the oldest rocks of the district, and have been placed by Collins(2) as earlier than the lower Huronian, of pre-Cambrian time. The series is comprised of sediments, volcanics (both acid and basic flows), tuffs, agglomerates, breccias, and basic intrusives, all highly metamorphosed, yet all forming a more or less regular picture. The controlling feature of the area has been the attitude of the sedimentary strata, from which has arisen the present sill-like character of the flow rocks, the basic intrusives, and the ore-body itself.

Jan 1, 1932

By Shahram Tafazoli

ABSTRACT: This article presents a novel technology for sensing the size of rocks after blasting in hard rock mines. Blast engineers require rock size statistics to carefully adjust the blasting parameters. The rock fragmentation requirements vary depending on the ore type and crusher specifications. The most popular statistical parameters in the industry are the so-called P numbers (e.g., P80 and P100). A machine vision based system is introduced here for automatic image collection and fragmentation analysis of the material right inside the bucket or dipper of mining shovels. A heavy-duty camera provides the required imaging data to an embedded computer mounted inside the cab. A custom machine vision software continuously analyzes the captured bucket images and stores the suitable ones in local storage which are then fed to a Desktop software for automatic fragmentation analysis. This technology has been developed by Motion Metrics International and is commercially available as FragMetrics?.

Oct 1, 2009

By Shahram Tafazoli

This article presents a novel technology for sensing the size of rocks after blasting in hard rock mines. Blast engineers require rock size statistics to carefully adjust the blasting parameters. The rock fragmentation requirements vary depending on the ore type and crusher specifications. The most popular statistical parameters in the industry are the so-called P numbers (e.g., P80 and P100). A machine vision based system is introduced here for automatic image collection and fragmentation analysis of the material right inside the bucket or dipper of mining shovels. A heavy-duty camera provides the required imaging data to an embedded computer mounted inside the cab. A custom machine vision software continuously analyzes the captured bucket images and stores the suitable ones in local storage which are then fed to a Desktop software for automatic fragmentation analysis. This technology has been developed by Motion Metrics International and is commercially available as FragMetrics?.

Oct 1, 2009

By Shahram Tafazoli

This article presents a novel technology for sensing the size of rocks after blasting in hard rock mines. Blast engineers require rock size statistics to carefully adjust the blasting parameters. The rock fragmentation requirements vary depending on the ore type and crusher specifications. The most popular statistical parameters in the industry are the so-called P numbers (e.g., P80 and P100). A machine vision based system is introduced here for automatic image collection and fragmentation analysis of the material right inside the bucket or dipper of mining shovels. A heavy-duty camera provides the required imaging data to an embedded computer mounted inside the cab. A custom machine vision software continuously analyzes the captured bucket images and stores the suitable ones in local storage which are then fed to a Desktop software for automatic fragmentation analysis. This technology has been developed by Motion Metrics International and is commercially available as FragMetrics?.

Oct 1, 2009

By K. G. Baxter, D. G. Dixon

The Sepon process plant utilises an autoclave to oxidize a flotation concentrate containing pyrite, residual copper minerals, and sulphur. The concentrate is produced from the residue of a preceding atmospheric copper leaching circuit. The function of the autoclave is to provide iron and acid for that atmospheric copper leaching circuit. The key issues in the operation of the autoclave are to maximise the production of acid and ferric ions and to avoid scaling issues related to sulphur balling in the autoclave. Scale control in the autoclave was examined using various dispersants and residue recycle without success. Operation of the autoclave at high temperature and high acidity addressed the scale issue through rapid oxidation of the sulphur and produced a ferric sulphate precipitate in the residue that could be re-leached to provide ferric iron. This paper presents the development steps followed, through batch and continuous piloting that resulted in an autoclave circuit design that addressed the above process requirements. Following definition of the process design basis, modelling of the autoclave operation was carried out to assist with engineering design. The model included thermodynamics and kinetics of oxidation of pyrite, elemental sulphur and covellite and also considered gas/liquid mixing, oxygen solubility as a function of temperature and solution composition, ferrous to ferric oxidation, gangue reactions with acid and precipitation/re-dissolution of basic ferric sulphate and alunite.

Jan 1, 2004

By B. A. Strathdee

An arsenical ore containing both pyrite and arsenopyrite was heated to a temperature at which decomposition and distillation took place. The condensate consisted of metallic arsenic and arsenic disulphide, although the analysis of the ore showed that volatile arsenic and sulphur were present in proportion to produce a condensate of arsenic trisulphide and sulphur. Distillation tests on the mineral arsenopyrite also produced a condensate of metallic arsenic and arsenic disulphide. This arsenic sulphide gave a distinct x-ray diffraction pattern which was not listed in the A.S.T.M. data file. This same sulphide can be produced by heating a mixture of arsenic and sulphur in vacuo. Its chemical analysis corresponds to As2S2. The dissociation pressures of arsenopyrite and the vapour pressures of arsenic disulphide and arsenic metal were measured, using a quartz "spoon" gauge. The dissociation pressures of arsenopyrite were compared with the published data for the dissociation pressures of pyrite to account

Jan 1, 1961

By S. W. Marcuson, P. J. Mackey

The Canadian non-ferrous mining and metallurgical industry has made great strides in environmental protection during the past half century. The path taken by the copper-nickel smelting industry in reaching today’s level is traced in this paper. Following the practice at early copper smelters in Wales and in the US, Canadian smelters originally used tall stacks to disperse furnace of-gases. This was the normal mode of operation and was accepted by society and by Government. Gradually, Government regulations required fixation of sulphur dioxide emissions and Canadian companies responded with significant technical developments to achieve this result. The initial development in Canada of the first new technologies such as the Cominco Flash Suspension Roaster and the Freeman Flash Smelting Process - both representing early versions of the modern established flash smelting technologies - and then later technologies such as the Inco Flash Smelting Process and the Noranda Process, both of which continue to this day, are discussed in this paper in terms of their contributions to the development of environmentally friendly plants. The evolution of these and other technologies is also discussed. Some comments regarding how the industry will face the future are also included.

Jan 1, 2015

By A. Becker, C. Gauvreau, L. S. Collett

"A scale model was designed to simulate the airborne Barringer INPUT time domain electromagnetic system. The amplitude of the response to a vertical conductive dyke varies considerably with the conductor's thickness conductivity product (TCP). The response increases from a minimum detectable level at a TCP of about 2 mhos, rises to its maximum value at a dyke TCP of 15 mhos and then falls again so that conductors with a TCP exceeding 500 mhos would probably remain undetected. Measurements made with both standard receiver coil configurations (maximum or minimum coupled) indicate comparable effectiveness for both systems, either from the viewpoint of vertical conductor detection or from the viewpoint of discrimination against overburden anomalies."

Jan 1, 1972

By A. Taylor, E. Thorn Corthay, R. Storey

In response to requests from its stakeholders, the International Standards Organisation is engaged in development of an international standard for Energy Management Systems (EnMS) which will become "ISO 50001". This new standard will build on the successes of both the EN16001 EnMS standard that has been used by dozens of European companies, as well as the ANSI/MSE 2000:2008 EnMS standard that is currently being used in several pilot projects in the USA and Ontario. This paper provides an overview of the key points of the EnMS standards, and describes how they can be used to drive sustainable energy reductions in the metallurgy industry.

Jan 1, 2010

By C. M. Kleemann

The paper describes the present milling practice at Western Mining Corporation Limited's new nickel mine at Kambalda in Western Australia. It details the crushing, autogenous grinding, flotation and spray drying circuits for the production of a nickel concentrate. It also indicates some of the metallurgical problems which have been encountered in concentrating this ore.

Jan 1, 1973

By Paul R. Terry

This paper presents a brief picture of the quality of coal produced in Eastern Canada for use in thermal generating stations. It describes, in particular, the characteristics of coals burned in six power plants -two in New Brunswick and four in Nova Scotia. Each station is dis-cussed in turn, and comments are made on the coals used therein with regards to origin and physical and chemical properties affecting station operation. A table of coal data shows, at a glance, the wide variation in the quality of coals received by these stations from producers in New Brunswick and Nova Scotia. "The promotion of improved coal quality for thermal generation can benefit our national economy." T HIS is the opening statement in a paper which was presented by Mr. D. A. Pirttinen at the Coal Division&apos;s Toronto meeting in April, 1960. In bringing the power engineer&apos;s viewpoint to the coal producers&apos; attention, Mr. Pirttinen made a survey of utility steam plants operating in Canada, and the results of this survey formed the basis for his paper, which he titled: "Generating Station Coal Quality.

Jan 1, 1965