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Chlorination of organic matter by direct injection of chlorine gas or hypochlorite has been investigated metallurgically worldwide with little understanding of the basic chemistry of the passivation mechanisms in- volved. In this paper, chlorination of carbon is attributed to oxidation-reduc- tions, resulting in surface halogenation of graphitic or amorphous carbon. It is proposed that chlorine and carbon interact to form thin coatings of chioro-carbon complexes that block the adsorption of gold cyanide com- plexes, thus passivating the gold adsorption sites of carbonaceous matter. Analytical, spectrographic, microscopic and electron-optical methods have been applied to demonstrate the proposed mechanism of chlorine-carbon bonding, as well as to evaluate the advantages and limitations of chlorination in the pretreatment of refractory carbonaceous gold ores.

Jan 1, 1991

By Semple DG, Leach TM

A continued exploration programme has further defined the geology of the Tolukuma vein system, verified the resource indicated by Newmont, and identified potential for additional mineralisation. The resource at Tolukuma Hill, designated as Zone C, is a measured 440,000t @ 17g/t Au and 46g/t Ag with an additional indicated resource of 120,000t @ 16g/t Au. A diatreme breccia localised at an intersection of structures, and a relationship of gold to base metal sulphides, are highly indicative of a porphyry association. Typical epi-thermal features such as crustiform banded quartz and quartz pseudomorphing. platy calcite are also present and locally contain lesser gold mineral-isation. Pre-existing dilatant structures have acted as a host to the ore fluids, resulting in the formation of the semi-continuous Tolukuma-Gulbadi veins over a 1100m strike. A fluid flow model suggests that mineralising fluids were sourced from the diatreme margins and migrated laterally along dilatant structures. Bonanza gold grades are derived through fluid quenching in the flexure between a hanging wall split which hosts much of the Tolukuma Hill resource and the feeder graben structure. Thus, the relationship between the pre-mineral structural geometry and fluid upflow at the margins of a diatreme breccia, controls the ore setting. Potential for more ore remains within the Gufinis and the 120 veins as well as in the outlying Prospects.

Jan 1, 1994

The Great lady gold deposit presented the challenge of providing a new grade control system for an usual type of orebody in the Eastern Goldfields. Mineralisation occurs as secondary enrichment about a quartz sand - granite saprolite contact 30m below surface. The ore horizon, which averaged 2.5m thickness, was near-horizontally disposed in contrast to the typical steeply dipping, shear hosted deposits of the region. A trial mining operation was undertaken on the richest, most continuous portion of the deposit to test the economic viability of this type of orebody. Controlling and minimising vertical ore dilution was considered crucial to the profitability of the operation.An understanding of the grade distribution combined with the practicalities of mining produced a grade control system which allowed for the mining of 1/2rn composited grades on level lm benches. Ore mining was combined with strict monitoring of levels, truck destinations and ore boundaries. Ore reconciliation results showed this system to be effective.

Jan 1, 1990

By Umetsu Y, Su Qing-quan

The electrical conductivity of electrolytes is very important in metal electrowinning and electrorefining processes as it has a very large influence on the energy consumption. There are few measurements of the electrical conductivity of zinc electrowinning electrolytes available. The electrical conductivity of zinc electrowinning electrolytes were measured over the following range of concentrations, 100 to 200 g/L H2SO4, 0 to 80 g/L Zn and 0 to 20 g/L Mg, at temperatures from 25 to 60 C. The specific conductivity of zinc electrowinning electrolytes may be expressed as a function of concentrations of sulphuric acid, zinc and magnesium and temperature by the following equation: k(S/cm) = 0.004 + 0.00115 t + 0.00282 [H2SO4] t - 0.00114 [M] t + 0.3442 [H2SO4] - 0.0451 [1-12SO4]2 - 0.1058 [M]ò[H2SO4] - 0.0224 (M] + 0.0286 [M] 2 where t is temperature (C), [H2S04](moI/L) is sulphuric acid concentration and [M](mol/L) is a sum of zinc and magnesium concentrations, ([Zn]+[Mg]). The specific conductivity of zinc electrolytes is a function of the concentrations of the hydrogen ion and free water molecule, which are calculated by taking into account the second ionisation constant of sulphuric acid and the stability- constants of zinc-sulphate and magnesium-sulphate complexes at 25 C.

Jan 1, 1993

By Qi P. H

Gold dissolution can be achieved with a number of complexing ligands, all with varying degrees of stability. Processes based on the use of halogens have been known for many years. Beside providing the necessary complex- ing role, the halogens under the appropriate conditions are very effective oxidants for gold. Of the halogens, the gold iodide complexes are the most stable in aqueous solution. Iodine can establish the desired oxidation poten- tial for oxidizing gold, and unlike chlorine and bromine, the oxidizing potential of iodine is mild enough to avoid the oxidation of impurity constituents like metal sulfides. A series of experiments to investigate the fundamental electrochemistry of gold in different halide solutions was performed. Cyclic voltammograms of gold in the presence of 10-2 M chloride, bromide and iodide, respectively show that for a given potential the rate of oxidation is much faster in iodide solution than in either chloride or bromide. An overlay of linear sweep voltammograms for the anodic oxidation of gold in iodide and the cathodic reduction of iodine species on gold provides an effective method for examining the dissolution of gold in iodideftodine solution. The dissolution rates obtained from both electrochemical and actual leaching results are compared. Optimum leaching conditions are analyzed in terms of the iodide/iodine concentrations. Conceptual processes for the recovery of gold and iodide and the regeneration of iodine are discussed.

Jan 1, 1991

By Liu Wenyong, Huang Yucheng, Yang Ba

High-water rapid-solidifying material, called æhigh-water materialÆ, is a new material developed by the authors over many years. The material can solidify nine times its volume of water into solid. The material is a fine kind of binder with special properties. The solidifying body of high-water material with water has quite a high early strength. The compressive strength of the material within three days can reach the same strength as conventional Portland in 28 days. One ton of the material can replace three tons of conventional Portland cement as binder. Some important achievements have been made in application of high-water material. In metal mines, based on the material, a new full-tailing cemented backfill technology has been developed. The characteristic of the new technology is that high-water material is used as binder and full tailing or alluvial sand is used as backfill aggregate. Because of the application of the new technology, major technical problems in backfill technology such as classifying of tailing, dewatering, transportation of pulp, low strength of backfill body, environmental contamination and so on, have been solved.

Jan 1, 1998

By Senanayake G

A sample of crude copper powder produced by the CLEAR Process was refined by dissolution and recovery in sulfate media using the Parker Process. The Parker Process offers an alternative method of copper recovery to electrorefining and allows a range of Eh and pH conditions to be used to provide further discrimination of impurities. High purity copper powder was recovered by the Parker Process even in the presence of added impurities when the Eh and pH was maintained near constant throughout the refining step.

Jan 1, 1984

The need to schedule ore production to make maximum use of the strength gained by cem- ented fill during curing is discussed, to show how cement content and hence fill cost can be kept down for any particular operation. Results from laboratory testwork on Isa Mine fill conducted by the author while employed by Mount Isa Mines Limited form the basis of the Discussion

Jan 1, 1973

MANPOWER RESOURCES The optimisation of human effort has been an ongoing and significant process in the coal industry since industrialisation as we know it began. The extent to which the changes sought have been achieved has, over the years, been in the main determined by the economic and political forces existing at that time and the determination and character of the individuals involved. The question of optimisation is therefore not new in our industry. Hopefully this presentation will demonstrate to the reader the effect of previous measures adopted by industry to optimise all facets of its operation and in particular that of the human Resource.

Jan 1, 1991

The B.H.P Company has been using shortwall mining methods for the past six years in the Southern Field. several aspects this experience shortwall equipm H.P. Company has been using shortwall mining methods for the past Northern Collieries and for several years at Corrimal in the Various papers have described and assessed that work. There are of recent work which supplement prior publications. The summary of to date is a background to discussion of the role of self-advancing ent in support in pillar extraction.

Jan 1, 1974

Bendigo is AustraliaÆs second-most productive goldfield, having produced some 22 million ounces of gold between 1851 and 1954. Bendigo Mining Limited (BML), the sole lease-holder of the Bendigo Goldfield, is developing a mine that is planned to produce ore from beneath the historical workings for at least the next 25 years. The high-grade Bendigo reefs occur in the proximity of the chevron anticlines, which characterise the goldfield. Typically the reefs display relatively small cross-sectional areas and large (subhorizontal) strike dimensions. They occur in clusters due to interrelated structural controls. Most of the gold occurs as visible grains and laminae, and as such grade estimation is not amenable to ænormalÆ sampling and estimation techniques. The initial phases of exploration and development of the mine focused on understanding and resolving these sampling and estimation issues. In 2005, BML reviewed and updated the March 2004 Feasibility Study, refining the life of mine development strategy. The strategy fundamentally aims to exploit the 11 million ounce Inferred Resource and additional exploration potential by developing the current Kangaroo Flat Mine to produce ore at an initial rate of 450 000 t/yr in 2006/07, expanding to 600 000 t/yr by 2009/10; and developing the Eaglehawk Mine to produce 1 Mt/yr by 2011/12. Ore will be processed initially at the Kangaroo Flat site, and from 2011/12 also at the Eaglehawk Mine 1 Mt/yr processing plant. The two mines will connect underground in 2009. Total ore treatment capacity will be 1.6 Mt/yr, producing 600 000 oz/yr from a head grade of 12.7 g/t gold. The project is planned to operate for 25 years, processing 33.6 Mt of ore producing 13.7 Moz of gold. To achieve this production rate, the exploration and ore delineation programs will require up to 16 diamond drill rigs producing over 200 km of core per year. At the same time, approximately 8 km of on-reef development must be monitored and typically 18 stopes managed concurrently. The processing plants will be located in geographically constrained areas, which will limit the ability for selective stockpiling and campaign treatment.

Jan 1, 2006

By J Emslie

Newmont AustraliaÆs Callie Underground Gold Mine is located on the Dead Bullock Soak Mining Lease, approximately 600 km NW of Alice Springs, NT, in the Granites-Tanami Goldfield. Dead Bullock Soak is part of NewmontÆs Tanami Operations, which also include the Granites Gold Mine and processing plant, Groundrush Open Pit and Tanami Mill. Callie is a world class Proterozoic gold deposit; production to date is in excess of 1.7 million ounces, with an additional Proved and Probable reserves at the end of 2002 of 10.8 Mt at 6.3 g/t. Gold mineralisation at Callie occurs in thin (1 - 30 mm) steeply dipping quartz-chlorite sheeted vein system that cuts across a 40¦ plunging folded sequence of medium to fine-grained metasediments. While the vein system is highly continuous, the gold distribution is highly variable and is controlled by the interaction of lithology, alteration, structure and vein density. The mineralisation is commonly coarse-grained and has a relatively high nugget effect, consequently the orebody is problematic to estimate and shows a high degree of sensitivity to drill hole density. Resource modelling at Callie is an example of a geologically driven model that has evolved with increasing data and understanding. Lithological and structural models are employed to define domains within which the grade estimation is undertaken using multiple indicator kriging. This gradual model evolution impacted greatly on the selection of the mining method. Uncertainty in the estimation of the orebody was a significant factor that led to sublevel open stoping with cemented aggregate fill being adopted as the mining method to improve extraction selectivity. Callie often shows strong positive reconciliation compared to the mill. The mine geologistÆs face the challenge of limiting the degree of underestimation of the core of stopes whilst ensuring that stope boundaries are not conservative. This can only be achieved through the mapping of subtle geological features in order to confirm the orebody model. The increased use of the geological mapping has improved our understanding of the controls on mineralisation and has been extended into the development of new models for near mine underground exploration.

Jan 1, 2003

Although AustraliaÆs coal mining industry is currently experiencing a pleasing period of price relief, long-term trends toward lower real prices will surely continue. Higher price levels attract expansion by existing operators and market entrance by new operators. History clearly demonstrates the relentless long-term march toward ever lower real prices. Therefore, the need for economic returns applies constant pressure to improve productivity. To be sustained, high productivity requires a systematic response based on a solid understanding of critical productivity determinants. The most powerful determinant of productivity is now widely understood to be workplace culture. Culture largely comprises a combination of behaviours, symbols and attitudes. This paper will examine and review scienceÆs latest discoveries in human behaviour. It will provide a proven, practical framework for understanding behaviour and applying this knowledge. Significantly, it will highlight why conventional approaches toward improving productivity often provide disappointing economic returns. The modern understanding of behaviour factors will cover coal face operations. More importantly, because executive and managerial levels in coal mining have significantly greater impact on industry and mine productivity the paper will concentrate on leadership. Particular emphasis will be placed on use of modern systems and in particular use of what are by far the most powerful drivers of behaviours û measurement, analysis and reporting systems. The paper and presentation will show how conventional systems rooted in antiquated American legislation from the early 1900s stifle productivity improvement and drive suboptimal and even counterproductive behaviours. These commonly used systems will be compared with accurate and effective modern methods for assessing performance to improve productivity. These principles are proven in all industries and effective application in mining will be highlighted. Actual results will be used to demonstrate practical approaches successfully applied in both metal and coal mining in Australia and overseas.

Jan 1, 2005

The Nelson province was chosen as the prime area for rhenium sampling, based on its mineral associations. Sample preparation involved benefication by grinding and flotation A modification of published procedures for rhenium analysis was developed and the results compared with those obtained for molybdenum on the same samples using atomic absorption spectroscopy. The results of the analysis for both metals is discussed and the relationships between rhenium and the molybdenum mineralisa- tion of this region is commented on. A metal- 1ngenic province is defined for molybdenum and r'.ienium and the tectonic setting for this is discussed. Some consideration has been given to rhenium possibilities in Fiordland and the Coromandel Range.

Jan 1, 1980

By Barro L

Very large reserves of gas are contained in coal. Because of the low permeability of the coal gas flow rates are very low. Fracturing of the coal can be achieved by use of the nitrogen - foam frac techniques described but the flow rates after fracturing are not sufficient to support economic development. Fracturing of the seams in the Bowen Basin was as predicted but in the Sydney Basin no trace of the fracture could be found when development proceeded past the fractured well. Testing of coal samples has provided some insight into parameters affecting desorption Rates.

Jan 1, 1982

By M W Kearns

The ERA - Ranger Mine ore processing operation consists of a sulphuric acid leach followed by counter current decantation and solvent extraction circuits. The most expensive unit processing operation at Ranger is the sulphuric acid leach. In 1992 and 1993 changes were made to the operation of the leach circuit. These changes have reduced power and reagent consumption in leach by 30 per cent and 20 per cent respectively with minimal effect on extraction efficiency. The first change was to operate the leach circuits at higher pHs than previously attempted. In addition a cap was placed on the amount of acid added to the leach circuit. Secondly, an on-line pH measurement system was installed and has reduced the variation with time of the leach circuit pHs. Finally, the number of leach vessels used was reduced from ten to seven. This action was undertaken after an examination of the uranium profile and the residence time in the leach circuit from previous years. This paper examines the above changes and assesses their effectiveness on plant performance and costs.

Jan 1, 1994

By Jackson GS

Since 1983 Cobar Mines Pty Ltd has madea concerted effort to improve the performance of its long hole open stopes, especially in the areas of dilution and fragmentation.This has resulted in modifications to stope design, drilling and blasting practice.

Jan 1, 1985

By B, G Strobos, J P. Maree, N Smit

In mining and processing operations where minerals, high in pyrite and low in calcite/dolomite are processed, acid is generated, which needs to be neutralised. Ticor at Empangeni in South Africa (SA) produces rutile (TiO2), leucoxene (TiO2 plus iron compounds), titanium (Ti), zircon (Zi) and ilmenite (TiO2 plus iron compounds). Neutralisation is required in the processing plant where acid is leached into the wash water. This water needs to be treated to a quality suitable for re-use in the metallurgical process or to a higher quality to make it suitable for discharge into the Empangeni sewage system (SA). For re-use the water needs to be neutral and under-saturated with respect to gypsum while for discharge into the sewage system the sulfate concentration needs to be reduced to less than 500 mg/L (as SO4). Acid mine water is generally neutralised with lime. Disadvantages associated with lime are the costs and maintenance of the slaking equipment as well as hazards, associated with handling of the alkali. The cost of powdered limestone (CaCO3) in South Africa, a by-product, is 50 - 60 per cent cheaper than lime. A technology has been developed where limestone is used for neutralisation of acid mine water instead of lime. This development includes: Limestone handling and dosing system. A novel, robust system has been developed where waste CaCO3 from the paper industry is slurried to a constant density. A full-scale plant was constructed to evaluate its performance (Figure 4). The dosing system consists of an inclined slab onto which the limestone is stored and from where it is slurried into a make-up tank. The density of the slurry in the make-up tank is controlled via a loadcell that measures the weight of the tank (operated at constant volume) and activates/deactivates the spray of the recycle slurry onto the slab. Integrated limestone neutralisation/lime treatment process. In this process powdered CaCO3 is used for neutralisation and partial sulfate removal of acid leached from the coal washing plant. The sulfate concentration can be further reduced to below the saturation level of gypsum (ie 1200 mg/L) through gypsum crystallisation by means of lime treatment, resulting in metal precipitation (eg Fe3+ and Al3+). CO2- treatment for CaCO3 precipitation. The pH of the lime treated water can be adjusted to pH levels of 8.5 and lower using CO2. The CO2, generated during limestone neutralisation (Equation 2), can be captured and used in this stage of the process. The first two stages (limestone- and lime neutralisation) of this technology have been implemented on full-scale at Ticor to treat the effluent of the process. The constructed plant is 80 m3/hr and differs from coal processing plants by way of not containing Fe(II) and Fe(III) in the water. The CO2-treatment stage (Stage 3) will soon be implemented at IHM as part of a program to optimise the technology for maximum benefits.

Jan 1, 2003

By H Kusumi, A Nishio, K D. Halim, Y Yun

In Japan, evaluation of rock mass is crucial in mountain tunnels that are constructed using the NATM (New Austrian Tunneling Method) to determine the support pattern that in turns determine the final support structure of the tunnel. The current evaluation method is highly dependent on the observations of on-site expert engineers that grades the rock mass in four levels across nine criteria: A. Condition of tunnel face. B. Condition of excavated surface. C. Compressive rock strength. D. Weathering. E. Spacing of discontinuity. F. Condition of discontinuity. G. Orientation of discontinuity. H. Spring water. I. Water degradation. However, in recent years, the number of said experts are decreasing rapidly due to labour shortage caused mainly by an aging population and declining birth rates. This is one of the biggest challenges that the construction sector currently faces, and this may affect the efficiency of tunnel construction projects in the future. Thus, this study proposes the implementation of a deep learning tool called the convolutional neural network (CNN) to quantitatively evaluate rock fractures on tunnel face. In addition, Gradient-weighted Class Activation Mapping (Grad-CAM) is applied to visualise CNN, as well as verify the applicability of CNN to the evaluation of rock fractures. In other words, by creating heat maps of tunnel face images, CNN is utilised to evaluate rock mass in categories that are associated with discontinuities. The CNN model is most accurate when six convolution layers, four pooling layers, and three dense layers are used. This yields an accuracy of 75.0~88.0 per cent. Thus, the CNN model is verified to be feasible method to evaluate rock fractures.

Nov 29, 2022

By Onal G, Celik MS, Dogan MZ

Chromite tailings assaying 21.2 per cent Cr2O3 was upgraded to 48.7 per cent Cr2O3 at a recovery of 72.0 per cent using column flotation with a mixture of anionic collectors at pH 11. Electrokinetic methods were used to elucidate the mechanism of collector adsorption and correlate the findings with the optimum flotation conditions. Multivalent constituent ions such as Cr3+, A13+, Fe2+ and Mg2+ were found to adsorb on chromite surface and shift the zpc of chromite in the direction of oxide form of the mineral. The anionic collectors also imparted a negative charge to chromite in the entire pH region. The higher zeta potentials obtained upon adding the anionic collectors is ascribed to the adsorption of anionic surfactant onto the positively charged chromite surface. The positive sites are generated through formation of significant amount of hydroxy complexes of magnesium at pH 11. Complementary infrared data reveal the absence of a shift in the spectra indicating the possibility of physical adsorption in the system.

Jan 1, 1993