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By W. K. Tolley, D. G. Kotlyar

Oxidized sulfide minerals, commonly formed by weathering, are becoming increasingly important resources as primary sulfide deposits are depleted. Oxidation, in general, reduces selectivity and recovery in flotation. The objective of this research was to determine the mechanisms of oxidation and collector adsorption in sulfide systems as a step towards developing improved technologies for beneficiation of oxidized sulfides. Data from microcell flotation tests are combined with electrochemical and spectrophotometric measurements. The adsorption of ethyl xanthate (EX) on oxidized sulfides was characterized using AC impedance and voltammetry techniques, and correlated to flotation response. Oxidation resulted in an electrically resistive, nonporous surface layer. The floatability of chalcocite, chalcopyrite and pyrite was dependent on the extent of oxidation. Oxidation for one day or more at 65ºC suppressed chalcocite flotation. Oxidized chalcocite also inhibited flotation of chalcopyrite and pyrite. Oxidation caused decreased chalcopyrite flotation. Pyrite flotation, however, increased after oxidation.

Jan 1, 1995

By M. K. Larson, R. G. Wade

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are studying the time- dependent response of rock stressed along weakness planes. The objective is to improve mine safety by reducing the number of roof falls that cause injuries and fatalities to miners. Researchers conducted direct- shear tests on mudstone overcored from a coal mine roof. Results showed frictional strength weakens with displacement along the shearing planes. Results of direct-shear creep tests also showed time-dependent deformation. Test measurements were compared to classical analytical models. Results suggest that the risk of roof collapse may be decreased through layout and support design to reduce creep rates and thus slow progression toward failure.

Jan 1, 2002

By W. E. (Bill) Stanley

Introduction This is an exciting day. It isn't often that you can find the best minds in a particular business gathered together in one place. But that is what we have here. You are the best and the brightest people there are in the business of gold mining. What we discuss at this conference confirms the major issues facing us and sets out the issues governing how our mines and mining companies will be run in the next few years. In looking over the list of papers to be given, I have noticed something. It is something that I have noticed at almost every mining convention I have ever attended. Almost every paper at this conference concerns itself with the technical side of mining. Most of us in this roan are professionals; we are either engineers, geologists, accountants or representatives of some other profession. In getting where we are today, we have had to work hard to acquire the technical skills needed for our individual professions. We are all proud of our knowledge and work hard to claim the right to be considered an expert in a particular technical field or subject area.

Jan 1, 1987

By Richard Engelmann

The mining industry, in particular the coal industry, has experienced the implementation of some major environmental regulatory programs during the past two decades. Over the coming decade the coal industry will probably experience only "fine tuning" of the regulatory programs they now operate under. The rest of the indus- try, however, appears to be on the verge of coming under a major new regulatory effort by the Environmental Protection Agency. Litigation and resulting court decisions will be the main force driving further changes in the SHCRA (Surface Mine Control and Reclamation Act) regulatory program. These changes are anticipated to be minor in compar- ison to earlier changes. EPA, however, is preparing a regulatory program which may carry as much impact to the rest of the mining industry as SNRA was to coal. Details of this program have yet to be worked out. Changes in the way EPAts Clean Air Program is applied to mining could also significantly impact the mining industry.

Jan 1, 1989

By Paul H. Lu

This paper proposes a novel method, "integrity factor approach," of mine-pillar stability evaluation based on in situ triaxial-loading measurement. The pillar integrity factor is defined as the quotient resulting from division of integrated total pillar strength across the critical dimension by the integrated total pillar load across the same dimension. The integrity factor is dynamic, while the conventional safety factor is static. With this approach, the pillar stability can be evaluated at any stage of mining progress during panel operation. It automatically considers the progressive failure of the pillar and post-failure strength without the need to clearly define the boundary between yielded and intact zones of the pillar. Based on two case studies, the integrity factor approach is shown to be a practical, effective technique for evaluating stability of conventionally designed pillars. It is suggested that a more realistic estimate of in situ pillar strength could be made based on the combination of in situ triaxial-loading measurements and laboratory true triaxial compression tests, rather than through the traditional combination of biaxial-loading measurements and conventional triaxial compression tests.

Jan 1, 1986

By Betty L. Gibbs

A clear and accurate knowledge of the status of ventilation in an underground mine is essential to continuing safe operation. In a small mine with a few working faces, the problem is simple and can easily be solved by choosing the appropriate fan. In larger, more complex mines the problem of supplying the working faces with fresh air is a problem beyond the scope of 'finger in the wind' analysis. In today's climate of stiffer government regulation and mining company concern for the safety of workers, computer programs which analyze ventilation networks are helping mining companies meet the standards. The development of computer programs for ventilation network analysis is summarized. Early programs were developed at universities or government agencies and required large expensive computers. As computers have become smaller and less expensive, the development or revision of programs for micro computers has become more available. Prices have lowered to the point of affordability even for medium and small companies. A list of ventilation network analysis programs is provided along with a summary of capabilities, costs, and hardware requirements for each program.

Jan 1, 1987

By A. T. Weber, G. T. Adel

Earlier studies on the hydrodynamic interactions between fine particles and air bubbles have shown that fine particle flotation can be improved by using small air bubbles. In the present work, microbubbles ranging in size from 70 to 250 microns have been used in a flotation column for the processing of fine coal. The performance of the microbubble column has been studied as a function of wash water addition rate, aeration rate, feed rate and column length to diameter (L/D) ratio. The information collected from these tests has been used to analyze column behavior and to develop scale-up criteria. The results of this investigation suggest that mixing within the column may not be as significant as bubble size and residence time in determining column performance. Improved recovery can be obtained by decreasing bubble size which increases the flotation rate constant, and also by increasing L/D which increases residence time for a fixed column volume. The increase in residence time with L/D is due to a decrease in the volumetric flow rate of wash water with column diameter.

Jan 1, 1988

By P. V. Avotins, D. R. Nagaraj, S. S. Wang

Xanthates and dithiophosphates are the most commonly used collectors in the flotation of sulfide minerals. Other reagents such as thionocarbamates, mercaptobenzothiazoles (MBT), mercaptans and xanthogen formates occupy niche positions in industrial collector use. Over the last ten years there has been much activity by chemical companies to develop new collector compositions. The new collectors are aimed at meeting specific process needs such as recovering an increment of valuable metals, improved sulfide separations, increased flotation kinetics, and reducing reagents costs. A review of the patent literature shows that American Cyanamid (Cytec), Dow Chemical, Phillips Petroleum, Sentrachem Ltd., Henkel, Montan Chemicals and Elf Aquitaine, among others, have been active in sulfide collector research. Several companies have achieved considerable success in laboratory and plant tests of the new collectors; however, commercial acceptance for plant usage has been slow. Those most advanced have been plant tested extensively and some are in day-to-day use. The new collector types in this category are: Modified thionocarbamates, dithiophosphinates, organic sulfides, trithiocarbonates, monothiophosphates, and modified thioureas. Others such as substituted mercaptobenzothiazoles and monothiophosphinates have been tested in the laboratory. The chemistry of collectors developed in the last 10 years, their preparation, physical properties and their potential for commercial use are reviewed in this paper.

Jan 1, 1994

By K. Koizumf, A. A. Cram, K. Whitchurch

The Expert Scheduling is a new, exciting method for scheduling underground and open-cut coal mines. A key feature of the Expert Scheduler is the adoption of an expert or artificial intelligence system. The expert system makes decisions regarding the schedule, such as which area should be mined. With existing scheduling systems these choices are made by the scheduling engineer. Developing one area may be better than another if it offers better quality or lower costs. Information the engineer considers in these decisions could be; • coal tonnage and quality targets, • equipment utilisation, • mining cost, • and other practical constraints. In expert scheduling a number of experts are appointed to make these decisions. A number of mining strategies are examined for each period. Information for each strategy is evaluated by "experts" and the "best" solution adopted. The method is based on the Blackboard Techniques. With this technique information is presented to "knowledge sources” or "experts" by the Blackboard Controller for their "opinions". These "opinions" are examined by the Blackboard Controller to select the best strategy. Engineers can readily add experts to the system, and modify the weighting of experts to suit mining conditions. Using an Expert Scheduler means that many schedule op- tions can be analysed quickly with full repeatability.

Jan 1, 1996

By Talaat A. B. Lawendy, Guerry H. McClellan

Batch laboratory-scale flotation tests were conducted on some carbonate-containing sedimentary phosphate ores to obtain concentrates suitable for chemical processing. The phosphate samples tested contained both calcite and dolomite. The calcitic phosphate ore was from Israel and the dolomitic ores were from China, India, Egypt, and Pakistan. The phosphate sample from Pakistan also contained a significant amount of silica. Several flotation techniques that have been proposed for upgrading carbonate -containing phosphate ores and concentrates were tested. Two processes gave better results compared with the other processes tested: a modified IMC anionic process and a. phosphoric acid depression process. At the best flotation conditions tested, phosphate concentrates assaying 32.5%-36.5% P205, 44.0%-51.0% CaO, and 0.6%-1.0% MgO were obtained at 69%-76% overall P205 recoveries from run-of-mine (ROM) ores containing 16.0%-25.0% P205, 40.0%-52.0% CaO, and 1.0%-11.6% MgO.

Jan 1, 1993

By L. A. Feldkamp, L. I. Davis, F. Yuan, G. V. Puskorius

Emerging technologies such as neural networks and fuzzy logic have many potential industrial applications in diagnostics, modeling, and control. In the automotive industry, applications can be divided into those that impact manufacturing processes and those that relate directly to the product. Though discussion often centers on neural networks deployed in hardware, their potential in the development of problem solutions (however deployed) could easily be of greater importance. Here we concentrate on the use of neural networks for modeling and control, using a simulation of vehicle active suspension as a concrete example.

Jan 1, 1993

By R. N. Rothan, V. Khunova, C. M. Liauw, G. C. Lees

The interphase modification activity of 1,3-phenylene dimaleimide (also known as m-phenylene bismaleimide (BMI)) has been studied in composites based on magnesium hydroxide (60% w/w) and a polypropylene block copolymer (PPBC) that featured an ethylene-rich elastomeric impact modifier phase. BMI was found to be a unique product that led to significant simultaneous improvements in composite strength and toughness, even at the high filler levels. BMI modification was found to promote encapsulation of filler particles with the elastomeric phase of the PPBC together with formation of a PP boundary layer of increased crystalline content.

Jan 1, 2003

By C. Ceccarini, I. Salvadori, G. Oggiano

GENERAL BACKGROUND The first mention of the presence of bauxite in the mesozoic series of north-west Sardinia (fig. 1) is owed to Oosterbaan, a Dutch geologist, who carried out a geological survey of the area in the ninetten thirties. A more detailed study of the mesozoic series was attempted in the fifties by Pecorini and other, who concentrated particularly upon the stratigraphy of the bauxitic horizons, through examination of the various outcrops. In the sixties a pining company, Monte Amiata S.p.A., turned its attention to a section of the deposit outcropping near Olmedo and, considering it to be of some promise, carried out prospecting works consisting essentially of various trenches, some bore holes, a few adit and a. layout plan for the preparation and execution of trial exploitation. The results, although positive, did not convince the company's shareholders to continue the exploration. This report, which is intended as a new contribution to knowledge of the Sardinian bauxite deposit, takes into account the information acquired not only from a drilling prospection begun in 1979 in connection with the SOMIT-PROGEMISA joint venture, but also the results of structural studies and numerous chemical, mineralogical and

Jan 1, 1984

By John Jonkman

Two major changes occured during the last 5 years in the applications of computers. First, the cost of computer equipment decreased drastically in an era of high inflation. Second, technological breakthroughs in hardware and software have been applied successfully so that the average person can successfully utilize the computer without having to be a computer expert himself. The mining industry has recognized that computing technology has evolved to a point where it can be applied successfully to assist in improving productivity. Since equipment downtime is one of the major reasons for lost production, the Kennecott Minerals Company has developed a comprehensive maintenance information system which now assists the maintenance department in minimizing equipment downtimes. This paper discusses the primary features and functions of this system, the state-of-the-art technology that has been applied, and the benefits that resulted from using this system. Programs to support mobile equipment maintenance scheduling, which currently are under development, are reviewed and a summary of future applications is given.

Jan 1, 1982

By D. J. Shields

This paper describes a dynamic short-nun mineral supply model that incorporates secondary processing, transportation, mineral market structure, and direct mining and milling costs. The method employed is network flow programming. Empirical tests utilizing domestic phosphate industry data have been conducted by the Bureau of Mines, U.S. Department of the Interior. In the model, nodes represent physical locations such as a mine or port. Arcs represent either a process, such as mining, or movement, such as rail or barge transport. Each arc is described by lower or minims allowable flow bounds, upper or maximum possible flow bands, and variable cost. Mines and previous period inventories represent potential supply. The model is optimized via a cost minimizing algorithm, which attempts to fulfill stated total demand at the minimum possible system cost given the arc constraints. An optimal solution of the model will predict production patterns by mineral property for each prespecified level of demand. A mineral property is defined as a separate accounting entity such as a mine. The results of serial optimizations are used to construct the short-run supply curve. Dynamic policy analysis can be conducted by altering the arc constraints.

Jan 1, 1986

By M. H. H. Mahmoud, T. A. El-Barbary, E. A. Abdel Aal, I. A. Ibrahim, A. K. Ismail

Fertilizer-grade phosphoric acid with a P2O5 concentration of 50% should contain less than 1.5% Fe2O3, otherwise, the P2O5 water solubility of the fertilizers prepared from high-iron acids will be low. High-iron Egyptian phosphate concentrates fromAbu-Tartur and Sebaiya- West were leached with sulfuric acid and recycled phosphoric acid to produce 50%-P2O5 phosphoric acids containing 4.0% and 2.7% Fe2O3, respectively. The high iron contents were reduced to the industrially accepted limit of 1.5% Fe2O3 by precipitation with potassium sulfate. The factors affecting the effi¬ciency of the precipitation process, e.g., temperature, time and K2O/Fe2O3 ratio, were systematically studied, and the optimum conditions were achieved. The clarification of the prepared phosphoric acid from iron-containing sludges was also investigated by varying the time and temperature. The utilization of the separated sludges as fertilizer and recovery of P205 by pulping in water were also evaluated.

Jan 1, 2000

By V. G. Papangelakis, G. P. Demopoulos

The high temperature (180-200 OC ) pressure oxidation (02 - HzSO4) process for the recovery of gold from refractory concentrates (FeS2/FeA8S) is simulated with the aid of a computer model. The model centers on the continuous operation of a multi-stage horizontal autoclave. In particular the effects of key process parameters controlling the autogenous operation of the autoclave are critically examined. The building elements of the model are (i) the continuous particle size distribution function of the concentrate, (ii) the residence time distribution function of the slurry and (iii) the shrinking core kinetics. Conversion is calculated on the basis of the segregated flow model. For the calculation of the particle size distribution at the exit of each compartment the population balance model is employed. The effects of feed rate, feed preheating, cooling, autoclave configuration and rate limiting regime (chemical reaction vs. gas-liquid mass transfer) on the autogenous steady state operation are discussed. Finally optimum reactor design and operation criteria are indicated.

Jan 1, 1990

By H. Zhu, A. G. Journel

Qualitative and interpretive information as obtained from geological and/or geophysical studies, in addition to precise measurement, is incorporated into the estimation process through an indicator variable. The indicator conditioned estimator is formulated as a cokriging, and its expression is data value dependent as opposed to that of the traditional kriging estimators. The solution of the dual cokriging system provides simultaneously an estimate of the unknown and an estimate of the conditional probability that the unknown belongs to a specific population or class. Being an unbiased and minimum-error-variance estimator by construction, the indicator conditioned estimator is better in the least square sense than the ordinary kriging estimator because it uses additional information carried by the indicator data. A case study using a large reference database is presented; the indicator conditioned estimates have a smaller conditional bias and a smaller error variance than the ordinary kriging estimates. The results also showed that the indicator conditioned estimator is more efficient for selection in mining.

Jan 1, 1990

By A. T. Sapulek, C. S. Özveren, D. W. Dixon

The prediction of underground methane emission from longwall coal faces has been extensively researched for a number of years and numerous prediction methods have been devised. Many coal mines employ sophisticated environmental monitoring equipment which generates large amounts of data including, methane concentration, air velocity and barometric pressure. Presently this information is mainly used only to indicate alarm and danger levels of the monitored data for management purposes, however, the potential uses of this data are enormous[1]. This information could be used to good effect within a production/methane emission strategy as detailed in a previous paper[2]. The paper presents a practical application of artificial neural networks to underground methane prediction. Data on methane concentration and coal production has been obtained from an underground coal mine. The data is used in a neural network architecture and forecasts of methane concentration have been obtained. The forecasts are examined and there is a discussion of the potential use of the predictions from neural networks in the field of mining production control.

Jan 1, 1995

By H. E. M. N. Moursy, Hassan El-Shall, M. N. Ahmad, Ponisseril Somasundaran, C. R. Holland, D. Chandler, G. Walker, Regis Stana, Patrick Zhang

The reaction kinetics of the acidulation of Moroccan phosphate rock (32% P?05) using 45% nitric acid were investigated using the Shrinking Core Model (SCM) , a newly developed Diffusion Model (DM) and a newly developed Combined Reaction and Diffusion Model (CRDM). This was achieved buy conducting a number of experiments in a controlled batch reactor system at different temperatures. The conversion and the reaction rate were calculated at different time intervals. The SCM based on reaction time and the CRDM characterize the acidulation process of phosphate rock. Diffusion of nitric acid and the products of acidulation at the early stages of reaction through the phosphate rock were found to be the rate-controlling step, resulting in a dif- fusion coefficient, which controls the mass transfer process. The reaction kinetics were found to fit first-order kinetics especially during early stages of reaction time. The deviation of the kinetics from first-order at later stages was due to the fact that the overall reaction was mass transfer controlled with respect to nitric acid and products diffusion.

Jan 1, 2002