The Effect Of Oxidation On Sulfide Mineral Flotation

Oxidized sulfide minerals, commonly formed by weathering, are becoming increasingly important resources as primary sulfide deposits are depleted. Oxidation, in general, reduces selectivity and recovery in flotation. The objective of this research was to determine the mechanisms of oxidation and collector adsorption in sulfide systems as a step towards developing improved technologies for beneficiation of oxidized sulfides. Data from microcell flotation tests are combined with electrochemical and spectrophotometric measurements. The adsorption of ethyl xanthate (EX) on oxidized sulfides was characterized using AC impedance and voltammetry techniques, and correlated to flotation response. Oxidation resulted in an electrically resistive, nonporous surface layer. The floatability of chalcocite, chalcopyrite and pyrite was dependent on the extent of oxidation. Oxidation for one day or more at 65ºC suppressed chalcocite flotation. Oxidized chalcocite also inhibited flotation of chalcopyrite and pyrite. Oxidation caused decreased chalcopyrite flotation. Pyrite flotation, however, increased after oxidation.