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By S. Mathieu, R. Mennillod-Blondin, P. Cousin, N. Valle, H. Bouzahzah, P. Marion

The gold deposit of the Lapa mine has a complex mineralogical gold state with coarse and fine native gold, aurostibite and submicroscopic gold within arsenopyrite. A specific mineralogical characterization of the refractory fraction was conducted combining various techniques such as optical microscopy, electron microscopy, electron microprobe and secondary ion mass spectrometry. In parallel, the mineral processing behaviour and the recovery of the refractory gold were studied by pressure oxidation and cyanide leaching. This paper presents the mineralogical methodology developed to characterize the refractory gold distribution within arsenopyrite. These results are presented and interpreted in order to plot gold recovery versus sulphide oxidation. The comparison of the metallurgical behaviour yields predicted from the mineralogical data and the one calculated from leaching tests shows a good agreement and allows mineralogical explanations of the gold metallurgical behaviour.

Jan 1, 2011

By R. Cammack

"A fundamental component of the Hoek–Brown empirical rock failure criterion is assessing an appropriate mi constant. In developing their empirical criterion Hoek and Brown normalised triaxial test results by dividing the principal stresses at failure by the uniaxial compressive strength to provide mi values for typical rock types. Experience shows that Hoek triaxial tests for individual lithology types commonly have a large inherent scatter. In addition, tests are often conducted on core from random locations, which although being of one parent rock type, display variations in density as well as minor variations in grain size and alteration.This paper presents experience from projects the authors have been involved in which large sample populations of triaxial and UCS tests on similar rock types were available. Geophysical logging data was also available for some projects. The methods used to estimate the compressive strength for each sample and the effects on normalising the data sets are described. The variability of the data and uncertainties and assumptions involved in the process of assigning a mi value from the normalised data are also discussed."

Jan 1, 2015

By X. Cao, A. Birur, R. R. Chromik, J. Cuddy, P. Wanjara, J. Gholipour Baradari, T. Shariff

In this study, 3.1 mm thick Ti-5553 (Ti-5Al-5V-5Mo-3Cr) butt joints were autogenously welded using a 4 kW continuous wave Nd:YAG laser. The effect of welding speed and defocusing distance on the weld quality was investigated in terms of the surface morphology, welding defects, microstructure and hardness. Welds with full penetration were achieved at a defocusing distance ranging from -1 mm to 0 mm and welding speeds from 2.25 to 6.0 m/min. Underfill and porosity were the two main defects most frequently observed but within the optimum process window these defects could be maintained to meet aerospace specification tolerances. The fusion zone (FZ) consisted entirely of retained beta with a refined dendritic morphology. Compared to the bimodal alpha (a) + beta (ß) microstructure of the base metal (BM), the dissolution of the a phase was observed in the heat affected zone (HAZ), which led to an 11 % decrease in hardness from the BM to the FZ. To determine the tensile properties of the welded samples, an automated 3D deformation measurement system was used to measure the local strain in the weld region. The yield strength (YS) and ultimate tensile strength (UTS) increased with increasing welding speed with a highest joint efficiency of 75 % being achieved, albeit with a concomitant reduction in the ductility.

Jan 1, 2010

By H. Aaltonen, T. G. Robinson, M. Morimitsu

"The energy required to plate pure zinc can be the most significant operating cost for an operator in the production of electrolytic zinc. This paper reports on developments on low energy Outotec coated titanium anode process technology with fully amorphous coatings, MSA®, and its application to brownfield zinc electrowinning operations around the world. This technology aims to reduce the operating cost and increase productivity for zinc producers.INTRODUCTIONZinc electrowinning is an energy-intensive process using more than 3,000 kWh/t of electric energy [1-4], and the reduction of the energy consumption is one of the key issues. The high energy consumption is due to a high cell voltage during electrolysis, which is mainly caused by a high overpotential of oxygen evolution reaction on lead alloy anodes which have been widely used in commercial zinc electrowinning processes. The overpotential of oxygen evolution is 0.6 V or more and which is approximately 4 times higher on average than that of the cathodic reaction (zinc deposition) [3,4]. Therefore, the reduction of oxygen overpotential is significant to reduce the electric energy consumption, and this will become more significant with increasing demand in metal production and rising energy costs.Oxide coated titanium anodes have been widely investigated for the oxygen evolution anodes in order to replace the lead alloy anodes [5-9], because it is known that the oxygen overpotential strongly depends on the material and structure of the anode. The most typical example of such anodes is an IrO2-Ta2O5 coated titanium anode, which is usually prepared at thermal decomposition of a precursor solution containing metal salts at 450 oC or more and obtained mixed oxide coating consists of crystalline IrO2 and amorphous Ta2O5. On the other hand, one of the authors of this paper, Professor Morimitsu, Doshisha University in Japan, has developed a novel oxide coated titanium anode, MSA® [10-25]. The most specialized point of MSA® is that the catalytic coatings are prepared at low thermal decomposition temperature and amorphous IrO2 or RuO2 is contained as the components in the coatings. Such amorphous coatings have high catalytic activity for oxygen evolution compared to lead alloy or crystalline coatings. Outotec acquired the international specialized MSA® patent licensing rights from Doshisha University and has produced and commercialized the amorphous oxide coated titanium anodes. These anodes have already been utilized mainly in copper electrowinning plants worldwide and have demonstrated a significant voltage reduction, a cost-efficiency, and a long lifetime. This novel technology is also effective to zinc electrowinning process, thus this paper presents the characterization and performance of amorphous IrO2-Ta2O5 coated titanium anodes and amorphous RuO2-Ta2O5 coated titanium anodes for oxygen evolution in zinc electrowinning."

Jan 1, 2016

By D. Royston

Reducing SAG Mill feed size has been a major trend in recent years. ?Mine to mill? strategies have reduced blasted-rock size, and in a growing number of operations reducing the primary crusher CSS and/or adding additional crushing upstream of the SAG mill have reduced rock feed size. While reducing feed size will increase SAG mill throughput, issues arise in terms of retaining charge in the mill, exposing the shell lining to impact damage, and maintaining milling performance should the pre-crush system shut down. This paper reviews the past experience on pre-crushing for SAG mills and provides an analysis of liner design (in particular grates and shell liners) for pre-crushed feed.

Jan 1, 2012

By A. H. Lang

"IntroductionMUCH PROSPECTING, exploration, and development work was done for uranium in Canada in 1952, chiefly in northern Saskatchewan and in the Great Bear Lake region of the northwest Territories. The outstanding feature of the year was the great amount of work done in preparing for production at the Ace mine of Eldorado Mining and Refining, Limited, in the Goldfields region . of Saskatchewan. Many private companies and prospectors were also active in this region. Most of the other parts of Canada where uranium has been found received less attention than during the last few years, partly because so much interest was taken in the Goldfields region.In presenting this short summary of the year's activities now, the writer is handicapped because the season is not yet over; some discoveries have probably not yet been announced, and there has not yet been time to digest the numerous reports that have been sent in by companies and prospectors. In any case it would be impossible to give details for most of the discoveries and properties, because that would require a long report, and because that information is classed as confidential until released by the discoverers and companies concerned. It is only possible, therefore, to give a few generalizations, a brief out-line of the activities in northern Saskatchewan, even briefer ,accounts of the work in other parts of the country, and a few details that property owners have informed the writer he may publish or that have already been published by the owners."

Jan 1, 1953

The primary (sulphide) resources at Aphrodite are refractory in nature, requiring an oxidation process stage to be introduced to facilitate extraction of the gold. The company is investigating the use of pressure oxidation (POX) as the oxidation method for processing of high grade gold bearing concentrate it plans to produce at Aphrodite. POX has been used extensively around the world for the past 30 years and continues to be the favoured option for a number of refractory gold plants currently in the design and construction stages. Initial pressure oxidisation testing investigated the effect of temperature, pressure and grind size on a bulk flotation concentrate prepared from Alpha lode material. The concentrate averaged 47.3 g/t gold and was prepared from a composite of core samples averaging 1.49 g/t gold. Sub-samples of the concentrate were subjected to POX for 1 hour resulting in rapid oxidation during this very short period. Testing undertaken showed that there was a significant increase in sulphide oxidisation at higher temperature (220°C) and pressure (2,500 k/Pa) for the two grind sizes (75 and 20 microns) evaluated. The proposed flowsheet, OPEX and CAPEX are critical aspects for project development.

Jan 1, 2014

By S. R. Stopic

The EU-financed INTREAT Project (Integrated treatment of industrial wastes to¬wards prevention of regional water resources contamination) addresses the environmental pollution associated with solid and liquid wastes/effluents produced by complex sulphide ore mining and metallurgical activities. The results concerning the electrolytic recovery of cop¬per from effluents formed after mixing of streams from Copper Refining, Precious Metals Plant and Electrolyte Regeneration in the Balkan Area will be shown. The waste water is characterized by low pH values and high contents of heavy metals, such as Cu, Ni, Bi, As, Sb. The majority of these waste water flow untreated into the natural water streams and through the network of existing rivers, which end up in the river Danube. The influence of current density and flow rate on the deposition rate, the quality of copper and the process efficiency will be presented. The full continuous process is based on cells with rotating disc cathodes and represents a pre-treatment step before common neutralisation in a cascade line

Jan 1, 2007

By Aaro E. Aho

Yukon, one of the most potentially accessible, relatively undeveloped, regions of Canada, has major mineral possibilities. The Klondike placer gold fields and the Mayo silver-lead ?district are the sole major producers but large base-metal re-serves have been discovered in re-cent years and important asbestos deposits are now being explored. Several major exploration companies are active in this region despite short seasons, permafrost overburden, remoteness, lack of transportation, and resultant high costs. Pro-posed new roads can be expected to accelerate development. At ?present the major future mineral possibilities are considered to be lead-zinc, copper, aslbestos, silver-lead, gold, and mineral fuels. These and other mineral possibilities are outlined for various geological subdivisions of Yukon. Major favourable metallogenic features of Yukon include complexity of rock types and structures, widening of the Cordillera with cross-trends, and variety and quantity of mineralization found even with limited prospecting. Comparisons with southern 'British Columbia and the U.S. Cordillera suggest that further exploration will result in discovery and development of more major ore deposits and reserves which will eventually revolutionize economy of mining in Yukon. Such mineral resources, with interior petroleum and natural gas possibilities, and ?huge coastal hydroelectric power potential, are the foundations of a much larger future mining industry in Yukon.

Jan 1, 1958

By J. Schmidt

The development of set of laboratory experiments, intended to help undergraduate students meet Canadian Engineering Accreditation Board requirements for Engineering Design outcomes, is described.The laboratory, which is part of a third year level course in hydrometallurgy, is aimed at advancing the ability of students to generate and use experimental results to design an industrial copper leach/SX/EW plant. Emphasis is placed on the students demonstrating the ability to use of their engineering knowledge in weighing the pros and cons of the various process options that they test in converging to a final flowsheet. INTRODUCTION Over the past number of years the Canadian Engineering Accreditation Board, CEAB, has dramatically shifted the way that they evaluate undergraduate programs. In the past, the focus was on measuring of the quantity and quality of material the students were intended to learn as well as the methods and resources used to deliver that material. Now, rather than principally evaluating the inputs of programs, the focus is more on measuring the quality of the outputs from the programs, i.e. the quality of graduating students. In this regard, the CEAB has developed a list of twelve attributes that learners must develop in the course of their studies. Engineering programs must, not only demonstrate that their curriculums provide opportunities to develop these attributes, but must measure student proficiency in each of these attributes as they progress toward graduation. One particular graduate attribute that Laurentian University’s Bharti School of Engineering has encouraged its faculty members to develop content for is “design”. Engineering Canada (2018) defines this attribute as “an ability to design solutions for complex, open-ended engineering problems and to design systems, components or processes that meet specified needs with appropriate attention to health and safety risks, applicable standards, and economic, environmental, cultural and societal considerations”. The previous laboratory component for the hydrometallurgy course was a collection of unconnected experiments covering leaching, solvent extraction, ion exchange, and electrowinning. Like in other undergraduate courses, students would perform stand-alone experiments, make the specified measurements, do the specified analyses of the results, and report the findings, all as strictly detailed in the lab manual. The vision for the new lab was to create an experience that would more closely mimic an industrial research program whereby students would start with a given feed material and would progress through a series of connected experiments. Emphasis is placed on the student demonstrating competency in, not only, generating and analyzing experimental data, but also in using the data along with their engineering knowledge to design and evaluate the pros and cons various plant configuration options. Principally, students are asked to weigh cost, safety, and environmental concerns in converging to their final flowsheet. In designed the leach circuit, students must weigh the costs/benefits of varying leach temperature. Higher leach temperatures will yield faster and more complete copper dissolution, which will allow for the specification of relatively smaller leaching circuits, saving capital costs. However, hotter acid solutions are more dangerous to handle and require increasing amounts of energy to heat the slurry, increasing operating costs. In solid/liquid separation, students must weigh the pros and cons of the addition of a flocculent to assist settling. The flocculant will allow for the design of a thickener circuit that employs units with a relatively smaller area, but will result in a thickener underflow with a lower pulp density, which may necessitate a larger number of thickeners. In addition, the environmental concerns of producing a tailings product that contains an organic contaminant should be addressed. In solvent extraction, students must specify the number of stages of loading and stripping, as well as organic and aqueous flowrates to produce suitable raffinate and rich electrolyte streams. Finally, in electrowinning, students will compare the costs/benefits and risks of the use of precious metal coated titanium dimensionally stable anodes (DSAs) versus conventional Pb based anodes.

Jan 1, 2019

By Charles Goodeve

"BEFORE I begin, I should like to thank The Canadian Institute of Mining and Metallurgy for the honour they have bestowed in inviting me to give this address at the fourth annual C.I.M. Conference of Metallurgists banquet.Secondly, I should like' to convey the greetings of the Iron and Steel Institute of Great Britain in accordance with a request made by its Council at its last meeting. The I.S.I. hopes for the continued growth in strength of this annual Conference and in the collaboration between our respective societies.When I read the program of this Conference, it was brought home to me what a non-ferrons country Canada is. Also, I realized what enormous advances have been, and are being made, and what an ex-citing field non-ferrous metallurgy is for the scientist. This made me wonder, as I have done before, whether the future for steel was proof against these advances.At present, iron and steel stand astride the metallurgical world like a Colossus; I hope that the bronze industry will pardon my stealing their thunder and mixing my metaphors! Will this still be so in the future?The best way to answer this question is to take a look at the fundamentals to see why the iron atom dominates to such an extent that al! other metals are called ""non-ferrons."" Is its present position due to historical and therefore ephemeral reasons, or is there a fundamental difference between the atom of iron and those of other metals?"

Jan 1, 1966

By J. B. Hamilton

The advantages of generating and distributing electrical energy direct from the coal-fields so closely affects the mining industry that a few remarks on the unbalanced phases of coal distribution is worthy of attention. The value of coal imported into Canada from 1912 to 1921 exceeded the sum of $580,000,000. In 1922 Ontario imported 1,640,000 tons of anthracite and 9,440,000 tons of bituminous coal. I submit that the use of Saskatchewan lignite in an electrical super-power plant equipped for the carbonizing of coal, and disposal of excess gases would be the commencement of a solution of the fuel shortage in Ontario. As Saskatchewan becomes more and more populated and manufacturing increases, the amount of by-product carbonized fuel available for shipment to Ontario will increase, and its shipment to that province would decrease the trade deficit of the national balance sheet. If and when this is carried out it will mean a better and wider market for Alberta fuels in Saskatchewan and Manitoba.

Jan 1, 1924

By E. Zucker

In this paper, as in the 1960 CIM paper of the same name, s1gmf1cant new developments in electrical-mechanical mining equipment are briefly described. These include static thyristor-supplied D.C. drives for mine hoists, load-haul-dump systems, process controls with small and medium-size computers, and several other new items of equipment and Concepts. All the new hardware descriptions are given in the context of over-all process integration. This means the actual mechanical linking together of two or more processes and the preliminary step in the development of production-line mining.

Jan 1, 1969

By E. Wraith, W. W. Culver, B. Wesstrom, P. J. Mackey

Electrodeposited copper of the 1860s was of unprecedented purity, although the profound significance of this achievement was not fully realised until the dawn of the electrical age a decade or so later. By the 1870s there were three somewhat large (4 to 4.5 tonnes Cu/day) electrolytic copper refineries in Germany based on J. B. Elkington’s process, first patented in the United Kingdom in 1865. More such refineries were planned throughout Europe. At the same time, copper output in the U.S.A. was starting to expand and with the spread of European electrolytic copper refining technology across the Atlantic, the door opened to major increases in North American output. The technology was first taken up in 1879 by James Douglas at the Chemical Copper Company in Phoenixville, Pennsylvania, where he was Superintendent. Douglas was assisted in this pioneering work by Edward Weston. The copper refinery at the Chemical Copper Company was small, not unlike the first plants in Europe. The present authors contend that the electrolytic copper refinery at the Chemical Copper should be regarded as the first copper refinery in the United States. The Balbach Copper Refinery in New Jersey, which commenced operations in 1883 with an initial production of about 2 tonnes Cu/day, has been erroneously considered as the “first commercial refinery”; it rightly belongs in second place. The early developments at these plants are discussed in this paper. INTRODUCTION In the mid-1800s, the main uses for copper were as sheathing on the wooden sailing ships of the day to protect from marine growth, boiler components in locomotives and steam engines, along with some construction uses. Copper ores were generally smelted, and further fire-refined for market. The recovery of gold and silver, if present in payable amounts, was a slow and relatively expensive step. This situation regarding copper would change by the 1870s with advances in the generation and use of electricity. The introduction of the dynamo led to major developments in electrorefining. First demonstrated in principle by Faraday in 1831 (Faraday, 1832), the dynamo was subsequently adapted and further developed by J.S. Woolrich for electro-metallurgical applications in 1842 (Woolrich, 1842; Napier, 1845). It provided a new source of power with the unprecedented potential to significantly change the scale of metal production by electrometallurgy. Interestingly enough, copper would be needed for the electrical age just beginning. By 1869, advances in dynamo design offered relatively reliable large machines, which enabled J. B. Elkington in the United Kingdom to use the dynamo in the radically new Pembrey copper electrorefinery — the first copper electrorefinery in the world (Wraith, 2013). Initial production at Pembrey was small — in the range of 1 to 2 tonnes/day — while gold and silver were recovered more readily by the treatment of the slimes than with methods used hitherto.

Jan 1, 2019

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter has been developed to predict the molten temperature. The primary assumption of the model was that all matte, slag and gaseous phases in the converter were in thermal and chemical equilibrium. In this model, the matte components were considered only as copper, iron and sulfur elements. In the slag making stage, all the reacted iron was converted to fayalite. The reaction rate of iron and oxygen in this stage was considered to be constant. The converter temperature was calculated by heat balance over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depends on process parameters such as oxygen efficiency and molten emissivity.

Jan 1, 2007

By D. Cronin, A. Plumtree, A. Hosseini

"Crack in corrosion (CIC) linepipe defects are hybrid defects not directly addressed by existing assessment methods. To investigate the collapse pressure of these defects, CIC defects were formed in 508 mm (20 in) diameter, 5.7 mm thick API X52 linepipe. These defects were 200mm long and varied in depth from 3.0 to 3.8 mm. The respective failure pressures decreased from 14.3 MPa for the plain pipe to 7.9 and 6.2 MPa respectively. A standard FAD method was applied to evaluate these defects as equivalent length and depth cracks, predicting the rupture pressure conservatively by 18% on average. However, when assessed as equivalent cracks with a reduced wall thickness corresponding to the corrosion depth, the predicted collapse pressures were more accurate, approximately 14% conservative on average.INTRODUCTIONPipelines are a safe and efficient method for transporting high volumes of oil and gas. However, aging pipelines may experience defects, such as cracks or corrosion. Present approaches include detection, assessment and repair of defects before they may become critical to the integrity of the line. There are different codes and standards for assessing pipeline defects, depending on the type of defect, with API 579 (API, 2000) being the most common code for the assessment of cracks in oil and gas pipelines . Corrosion is commonly assessed using RSTRENG (Kiefner & Vieth, 1989). Other methods such as the Finite Element method and the CPS method (Cronin & Pick, 2002) may be used for crack and corrosion, respectively.At present, there is no specific method or procedure for assessing crack in corrosion (CIC) defects, and as a consequence there is a need to provide an assessment and evaluation of the integrity of these defects in order to determine the requirements for defect repair or hydro line testing. Hence, the goal of this study was to provide guidance for the assessment of CIC defects for linepipe.CRACK IN CORROSION DEFECTS (CIC)Significant amounts of corrosion and cracking are not generally found together (Hosseini, 2010). However, a new hybrid defect including cracking within corrosion (CIC) has been identified in operating pipelines. In this case, cracking coincident with corrosion (schematic shown in Figure 1) provides the motivation for the current study."

Jan 1, 2012

By A. Hashempour, D. Javani

"Selection of an optimal bit is a critical issue in drilling engineering. Specific energy (SE) and Cost per Foot (CPF) are the most common methods for evaluation of bit efficiency and optimal bit selection. The major shortfall of both methods is that they do not directly account for geological and geomechanical parameters of formations being drilling. In this paper, results of using the two foregoing methods are compared using Formation Drillability (FD) method, which directly accounts for geological and geomechanical parameters of a formation. This method combines various geological and geomechanical parameters and yields a dimensionless parameter indicating the formation drilling hardness (drillability). Results of this study show that the amount of energy, cost and time spent for drilling a unit volume / length of an identical formation may vary in different wells. This is due to the fact that geological and geomechanical characteristics of a formation may vary among wells and even within short intervals of a single well. Therefore, an optimal bit may not be appropriately selected, if drilling and economical parameters are the only factors considered and the formation geological and geomechanical specifications are ignored.INTRODUCTIONMany authors such as Bilgesu, Al-Rashidi, Aminian, and Ameri (2000) and Clegg (2006) conducted research in the evaluation of bit performance and optimum bit selection. Almost all of them tried to establish a good relationship based on geomechanical parameters. Primary examples are the research done by Ubaldi (1999), Macini, Magagni, Da Dalt, and Valente (2007)."

Jan 1, 2015

"Liberation is a key requirement for efficient separation in mineral processing. As a consequence of this an understanding of the inherent textural features of an ore is no longer possible since during the process of liberation, texture is destroyed. Knowledge of key textural features, such as mineral grain size and distribution, prior to breakage processes provides the opportunity to understand the textural drivers for ore hardness. Modern characterisation methods, including automated SEM-based techniques, provide the possibility of measuring mineral characteristics at a range of scales. This paper discusses how textural features of two different ore types in a porphyry copper deposit can be measured and interpreted at a number of scales. Standard breakage tests conducted on the ores indicate that one of the ores can be characterised as hard and the other as soft. The impact of mineral grain size and the presence and scale of vein type structures in the two ores have been used to determine the extent to which these features influence ore hardness.INTRODUCTIONIn order to effectively convert ore into metal, knowledge of both the processing stages and the characteristics of the ore are essential. Prior to the advent of technologies that enabled the fundamental understanding of the sub-process at each stage of processing and the measurement of appropriate ore properties the most effective way to understand how an ore would respond to a process was to put it through that process, for example the way to determine how an ore would break was to first break it. Existing comminution models seek to predict the size distribution of rock fragments as the result of applied energy based on knowledge of the rock strength. It is common for these models to consider the rock as homogeneous and despite providing important data for the design and optimisation of industrial comminution circuits these models are only applicable within a narrow range of operation. In order for reliable predictive models to be developed that account for the inherent ore characteristics, a step change is required in the type of measurements that are carried out to characterise an ore and the type of data that is extracted and used as model inputs."

Jan 1, 2016

By E. Quaquero

This article reports on the current state of an ongoing research project which is aimed at implementing intelligent models for hardly predictable hazard scenarios identification in construction sites. As past evidences showed that no programmatic action can deal with the unpredictable nature of many risk dynamics, we tried to survey on how the current approach for safety management in the construction industry could be improved. In our previous research the use of Bayesian networks elicited from subjective knowledge were preliminarily tested. Those networks might be meant as a reliable knowledge map about accident dynamics and they showed that a relevant ratio of occurrences fall in ?hardly predictable hazards? class, which cannot be warded off by programmatic safety measures. This paper reports the second outcome of our research project, which focused on the development of first elementary fragments, regarding the occurrence of a possible ?hardly predictable scenario?. Instead of experts? contributions (who, over their carrier, seldom incurred in accidents), we used ?legal cases? as an accurate source of information. They suggested which categories of ?hidden hazard scenarios? are more likely to happen. We found that the most frequent hidden hazard scenarios are linked to operator?s negligence and abnormal behavior, e.g. irregular removal of scaffolding?s components, unprotected openings, improper use of PPE, etc. Every pattern determined by legal cases has been formalized by a fragment (i.e. elementary network) of the overall Bayesian network. Finally, all the elementary networks were integrated into a comprehensive intelligent tool for realtime hardly predictable hazards prevention. The final setup, asked for interfacing these intelligent models to a low-level sensor network and used to feed them with inputs about the current state of the context, is discussed too.

Aug 1, 2013

By Jerry Gagnon, Matt Burr, Timothy Ellis, Abbas Mirza, Larry Webb

"The mechanical properties of RSR anode alloys (lead-calcium-tin, 009+ and lead-strontium-tin) were investigated as a function of time with an objective of developing lead anodes for use in high temperature electrolytic processes such as in copper liberator cells and in cobalt and nickel electrowinning. At a temperature of 70 oC, the mechanical properties of rolled RSR lead-calcium-tin (PbCaSn) alloy currently used in copper electrowinning decreased gradually while the mechanical properties of rolled RSR lead-strontium-tin (PbSrSn) decreased relatively quickly and stabilized at low strength levels. Cast PbSrSn started off as the weakest alloy but its properties remained stable with time. Rolled RSR 009+ anode alloy showed improvement in ageing properties over the other alloys tested. However, its mechanical properties did not stabilize in the study timeframe of 284 days. Further investigations are planned to study the effect of alloying elements on mechanical properties of RSR 009+ anode alloy over several years as a function of time at 70 oC. The mechanical properties will be evaluated to determine the time at which they stabilize. Comparative plant trials with rolled RSR PbCaSn and RSR 009+ will also be performed in copper liberator cells and in cobalt and nickel electrowinning tankhouses to determine their mechanical and electrochemical performance at temperatures of 65-75 oC.INTRODUCTIONLead-based alloys are the primary anodes used in the electrowinning of copper, zinc, nickel, cobalt and manganese from sulfate-based aqueous systems. Lead anode technology has evolved over the years migrating from pure lead and lead-antimonial alloys to the present day PbCaSn alloys for copper and PbAg and PbCaAg alloys for zinc electrowinning (Prengaman, Ellis and Mirza, 2010). It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new lead anode alloys and production processes for lead anodes to be used in copper electrowinning, the industry still has some unresolved issues. These relate to the necessity of having higher mechanical properties especially for the lead anodes in liberator cells in copper electrorefining and for cobalt and nickel electrowinning as these tankhouses operate at temperatures of 65-75 oC compared to 40-45 oC in case of copper electrowinning."

Jan 1, 2016