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By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

Recycling has become an important part of the lithium-ion battery (LIB) life cycle due to the growing demand for energy storage in applications like electric vehicles and renewable energy. Recycling spent LIBs provides a secondary source for strategically scarce metals, like lithium and cobalt, helping to reduce the environmental impact of LIBs. Organic acids have been proven to be effective lixiviants with the benefit of reduced environmental impacts, amongst which citric acid has shown to exhibit similar extraction performance when compared to mineral acids. Leaching LCO and NMC batteries with 1.5M citric acid and 2 vol.% H2O2 at 95°C, 20 g/L for 20 minutes achieved 93% Al, 90% Co, 96% Li, 94% Mn and 94% Ni dissolution. The strong chelating property of citric acid affects the separation of the metals, providing unique extraction opportunities. The first extraction uses 12 vol.% D2EHPA at a pH of 2.5 and O/A ratio of 2 to separate 96.4% Mn and 100% Al from the PLS in two counter-current stages. Stripping the loaded organic with 1.25M citric acid at an A/O ratio of 3 allows for up to 91% stripping of the manganese in a single stage. The second extraction then separates 96.5% Li from the PLS in three counter-current stages using 20 vol.% D2EHPA at a pH 5.5 and O/A ratio of 5. The raffinate remaining after the second separation contains 48.4 wt.% Co and 50.3 wt.% Ni. Keywords: Hydrometallurgy, lithium-ion batteries, metal recycling, citric acid, solvent extraction

Jan 1, 2020

By T. S. Kagogo

The factors affecting haul truck tyre performance and the effectiveness of the management system at Rossing Uranium Mine were investigated with the aim of increasing tyre performance in terms of running hours until failure. The main objectives were to identify the types of tyre failure, their causes and cost implications, and evaluate the effectiveness of the management system. A site severity survey, weight study, and TKPH studies were conducted to determine the pit conditions, and an analysis of failed tyres carried out. The results showed that tyre performance at the mine has declined from 2009 to date, and the increase in lost value amounted to R5.7 million in 2012 alone. The main cause of tyre failure is loose rocks in the pit. The present management system in the load and haul department is not effective enough due to operational constraints it is facing.

Jan 1, 2014

By Daniel W. Kappes, Pierre F. X. Mousset-Jones

"In this paper a discussion is presented of a program designed to produce a 40-day production forecast for an underground stoping system.The program is intended to be a tool for the operations department in an underground mine, and is designed to utilize data readily available from production reports. Brevity of data input, ability to revise slope conditions easily and the accuracy of starting stope status are stressed. Applicability of the program to a wide variety of sloping methods makes the program potentially useful in a large number of mines.The general functions of the program subroutines, and input and output lists are discussed. An example is also given of a stope in operation for a three-day period, which shows how the program can handle production irregularities as they arise."

Jan 1, 2014

By L. E. Salinas-Farran, S. J. Neethling

Key variables in heap leaching include permeability, mechanical stability and mass transport. All of these properties can be manipulated by agglomerating and curing the ore before stacking it into heaps. The chemical and structural evolution of the agglomerates during curing is key to improving agglomerate properties and, ultimately, heap performance. It is possible to image the internal structure of agglomerates using SEM/EDX (e.g. QEMSCAN or MLA), although these methods are destructive and do not represent the 3D structure of the agglomerates. A non-destructive alternative is to image the agglomerates using X-ray Microtomography (XMT). Not only does this provide 3D information, it also allows the same samples to be repeatedly scanned, allowing the time evolution of the agglomerate structure and chemical composition to be tracked. In this paper we compared the behaviour of ores agglomerated using a combination of sulphuric acid and ferric sulphate with ones in which chloride ions are added to the recipe, since chloride leaching is gaining in popularity as a chemical alternative to bioleaching for sulphide ores. We tracked the curing process beyond the typical time scales to see the impact that this has on both the agglomerate structure and the subsequent leaching behaviour. Keywords: Heap leaching, curing extent impact, leaching kinetics, ferric-chloride leaching

Jan 1, 2020

By M. C. van Eeden, R. Vermeulen, K. B. Le Bron

This paper presents the lessons learnt during the transition from an open pit method to a sub-level open stoping method at the Koidu Limited kimberlite pipe. These learnings may assist other mines with planning, both from a practical implementation perspective (layout, charging up challenges), and a method for estimating potential dilution and stability challenges associated with the interaction between the surface and underground excavations. Predictive geotechnical stability modelling was successfully applied to highlight potential failure zones, which allowed modification and enhancement of the mining layouts and quantification of the potential dilution of the kimberlite from indicative instabilities.

Sep 1, 2025

By A. Koning

Pressure hydrometallurgy operations require vessels to be lined with an impermeable membrane for corrosion protection and one or more courses of refractory or ceramic brick. Examples of unit operations that utilize composite lining systems include pressure oxidation autoclaves, sulphide precipitation autoclaves, chloride leach reactors, flash vessels, cyclone separators, and direct contact condensers (heater vessels and quench vessels). The refractory lining must satisfy multiple requirements: it must thermally insulate the membrane from process fluid, be structurally stable, provide erosion resistance, be chemically compatible with process fluid, and provide an economic service life. New hydrometallurgical processes are pushing the pressure, and temperature with each new generation of plants. A fundamental understanding of all factors affecting the mechanical stability of the lining system is essential as lining designs move further away from the industry?s experience base. The method of designing a refractory lined vessel is examined taking into account the impact of irreversible chemical swell, operating factors, design factors, and installation factors. The effect of geometry and incorporating additional degrees of freedom to the analysis is explored using two-dimensional and three-dimensional finite element analysis (FEA). The effect of these additional degrees of freedom on the results of the one-dimensional model are discussed. Keywords refractory lining design,autoclave, finite element analysis.

Aug 1, 2013

Limestone formations in the United States can be subject to relatively high horizontal stresses due to the existence of tectonic loading of the limestone strata. Underground limestone mines use the room-and-pillar method, in which 12- to 18-m-wide rooms are typically excavated. The stability of these excavations can be compromised by the horizontal stress, resulting in a rockfall hazard. Rockfalls are the cause of 15% of all reportable injuries in underground limestone mines. Horizontal stress related damage can occur in the form of guttering along one or more sides of an excavation, roof beam buckling or oval shaped roof falls, with the long axis perpendicular to the major horizontal stress. Numerical analyses show that the pillar layout and orientation of the mine workings have an effect on the horizontal stress distribution within the roof. The effects of high horizontal stresses can be mitigated by orientating the heading development direction parallel to the maximum horizontal stress, reducing the number of cross-cuts and offsetting the cross-cuts to limit the potential lateral extent of horizontal stress related roof falls. The modeling approach described in this paper can be used as a tool to evaluate potential roof failure and optimize the stability of room and pillar layouts.

Jan 1, 2008

By L. C. Stilwell

The paper will attempt to identify the threats, however obscure, that could confront the South African platinum industry. South Africa has the largest reserves of platinum group metals in the world, and is the largest producer of those metals. This situation is no different from that which existed in the gold sector fifty years ago. Since then South Africa?s share of world gold production has dwindled, and the gold mining industry has lost its dominance. Unlike gold, platinum has widespread use as an industrial commodity. Its investment value is a minor portion of its total value. It is therefore subject to different market forces. The sheer magnitude of the industry in South Africa obscures the fact that it is a wasting industry, and that South Africa exports almost all its production as a refined metal in the form of autocatalyst. Since Hotelling published his seminal work The economics of non-renewable resource in 1931,the science of mineral economics has developed exponentially. The paper will present a background of mineral economic theory and compare to this the development of the South African platinum industry. Of particular concern to a mineral exporting country is the question of mineral rent?its definition and employment. This will be the mail theme of the paper.

Jan 1, 2006

A knowledge of the steady-state mass and energy requirements of a particular process is essential to a determination of the economic feasibility of that process. A predictive simulation technique can be of great value in this respect. A versatile computer program based on a fundamental thermodynamic approach has been developed for the prediction of process requirements. The equilibrium composition of a multiphase system is determined by the technique of free energy minimization. Energy-balance calculations are performed using the appropriate thermodynamic data for the chemical species present in the composite materials used. All models for the process units under consideration are written in modular form, the output being calculated from the input and the specified operating conditions. The computer program is written in such a way that it can be used easily by anyone familiar with the processes involved, even though he may have no previous experience with a program of this type. The program is structured so as to facilitate the varying of one parameter without any alteration to the others, thus simplifying the investigation of the effects of any parameters considered to be important. The program has the advantage of being able to compare existing and new processes on the same basis, namely from the ores to the molten metal.

Jan 1, 1987

By Phil Morriss

During the last 12 months, Sandvik?s Technical Service Group has carried out nine Scoping and Pre-feasibility studies for the application of In-pit crushing and conveying (IPCC) for large mining companies; the majority in conjunction with the Snowden Consulting Group. During these studies several key and recurring drivers have been identified: 1. Mining schedule issues ? there are several issues which crop up repeatedly, including: ?the unnecessary curvature of pit walls, ?very high rates of vertical advance which are (created by schedule optimisers to minimise stripping at all times) which are at the limit of what can be realistically achieved (and which of course make it harder for IPCC to achieve any impact), and ?The allocation of material to semi-mobile systems to maximise the ability for IPCC to be an effective alternative. 2. IPCC productivity issues ? the key issues are the IPCC system operating hours achievable, and the system throughput (both instantaneous and the average). 3. IPCC Risk issues ? there are perceptions about the risks associated with the use of IPCC which are a mix of reality and fiction, but which nonetheless create negativity towards the use of IPCC. In this paper, the authors wish to address specifically the factors affecting the IPCC productivity.

Jan 1, 2008

By R. Tinsley

Project-finance risk assessment is mature and approached systematically. Mining industry due diligence remains fragmented with specialists addressing different aspects of the project such as reserves/JORC, environmental impact, commodity market, even financial analysis/ modelling. Each professional has a natural tendency to believe that the risk factors they have examined are the key ones necessary to be reviewed, as if their review will stand in isolation from others in the way a project materialises. By first laying out the project risk categories and risk matrices, this paper examines the due diligence process with a keen eye to the risk assessment and overlap/interaction. Some cross fertilisation of due diligence techniques from other industry sectors is placed into the mining context. Six case studies are then presented with regards to due diligence features in each project's feasibility review or financial information/ offering memorandum. A power case first shows the differences between the due diligence expectations of banks versus bond financings. Then some Australian and Indonesian mining development cases are analysed to see the due diligence learning points. Some of these were project/due diligence failures. The conclusion focuses on the value of a systematic risk assessment for project evaluation, all from the project-finance perspective.

Jan 1, 2007

By H. W. Read

The South African platinum industry finds itself in the midst of a rapidly evolving society that is no longer characterized by the apparent stability of the previous decades. The features of this society include increasing global competition, rapid technological innovation, a declining skills pool, major political transformation, a more challenging working environment as the mines reach deeper into the earth?s crust and a greater concern for human welfare. It is therefore axiomatic that new ways will have to be found to engage the all-pervasive change in the mining environment. Although in general terms project management is a universal endeavour for managing change, it takes place in a specific socio-techno-economic environment and geographical setting that gives it a particular context. The argument of this paper explores, analyses and synthesizes the impact of these changes on the emerging project management methodology. In essence, the management of change will inevitably contribute to the emergence of new dilemmas, issues and challenges. The change management process and procedures will also be affected by this change and in response, drive internal change of its own structures and organization. And, therefore, a new paradigm of project management will become apparent. A new project management model will then be proposed to the industry.

Jan 1, 2006

By R. Ciccu

This paper examine the optimization of a beneficiation plant for recovering marketable barites from crude ores of different characteristics. The plant, part of a mining complex in Sardinia, consists of a jig section integrated with a flotation line. The problem has been studied using a suitable model of the process, based upon experimental and field data pertaining to both the characteristics of the feed material and the performance of machinery. Data have been automatically processed with the aid of a computer to find the optimum setting of each section, in order to maximize profit for each kind of ore separately fed to the plant. Moreover, the advantages of blending the various concentrates - not all of them individually marketable - are also demonstrated. The overall economic result can be improved provided suitable proportions of each kind of ore are fed to the plant. Such information is fundamental for the long-term planning of exploitation of available reserves, and provides guidelines for further prospecting. The paper illustrates the washability characteristics of the ore's and describes in detail the model adopted. The results of data processing are then presented in the form of computer graphs and discussed. Finally, conclusions are drawn regarding the advantages of resorting to Operations Research as an aid to management.

Jan 1, 1987

By SAIMM SAIMM

To the members of The South African Institute of Mining and Metallurgy We have audited the annual financial statements of The South African Institute of Mining and Metallurgy set out on pages 575 to 586 for the year ended 30 June 2005. These financial statements are the responsibility of the Institute?s Council. Our responsibility is to express an opinion on these financial statements based on our audit. Scope We have conducted our audit in accordance with International Standards on Auditing. Those standards require that we plan and perform the audit to obtain reasonable assurance about whether the financial statements are free of material misstatement. An audit includes: examining, on a test basis, evidence supporting the amounts and disclosures in the financial statements, assessing the accounting principles used and significant estimates made by management, and evaluating the overall financial statement presentation. We believe that our audit provides a reasonable basis for our opinion. Audit opinion In our opinion, the financial statements fairly present, in all material respects, the financial position of the Institute at 30 June 2005 and the results of its operations and cash flows for the year then ended in accordance with South African Statements of Generally Accepted Accounting Practice.

Jan 1, 2005

By D. J. Mourant

Day-to-day operations on the Broken Hill mine of the Black Mountain Mineral Development (BMMD) Company require a detailed knowledge of the distribution of the ore minerals within the orebody. The data are acquired by systematic underground diamond drilling of the orebody and subsequent geological and analytical borehole logging. These data are then captured onto a database, available for further analysis. Before mining commences in a mining block, copper, lead, zinc, silver and bismuth assay values, and the specific gravity of each sample, are extracted from the database. 3-dimensional variogram and kriging calculations are performed for each geological zone; for all the metals of interest. A computer representation of the mining block in the form of an ore model is then built using these kriged data. From these ore models information is extracted as required by the Geology Department on the mine, and used in numerous operations. These include: daily grade control to supply optimum feed grades to the treatment plant; the compilation of short, medium and long term production schedules; orebody outline definitions for the detailed planning of mining operations; ore resource calculations. The system has been modified and updated since its inception and provides timely information in a production environment.

Jan 1, 1987

By R. V. Ramani, R. Stefanko

"The favorable mining conditions in the United States of America that resulted in the development of the highly productive room and pillar systems are largely disappearing. Increasing mechanization, poorer natural conditions, and greater concern for health, safety and environment gave impetus to the enactment of the Federal Coal Mine Health and Safety Act of 1969. These regulations prescribe more stringent requirements in face ventilation and mine air distribution, necessitating significant changes in existing ventilation systems. Stringent mandatory standards were applied to respirable dust control for the first time, and simultaneous control of both gas and dust has affected the face as well as primary distribution, most notably on haulage entries.The size and complexity of the present-day mining operations, and the need to evaluate various system changes in a limited time, call for scientific methods in mine planning. In this paper, the authors trace the previous applications of computers to mine ventilation planning and discuss the results of their work in applying a ventilation simulator developed at Penn State. The paper includes an analysis of current trends and suggestions for future research and development."

Jan 1, 2014

Alluvial diamond deposits covered with a thick overburden cannot be explored effectively and mined profitably with the available conventional techniques. A novel directional drilling technique has been developed and site trials have been conducted at the De Beers Namaqualand Mines situated at the western coast of South Africa. This paper describes the technique developed as well as the results of the site trials. The main task of the project is to develop a tool and a supporting system to achieve a remote exploration and ore extraction method for inaccessible alluvial diamond deposits. The project involves the acquisition of a system, commissioning on-site and evaluating the information obtained during assessment. The project consists of the design -of certain tools and instrumentation for the system, investigations and desktop studies as well as development of the system's logistics. The operating philosophy of the system is based on the keyhole surgery principle. In this study a pilot hole was drilled first, starting from the surface with an inclination to reach deeply seated diamondiferous gravel layers, followed by drilling into a more or less horizontal gravel layer for a certain length and finally pointing-upwards reaching ground surface at a predetermined exit point. The pilot drill bit was then replaced with a larger diameter reamer/mining tool and an HDPE tail pipe was attached behind the reamer. The drill string was retracted back to enlarge the guide hole and flush the excavated ore to the surface through the tail pipe. The material flow in between the sections of the system was' carefully measured to assess and record the gravel recovery rates. Several horizontal holes were drilled at preplanned drill paths to reach and follow the ore layer and the Ore extraction was achieved by means of a reamer/mining tool. Principles of the concept have been proven viable in this investigation.

Jan 1, 2010

By A. Singh, R. R. Maclachlan

SYNOPSIS A back-analysis procedure based upon 35 mm photography was developed on a laboratory scale for the pur¬pose of determining the percentage of oversize particles known to be present in heaps of fragmented rock. Eight simple blends of crushed stone containing varying percentages of oversize on a 1:40 modelled scale were examined. Simulated test conditions for the following were subjected to the photographic study: (1) a bench heap, (2) the surface exposure of a partially excavated heap, (3) a gravity-sorted surface as occurs on an apron dump, and (4) four quadrant views of an incrementally built conical heap of rock fragments. The best back-analysis determinations were obtained from (4), the cone, over all eight blends of fragments. The mean error was within -0,16 per cent of the true value, with a range of ± 1,872. This was for oversize contents of 5 to 20 per cent where a minimum 25 per cent of the photograph area was processed by digitizer. The worst results were from the apron dump at - 1,462 per cent for a mean error of ± 4,174 per cent. The intermediate results were from the undisturbed bench at -0,186 per cent with a mean error of ±2,862 per cent.

Jan 1, 1989

1. Book reviews Mill Operators' Conference. Parkville (Australia), Australasian Institute of Mining and Metallurgy, 1982. 425 pp. Reviewer: B. K. Loveday Off highway truck haulage. Newman Combined Group, the Australian Institute of Mining and Metallurgy and the Institute of Engineers in Australia. Sep. 1982. Reviewer: B. J. Vorster Environmental engineering in South African mines.Johannesburg, Mine Ventilation Society of South Africa, 1982. 974 pp. Reviewer: A. N. Brown Underground Operators Conference. West Coast Tasmania Branch. Australasian Institute of Mining and Metallurgy. Reviewer: D. R. Aspeling 2. New publications Electric steelimaking in the eighties: challenges and opportunities. Rotterdam, Balkema, 1982. 362 pp. $50.00 or £33. Tungsten: a review, by P. M. Harris and D. S. C. Humphreys. London, Institution of Mining and Metallurgy (Occasional Paper 2), 1983. Members: £3, nonmembers £6. The platinum industry - prospects in recovery. London, Shearson{American Express Ltd (St. Alphage House, Fore Street, London EC2Y 5DA), 1983. £75. The best of E&MJ mining and processing idea book' New York, Engineering and Mining Journal, 1983. 128 pp. Free with subscription to Engineering and Mining Journal. Mining 1983. Harlow (U.K.), Longman Group Limited, 1983. 500 pp. £39.50. Ooncise guide to world coalfields. London, World Coal Resources and Reserves Data Bank Service (14/15 Lower Grosvenor Place, London SW1W OEX), 1983. 380 pp. £45. 3. Canadian publications Asbestos, by G. O. Vagt, 9 pp. Ooal and Coke, by J. A. Aylsworth, 16 pp. Orude oil and natural gas, by R. L. Thomas, 12 pp. Phosphate, by G. S. Barry, 8 pp. Rhenium, by S. A. Hamilton, 3 pp. 4. Mintek reports Report 2102D The recovery of magnesite from dump fines from the Strathmore Mine. (First issued Feb. 1981.) Report 2106D The evaluation of drill cores and a bulk sample from a deposit of andalusite near Thabazimbi. (First issued Mar., 1981.) Report 2108D Evaluation of a grinding aid in batch grinding, classification, and gravity concentration. (First issued Jul. 1981.) Report 2109D The evaluation of an andalusite deposit from Kleinfontein, Groot Marico. (First issued Apr. 1981.) Report M7D The beneficiation of chromite ore from the Ma-l seam near Marikana. (First issued Nov. 1981.) Report M62 A preliminary investigation into the extraction of zinc by direct oxidative leaching of high-manganese sphalerite. Report M76 A mineralogical investigation of a refractory gold ore, and of a sulphide concentrate and calcined tailing from that ore. Report M85 List of unrestricted Mintek publications issued from 1966 to 1982. Report M97 Reduction in metal consumption by the use of alternating lines of higher and lower lifter bars in a rod mill. Report M98 Multivariable control and optimization of the operation of a milling circuit at East Driefontein Gold Mine. Report M101 The potentiality of heat-treated balls in the grinding of gold ores. X-ray diffraction The Southern Transvaal Section of the South Mrican Chemical Institute is to present a mini-course on 'X-ray Diffraction: Theory and Application' in Johannesburg on 18th and 19th October, 1983.

Jan 1, 1983

By C. Chibwe, M. Tadie

Copper electrowinning models are useful for prediction of process performance, optimisation and improved understanding of complex phenomena such as current distribution without the expense of physical experiments. Recently, finite element models such as those generated in COMSOL Multiphysics have been developed for the electrowinning process. The predictive capacity of these models is improved by incorporating physical and chemical phenomena. Since physicochemical properties of electrolytes can have a significant effect on the quality of copper produced, this work was conducted to investigate the effect of such properties on electrodeposition at varying levels of copper, sulphuric acid concentration, iron concentration and temperature, in the presence of a smoothing agent. Tests were conducted at conditions similar to those for industrial copper electrowinning. Mathematical correlations were developed for the following properties; density, conductivity and diffusivity which were compared to existing models in literature and thereafter applied in a COMSOL generated model. The model predicts, current distribution at the cathode surface, deposit thickness (morphology), concentration of species within the cell and current efficiency. Current distribution output shows the impact of several phenomena on the deposit generated including the relationship between increasing copper concentration and current density and lack of influence of acid concentration on this property. Keywords: Electrowinning, physicochemical properties, electrolyte composition, modelling

Jan 1, 2020