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The Mammoth Copper Deposit consists of three distinct orebodies adjacent to the Mammoth Fault. This fault is arcuate, changing from a normal tension fault to a shear strike fault just to the north of the mine. Movement on the fault was probably contemporaneous with deposit- ion of the adjacent sediments. In the upper levels the No. 1 orebody occurs within a brecciated zone in the footwall of the fault, but at depth the No. 2 and 3 orebodies are stratabound by two brecciated lithologic horiz- ons. The host rocks are impure sandstones, arkoces and quartzites, which in the mine area are near the top of the Lower Proterozoic Myally Beds. Overlying these beds is a conglom- erate siltstone sequence which has been assumed to be the base of the Gunpowder Creek Formation. North and south of the mine the conglomerate rests on an erosional unconformity representing a major time break, but in the mine the uncon- formity and conditions of deposition of the conglomerate are obscure. Some mineralization is contained within the conglomerates. The sulphides present are chalcocite, bornite, chalcopyrite and pyrite. Chalcocite is dominant in the upper levels but could be en- riched by supergene processes. At depth, bornite becomes the dominant copper sulphide with lesser amounts of chalcopyrite, pyrite and primary chalcocite. Throughout the orebody minor digenite and covellite occur and arsenic is a minor constituent bound up with the pyrite. The bulk of the sulphides occur in stringers, fractures and breccia interstices but finer grained primary bedded sulphides can be observed. The genesis is probably a complex process in- volving active tectonic movements extending from deposition to post lithification giving numerous phases of brecciation and redistribut- Ion.

Jan 1, 1974

The longwall system with caving is the most common mining system in Polish Collieries and the extraction is carried out simultaneously on several levels and in different seams. The extent and diversity of the methane hazard occurring is strictly connected to the specific geological and gas conditions as well as to the applied mining methods. Taking these factors into consideration the following methane drainage methods are applied as additional means of combatting the methane hazard in Polish gassy coal mines: 1. predrainage by means of boreholes drilled from the surface, 2. predrainage from stone drivages and devel- opment workings, 3. degasification of coal extraction workings, and 4. degasification of sealed-off areas/old goaves. Predrainage gave satisfactory results when holes were drilled from the surface or from underground workings, but only to depths to 300 m. It was necessary to adapt methane drain- age methods to the geological and mining con- ditions as gassiness increased with depth. The results of methane capture, both pre- drainage and post drainage were obtained by investigating several gassy mines.

Jan 1, 1982

By D L. Richardson, B Tiedt, C D. Morgan

Following residentsÆ concerns that the ongoing operations of Collinsville Coal (CCP) mine may be resulting in the release of contaminants, including products of acid mine drainage (AMD), into downstream environments, the Queensland Environmental Protection Agency (QEPA) issued CCP with a Notice to Conduct or Commission an Environmental Evaluation at Three Mile Creek. A key objective of the Environmental Evaluation was to assess the extent and magnitude of impacts to aquatic communities and their habitats. A multidisciplinary investigation examined a suite of physical, chemical and biological indicators to meet this objective. The study also aimed to identify contaminants of concern and the location of potential pollutant sources. Potential indicators of AMD, including elevated dissolved solids concentrations and low pH, were evident within the mine lease. However, significant differences in concentration of these indicators upstream and downstream of the confluence with Three Mile Creek were not observed. Although only proxy indicators of AMD contamination, these results suggest that the extent of impacts downstream is minimal. For the purpose of this study, physio-chemical indicators were selected on the basis of those best likely to provide an understanding of the likelihood of contamination, within the constraints of readily available long-term monitoring data. Ecosystem health indicators were adopted to supplement the existing data set and provide a more æroundedÆ perspective of water quality attributes within the system, generally unattainable by standard physio-chemical assessments. In contrast to AMD products, sediments were considered more likely to have a widespread impact on aquatic ecosystems. Waterways throughout the study region, including those unaffected by mining, have been affected by broad-scale sedimentation and were typically highly turbid. Due to the many diffuse sources of sediment potentially liberated within the catchment, the contribution of the mine compared to other land uses on total sediment loads entering streams is difficult to determine. This is clearly a major management issue for mines throughout the Bowen Basin. Streams of the central Queensland region display enormous variability in water flows and physio-chemical characteristics over a range of spatial and temporal scales. This variability presents major difficulties in distinguishing anthropogenic impacts from natural variability (noise). Despite this variability, impact monitoring by mines in the central Queensland district has tended to focus almost entirely upon physio-chemical indicators. The results of the present study indicate that a multiple indicator approach to environmental assessment is more useful for separating mine related impacts from natural ænoiseÆ and impacts from other land uses. In the absence of such information, by adopting the precautionary principle of Ecologically Sustainable Development (ESD), there is potential for an environmental impact to be incorrectly attributed to mining when other activities in the catchment may be contributing to changes in stream æhealthÆ.

Jan 1, 2003

By Wang S

Fragmentation is the basic concern in rock blasting and serves as the main measure of blasting effectiveness. A good estimation of fragment size distribution before blasting is very useful and helpful for selecting the proper equipment for loading, transporting, and crushing rocks. A fragmentation model is presented that is based on a hole by hole analysis and correlates the rock properties, burden, spacing, and explosive column with the blasted volume and fragmentation obtained. The drill bench is divided into three separate areas corresponding to different breakage mechanisms. They are: 1) a main breakage or casting area, 2) a secondary breaking area, and 3) an overbreak area. The boundary of the main breakage area is found from the magnitudes of strains in the stress waves and the tensile strength of the rock. The secondary breaking area is determined by stress wave reflections at discontinuities and interactions between colliding stress waves from adjacent boreholes. The overbreak area is that beyond the main breakage area "where the reflected tensile waves no longer break the rock. This analysis is applied on a hole by hole basis to locate the breaking points. Then connecting the breaking points on each side of a borehole forms the triangle of the main breakage area. This is repeated for the next hole and the remaining area is the secondary breakage area. After the angle and area for each hole are found the Kuz-Ram model is used to predict the fragmentation size distribution for each hole. Then summing up the size distribution for each hole gives the total fragmentation distribution. This analysis has been successfully applied to field tests performed in a limestone bench where the entire spoil pile was screened to determine the fragment size distribution. Knowing the explosive and rock properties the breaking area was found for each hole, the strain and stress values, the breaking point, and angle of breakage (104 degrees). The fragmentation size distribution was then calculated and compared to the field data with excellent agreement.

Jan 1, 1990

By Jagger N. D

Lead residue from the Zinc Leach Plant at Pasminco's Port Pirie Lead Smelter was previously filtered on a vacuum drum filter and further dried in a gas fired rotary kiln prior to stockpiling and transport to the Sinter Plant. This process involved several materials handling stages, recycled significant amounts of zinc and often resulted in poor environmental conditions. These problems have been overcome by pumping the thickened leach residue approximately 450m to the Sinter Plant where it is filtered in a Larox Automatic Pressure Filter. The filter cake is discharged onto a conveyor belt, held in a storage hopper and then fed directly to the main sinter plant feed stream. Filtrate is returned to the process for additional zinc recovery. The laboratory and pilot plant filtration results are briefly discussed and compared with the operating plant data. The filter installation and ancillaries are described in detail along with the commissioning, operating and maintenance experience over the past 4 years. This installation has overcome the environmental and materials handling problems and resulted in annual savings of approximately $1 million.

Jan 1, 1989

By Lockhart D. A, Gleeson P, Lang S. C

The Glenrock Group forms the uppermost part of the Early Devonian to Early Carboniferous Burdekin Basin sequence in the Townsville hinterland, north Queensland. As redefined, three formations make up the Glenrock Group. The Percy Creek Volcanics (base), the dominantly epiclastic Mount Douglas Formation, and the Horse Pocket Volcanics (top). The Ellenvale beds unconformably overlie the Mount Douglas Formation and Percy Creek Volcanics and have been excluded from the Glenrock Group as defined by Wyatt and Jell (1980). Three facies associations are recognised in the Mount Douglas Formation: Alluvial Plain facies, Alluvial Fan facies and Lacustrine facies.Deposition of the Glenrock Group, began with the eruption of massive basalt and basaltic andesite lavas, probably in a volcanic arc setting. With time, the volcanism evolved to become more dacitic to rhyolitic in composition. Waning of the volcanic activity appeared to coincide with uplift of source areas (probably to the west). Deposition on an alluvial plain during this waning volcanic cycle, gave way to alluvial fans at the margins of the uplifted terrain. As the uplift ceased and the system became more mature, the alluvial fans gave way to widespread lakes. Rhyolitic ignimbrite and airfall tuff, interbedded with the alluvial plain, alluvial fan and lacustrine facies, indicate that some volcanism continued, probably vented in the uplifted terrain to the west.

Jan 1, 1990

By M Logsdon, T R. Clark, T I. Mudder

Oxidation of pyrite and other metal sulfides is accelerated by the activity of acidophilic iron- and sulfur-oxidising microorganisms. The ideal biocide for controlling biocatalysed acid rock drainage (ARD) would be inexpensive, inhibitory toward sulfide-oxidising bacteria at low concentrations, relatively non-toxic toward non-target organisms, degradable in the environment outside the zone of application, stable and long-lived in the impacted environment, sufficiently mobile to penetrate into piles of waste rock or tailings, and effective regardless of the metal sulfides present. A potent agent for combating ARD that fits these criteria is the thiocyanate anion (SCN-). The objective of this study was to determine the effectiveness of thiocyanate in controlling or preventing ARD within several types of sulfidic waste rock and tailings. Results were evaluated within a context encompassing process water and solids management strategies employed at different precious and base metal mines. Sulfidic rock was treated with solutions of potassium thiocyanate and subjected to accelerated weathering tests in lab-scale humidity cells, trays, and columns. Certain tests also utilised solid phase copper thiocyanate (CuSCN) to evaluate a ærelease on demandÆ strategy. Leach solutions were analysed for parameters indicative of ARD including pH, redox potential, conductivity, acidity, sulfate, iron, and certain heavy metals. Two larger scale field tests were also initiated by personnel at separate mines using, in the first case, ore containing a pyritic component in large columns and, in the second case, waste rock containing base metal sulfides in lined pits. Humidity cell tests showed low concentrations of thiocyanate solution applied to pyritic waste rock could reduce ARD formation by 90 per cent or more compared to untreated controls, with the residual release of ARD components (eg sulfate, Fe, acidity) probably reflective of strictly chemical oxidation of the sulfides by molecular oxygen. Thiocyanate applied at a concentration of 22 mg/kg to waste rock from a base metal mining operation in large laboratory scale columns reduced acidity and sulfate release by 75 per cent to 80 per cent compared to untreated controls. This extent of reduction in ARD may not meet discharge water quality criteria, but has the potential to significantly reduce lime consumption and sludge production in a conventional neutralisation facility. The use of a solid-phase metal thiocyanate compound (CuSCN) at a dosage of 194 mg/kg pyritic ore resulted in the following per cent reductions in leach solution parameters in comparison to controls: sulfate (78 per cent), acidity (93 per cent), dissolved Fe (99.4 per cent), and dissolved arsenic (99.9 per cent). This compound has the further advantage of being relatively stable until needed, dissolving only in the presence of an acidic and oxidising ARD solution. If this line of investigation progresses favorably, it offers the possibility of an ARD prevention technique that may be applicable in some settings. Mine-site pilot scale tests with pyritic ore resulted in reductions in sulfate (56 per cent) and Fe, As (66 - 68 per cent). In sum, thiocyanate at relatively low concentrations dramatically reduced ARD from sulfidic rock in a simulated heap. The pilot test using waste rock containing base metal sulfides has begun only recently. A preliminary process design and cost estimate was made for fullscale application of thiocyanate to waste rock at a hypothetical gold mining operation producing 5000 tpd of ore and 10 000 tpd of sulfide containing waste rock. The combined capital and operating costs for the full-scale thiocyanate application facility were about $US 0.25/tonne of waste rock and $US 0.50/tonne of ore. Although thiocyanate is readily available commercially, it also occurs in process solutions associated with certain types of mining processes. Such solutions after selective treatment might be recycled to sulfidic waste rock or tailings, rather than being treated for thiocyanate degradation.

Jan 1, 2003

The mineral pulp as it passes through grinding-classification, flotation and solid-liquid separation is examined in the context of it being a particulate fluid. By focussing on the complex viscosity and yield stress of the fluid, new control strategies are discussed. The mineral-particulate fluid is dominatred by non-Newtonian rheology (ie shear thinning, shear thickening, shear yield stress and compressive yield strength). The control of this Theology is seen to be dependent on the fundamental practice-particle interaction forces and with adequate information, it is possible to use the complex shear properties to advantage. The advantages, in terms of final waste and concentrate management, to high weight per cent solids in the mineral particulate fluid, are explored and control strategies outlined.

Jan 1, 1993

By Kallioinen J

This paper discusses different possibilities to enhance coarse particle flotation using forth manipulation and improved flotation cell design. Experiments were carried out in laboratory, pilot and industrial scale ranging from 0.0015 to 100 m3/axle. During the work it could be shown that the conventional idea of one single flotation cell type for both fine, immediate and coarse flotation of coarse and fine particles need different impeller tip speeds and a different froth control objective for effective operation. For optimal operation for coarse feeds the tip speed must be reduced and the froth vertical velocity must be increased to compensate the respective drainage velocity and also the water film thickness must be taken care of. Turbulent eddies below the froth interface should be suppressed. The paper discusses the effects of different froth manipulation variables like froth vertical velocity and froth residence time to the recovery and selectivity. A function has been developed, between the residence time of the froth and the flotation cell's ability to produce an improved concentrate grade as a function of different operating and froth manipulation variables.

Jan 1, 1993

By M Skead, H Michael, R Chase, A Davidson

Ashanti Goldfields CompanyÆs (AshantiÆs) most recent development is the Geita Project in the Lake Victoria Goldfield of NW Tanzania. It comprises six distinct gold deposits within two mineralised trends: Nyankanga, Lone Cone, Geita Hill (Geita trend) and Matandani, Kukuluma and Area 3 West (Kukuluma trend). Between 1936 and 1966, the Geita area produced an estimated 5.5 M tonnes of ore from five underground deposits at an average recovered grade of 5.3 g/t. The discovery of Nyankanga was made by Ashanti in 1996 from RAB drilling of a +100 ppb Au anomaly in laterite soil above ferricrete cover. The Kukuluma trend was discovered by SAMAX Resources (taken over by Ashanti in 1998) between 1996 and 1997 from RC drilling of a +80 ppb Au laterite soil anomaly. Oxide facies banded iron formation (BIF) of the Upper Nyanzian System forms prominent topographic ridges and is the dominant host lithology for gold mineralisation. The ridges are flanked by felsic tuff units which lie stratigraphically above. Syn-genetic lamprophyre (vogesite) and post-genetic felsic dykes are also seen in the Geita trend. At Nyankanga a granodiorite-diorite suite has intruded as dykes and sills into BIF from a plug centred on a WNW fault and has produced wallrock alteration assemblages similar to those seen in Cu-porphyry systems (potassic, propylitic, etc) as well as sulphide and gold deposition. However, the main ore-grade mineralisation (as in the rest of the Geita trend) is controlled by low-to-medium angle structures dipping north-west and north with numerous splays in the hanging wall. High-grade shoots at Nyankanga plunge to the west and to the north-west, being lithologically and fault-controlled respectively. At Geita Hill the higher grade shoots are controlled by fold noses in BIF dipping to the north. Free gold occurs within fractures of sulphides. The deposits of Kukuluma and Matandani occur on an ancient (possibly Cretaceous) erosional plateau and are related to two WNW to NW trending shear zones, discordant to the local strike of the BIF sequence. Complete oxidation occurs up to 120 m depth and there is a strong supergene component to the gold distribution. Primary gold mineralisation is divisible into two distinct assemblages: arsenopyriteûpyrrhotiteûmagnetiteûchlorite associated with brecciated cherts and pyrite associated with shaley banded ironstones. Area 3W is most likely the fault-displaced extension of the same mineralised trend and comprises thin, intermittent zones of high-grade gold mineralisation occurring adjacent to a ridge in banded cherts and minor BIF. Current resources (measured, indicated and inferred) for the project are estimated at 89.24 Mt at an average grade of 4.17 g/t (11.97 Moz of contained gold) at a 1.0 g/t cut-off grade. Of this 9.83 Moz is within the Geita trend and 2.14 Moz is within the Kukuluma trend. A resource of 2.74 Moz is from an inferred resource at depth at Nyankanga where the viability of an underground operation is being studied. Proven and probable reserves are 49.77 Mt @ 3.46 g/t (5.54 Moz) based on a $325/oz gold price providing a mine life of ten years at an average production rate of 500 000 oz per year. Reserve estimation was carried out using mineable polygons to select resource blocks based on a series of mining and costs parameters. In addition key cost parameters were tested to provide sensitivities for pit optimisations and pathfinders for negotiations with suppliers and contractors. Construction began in March 1999 and first gold is expected to be poured in the second-quarter 2000.

Jan 1, 2000

By Xizhen J

Point load testing for irregular rock specimens was studied to determine the relationship between tensile and compressive strengths, drill penetration rate and other rotary drilling parameters. The DH-l type point load tester was developed and more than 2 000 irregular specimens of over 60 kinds of rock from 16 mines and quarries were tested. The effects of size, shape and number of samples on the point load strength index were investigated, using regression analysis. Experiments were carried out to investigate the relationship between point load strength index and uniaxial compressive strength on 29 kinds of rock. The relationship between these values and the drill penetration rate for rotary and percussion drills is discussed.

Jan 1, 1986

By Gao K, Wu C, Langley J. M, Waugh B, Farrell K

The dissolution of carbon from carbonaceous materials into molten iron is a key step in various ironmaking operations. For example, in new direct smelting processes, carbon in the form of coal is injected into the molten iron bath, which leads to the dissolution of carbon. In foundry operations, typical recarburizer materials can range from high purity graphite to chars. The dissolution performance of these" materials is critical to the operation and could dictate the efficiency and economics of the process.Dissolution kinetics has been studied by various investigators to explain the influence of melt conditions and carbon type (Sahajwalla et al, 1994; Shigeno, Tokuda, and Ohtani, 1985; Orsten and Oeters; 1988; Ganguly and Reid, 1992; Wright and Taylor, 1993). The influence of melt sulphur content on the dissolution kinetics has been characterised (Sahajwalla et al, 1994), with sulphur retarding the rate of carbon dissolution. The carbon dissolution from different sources is seen to vary significantly even under similar melt conditions. This observation has been explained by investigators on the basis of the varying ash content present in the carbonaceous materials. However, ash content alone cannot account for the variability in dissolution kinetics reported in other studies. One such study is presented below.In a recent study (Sahajwalla et al, 1994), pulverised carbonaceous materials were injected into the molten iron bath and the" dissolution kinetics was established. The dissolution of graphite and glassy carbon, which contain almost 100 per cent carbon, was seen to be significantly different when the molten iron contained sulphur. The influence of melt sulphur content was explained on the basis of different wetting behaviour observed.Importantly, the study showed that even pure carbon sources dissolved at significantly different rates. Hence, their performance could not be explained on the basis of ash content.The key difference between graphite and glassy carbon is in their atomic structure. Graphite is highly ordered whereas glassy carbon has relatively poor ordering in its atomic structure. This study showed that the atomic structure in carbonaceous materials can have a significant effect on their dissolution performance.The focus of the present investigation which stems from the past study described above (Sahajwalla et al, 1994), is to investigate the influence of atomic structure of carbonaceous materials on their dissolution into Fe-C-S melts.The specific objective of this study is to determine the relationship between dissolution kinetics and crystallographic character of carbon sources. In order to accomplish this goal, a range of different materials representing a spectrum of carbon sources have been chosen for the investigation. These materials include brown coal char, two types of Auscarb (A and B), and commercial graphite. Auscarb is prepared by calcining Auscoal at 1000°C. Auscoal is made from chemically cleaned Australian coals (Bowling, Chandler and Waugh, 1990). Part 1 of this paper details the dissolution performance of the materials studied, while Part 11 describes the X-ray diffraction study. The relationship between the atomic structural dimension and dissolution rate constant is discussed in light of the results obtained.

Jan 1, 1996

By Li YQ, Yoon RH

The photoresponse of natural mineral pyrite and galena electrodes has been studied in aqueous solutions on freshly fractured surfaces (some fractured in situ) using moderate overvoltages. When fractured in situ, the electrode potential of both minerals instantly drops several tenths of a volt. Pyrite exhibits a spontaneous anodic photocurrent at fracture, which indicates upward band bending (depletion layer) on the n-type electrodes. The negative surface charge responsible for the depletion layer is believed to arise from a surface state that is intrinsic to pyrite surfaces, possibly modified by hydroxide ion adsorption. The flat band potential, Vty, of pyrite is at approximately -1.0 V (SCE) at pH 9.2 but to reach V(b, pyrite has to be cathodically decomposed. In contrast, galena assumes the flat band potential at fracture. Subsequent polarisation of galena at potentials positive of Vth produces an anodic photocurrent (upward band bending) and polarisation negative of Vro a cathodic photocurrent. Most of the galena electrodes studied were degenerate n-type and at potentials negative of Vtb, no cathodic photocurrents are observed, indicating the bands cannot be bent downward, consistent with the Fermi level at the surface merging with the conduction band edge near Vn,. Several were close to intrinsic, with the photocurrent changing sign near Vn,.

Jan 1, 1993

By Peng S. S

Measurement of pressure distribution under the base plate of the Hemscheidt 2-leg 800-ton shield was performed underground for two shifts using 12 pressure cells installed in two rows, one each under each split base plate. Pressure distribution was uneven depending on contact condition. In general the highest base pressure occurred at 1/3 of the base plate contact length from the rear edge. The resultant was near vertical, and the pressure under the tail side split base plate was always higher than the head side. For comparison, pressure distribution on the canopy and under the base plate was also measured under controlled conditions at the USBM's Mine Simulator Testing Facilities in Pittsburgh, PA. A total of 45 tests were conducted under several simulated contact conditions. The results showed that the actual contact area is highly dependent on the compliance of the immediate roof and floor due to the sloped canopy tip and a base lifting device under the base tip. The loading distribution tends to change in magnitude and profile as the leg pressure increases. The base lifting device exaggerates the high toe loading on the base plate characteristics of this type of shield support.

Jan 1, 1992

The fragmentation of whole rock by blasting has an influence on the subsequent loading, hauling and crushing operations. However, no method of calculating the frag- mentation has yet been developed. This paper gives a method of calculating the fragmen- tation for the simplest form of blasting, i.e. cratering. Cratering consists of the detonation of a spherical charge of explosive in a blasthole breaking to one free surface. This paper gives a method of calculating the extent of the system of radial cracks generated by the explosive in the rock. This system of radial cracks is then used to calculate the fragment size distribution curve from blasting. The calculated curves are shown to be in good agreement with experiment.

Jan 1, 1977

By Moore A. J

Blasting in mines in an urban environment can be conducted safely and within regulatory vibration limits by careful attention to detail and the application of correct techniques. Factors affecting blast vibration are described using surface and underground mining examples. An understanding of these factors provides an essential base for effective planning and operational control. Techniques are described for assessing and predicting vibration levels and the presentation of data for planning purposes such as environmental impact statements for new projects and the protection of buffer zones around existing operations.

Jan 1, 1997

By Monette J. C, Nulty J. H

High temperatures and pressures are required to obtain acceptable stripping rates. Higher chemically induced stripping rates could reduce the need for higher temperatures which lead to cyanide losses. The higher rates could lead to lower carbon inventories and higher gold production. This paper reports laboratory and continuous test unit data which strongly suggest that the preceding can be achieved. New stripping agents demonstrate efficient stripping under conditions of cyanide depletion such as after carbon acid washing. Stripping times for gold and silver can be reduced by at least half compared to caustic cyanide through the use of these novel substances.

Jan 1, 1991

By Krouse RH, Aleinikoff JN, Nokleberg WJ, Church SE, Newkirk SR

A belt of volcanogenic massive sulfide (VMS) deposits and occurrences extends for over 150 km along the southern margin of the Yukon-Tanana terrane in the eastern Alaska Range. The VMS bodies occur mainly in the Jarvis Creek Glacier subterrane (JCGS), one of the highest structural/ stratigraphic levels of the Yukon-Tanana terrane. The JCGS consists of a VMS--bearing metavolcanic rock member and a metasedimentary rock member. The VMS deposits and enclosing rocks exhibit two periods of regional metamorphism.From northwest to southeast, the major VMS districts are the Bonnifield, Hayes Glacier, McGinnis Glacier, and Delta districts. The Bonnifield, Hayes and McGinnis Glacier district sulfide bodies consist of pyrrhotite and lesser amounts of pyrite, chalcopyrite, with or without arsenopyrite, sphalerite and galena. The larger, 800 km Delta district deposits and occurrences contain variable amounts of pyrite and pyrrhotite and lesser amounts of primarily chalcopyrite, galena, sphalerite, and arsenopyrite.The sulfide accumulations are interpreted as Kuroko-like deposits that formed along the submarine volcanic part of a Devonian, continental-margin igneous arc. U-Pb isotopic data from zircons from the metavolcanic rocks indicate an age of about 370 Ma (Devonian). 207Pb/204Pb ratios for sulfides from the districts are similar and indicate lead was in part derived from first cycle sediments eroded largely from Precambrian crystalline rocks. 207Pb/204Pb ratios from feldspars in Devonian metavolcanic rocks are similar to those in sulfides, and indicate incorporation of radiogenic Precambrian lead into the Devonian magmas. A Precambrian crystalline source for quartz in metasedimentary rocks is indicated by 2.3 Ga old zircons. Common-lead isotope studies of igneous phenocrysts in metaigneous rocks and sulfides in volcanogenic massive sulfide deposits indicate a unique isotopic signature. The data permit an exotic origin of the Yukon-Tanana terrane with respect to North America.

Jan 1, 1990

Tholeiitic metabasalts comprise at least five geochemically distinct mafic volcanic associations of Late Palaeozoic age within the Gympie Province, southeast Queensland. Geochemical features indicate that parental magmas of the various metavolcanic suites were generated in contrasting tectonic regimes, although each of the suites shows some affinities with eruptives from convergent plate margin settings.Basalts from the Highbury Volcanics of the Gympie Group are island arc tholeiites (IAT) formed during an immature stage of eruptive activity in an intra-oceanic arc. They are unique among the analysed metabasites in possessing high Zr/Nb (Zr/Nb - 30) and very high Ba/Nb, and as well as low Ti/V, Ti/Zr and Ti/Y. These features are explicable solely in terms of contributions from a depleted, convecting upper mantle source, and large ion lithophile element (LILE) enriched fluids ascending from subducted oceanic crust.

Jan 1, 1990

By Umetsu Y, Su Qing-quan

The electrical conductivity of electrolytes is very important in metal electrowinning and electrorefining processes as it has a very large influence on the energy consumption. There are few measurements of the electrical conductivity of zinc electrowinning electrolytes available. The electrical conductivity of zinc electrowinning electrolytes were measured over the following range of concentrations, 100 to 200 g/L H2SO4, 0 to 80 g/L Zn and 0 to 20 g/L Mg, at temperatures from 25 to 60 C. The specific conductivity of zinc electrowinning electrolytes may be expressed as a function of concentrations of sulphuric acid, zinc and magnesium and temperature by the following equation: k(S/cm) = 0.004 + 0.00115 t + 0.00282 [H2SO4] t - 0.00114 [M] t + 0.3442 [H2SO4] - 0.0451 [1-12SO4]2 - 0.1058 [M]ò[H2SO4] - 0.0224 (M] + 0.0286 [M] 2 where t is temperature (C), [H2S04](moI/L) is sulphuric acid concentration and [M](mol/L) is a sum of zinc and magnesium concentrations, ([Zn]+[Mg]). The specific conductivity of zinc electrolytes is a function of the concentrations of the hydrogen ion and free water molecule, which are calculated by taking into account the second ionisation constant of sulphuric acid and the stability- constants of zinc-sulphate and magnesium-sulphate complexes at 25 C.

Jan 1, 1993