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By E. A. Gulbransen, K. F. Andrew

Weight loss measurements were made using a sensitive microbalance operating in a high vacuum system. The Langmuir equation was used to Calculate the vapor pressures of the several metals and alloys. Aluminum lowered the vapor pressure of i9,on in a 5.4 Al-94.6 Fe alloy, and of iron and chromium in a 4.8 Al-21.5 Cr-73.7 Fe alloy. The influence of oxide films formed on the alloys on the effective vapor pressures of the alloys was also studied. These studies were used to aid in the inte9,pretation of the high temperature oxidation of alloys based on iron, chromium, and aluminum. RECENT studies on the oxidation of chromium1 and the heat resistant alloy 5 Al-22 Cr-73 Fe showed transitions in the rate of oxidation at 900o and 1050oC respectively. The transition for chromium occurred at a temperature where the rate of evaporation of chromium from oxide-free surfaces equalled the rate of chromium atoms reacting with oxygen. This paper presents new vapor pressure studies on iron, chromium, and the specially prepared alloys 5.4 Al-94.6 Fe, 21.9 Cr-78.1 Fe, and 4.8 Al-21.5 Cr-73.7 Fe. The ternary alloy is similar in basic composition to the patented heat-resistant commercial alloy known as Kanthal. The binary alloys were studied to show the individual effects of aluminum on the vapor pressure of iron and of iron on the vapor pressure of chromium. The purpose of the proposed studies was to test the influence of metal volatility on the oxidation behavior of heat-resistant alloys based on iron, chromium, and aluminum. Since oxide films formed on the metal may limit metal transfer to the surface, the influence of oxide films on metal volatility was also studied. LITERATURE A) Vapor Pressure. The vapor pressure of iron has been studied by Jones, Langmuir, and Mackay,' Dornte and Nrton. Edwards. Johnston. and Ditmar. and McCabe, Hudson, and Paton. Stull and SinkeT have calculated a heat of sublimation at 298° K of 99.83 kcalper g atom. The vapor pressure of chromium has been reported by Bauer and Brunner,' Speiser, Johnston, and Blakburn, Gulbransen and Andrew,'' Vintaikin,o McCabe, Hudson, and Paton, and Kubaschewski and Heymer.12 Good agreement was obtained except for the early work of Bauer and Brunner.' Stull and Sinke7 calculate a heat of sublimation at 298°K of 95.0 kcal per g atom. Vapor pressure measurements on aluminum have been made by Brewer and Searcy,13 Bauer and Brunner,aand Farkas.I4 Stull and Sinke,7 giving Brewer and Seary's' data the most weight, derive a heat of sublimation of 77.5 kcal per g atom at 298 oK. B) Method. Two methods15 are used for measuring the vapor pressure of metals: 1) The Langhuir free evaporation method, and 2) the Knudsen effusion method, In the Langmuir method, used in the present work, the vapor pressure of the metal P is given by the equation: Here M is the molecular weight of the vapor species. T is the absolute temperature. (dw/dt) is the rate of sublimation in g per sq cm per sec and a is the condensation coefficient. a is a measure of the efficiency of condensation of molecules striking the metal surface from the vapor. If condensation results from each collision a is unity. This coefficient has been found to be unity,a, le for metals. These results establish the general validity of the Langmuir free evaporation method as applied to metals. EXPERIMENTAL A) Vacuum Microbalance Method. A modification of the Langmuir free evaporation method was used. Strip specimens were suspended from a sensitive microbalance operating inside of a high vacuum system. For alloys, microbalance methods17 must be used on large area samples at relatively low temperatures to minimize composition changes. The

Jan 1, 1962

By Ralph Sweetser

THE Round Table. on Qualities of Pig Iron, under the auspices of the Joint Committee on Qualities of Pig Iron, which is made up of members of the American Institute of Mining and Metallurgical Engineers, the American Foundrymen's Association, the American Society for Testing Materials, the Gray Iron Institute, and the. Malleable Iron Institute, was held at the Palmer House, Chicago, Ill., on Oct. 1, 1935. PROCEEDINGS R. H. SWEETSER,* New York, N. Y.-Seven years ago last June we had a round table on qualities of pig iron1, and at that time the foundrymen were out with their battle-axes for the blast-furnace men, and the open-hearth men were doing the same thing. After that meeting there was really a determined effort to find out about the qualities of pig iron, and great progress has been made all along the line. This afternoon we want to have a frank discussion of the qualities of pig iron, whether it is the molten pig iron going into the steel plant, or cold pigs going to the different foundries. We ought to hear something from Dr. J. T. MacKenzie, who is chairman of the Joint Committee, and from Mr. R. E. Kennedy, the tech-nical secretary. J. T. MACKENZIE, t Birmingham, Ala.-As a result of that meeting in Chicago, there was considerable agitation in the Foundrymen's Association to develop a set of tests for pig iron. One of the difficulties was that nobody talked the same language on shrinkage, draws, live iron, dead iron, and so forth, which were the main com-plaints against pig iron. By request of a committee of the Foundrymen's Association, the Bureau of Standards ran a comprehensive set of tests that did develop the prin-ciples governing the optical pyrometer as applied to cast iron and pig iron. Then the Bureau went on further with the fluidity test, and developed a method for the absolute changes of volume at the freezing point.

Jan 1, 1936

By William E. Ford, Edward Salisbury Dana

5. Crystallography. - The subject of Crystallography includes the description of the characters of crystals in general; of the various forms of crystals and their division into classes and systems; of the methods of studying crystals, including the determination of the mathematical relations of their faces, and the measurement of the angles between them; finally, a description of compound or twin crystals, of irregularities in crystals, of crystal- line aggregates, and of pseudomorphous crystals. 6. Definition of a Crystal.- A crystal * is the regular polyhedral form, bounded by smooth surfaces, which is assumed by a chemical compound, under the action of its intermolecular forces, when passing, under suitable conditions, from the state of a liquid or gas to that of a solid. As expressed in the foregoing definition, a crystal is characterized, first, by its definite internal molecular structure, and, second, by its external form. A crystal is the normal form of a mineral species, as of all solid chemical com- pounds; but the conditions suitable for the formation of a crystal of ideal perfection in symmetry of form and smoothness of surface are never fully realized. Further, many species usually occur not in distinct crystals, but in massive form, and in some exceptional cases the definite molecular structure is absent. 7. Molecular Structure in General.- By definite molecular structure is meant the special arrangement which the physical units, called molecules, assume under the action of the forces exerted between them during the formation of the solid. Some remarks are given in a later article (p. 22 et seq.) in regard to the kinds of molecular arrangement theoretically possible, and their relation to the symmetry of the different systems and classes of crystals.

Jan 1, 1922

By Thomas E. Leontis

INTRODUCTION THE importance of magnesium alloys in the manufacture of aircraft engines has been realized for many years. A concentrated effort has been exerted in the laboratories of the Dow Chemical Co. to develop magnesium-base alloys with improved properties at elevated temperatures whereby greater advantage can be taken of the inherent lightness of these materials. In an earlier publication,1 attention was called to the superior tensile properties and resistance to creep of cerium-containing magnesium alloys at temperatures up to 700°F. More recently, additional data on magnesium-cerium alloys have been furnished by Murphy and Payne.2 The present paper deals with the mechanical properties of sand-cast magnesium alloys containing zinc, at temperatures up to 500°F. The study includes binary Mg-Zn† alloys containing up to 10 pct zinc and several ternary and some polynary alloys based on the Mg-1Zn,†Mg-3Zn, Mg-4.4Zn, Mg-6Zn, and Mg-10Zn binaries. The compositional variation in the tensile properties, hardness, and creep at room and elevated temperatures, and in the electrical conductivity at room temperature has been determined. The results of these tests show that many zinc-containing magnesium alloys exhibit resistance to creep at elevated temperatures significantly higher than that of present commercial magnesium alloys, but lower than that of alloys of the magnesium-cerium type. In addition, they have high tensile properties at room and elevated temperatures and high conductivity. This combination of mechanical properties and conductivity indicates that these alloys should be given serious consideration for commercial applications involving exposure to temperatures higher than those to which present commercial magnesium alloys can be taken safely. LITERATURE The properties of sand-cast magnesium alloys containing zinc as a principal alloying element have not been investigated very extensively, especially at elevated temperatures. The following remarks, which are confined to sand-cast alloys, will serve as a summary of the most important references on this phase of magnesium metallurgy. The first recorded determination of the tensile strength of binary Mg-Zn alloys as a function of zinc content was reported by Aitchison.3 Similar studies, including the measurement of elongation and hardness, have been performed by Gann and Winston,4 Dumas and Rockaert,5 Haughton and Prytherch,6 and by Spitaler, the last being reported by Beck.7 A slight superiority in the tensile strength of chillcast Mg + 8 Zn alloy over the sand-cast alloy was noted by Maybrey 8 That alloys of magnesium containing 5 to 12 pct zinc

Jan 1, 1948

By C. B. Foster, S. I. Freedman, E. M. Jamgochian

Coal-oil mixture (COM) combustion technology is regarded by the US Department of Energy (DOE) as near term and Potentially applicable to existing utility and industrial steam generators and for injection into blast furnaces. From work done previously, it has been established that COM can be burned in existing boilers and blast furnaces. Therefore, the issues being addressed by the current DOE program are: (1) determination of best available technology to achieve environmentally acceptable long-term reliable operation and (2) determination of applications for which COM can be utilized economically. Some of the technological options have begun to be determined by projects already under way. However, many projects are still in the early stages of development.

Jan 1, 1980

[NOTE.-The names of authors of papers are printed in small capitals, and the titles of papers, in italics. Casual notices, giving but little information, are indicated by bracketed page numbers. Large Roman numerals are volume numbers; small Roman numerals after volume numbers following titles indicate the page on which the presentation of the paper is mentioned; Arabic figures refer to the text of the printed papers.] A Use Classification of Coal, (ASHLEY) LXII [xiv]; LXIII, 782; Discussion: (HALL), 794; (ZERN) , 795; (ASHLEY), 795 Absorbent material, liquid-oxygen explosives, LXXI, 1251. Absorbents for liquid-oxygen explosives, LXIX, 292, 299. Absorption : cupellation : gold, special cupels, LIX, 194. primary and secondary, LIX, 213. ratio of silver to gold, LIX, 212. silver, specla1 cupels, LIX, 195. Absorption method, gasoline from natural gas, LIX, 584, 585. Absorptzon of Sulfur from Producer Gas zn Open-hearth Furnaces (NEAD), LXX, 176; Discussion: ( WATERHOUSE), 184 ; (REYNDERS) , 184; (KINNEY), 184 Accelerated wearing tests, bearing metals, LXIX, 973. Accident prevention, results, Utah, LXVIII, 360 Accident Prevention, 1919 (SINN), LXIII, [xiii] Accidents: causes in coal mines, LXXI, 1229. classification, Anaconda Copper Mining Co., LXVIII, 9. coal mining: comparison with metal mining, LXVIII, 360. pillar mining, LXVIII, 323. relation to method, LXVIII, 323 shafts, LXVIII, 207, 209 Utah, LXVIII, 363 - concentrating mills, Utah, LXVIII, 362 liquid-oxygen explosives, LXIX, 330, 339 losses through, LVIII, 65 metal mining, LXVIII, 361, 363. mine: causes, LIX, 652. curve of decrease, LIX, 655 days of greatest frequency, LIX, 657 human element as cause, LIX, 652, 653. intemperance as cause, LIX, 658 labor relation, LIX, 652 prevention, LIX, 653. record, New Jersey Zinc Co., Franklin mine, LIX, 655 time of greatest frequency, LIX, 657, 658 Utah, LXVIII, 360 prevention, LVIII, 65 report blanks, Anaconda Copper Mining Co, LXVIII, 13, 15. statistical base, Anaconda Copper Mining Co, LXVIII, 9 time lost, LVIII, 70 transportation, Clifton-Morenci district, LXX, 851.

Jan 1, 1926

By J. C. Fisher

Nucleation theory is applied to martensite nucleation in substitutional iron alloys. Composition fluctuations are neglected, and a steady rate of nucleation is predicted for any composition and temperature. The maximum rate of nucleation (as a function of temperature) is shown to be measurable only for on extremely narrow composition range, being too great or too small outside this range. A number of experimental observations, including completely isothermal transformation in some alloys and composition-dependence of M. temperature in others, are compared with the calculated behavior. IN a previous report,¹ nucleation theory was applied to the formation of isothermal martensite in an Fe-Ni-Mn alloy. The experimental observations of Cech and Hollomon² were accounted for quantitatively. It now is of interest to examine the predictions of nucleation theory with respect to martensite transformation in substitutional iron alloys of other compositions. Since Fe-Ni alloys have received considerable attention, both as to their transformation kinetics and their free energies, they will be treated in detail, although the results apply with equal validity to other substitutional alloys. In substitutional alloys, where composition fluctuations can be neglected in volumes of critical nuclear size, the rate of nucleation of martensite in subcooled austenite is¹ n - Nv exp (—W*/kT) [I] where the free energy of formation of the critical size nucleus is W* = 8192 p (?² s³) [2] In the expressions for n and W*, the symbols have the following meanings: N is the number of atoms per unit volume; v, the atomic vibration frequency; 8, a function of the elastic constants of austenite and the shear angle of martensite; , the austenite/mar-tensite inter facial free energy; and ?fc is the free energy change per unit volume accompanying the transformation. Jones and Pumphrey² have determined the austenite to martensite free energy change as a function of nickel content and temperature for Fe-Ni alloys. Their expression is ?F = 2500 C + 1.25 (1 —C)?FFc cal per mol [3] where C is the atom fraction of nickel, and ?Ffe is the free energy change per unit volume for pure iron as tabulated by Zener4 (or, equivalently, Fisher"). From Eqs. 1 to 3, it is possible to calculate isothermal nucleation rates as a function of temperature and composition for Fe-Ni alloys. The only unknown parameter is (?² s³). The best value of this parameter for Fe-Ni alloys, determined from M. temperatures in a manner to be described shortly, is (?² s³)= 9.92 (10)21 cgs units [4] Taking this value of (?² s³), C-curves for isothermal nucleation were calculated for Fe-Ni alloys of several compositions, and are plotted in Fig. 1. It is evident from Fig. 1 that completely isothermal nucleation of martensite in Fe-Ni alloys can be observed experimentally for only a very narrow range of compositions. Cech and Hollomon find that a nucleation rate of about 10' nuclei per cc per sec is as fast as they can follow dilatometrically, and a rate of about 10-1 nucleus per cc per sec is about the slowest that can be measured conveniently. If the nucleation rate is to lie between the limits 10-1 10 the nickel content of an Fe-Ni alloy must fall in the atomic fraction range 0.299 5 C 5 0.302. Nickel contents lower than 0.299 correspond to nucleation rates too great to follow, and those higher than 0.302 to nucleation rates too slow to measure in a reasonable time.* In view of the narrow corn- position range in which successful isothermal measurements can be made, it is not surprising that only one substitutional alloy has been described' that comes close to being in the proper range.

Jan 1, 1954

By J. L. Huitt, D. K. Lowe

This laboratory flow study covers propping agent transporl in horizontal fractures as influenced by the characteristics of the propping particles, fluid and fracture. Correlations are presented for the transport of particles, deposition and fingering through dunes. For particles moving individually, the article velocity in some cases may be low compared to the hulk average fluid velocity; in other cases, the particle velocity may exceed the bulk average fluid velocity. At high propping agent concentration or low fluid velocity, the likelihood of particle deposition and dune formation increases. Fingering and channeling accompany dune formation. Dune formation can be limited to the outer region of tile fracture by adjustment of pump rate, fluid viscosity and particle concentration. A method is presented by which pump rate and fluid vircosity may he selected to control dune formation for given propping agent concentrations. INTRODUCTION The area and flow capacity of a fracture predominantly control the stimulation derived from hydraulic fracturing. Generation of fracture area exposes the rock matrix to a flow channel; the flow capacity of the fracture controls the flow through the channel to the wellbore under a given pressure gradient. This paper pertains to an important factor that affects the flow capacity of a fracture: the transport of the propping particles in the fracturing during the hydraulic fracturing treatment. With a better understanding of particle transport, fracturing treatments may be designed to obtain more effective distribution of the propping agent. RELATED STUDIES In recent years, the approach to obtaining high fracture flow capacity has been partial monolayer propping. Three papers1-3 have dealt with various facets of this concept. However, in some papers dealing specifically with particle transport, the results generally indicate that packing the propping particles within a fracture is inevitable. In early work&apos; with a sand slurry flowing in a pie-shaped flow cell, qualitative results showed that particle deposition in a fracture during transport should be expected. In other studies"" correlations based on slurry flow in vertical linear flow cells showed particle deposition was primarily a function of fluid velocity. In a recent paper the rate of sand advance (movement of dunes) in a horizontal linear flow cell was discussed. Subsequently, a method was given for designing fracturing treatments, based on the extent of sand advance during a treatment. In this work, particles whose diameter was small relative to the fracture width (i.e., dl W< 0.2) were primarily considered. The particle transport approaches that of sand transport in a stream bed. The industry trend, however, has been to use larger size propping agents. That is, particles with diameters approaching fracture widths predicted by Perkins and Kern.&apos;&apos; This trend has led to generally better fracturing treatments with particle relative sizes in the range 0.2 <d/W < 1.0. In all of the particle transport studies previously cited, the fluid characteristics were discussed. However, little or no attention was given to the parzicle characteristics. In this study the particles. as well as the fluid and fracture, are considered. VARIABLES AFFECTING PARTICLE TRANSPORT In the exploratory work to set LIP a program for this study, it was noted that particles within a batch moved at different velocities in a horizontal linear flow cell. In some cases the particles moved independently. In others there was particle interference. Also, particle deposition and fluid fingering occurred in some cases (Fig. 1). As a result of observing the easily distinguishab&apos;le types of particle movement, the particle variables as well as the fluid variables were included. In addition, the fracture width was included because the fluid velocity profile surely must affect the movement of the larger particles differently than that of smaller particles. Particle variables were density, diameter (based on a sphere of equal volumetric displacement), long and short dimensions, drag coefficient and velocity. Fluid variables were density, viscosity, yield shear strength and velocity. Fracture variables were the width and the angle between the plane of flow and a horizontal plane. Two factors which may prove to be important were omitted because of the complexity resulting from the parameters cited above. These are the fracture-surface roughness and gross irregularities that cause changes in the direction of flow. EXPERIMENTAL EQUIPMENT AND PROCEDURE A linear parallel-plate flow cell (Fig. 2) was used in the study. Lucite plates 1 in. thick formed the test section and permitted a viewing section 11 ft long and 10 in. wide. Spacing between the plates was adjusted with shims to give fracture widths 1/36 to 1/2 in. The model could be tilted to an angle of 45" with the horizonltal plane. Fluid flow was maintained with a Moyno positive displacement pump. Single particles were placed in the flow stream with a particle injector. A .4 - in. diameter plunger moving at a constant rate in a

Jan 1, 1967

By J. C. Fisher, J. H. Hollomon

The fundamental problem concerning the fracture of both crystalline and noncrystalline solids is the divergence between the actua1 and the theorcticallY computed fracture stresses; the stress required for fracture, computed from the forces between atoms, is many times that actually observed with commcrcinlly available materials. Computatiolls have been made,,2 indicating that the theoretical fracture stress should be from 100 to 1000 times that actually observed. There are other incidental problems that have arisen, perhaps the most importallt of which is the problem of size effect often observed in the measurement of the fracture stress of non-metallic solids, such as glass. Another effect conccrns the relation between deformation and the stress required for fracture, Experiments recently made with pearlitic steels indicate that the tensile fracture stress increases with increasing tensile deformation and decreases with increasing prior com-pressive deformation, This marked ani-sotropy of the effect of deformation on the fracture stress is in contrast with the essential isotropy of the flow stress. Early experiments on rock salt crystals by Joffe, et al.3 have illustrated the effect of tensile strain in increasing the tensile stress required for fracture. A consistent theory must be constructed that will explain not only the divergence, of the measured fracture stress from the theoretical value, the size effect, and the ergence of deformation; but will also explain and predict the effects of combined stress, of temperature, of strain rate, and of metallurgical structure. With respect to this last variable, it has now been relatively well established that the carbide particle is the clement of structure controlling the fracture of steels. In steels carbide particles vary in shape from plates to spheroids. It has been found that not only docs the magnitude Of the Fracture stress depend upon the size and shape of these particles. but also its dcpendencc upon strain is affected by changes in &apos;hap&apos; an&apos; size Or the particles. The precipitate resulting from the age hardening Of duralumin also modifies the fracture stress of this alloy. Nonmetallic inclusions greatly lower the fracture stress of all metals. The magnitude of the lowering depends 0&apos; the size and shape of the included particles. In glass, the major source of the low fracture stress has been fairly conclusively demonstrate&apos; by Griffith4 &apos;0 arise from real flaws or cracks present in the material. He showed that the stress concentration at the end of a defect was of suficient magnitude to raise the stress at this location to a value comparable with the theoretical strength Of the material. If the cracks were reduced in size, Griffith showed that the observed fracture slrength the by virtue Of the decrease in stress concentration. He also pointed out that cracks disposed perpendicularly to the applied tensile stress would be more effective in lowering the fracture

Jan 1, 1947

By J. H. Hollomon, J. C. Fisher

The fundamental problem concerning the fracture of both crystalline and noncrystalline solids is the divergence between the actua1 and the theorcticallY computed fracture stresses; the stress required for fracture, computed from the forces between atoms, is many times that actually observed with commcrcinlly available materials. Computatiolls have been made,,2 indicating that the theoretical fracture stress should be from 100 to 1000 times that actually observed. There are other incidental problems that have arisen, perhaps the most importallt of which is the problem of size effect often observed in the measurement of the fracture stress of non-metallic solids, such as glass. Another effect conccrns the relation between deformation and the stress required for fracture, Experiments recently made with pearlitic steels indicate that the tensile fracture stress increases with increasing tensile deformation and decreases with increasing prior com-pressive deformation, This marked ani-sotropy of the effect of deformation on the fracture stress is in contrast with the essential isotropy of the flow stress. Early experiments on rock salt crystals by Joffe, et al.3 have illustrated the effect of tensile strain in increasing the tensile stress required for fracture. A consistent theory must be constructed that will explain not only the divergence, of the measured fracture stress from the theoretical value, the size effect, and the ergence of deformation; but will also explain and predict the effects of combined stress, of temperature, of strain rate, and of metallurgical structure. With respect to this last variable, it has now been relatively well established that the carbide particle is the clement of structure controlling the fracture of steels. In steels carbide particles vary in shape from plates to spheroids. It has been found that not only docs the magnitude Of the Fracture stress depend upon the size and shape of these particles. but also its dcpendencc upon strain is affected by changes in &apos;hap&apos; an&apos; size Or the particles. The precipitate resulting from the age hardening Of duralumin also modifies the fracture stress of this alloy. Nonmetallic inclusions greatly lower the fracture stress of all metals. The magnitude of the lowering depends 0&apos; the size and shape of the included particles. In glass, the major source of the low fracture stress has been fairly conclusively demonstrate&apos; by Griffith4 &apos;0 arise from real flaws or cracks present in the material. He showed that the stress concentration at the end of a defect was of suficient magnitude to raise the stress at this location to a value comparable with the theoretical strength Of the material. If the cracks were reduced in size, Griffith showed that the observed fracture slrength the by virtue Of the decrease in stress concentration. He also pointed out that cracks disposed perpendicularly to the applied tensile stress would be more effective in lowering the fracture

Jan 1, 1947

By AIME AIME

MOST recently elected to the limited group of Honorary Members in the A.I.M.E. is the distinguished Australian metallurgist, Guillaume Daniel Delprat. His citation reads: "in recognition of his distinguished achievement as metallurgist, engineer, and administrator in the production of ferrous and nonferrous metals," Mr. Delprat&apos;s ability and experience in both the ferrous and nonferrous fields at once distinguishes him from most of his professional brothers. Mr. Delprat&apos;s nativity was neither Australian nor English, for he was born in Delft, Holland, in 1856, and educated in Amsterdam. At the age of 22 he went to Spain, as metallurgist for the Tharsis Sulphur and Copper Co., Ltd. Afterwards he spent some time with the Bede Metal and Chemical Co., which had mines in both Spain and Norway, and of which company he became general manager. Other positions of responsibility held by Mr. Delprat before he went to Australia included the managing directorship of the Cordova Exploration Co., with properties in Spain and Canada; of the Rincon Silver-Lead Mining Co., in Spain; and of the Deloro Gold Mines, in Canada.

Jan 1, 1936

Jan 1, 1969

By E. R. Helderman, C. Y. Ang, C. C. Nealey

Beryllium-base alloys have been successfully p7.-epared by the liquid-phase sintering technique. Depending orz the composition and amount of the intended liquid please, microstructures either single -phase or duplex in feature with randomly oriented grains have been obtained. Qualitative and semi-qualitative determination of distribution of alloying elements md microsegregations in some experi)uzental alloys haue been made by electron-micro-probe analysis in conjunction with microliardness testing and standard metallography. Tensile tests reoealed that some conzpositions possess attractive elastic properties with Young&apos;s mot1uli greater than 40 X 10&apos; psi. In powder metallurgy, liquid-phase sintering is a process or phenomenon that has proven to be of practical value. For example, the heavy metals such as tungsten-copper-nickel, high-strength heavy gyro alloys,&apos; heavy-duty electrical contacts,&apos; and tungsten carbide tool materials are all products of liquid-phase sintering. Mechanisms involved in liquid-phase sintering, however, are not completely understood. Questions regarding the exact roles played by rearrangement of particles, liquid/vapor surface energy, solution and precipitation, and so forth, have not been completely answered. Evidence has been cited3 that at least volume shrinkage in the densification process is diffusion-controlled. It is possible that the predominant mechanisms for the complete densification and grain growth in a liquid-phase sintered system depend primarily on the alloy systems involved, in addition to processing conditions. Despite the lack of sound understanding of the mechanisms of the process, liquid-phase sintering has been and is being used to advantage either to synthesize microstructures for their special properties or to prepare alloys which are difficult to form by fusion process. Liquid-phase sintering of beryllium alloys was first attempted by Jones and Williams.4 They first tried infiltrating beryllium with magnesium, and then succeeded in preparing the alloy by sintering Be-Mg powder compact in molten magnesium bath. This investigation resulted in the identification of some Mg-Be intermediate phases. Crossley et a1.5 also used liquid-phase sintering technique in an attempt to produce ductile beryllium alloys for structural applications. The major liquid-phase components investigated by Crossley et al. were aluminum and silver with minor additives of germanium, calcium, lanthanum, cerium, and yttrium. The lack of wetting and the bleeding out of liquid phase were the difficulties encountered during experimentation. According to Hodge,6 the two compositions investigated by Crossley, which showed some promise based on compression tests, involved large amounts (over 35 wt pct) of silver, thus making them too heavy to be of practical interest to the aerospace industry and military users. The present investigation was prompted by the search for light-weight (density less than aluminum) beryllium alloys exhibiting small anisotropy in physical properties for precision inertial navigation instrument applications. In addition to isotropy, good structural properties such as high elastic modulus or desirable combination of mechanical and physical properties are also objectives of this investigation. The technique of liquid-phase sintering was chosen for its versatility in producing either duplex or homogeneous microstructures. This report is concerned with the use of copper and aluminum, with or without silicon addition, as the intended liquid phase, and the resultant micro-structures and some physical properties of the beryllium alloys. Qualitative and semiquantitative electron-microprobe analyses of some of the alloys are presented to illustrate the usefulness of this microanalytical technique for the identification of microconstituents and their distribution. EXPERIMENTAL PROCEDURES The beryllium powder used was -200 mesh Brush Beryllium Co. QMV NP-50 grade. Typical chemical analysis of the powder is shown in Table I. Commercial high-purity copper, aluminum, and silicon powders all screened to —100 mesh were used as additions. Mixed powder compositions were ball-milled in ceramic jars for 1/2 hr to ensure thorough blending. Milled powder was loaded either in 3/4-in.-diam button die or in Metal Powder Association flat tensile specimen die and compacted under top and bottom pressure. No lubricant or organic binder was used. Sintering was carried out in a quartz tube under a vacuum of 50 to 100 µ pressure. Surface hardness and some microhardness readings were taken on sintered specimens. Sintered density was

Jan 1, 1965

By AIME AIME

A PAPER prepared by James A. Adams, development engineer of the fitline & Smelter Supply Co., and presented at the last Annual Meeting of the A.I.M.E. in New York City, de- scribed a new automatic pulp density controller which has had a most favorable reception. Manual control has until now been the universal practice in spite of its shortcomings; samples of pulp for density determination were often improperly taken, and only at the operator&apos;s convenience, so that the trend in density changes was frequently missed, and the grinding circuit al- lowed to operate under something less than the most efficient conditions.

Jan 1, 1940

GENTLEMEN : Herewith are submitted reports for the calendar year 1933 of your Treasurer and the Chairmen of the following standing committees: Finance, Admissions, Membership, Papers and Publications, Library, and MINING AND METALLURGY. TO these reports you are referred for additional details of the year&apos;s activity. Finances.-Income for 1933 from all sources totaled $121,690 com- pared with $138,331 in 1932. Incidentally, this exceeded the income as estimated in the budget by $7,190; the largest item being a "surplus" of $3,316 over the budget expectancy as to member dues. As compared with 1932 the most important items of shrinkage in income were $9,000 from dues and initiation fees; $5,500 from the magazine, MINING AND METALLURGY; and $2,500 from sales of publications other than the magazine.

Jan 1, 1934

By P. Pollard

A method has been developed for evaluating acid treatments in fractured limestone fields by breaking down pressure drawdown into three component parts: (I) pressure differcntial across "skin" near the borehole face, (2) pressure differential due to flow resistance in the coarse communicating fissures and (3) pressure differential between the fine voids and the coarse fissures. It is apparent that in most successful acid treatments the first term, skin resistance, has been reduced or eliminated. Further, it is often possible to estimate the volume of coarse fissures associated with the second term, coarse fissure flow resistance. In cases where this volume is comparable with practical acid volumes it seems likely that this resistance also may be attacked with a suitably retarded acid. INTROD UCTION Acid treatment has been successfully applied as a general practice in the limestone wells in the Mara/ Maracaibo districts of Venezuela for some 10 years. At the same time the need has been felt for a more precise method of: (1) evaluating the effect of an acid job and (2) selecting wells which should benefit from an acid treatment. The following method, based on an analysis of build-up curves for wells producing from fractured limestone, provides a means of forecasting the effect acid will have on a well and in many cases the probable order of production rate increase which may be expected. In certain cases it is also possible to calculate the fissure volume through which the acid has to be displaced for best results. Various approximations are introduced in the method, but within the limitations of these the analysis gives an indication of how a well, whether previously acidized or not, may be expected to respond to acid treatment. Suitable build-up curves cannot be obtained on "tight" wells which do not give sustained production and the method is not applicable to such wells. Figs. 1 through 7 illustrate various types of build-up curves obtained from limestone wells in Western Venezuela. Curves are included showing (1) both skin and coarse fissure resistance, (2) skin resistance only, (3 and 4) reduction of skin resistance by acidization, (5) fissure resistance only, (6) reduction of coarse fissure resistance by acidization, and (7) acidization failure. This theory has been successfully applied for over three years during which 22 acid treatments have been carried out specifically to reduce skin resistance and three treatments to reduce coarse fissure resistance. The method has been found to be a useful aid in the selection of wells for acidization.

By Stanley D. Michaelson, Norman Weiss

This was a year of realization. Some years are for planning and development, some for designing and building, others for fulfillment. With greater hopes and plans for the future than ever before, the year 1954, nevertheless, will be remembered principally because of project completion. Among copper mines, for example, there were Silver Bell, Copper Cities, Bisbee, Yerington, and White Pine. In iron, there were the Humboldt, Coleraine, Cerro Bolivar, and Eagle Mountain. In asbestos, Johns-Manville&apos;s new mill at Asbestos, Que. In uranium, completion of the ninth mill on the Colorado Plateau-Kerr-McGee&apos;s at Shiprock, N. M. In research, 1954 marked the completion of Kennecott&apos;s Research Center in Salt Lake City, one of the historic forward strides in the science of minerals beneficiation. The year was fruitful in other directions as well. Investigations of a fundamental nature were on the upswing, and pilot plant projects have also increased in size and number. Progress in new reagents and equipment was greater than normal. It can already be conservatively predicted-from the technological point of view-that 1955 and 1956 will be tremendous years.

Jan 3, 1955

By W. V. Vietti, E. P. Hayes

OpeRations on the Texas Gulf Coast during 1936 increased materially over 1935. A number of new fields were discovered and a few of the older fields were extended, both by the discovery of deeper pay sands and by lateral expansion of the known producing horizons. Twenty-seven new fields have been discovered, of which 25 are oil fields and the others are gas fields that have every indication of becoming oil-producing areas. Amelia, Anahuac, Bay City, North Pettus, Placedo, Pickett Ridge and Tomoconnor have had major extensions. Production for 1936 amounted to 91,224,844 bbl., an increase of 21,627,033 bbl., or 31 per cent, over the 1935 production of 69,597,811 bbl. The number of producing wells at the end of 1936 was 6727, as compared with 4851 at the end of 1935. Proration has continued in force, thus decreasing the rate of depletion and the number of abandonments normally expected. New Fields A brief discussion of the new fields follows, in addition to Tables 1 and 2, which contain the general data on these fields. Aransas (McCampbell).-Buckingham and McCampbell No. 1 McCampbell was drilled to 7501 ft., then plugged back to 6560 ft. and completed in the Marginulina for a 100-bbl. flowing well on July 18. Bee County.—The Voss field, discovered by Swiger and Devonian&apos;s No. 1 Voss, and the Holzmark field, discovered by Miller and Donzis on the Holzmark farm, are both of the same type structurally and are caused by folding against a fault, one field being on one side of a fault and the other on the opposite side of the same fault. Brooks County.—-Standard Oil Company of Texas Garcia No. 1, the discovery well in the Alta Mew field, and Dick Young&apos;s Singer No. 1, the discovery well of Alta Verde, appear to indicate small fields. Garcia No. 1 was drilled to 8022 ft. and plugged back to 2485 ft., at which depth the well made 189 barrels. Lockridge.—This gas field was discovered by Gulf Production Company&apos;s Fairfield No. 1, in Brazoria County. It was originally drilled to

Jan 1, 1937

By N. A. Zeigler

GRaphitization phenomena occurring in solid cast iron have principally been studied from the angle of the reactions taking place during annealing of white castings in the manufacturing of malleable iron. The selected bibliography at the end of this paper presents the high spots of the published information in this field. Graph-itization of gray iron upon reheating has received much less attention, primarily because only on rare occasions is this material subjected to any kind of industrial heat-treating. Moreovcr, articles made from gray iron are seldom used commercially at temperatures when any graphitization can take place. When used in such conditions, it is assumed that the articles can be replaced at frequent intervals, which can be afforded because of the low cost of gray iron. However, there is at least one commercial process in which articles made from gray iron, during their manufacturing processing, are subjectcd to rather high temperatures; that is, manufacturing of cast-iron enamelware, which is glazed at about 1600° to 1700°F. (870&apos; to 930°C.) From practical experience, it has been found that one of the convenient and economical compositions of gray iron suitable for enameling is, in round figures, as follows: Si, 2.50 per cent; Mn, 0.35; S, 0.07; P, 0.80; T.C., 3.35; C.C., 0.70. Since this iron usually is cast into thin-walled sections, the percentage of com- bined carbon in it is relatively high. Upon heating in the enameling furnaces, this combined carbon graphitizes, which causes permanent dimensional changes of the articles. Obviously, from practical considerations, it is desirable to maintain these dimensional changes as constant as possible. In the course of experimentation with this iron, two series of experimental heats were prepared in which the manganese to sulphur ratio of the standard cupola metal was offset by ladle additions of: (I) progressively larger amounts of sulphur, and (2) progressively larger amounts of manganese. Each one of these ladle charges was cast into experimental plates 8 by 4 in. and about 5/16 in. thick. All told, 13 ladle charges were thus treated. All of them are listed in Table I, together with their chemical analyses. It may be noted that the manganese to sulphur ratio in these samples ranges between 1.2 and 30.2. Every one of these compositions was subjected to thermal allalysis, using an automatic, self-recording differential dila-tometer. The specimens used in this instrument are 50 mm. long and 4 mm. in diameter. During the dilatometer cycle they are kept under a vacuum of about 3 microns. Each one of them was subjected to a thermal cycle by heating it to I830°F. (1000°C.) in 3 hr. and cooling to room temperaturc in 5 hr. Figs. I, 2 and 3 present three automatically recorded dilatometer curves for irons: Serial No. I (normal composition), Serial No. 6 (high sulphur), and Serial No. 13 (high manganese). All three of these figures are

Jan 1, 1945

By Frank Clemes Smith

The study of the so-called refractory gold-ores of the Potsdam sandstone, ores which are probably of wider occurrence and of much greater economic importance in the Black Hills than is generally supposed, has led the writer to formulate in the present paper some of the results obtained in the course of a special examination of these particular ores, conducted at the State School of Mines at Rapid City, So. Dak. Various circumstances have interrupted the work, and it will easily be seen that relatively little has yet been accomplished; but it is hoped that this little may be of sufficient interest to justify a later supplement. Tellurium, discovered by Muller von Reichenstein in 1781, is generally classed as a very rare metal; it is further mentioned by one of our late writers as " of comparatively little importance," and as obtained from its ores by a " complicated process.&apos;&apos; Concerning its rarity, we have some trustworthy evidence below. Its commercial importance, particularly in connection with electrical appliances, has been passed upon by Mr. Edison ; * and it is certain that, in some metallurgical processes for the treatment of gold- and silver-ores, it may be saved as a byproduct at a relatively reasonable expense. The importance of tellurium as a mineralizing agent is emphasized by the remarks of one of our leading metallurgists,jwho, in his own practice and by a wide series of experiments, has found its occurrence to be much more general than has been supposed. Recently the same writer has discussed the occurrence of tellurides and oxidized tellurium compounds in the gold-ores of Cripple Creek, Colo., and in those of the Black

Jan 1, 1897