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By Youze Xu

The leaching and reduction of Cr(VI) in soils contaminated by chromium-containing slag were investigated with column experiments. The results showed that Cr(VI) concentration in leachate decreased from 988 mg L-1 to 407 mg L-1 after 7 days when water was used as leaching agent. However, Cr(VI) in leachate in culture medium treatment was not detected at above periods. In comparison, Cr(VI) concentration in leachate from autoclaved soil remained 398 mg L-1 at the end of experiment. The results indicated that the indigenous microorganism was capable of reducing Cr(VI). The amount of Cr(VI) reduction was 335 mg at the whole experiment period and the reduction rate was 67.09 mg d-1. Carbon supply showed minor effect on Cr(VI) reduction. However the reduction capability of Cr(VI) could be improved by combination of the carbon and the nitrogen. The optimal quantity was 5 g L-1 of yeast extract and 4 g L-1 of glucose.

Jan 1, 2009

By Hui-gang Wang, Mei Zhang, Min Guo

Metal-doped Ni–Zn ferrite with spinel structure was directly synthesized from treated zinc-containing electric arc furnace dust (Zn-containing EAFD) by solid state reaction method, realizing the transformation of Zn-containing EAFD from solid waste to high value-added material. A certain mass of NiCl26H2O was added to the treated Zn-containing EAFD before calcination. Then the effects of the mass ratio of treated Zn-containing EAFD to NiCl26H2O (RTZE/N, g g−1) and calcination temperature on the synthesis and magnetic properties of as-synthesized samples were systematically investigated by X-ray Diffraction, Raman Spectroscopy and Physical Property Measurement System. It is indicated that RTZE/N and calcination temperature had important influences on the synthesis of single-phase spinel ferrite and their magnetic properties. Pure metal-doped Ni–Zn ferrite, which exhibited good magnetic properties of higher saturation magnetization (Ms, 60.5 emu g−1) and lower coercivity (Hc, 49.8 Oe), was obtained when the calcination temperature was controlled at 1100 °C for 2 h with RTZE/N of 1:0.9.

Mar 1, 2017

By Shirleny Fontes Santos

Muscovite mica crystals lower than 15 mm diameter are discarded as waste in the mining area of Borborema-Seridó (BRAZIL). The objective of this work was the ore dressing and purification of this waste to be used in the preparation of pearlescent pigment. Muscovite was dry ground using knife mills and an ultrasound treatment. It was possible to achieve 67% of mica with particle size lower than 100 µm. This product was used in the preparation of brilliant pigments based on muscovite flakes covered with rare earth oxides (CeO2, PrO2, Ce0,95Pr0,05O2). The pigments were characterized by X-ray diffraction, thermal analysis and scanning electronic microscopy. The color of the resulting pigments was analyzed using the CIELAB method and it showed the following colors: muscovite-CeO2 ? yellow, muscovite-PrO2? black and muscovite-Ce0,95Pr0,05O2 ? orange. Those results have shown that ?trash mica? is suitable for use in pigment preparation.

Jan 1, 2010

By NRMR Bhargava

With the increasing use of lead-free solder alloys, low melting point alloy is often required due to the heat- sensitive parts or substrates in modern electronic devices. For such demand of low melting point, the nanostructure lead- free solder alloy, having excellent metallurgical characteristics and a melting point of <215oC, were developed by mechanical attrition of conventional lead free solder alloys (Sn-Ag-Cu, Sn-Ag and Sn-Cu). The decrease in melting point due to nanosize effect was calculated theoretically as function of particle size and the theoretical results were compared with experimental values measured by differential scanning calorimetry. The newly developed alloys have eutectic composition of Sn-3.5Ag-0.7Cu, Sn-3.5Ag and Sn-0.7Cu and the melting point depression found to be 5.10C, 4.10C and 6.20C when the bulk alloys reduced to 80 nm, 92nm and 96nm sizes respectively.

Jan 1, 2009

By T. T. Chen

Copper anodes generated from copper scrap are relatively rich in Sn, Zn and Fe. Because of the presence of oxygen, only trace amounts of Sn occur in solid solution in the copper crystals. Thus, Sn occurs mainly as SnO2, Cu-Sn-Ni oxide and Sn-Ni-Zn oxide in the copper anodes, and Zn and Fe occur mainly as minor constituents in the Sn-Ni-Zn oxide and Cu-Sn-Ni oxide. During electrorefining, these oxide species are liberated from the copper anodes and report directly to the anode slimes. The trace amounts of Sn present in solid solution in the copper crystals dissolve but reprecipitate as Sn arsenate or a Sb-As-Sn-O phase. Accordingly, high Sn contents in copper anodes do not lead to elevated Sn concentrations in the electrolyte.

Jan 1, 2010

By Liang Sha

In this study, adsorption of copper by chemically modified orange peel was investigated. A conspicuous change occurs in the surface morphology of the biomass due to modification, which is depicted by SEM images. Equilibrium isotherms and kinetics were obtained and the effects of various factors, including solution pH, contact time, initial metal ions concentration and temperature, were studied by batch experiments. Kinetics was found to be best-fit pseudosecond- order equations. Equilibrium was better described by Langermuir isotherms rather than Freudlich isotherms. At 25?, pH5.30, the maximum adsorption capacity was 70.67mg?g-1 . With increase of temperature, adsorption efficiency decreased. The biosorbent was suitable for repeated use for more than five cycles.

Jan 1, 2009

By Jinwu Kang

The hydraulic turbine blade of the matensitic stainless steel (Cr13%,Ni5%,Mo1%) is a kind of large and curved shape, which is susceptible to deformation in both casting and heat treatment processes. The coupling analysis of heat transfer, phase transformation and stress in heat treatment process of the turbine blade for Three Gorges Project is carried out by using Deform-3D software. Its temperature fields, phase fields and stress fields in heat treatment process are obtained. And its deformation is predicted. In the cooling process of normalizing, the blade exhibits relatively large deformation. Based on the stress analysis and deformation prediction in heat treatment process, an algorithm for the determination of reverse deformation of the blade casting in heat treatment process is presented. And the reverse deformation distribution of blade is obtained.

Jan 1, 2010

By M. Faraji

Inclusions formed in a high-carbon, manganese-silicon killed plain steel (Fe-0.77C wt%) were studied. Various techniques were used to characterise the inclusions, and the latter were classified according to their chemical composition, size and morphology. The main constituent elements entering the inclusions were Mn, S, Al, and oxygen. Alongside MnS and some Al2O3 inclusions many non-metallic inclusions appeared in complex forms, consisting of silicates, sulphides and oxides. Duplex oxy-sulphides, mainly MnS combined with Al2O3, or SiO2 were the most common complex multiphase inclusions in this steel. The nanoindentation technique was used to assess and rate different types of inclusions and data of the hardness and elastic modulus of individual inclusions at room temperature are presented.

Jan 1, 2010

By Qingwei Wang

This study focused on acidic wastewater from producing sulfuric acid system in zinc smelter containing mercury 21.48mg/L, zinc 55.85mg/L, lead 38.50mg/L, copper 1.68mg/L, cadmium 10.25mg/L, As 29.86mg/L treated by biologics. The factors of pH value, the ratio of biologics to mercury, complexing time, hydrolytic time and temperature were studied in this paper. Experimental results indicated that at pH value 10, quantity of biologics to mercury ratio was 16, complexing time 30min, hydrolyzation time 20min, temperature at 40?, concentration of mercury in treated water was removed to 22.15µg/L. At same time heavy metals such as Zn, Pb, Cu, Cd, As was removed by biologics, the remained concentration in treated water was Zn 0.53mg/L, Pb 0.12mg/L, Cu 0.01mg/L, Cd low to 0.01mg/L and As 0.023mg/L. According to EDAX analysis, mercury content in complexing sediment reached 28.49% easily to recycle as raw material and low concentration of heavy metals in hydrolytic sediment easily to dispose and treat.

Jan 1, 2009

By B. B. Agrawal

Iron ore fines is an area of concern in India. A possible avenue is to use these fines for sponge ironmaking. Work has been carried out to pelletize these fines with coal and a suitable binder, and cure them in ambient atmosphere to retain in-situ reductant. Pellets were characterized for physical strength and metallisation. Critical factors were granulometry was percentage of coal & binder. In laboratory tests, pellets got metallized faster compared to lump ore. Large-scale trials were conducted in a 12-meter long rotary kiln plant. For 90% metallization, required residence time was only 60 minutes against 240 minutes for lump ore. Coal requirement also decreased. Investigations established the fast reduction nature of pellets. This is due to reduction-reactions occurring simultaneously at many sited within the composite pellets, in addition to the diffusion of reducing gases from the surface of the pellets to its core. The developed process is a value addition in the conventional pelletmaking and is environment-friendly also.

Jan 1, 2006

By Sergio N. Monteiro

Polymeric composites reinforced with natural fibers are increasingly been used in several engineering applications, from automotive parts to building construction elements. In addition to the relatively low cost, the natural fibers are also appraised by their renewable and biodegradable characteristics. Fibers extracted from the crust of coconut fruits, also known as coir fibers have been investigated for a possible use in composite materials. In the present work, the coirfiber/polyester matrix interfacial strength was evaluated by means of pullout tests. The variation of the pullout tensile stress vs. the embedded coir fiber length permitted to determine the critical fiber length and, thus, to calculate the interfacial strength. Observations by SEM complemented the results from pullout tests, indicating that coir fibers have a potential for application aspolymeric composites that could replace conventional materials such as wooden and gypsumpanels.

Jan 1, 2006

By Wang Zhi

High-Mg-content concentrates are usually treated in Jinchuan flash smelting Furnace. Because the viscosities of high-Mg-content slag is very high, the operation of flash smelting becomes very difficult. To solve this problem, the viscosities of the semi-synthesized FeO-MgO-Si02 slag of different compositions were measured. The results showed that when in the slag the weight percentage of MgO [m(Mgo)] is 6-10%, the ratio of the weight percentage of iron to that of Si02, m(Fe)/m(SiO2) is 1.1-1.4 and the temperatures are within 1473?1773K, the slag viscosities increased with the increase of m(Mgo) and m(Fe)/m(sio,). When m(Mgo)<6%, the smelting temperature should be controlled at I 300°C in order to to keep the smooth operation. When m(Mgo» 10%, the temperature should be kept above 1633K. When the content of MgO is higher, a lower viscosity slag ean be produced by decreasing the ratio of m(Fe)/m(sio,). The appropriate ratio of m(Fe)/m(sio,) for Jinchuan flash smelting furnace is about 1.2.

Jan 1, 2003

By Wellington Pereira Inácio, Fernando Wypych, Sergio Neves Monteiro, Artur Camposo Pereira, Rafael Marangoni

"The efficiency by which an applied load is transmitted from the matrix to reinforcing fibers in a composite depends on the fiber/matrix adhesion strength. This is determined as the interfacial shear strength, IFSS, which may be measured by means of pullout tests that measure the force needed to pull a single fiber out of a block of material simulating the composite matrix. Different techniques are used to perform pullout tests. The objective of this work was to characterize the IFSS of sisal fibers embedded in epoxy matrix through the determination of the critical length pullout curves. As the main results, a relatively small critical length was found for the sisal fiber/epoxy pullout specimens, corresponding to a weaker IFSS. This was compared to other results applying different pullout techniques. Scanning electron microscopy observation identified the mechanism responsible for the weak sisal fiber adhesion to the epoxy matrix.IntroductionSynthetic fiber reinforced composites is today one of the most successful class of materials with increasing industrial applications from house appliances to large airplanes like the modem Airbus 380. However, environmental issues are revealing serious drawbacks related to the fabrication, use and post-use discard of these composites. For instance, the thermoset polymer composite reinforced with E-glass fiber, known as ""fiberglass"" has an energy-intensive fabrication associated with a surplus emission of C02, which is responsible for global warming [1]. Moreover, the glass fiber is considered toxic and also causes long term pollution after being discarded."

Jan 1, 2011

By Manis Kumar Jha, D. D. Pathak, Archana Kumari

Treatment of secondary/waste to recover rare earth metals (REMs) is gaining importance due to its increasing global demand, lack of availability of high grade natural resources and huge generation of secondaries. Present paper reports the critical review on available processes for recovery of REMs from secondaries viz. manufacturing scraps, e-waste, industrial residues such as red mud, fly ash, waste water, etc. Hydrometallurgical processes with combination of Beneficiation/ Pyro-/Electro techniques are discussed to recover REMs effectively. The recommended processes require less energy to deliver high purity yield which is one step towards green environment. Salient findings on various methods are reported with recommendations which will be helpful to researchers working in the area of REMs extraction.

Mar 1, 2018

By Art Cooper

Granulation systems are common in the metals industry. The process of granulating slags, mattes and metals is more than a century old, and a number of different systems have been developed to accomplish this task. These systems have followed an evolutionary path, and may be characterized by common elements in terms of molten material handling, granulation methods and post-granulation processing. This paper will summarize the more common systems used in the metals industry, with particular reference to non-ferrous applications.

Jan 1, 2006

By Youliang He

Twin-roll casting is an integrated casting and rolling process that involves the continuous solidification of a melt and the plastic deformation of the solidified metal between two rotating rolls. Computer modeling is a valuable tool to help engineers understand the metallurgical process during twin-roll casting. However, commercially available software can only model either the fluid flow/heat transfer of the melt or the plastic deformation of the solid, but not both. In this study, an object-oriented finite element program was developed to simulate the steady-state fluid flow, solidification and plastic deformation of an A7,31 magnesium alloy in a horizontal twin-roll caster. The melt, the mush zone and the solid were treated as a generalized Newtonian flow in an Eulerian reference frame and different constitutive equations were employed to describe the material behaviours. The effect of operational parameters on the solidification process was discussed based on the simulation results.

Jan 1, 2010

By Hongyang Cao

The iron constituents selectively separated from the modified copper slags by magnetic separation and flotation.were studied. The results of magnetic separation for modified copper smelting slags show that the grinding size, current intensity and dispersant agent had great influence on grade, and recovery ratio of TFe in preparation concentrate; The results of flotation for magnetic concentrate show that the positive flotation of sodium oleate negatively upgrade the grade of magnetic concentrate, but the reverse flotation of lauryl amine and soluble starch are effective. The grade of TFe can reach 54% and the recovery ratio can reach about 90% in magnetic concentrate, when the grinding size is 45.8µm and the current intensity is 2.5A. The optimal effect is obtained by using lauryl amine as collector and soluble starch as depressant to reverse flotate magnetic concentrate, and the grade of TFe is upgraded 2.37%.

Jan 1, 2009

Achieving continued economic growth with social equity within the natural limits of the Earth&apos;s &apos;eco-systems is the major issue facing the world today. The material and energy needs of the world cannot be met with the current ways of addressing this issue. The need for metals, an important class of materials, will continue into the future because their unique properties make substitution by other materials impossible in many applications and this need will continue to be met from primary metal production and recycling. However, the recycling rate will increase and the usage pattern of metals will change to reflect the environmental impact of their production and use. Pyrometallurgy has an important role in meeting the metal needs of the future since some metals can only be produced pyrometallurgically; the energy required to produce some metals pyrometallurgically is significantly less than by other methods; most metals are most efficiently recycled pyrometallurgically; and the release of harmful and toxic elements into the biosphere can sometimes best be controlled through pyrometallurgical processing. The development of strategies for pyrometallurgical processing for the future lies in the recognition that sustainable development calls for large step improvements in value delivered per unit of environmental impact over the entire supply chain. Pyrometallurgists can respond to this challenge by contributing to reducing the environmental impact of meeting metal needs using three broad strategies: "end-of-pipe" approaches to convert emissions into benign materials for storage or disposal; flowsheet redesign to limit or eliminate emission production; and improved recycling technologies. A number of examples are discussed to illustrate how the sustainability driver is already influencing the technological development of pyrometallurgical processes, and how these will develop further as the sustainability driver strengthens.

Jan 1, 2003

By Varadarajan Seshadri

A physical model based on similarity principles was constructed for simulating the RH degasser of CST (Companhia Siderurgica Tubarao, Vitoria, ES, Brazil) to evaluate the circulation rate of the metal which essentially defines the degree of exposure of the metal to vacuum in the chamber and thus of the refining rate, The circulation rate on the other hand will influence the decarburization rate and removal of dissolved gases like nitrogen and hence it is essential to optimise this parameter to get maximum refining efficiency with minimum refining times, thus improving the productivity of the secondary refining process. Mixing characteristics in the ladle is evaluated by pulse tracer addition using conductivity-meters located at the down leg as well as at several locations in the ladle. The influence of gas injection through nozzles in the upleg with simultaneous bottom injection of gas as well as nozzle blockage on the circulation rates were investigated. Also simulation experiments of kinetics of decarburization were carried out using CO2 adsorption-desorption process in sodium hydroxide solution as circulating fluid and the effect of, bottom gas flow rate in this case was also evaluated. The results were carried over to prototype and to optimize the process.

Jan 1, 2003

By P. N. Anyalebechi

The effects of a cross-hatched grooved mold surface topography, casting speed, and superheat on the morphology of solidifying shells of aluminum alloy 3003 have been characterized by a series of immersion tests. The cross-hatched grooves were 0.232 mm deep with wavelength or spacing between 1 mm and 15 mm. The shells solidified at casting speed of less than 10 mm/s on the 1 mm spaced cross-hatched grooved mold surface were fairly uniform with little or no localized variations in thickness. However, the propensity for non-uniform shell growth morphology was exacerbated by an increase in casting speed, melt superheat, and the wavelength of the cross-hatched grooves. This is provisionally attributed to their effects on interfacial heat transfer and wetting of the mold surface by the molten metal.

Jan 1, 2008