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By G. Gabra, M. Nagamori, J. J. Panneton

"RESUMELa calcination contrôlée de 10 serpentine permet de produire de 10 magnésie active. Le degré de I'activation est mesure par 10 solubilité du magnésium dans les acides faibles tel que I'acide acétique, La serpentine contenue dans les résidus d'amiante du Québec peut donc être activée par calcination. Le teneur en magnésie active des rejets d'amiante calcinés est fonction de divers paramètres: température, temps de calcination, granulométrie, etc. Les rejets d'amiante de différentes provenances démontrent des comportements thermochimiques différents qui sont étudiés dans Ie présent travail au moyen d'ATD, de TG, de la diffraction des rayons X et de la lixivation par l'acide acétique. On constate qu'un maximum d'environ 80% de la magnésie totale peut être activé dans certains rejets d'amiante du Québec et Ie degré d'activation dépend de la provenance.vIntroductionOn sait depuis longtemps que la serpentine, Mg3Si2O5(OH)4, un silicate hydroxylé de magnésium, devient amorphe lorsqu'elle perd de I'eau d'hydratation entre 600 et 700 °C. La serpentine ainsi calcinée est alors dissociée en magnésie et en silice. Cette magnésie, dite active, est soluble dans un acide faible ou même dans les solutions de sels d'ammonium.Plusieurs precédés chimiques ont été proposés afin d'extraire sous forme de composés magnésiens la magnésie de la serpentine. La plupart de ces procédés comportent une activation par calcination de la serpentine préalablement à une Iixiviation par un acide ou par une solution d'un sel d'ammonium.Malgré la contamination par Ie fer et par d'autres éléments, les compositions chimiques des rejets de différentes mines d 'amiante du Québec, présentées au tableau 1, sont très proches de la serpentine typique. Puisque Ie degré d'activation de la magnésie varie grandement d'une serpentine à I'autre lors de la calcination, la première étape de la recherche sur la transformation chimique des rejets d'amiante du Québec se résume à une étude de leurs comportements thermochimiques."

Jan 1, 1982

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

In this work, a new flotation strategy was proposed for the flotation of rutile. In this strategy, rutile was activated by Pb(NO3)2 and then floated with amyl xanthate (AX) as a collector at pH 8. Pb(OH)+ was the dominant lead species in the solution at pH 8 and is believed to be the major species reacting with the rutile surface. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) study revealed that the lead activation products were well distributed on the rutile surface, and AX− could further bind with the Pb atom on the Pb-activated rutile surface. In this regard, the Pb-activated rutile could be floated by AX. Furthermore, X-ray photoelectron spectroscopy (XPS) analysis indicated that Pb(OH)2 was generated on the Pb-activated rutile surface. The electron transfer during the adsorption of the AX− on the Pb-activated rutile surface was also investigated by XPS analysis.

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

In this work, a new flotation strategy was proposed for the flotation of rutile. In this strategy, rutile was activated by Pb(NO3)2 and then floated with amyl xanthate (AX) as a collector at pH 8. Pb(OH)+ was the dominant lead species in the solution at pH 8 and is believed to be the major species reacting with the rutile surface. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) study revealed that the lead activation products were well distributed on the rutile surface, and AX− could further bind with the Pb atom on the Pb-activated rutile surface. In this regard, the Pb-activated rutile could be floated by AX. Furthermore, X-ray photoelectron spectroscopy (XPS) analysis indicated that Pb(OH)2 was generated on the Pb-activated rutile surface. The electron transfer during the adsorption of the AX− on the Pb-activated rutile surface was also investigated by XPS analysis.

By M. Hao, S. Hu, X. Lyu, M. Lian, C. Anning, G. Yao, Z. Wang

The results revealed that the pozzolanic activity of the gold mine tailings and their main mineral phases improved by mechanical activation. Under the same activation conditions, the activated mica powders possessed the highest pozzolanic activity index, followed by the activated feldspar, and the activated quartz exhibited the lowest pozzolanic activity index. The addition of calcium oxide promoted the formation of amorphous C–(A)–S–H gel for all paste samples, and stratlingite and hydrotalcite were observed in calcium oxide activated mica paste. The addition of natural anhydrite promoted the formation of ettringite for the pastes of calcium oxide activated aluminosilicates materials (gold mine tailings, mica, and feldspar). Furthermore, the pozzolanic activity indexes of the mechanically activated gold mine tailings and their main mineral phases were tested to be qualified for use as supplementary cementitious material in cement. This paper provided an innovative approach for recycling gold mine tailings as supplementary cementitious materials in cement, which would be environmentally friendly and cost-effective. Keywords: Mechanical activation, gold mine tailings, supplementary cementitious material, hydration properties, pozzolanic activity

Jan 1, 2020

By T. Qiu

"The purpose of this study is to investigate the effect of the dosage of sodium hypochlorite as activator on the flotations of depressed marmatite and depressed chalcopyrite, with a focus on activation-flotation kinetics. Four flotation kinetic models were applied to test data using 1stOpt statistical analysis software to estimate the relationships between the maximum flotation recovery rates for the depressed marmatite and depressed chalcopyrite, the flotation rate constants and the sodium hypochlorite dosages. Within the range investigated, the highest flotation performances of depressed marmatite and depressed chalcopyrite were obtained at 2.5 mL/L sodium hypochlorite with zinc recovery rate of 93.8 percent and 3 mL/L sodium hypochlorite with copper recovery rate of 94.6 percent, respectively, after four minutes of flotation. A second-order model with rectangular distribution of flotabilities gave the best fit to test data collected at various sodium hypochlorite dosages. For the highest flotation performances of depressed marmatite and depressed chalcopyrite, the respective equations of their flotation models were derived and presented.IntroductionCyanidation tailings are the solid residues generated by gold plants that use cyanide to extract gold (Lv, Ding and Qian, 2015; Zhang, Li and Yu, 2013). Because of increasing demand for gold, the Chinese gold industry has developed rapidly, with production amounting to 451.799 tons in 2014, an increase of 5.5 percent from 2013. Chinese gold production has been the highest in the world for eight consecutive years. As a result, more than 2.45 million tons of cyanidation tailings are estimated to be discharged into tailings ponds every year (Li et al., 2010; Lv, Ding and Qian et al., 2015; Wang et al., 2015; Zhang, Li and Yu, 2013; Zhang, Li and Yu, 2012), and approximately 300 million tons of cyanide tailings are stockpiled in China, with the potential to cause serious environmental pollution as well as death to wildlife (Adams and Lloyd, 2008; Donato et al., 2007; Hewitt, Breuer and Jeffery, 2012; Velasquez-Lopez et al., 2011; Stephen et al., 2009; Zagury, Oudjehani and Deschenes, 2004). Concerns over cyanidation tailings are not exclusively environmental but also economic, as tailings occupy considerable land area, and tailings storage facilities increase the production costs of gold enterprises (Donato et al., 2007). Tailings often contain other valuable metals such as zinc, lead and copper. For example, the cyanidation tailings of Gaoyao Hetai Gold Plant in Guangdong Province contain 2.5 percent copper (Cu), 0.31 percent lead (Pb), 0.23 percent zinc (Zn) and 15.36 percent iron (Fe) (Shi, 2008), and the tailings of Tianshui Gold Plant in Gansu Province contain 1.94 percent Cu, 5.96 percent Pb, 0.27 percent Zn and 24.62 percent Fe. Cyanidation tailings have therefore been increasingly viewed as a secondary resource rather than waste."

Jan 1, 2016

By Alejandro Uribe-Salas, Fabiola Nava-Alonso, Gloria Dávila-Pulido

This paper presents results of an experimental study performed on the role of calcium sulfate present in flotation water on sphalerite flotation in the Pb/Cu circuit (non Cu-activated sphalerite) and in the Zn circuit (Cu-activated sphalerite). In the Pb/Cu circuit calcium ions adsorb on the negatively-charged sphalerite favoring xanthate adsorption and therefore making sphalerite floatable; experimental measurements show sphalerite contact angle increases with calcium concentration while xanthate adsorption onto sphalerite increases with the increase of pH and calcium concentration. Gypsum (CaSO4·2H2O) eventually present due to calcium sulfate precipitation is not detrimental to flotation at this stage since it is negatively charged at pH 9 and therefore, does not adhere onto the surface of negatively-charged sphalerite. In the zinc circuit, Cu-activated sphalerite decreases its negative charge (or even becomes positively charged) and develops some hydrophobicity due to the polysulfide produced by Cu-activation. At this stage calcium ions do not interact with the mineral surface and therefore do not favor xanthate adsorption; nevertheless, precipitated gypsum particles do adhere onto the mineral surface, greatly affecting its floatability (e.g., contact angle). Addition of sodium carbonate to dissolve gypsum and to precipitate calcium as calcium carbonate, which disperses in the bulk of the suspension, effectively restores mineral hydrophobicity. SEM observations coupled with EDS analysis clearly illustrate and support the above sequence of events.

Jan 1, 2014

Active geothermal fields show many of the characteristics seen in hydrothermal ore deposits but there are important differences as well. There are, for example, many differences in geology and chemistry between individual geothermal fields, even some nearby, and these include variations in host rock types (volcanic, sedimentary, plutonic and metamorphic), structures controlling fluid flow (normal, lateral, and, rarely, reverse faulting occur) and hydrological setting (valleys to elevated terrain).

Jan 1, 1986

By R A. Lynch

The state-of-the-art in cave seismic monitoring is reviewed, with the latest developments in active seismic monitoring included. Seismic monitoring systems are routinely used by most of the world’s block and panel caving mines to track the cave initiation and progression. The current best practice is to use the cloud of seismic event locations as a proxy for cave growth somewhere below. Problems with event location reliability due to seismic ray bending around the (unknown) cave are side-stepped by using sensors installed above the cave. However, the aseismic gap – the (unknown) distance between actual cave back and seismic event cloud – currently hinders reliable estimation of cave geometry.Velocity inversions using the passive seismic data are inexpensive and should be undertaken more routinely. The straight-ray methods should be used with caution, as the underlying assumptions are invalid in caving environments. The double-difference method is more correct for the caving situation, and there have been some promising results published. Constrained geometric inversions make a lot of sense, but have yet to be demonstrated successfully.Two active seismic source have recently been developed for use in the caving environment: a piezoelectric source for ranges up to a few hundred metres and a pneumatically-powered source for ranges up to a kilometre. These sources produce signals on standard mine seismic sensors that can be used to measure seismic velocity variations down to 0.01 per cent resolution. This allows the cave progression to be monitored by measuring tiny changes to seismic velocities as the rock above the cave is fractured and destressed.CITATION:Lynch, R A, 2016. Active and passive seismic monitoring of cave front evolution, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 217–224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Mark C. Malamphy

MAJOR JUAREZ TAVORA, who recently accepted the post of Minister of Agriculture in Brazil, has reorganized his department. Not least among those sub: divisions of the "Ministerio" which underwent radical changes in the general reform was the Serviqo Geologico e Mineralogico do Brasil. This well- known organization was declared extinct, and in its place was created a new cleparttnent ' termed "Departamento Nacional cle Producqao Mineral," which immediately took over all the work of the olcl Servico Geologico ill addition to certain new duties. Dr. .. Domingos Fleury- da Rocha, former head of the School of Mines of Ouro Preto, was called to Xio to assume the newly created post of Director General of the department of Mineral Production. His department will have live divisions :

Jan 1, 1934

By A Späth

Active explosion barriers are used to contain and suppress a methane gas and/or coal dust explosion propagation, including localised mine fires. Early research indicated that these active explosion barriers could be used on a mechanised cutting machine, making it the only technology that could suppress an explosion during its propagation phase at the cutting face. Thereby not only adding protection during mining operations but also reducing the development of toxic gases, fatal temperature increase and fatal overpressure build-up. During their evolution over the last two decades, further advantages of Active explosion barriers were proven in mine operations in countries such as South Africa and China. Characteristics such as effectivity, efficiency, mobility and space restrictions allow these systems to be used in various locations within a mine operation, including highwall operations. This improved technology contribution to safer coal mining was recognised by mine operators, workers and regulators. The Queensland’s Recognised Standard 21 (Resources Safety and Health Queensland (RSHQ), 2021) stipulated active explosion barriers as a technology to ensure the safety within their underground coalmines. The mobility and flexible implementation of the active explosion barriers allow a feasible and practical solution for all critical locations for explosion and fire management in an underground coalmine. The conformance to the Recognised Standard can be achieved all underground coal mining operations such as Bord and Pillar, and Longwall mining. This paper describes the conformance, implementation and use of Active explosion barriers for Longwall mining and development as well as Bord and Pillar mining in Queensland’s underground coalmines.

Oct 12, 2022

By G E. Holt

Active EM subsurface imaging is a proprietary technique developed by Marschall Acoustics Instruments Pty Limited (MAI) to image subsurface features at depths useful for the mining industry. Similar in field operations to high resolution seismic surveying, the Active EM technique employs electromagnetic energy rather than elastic wave energy. Received backscattered energy in the Active EM technique is thus due to differences and contrasts in electromagnetic permeability and permittivity in the subsurface, analogous to LamTÆs constants in elastic wave imaging. Carrying the analogy to seismic imaging even further, the Active EM method employs high power transmissions of very wide-band coded signals of a controlled polarisation. Likewise, the array pattern and polarisation of the receiving transducers is also tightly controlled. Thus, in a certain mathematical sense, Active EM is the electromagnetic equivalent of high power high resolution vibroseis seismic surveying. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Martin B. Hudson, Andrew K. Cho, Rolff B. Knobel, Les R. Chernauskas, Jonathan L. Ernst

ABSTRACT The Bruce Museum, located in Greenwich, Connecticut, is home to an extensive display of art and natural history exhibitions. A large addition was designed to be constructed adjacent to the museum requiring new spread footings to be installed up to 16.5 feet below the existing foundations. The soil conditions at the site consist of highly variable sand and gravel overlying weathered rock and sound bedrock. The Contract Documents called for traditional foundation underpinning. Traditional underpinning techniques, however, presented two major challenges on this Project; (1) deep underpinning pits would be required involving multiple levels and staging with tieback support and (2) the highly variable soil and bedrock composition and elevations presented uncertainty in the design and construction of the pits. In lieu of traditional underpinning, Geosciences Testing and Research, Inc. (GTR) proposed an “active” soil nail underpinning system. A major reason that the soil nail underpinning option was feasible, related to the fact that the soil nails and facing could be installed slightly in front of the existing footings rather than directly underneath the existing footings. The soil nail wall design involved one to four rows of soil nails with nail positions and wall depth able to be adjusted “on the fly” as excavation progressed depending on the field conditions encountered. To create the “active system,” the soil nails were pre-loaded to mitigate wall deformations that would be associated with a standard passive soil nail wall design. To evaluate the performance of the active soil nail wall and confirm design assumptions, an extensive automated monitoring, on-site testing and inspection program was proposed and executed by GTR to monitor deformations of the wall and the museum in real-time, evaluate and confirm bedrock and soil bond stresses and ensure that each soil nail was pre-loaded and locked off. Careful analysis, planning, and use of the observational method illustrates the importance of collaboration between design and construction personnel and applying engineering judgement throughout construction. The use of the observational method includes the potential for modifying design based on conditions observed. This paper presents a unique case study of the “active” soil nail underpinning system to support and protect sensitive structures, close collaboration between design and construction facilitated by real-time deformation monitoring, and its successful application as a safe and cost-effective alternative to traditional underpinning.

Oct 1, 2022

By Camilo Ferreira, Franco Olcese

Hay intensos debates respecto a los impactos de la minería en sobre el desarrollo de las comunidades en su entorno. Inclusive existen corrientes ideológicas que consideran que la minería empobrece y amenaza la salud de las comunidades en su entorno. En esta investigación evaluamos la medida en la cual exista evidencia que sustente estas posturas. Estimamos el impacto de la minería a nivel de los distritos del Perú, tanto mediante el canon como por el valor de la producción minera, sobre el índice de desarrollo humano, ingreso familiar per cápita y esperanza de vida.

Sep 30, 2022

By Georg Petersen

El presente artículo describe la actividad petrolera realizada durante el año 1962. En 1863 el Gobierno del Perú derogó al Ing. A. E. Prentice el estudio de las posibilidades petroleras de Piura y Tumbes, a través de la perforación del primer pozo de petróleo en Zorritos a través de herramientas imperfectas. Ante tal éxito, en 1864 Lama y Rudens gestionaron que se constituya en Nueva York la "Compañía Peruana de Petróleo". Posteriormente, doce compañías petroleras han desarrolado trabajos de exploración y nueve se encuentran en estado de producción. En este plano tenemos a Belcom Petroleum Corporation Perú, Cerro de Pasco Company, Empresa Petrolera Fiscal, Compañía peruana de Petróleo "El Oriente", International Petroleum Company, Mobil Oil Company, Mobil Oil Company of Perú, Compañía de petróleo Ganso Azul, Peruvian, entre otros.

Jul 1, 1963

By Georg Petersen

El presente artículo describe la actividad petrolera realizada durante el año 1962. En 1863 el Gobierno del Perú derogó al Ing. A. E. Prentice el estudio de las posibilidades petroleras de Piura y Tumbes, a través de la perforación del primer pozo de petróleo en Zorritos a través de herramientas imperfectas. Ante tal éxito, en 1864 Lama y Rudens gestionaron que se constituya en Nueva York la "Compañía Peruana de Petróleo". Posteriormente, doce compañías petroleras han desarrolado trabajos de exploración y nueve se encuentran en estado de producción. En este plano tenemos a Belcom Petroleum Corporation Perú, Cerro de Pasco Company, Empresa Petrolera Fiscal, Compañía peruana de Petróleo "El Oriente", International Petroleum Company, Mobil Oil Company, Mobil Oil Company of Perú, Compañía de petróleo Ganso Azul, Peruvian, entre otros.

Jul 1, 1963

By Shigeatsu Nakazawa

Activities of Bi and In in the Bi-In liquid alloy were measured over the whole range of eomposition at the temperatures from 850K to 1050K. An alloy was vaeuum-sealed in a quartz cell and heated at the temperature of interest. The absorption for 307nm radiation from Bi lamp was measured for Bi atom vapor in the cell. By heating a pure metal as a standard and measuring the absorbance as a function of the temperature, an analytical curve for Bi atom vapor was constructed and used for conversion of the absorbance to the vapor density. Bi activity was determined as the ratio of the Bi atom vapor density over the alloy to that over a pure metal. The same procedure was applied to the In 304nm radiation from In lamp and In activity was determined independently of Bi. Results showed that the liquid Bi-In system behaves like a regular solution.

Jan 1, 2003

By Shigeatsu Nakazawa

Activities of Bi and In in the Bi-In liquid alloy were measured over the whole range of composition at the temperatures from 850K to 1050K. An alloy was vacuum-sealed in a quartz cell and heated at the temperature of interest. The absorption for 307nm radiation from Bi lamp was measured for Bi atom vapor in the cell. By heating a pure metal as a standard and measuring the absorbance as a function of the temperature, an analytical curve for Bi atom vapor was constructed and used for conversion of the absorbance to the vapor density. Bi activity was determined as the ratio of the Bi atom vapor density over the alloy to that over a pure metal. The same procedure was applied to the In 304nm radiation from In lamp and In activity was determined independently of Bi. Results showed that the liquid Bi-In system behaves like a regular solution.

Jan 1, 2003

By K Saito, M Hasegawa

In steelmaking processes, it is known that P2O5 in dephosphorisation slags often exists in solid solutions between Ca2SiO4 and Ca3P2O8, <C2S-C3P>SS, and thus the solid solutions play an important role in the dephosphorisation reaction. Hence, the knowledge of thermochemical properties, ie phase relations and activities of components, in slags containing <C2S-C3P>SS are necessary for the effective removal of phosphorus from hot metal. In this study, the P2O5 activities in <C2S-C3P>SS were measured through the gas equilibrium method. In the present experiment, oxide samples were equilibrated with Cu-P liquid alloys at 1573 K under a stream of Ar + H2 + H2O or Ar + H2 + CO2 gas mixture in which oxygen potential was fixed and then equilibrium phosphorus concentrations in the Cu-P alloys, [mass%P]Cu, were analysed with ICP-OES.

Aug 21, 2024

By S. Sun

The equilibrium distribution of Cu, Fe and Ni between Cu-Ni-Fe mattes and Pt alloy was measured as functions of the sulphur partial pressure (pS2), oxygen partial pressure (pO2),temperature and Fe content of the matte. The distribution ratios of Cu, Fe and Ni between matte and alloy were independent of oxygen pressure when the pS2was fixed at 2.5x10-5atm and pO2was varied between 10-15and 10-12atm. The distribution ratio of Cu, Fe and Ni increased as the sulphur partial pressure increased. The Cu and Ni distribution ratios decreased with increasing temperature and the Fe distribution ratio increased slightly over the temperature range of1350?1500°C. For mattes where the proportions of Cu and Ni were kept constant, the distribution ratio of Cu increased as the Fe content in the matte increased. The Fe and Ni distribution appeared to be independent of the iron content in the matte and had a value of 1.2 and 1.6 respectively. The activity of Cu, Fe, Ni in the matte was calculated using a regular solution model for solid Pt-Fe-Ni-Cu alloy. The activity coefficient of Cu, Fe and Ni decreased as pO2and pS2increased.The activity coefficients also appeared to be independent of the Fe content and temperature over the range of 36 to 54 wt% iron and 1350 to 1500°C respectively. Keywords: activity, alloy, matte, thermodynamics

Jan 1, 2004

By Grigore Matei

The thermodynamic properties of CU2S-FeS system are important not only in the case of copper smelting but also in the case of general pyro-mctallurgy, However there are not many reported activity data In this study, activities of FeS and CU2S in the CU2S-FeS system were calculated using the Darken&apos;s method from the activity data of the CU2S-FeS-Sb2SJ systems measured by the transportation method at 10S0°C. The activities of CU2S and FeS in the CU2S-FeS system showed negative deviation from the ideal behaviour and satisfied the relation of the Gibbs-Duhem equation,

Jan 1, 2003