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By Liang Sha

In this study, adsorption of copper by chemically modified orange peel was investigated. A conspicuous change occurs in the surface morphology of the biomass due to modification, which is depicted by SEM images. Equilibrium isotherms and kinetics were obtained and the effects of various factors, including solution pH, contact time, initial metal ions concentration and temperature, were studied by batch experiments. Kinetics was found to be best-fit pseudosecond- order equations. Equilibrium was better described by Langermuir isotherms rather than Freudlich isotherms. At 25?, pH5.30, the maximum adsorption capacity was 70.67mg?g-1 . With increase of temperature, adsorption efficiency decreased. The biosorbent was suitable for repeated use for more than five cycles.

Jan 1, 2009

By Pietro Navarra

A great deal of effort has been expended on how to optimize conventional water cooling circuits in furnace cooling elements, and the results have been largely satisfactory. However, there is a general agreement that the proximity of high-pressure water passages to the flow of molten furnace products is a safety concern. Nonetheless there exists little alternative to the formula: increasing furnace integrity implies the incorporation of more extensive forced-convection water cooling systems. Recent developments in evaporative cooling technology have resulted in the development of a high-capacity heat pipe capable of operating under the thermally intense environments of a metallurgical furnace. The system functions using several kg of a working fluid (water) in total, has no moving parts, and allows for a significant reduction in cooling water requirements. Full-scale pilot tests of a copper tap hole and slag launder were done in 2003 and2005, with detailed results given in this paper.

Jan 1, 2006

By Tian Sugui

By direct aging treated, creep properties measurement and microstructure observation, the influences of the direct aging treatment on the creep behaviors of Hot Continuous Rolled GH4169 superalloy are investigated. Results show that the creep resistance of Hot Continuous Rolled GH4169 superalloy may be obviously improved by directly aged treatment. Under the applied stress of 700MPa at 660, the creep lifetime of the alloy is enhanced to 126h from 60h. During hot continuous rolling, the deformation features of the alloy are the twinning and the double orientations slipping of the dislocation activated within the twinning regions. After direct aging treated, the alloy displays a smaller grain size, and the finer g² phase is dispersedly precipitated in the matrix of the alloy, which is thought to be a main reason of enhancing creep lifetime of the alloy.

Jan 1, 2010

By M. Faraji

Inclusions formed in a high-carbon, manganese-silicon killed plain steel (Fe-0.77C wt%) were studied. Various techniques were used to characterise the inclusions, and the latter were classified according to their chemical composition, size and morphology. The main constituent elements entering the inclusions were Mn, S, Al, and oxygen. Alongside MnS and some Al2O3 inclusions many non-metallic inclusions appeared in complex forms, consisting of silicates, sulphides and oxides. Duplex oxy-sulphides, mainly MnS combined with Al2O3, or SiO2 were the most common complex multiphase inclusions in this steel. The nanoindentation technique was used to assess and rate different types of inclusions and data of the hardness and elastic modulus of individual inclusions at room temperature are presented.

Jan 1, 2010

By Nam-Il Um

Bottom ash contains several ferrous materials (ferrous metals, Fe3O4, Fe2O3, FeS, etc.). In particular, ferrous metals contain heavy metal because Ni and Cr are chemically attracted to iron. Likewise, Cu is used to coat Ni and Cr metals as polish or to prevent corrosion. In this study, an Fe3O4-Fe2O3 double layer (similar to pure Fe) was found to have been formed in ferrous metal during air-annealing in an incinerator (1000°C). A strong thermal shock such as one that occurs during the water-cooling of bottom ash results in the breakdown of this oxidation layer, facilitating the degradation of ferrous metals and formation of corrosion products. Therefore, Fe-ion (heavy metal) oxides may be formed on ferrous metals and may be separated from bottom ash via magnetic separation. This study sought to investigate the separation ratio of heavy metals as magnetic separation and mineralogical formation of Fe-ion (heavy metal).

Jan 1, 2006

By M. Hochenhofer

Due to economic aspects and environmental regulations recycling of slag and waste from ferroalloy production became a very important issue for the companies during the last years. The treatment of slag depends prior on the composition, especially on their content of valuable metals and impurities. The final aim should be a total re-use of these materials in the industry e.g. cement industry, pig-iron production etc.. Therefore, to reach the required physical and chemical properties for a further use, possibilities of a metallurgical treatment have been investigated. The conditioning of slag with a high V-, Mo- and P-content via reducing metal bath showed to be one alternative. To determine the optimal process parameters, practical investigations with different slag compositions and thermodynamic calculations were carried out.

Jan 1, 2006

By Xiaowen Liu

The thermal decomposition of diaspore was investigated by thermogravimetry (TG),differential scanning calorimetry (DSC), X-ray power diffraction(XRD),infrared (IR)spectrain this paper. The thermal decomposition mechanism of diaspore was discussed according to Coat-Redfer equation. It was found that the decomposition of diaspore was carried out at 500?,and the peak temperature was 530?. The electrovalent balance of diaspore was destroyed. The previous crystal structure was changed. a- Al2O3 was obtained after thermal decomposition. The activation energy is 287KJ/mol.

Jan 1, 2006

By Tian Sugui

By means of the measurement of the enduring property and microstructure observation, an investigation has been made into the influences of the element Re and TCP phase on the enduring property of the single crystal nickel base superalloys. Results show that the needle-like TCP phase is precipitated along the <110> orientation on {111} planes in Re-containing/free superalloys during the long term aging, the TCP phase is identified as µ phase, and the precipitated µ phase in 4.5%Re alloy is gradually spheroidized during aging. Thereinto, the needle-like µ phase may obviously decrease the enduring lifetimes of the alloys due to the consumption of the refractory elements and the effect of the stress concentration. But the stress concentration is not easily generated in the regions near the spherical-like µ phase, which is a main reason of reducing the enduring lifetime of 4.5%Re alloy to a small extent.

Jan 1, 2010

By Varadarajan Seshadri

Geometallurgical characterization of iron ore which is a raw material for Iron making as in the case of charcoal blast furnaces operating in Brazil or for production of agglomerates such as iron ore sinter which serves as burden material for blast furnces of high productivity or pellets extensively used in the direct reduction processes all over the world in the iron and steel industry. Selection of proper raw material after due characterization should lead to an improvement of the productivity of the respective processes The usual classification of quality of iron ore is uniquely based on chemical analysis, granulometric and physical parameters. However not much emphasis has been given to the structural characteristics which also are important in the processes. Different typological categories of Brazilian iron ores have been used in the characterization . For instance, several kinds of hematite crystals like specularite, martite and microgranular hematite, etc with variable crystal sizes are found in the different ore types. They are also composed of different of fabrics and types of accessorial mineralogical constituents and have different porosities, pore diameters, etc which influence the cold and the hot agglomeration stages of the ore fines, and also chracteristics such as reducibility, decrepitation etc, important for assessment of quality of iron ores. . The first step for attaining a good characterization of ores is to know in detail about the structure of the deposit, shape of the body, types of iron ores and their distribution. This requires a geological-structural study and the mapping of the bodies using mineralogical criteria for typological classification of ores. followed by structural characterization of materials in stages of mining, comminution, screening and concentration processes. In this contribution a geometallurgical approach for quality control of Brazilian iron ores for sintering and pelletizing processes is highligted.

Jan 1, 2006

By Xiaofei Guan, Adam C. Powell, Uday B. Pal, Srikanth Gopalan

This paper reports a solid oxide membrane (SOM) electrolysis experiment using an LSM– Inconel inert anode current collector for production of Mg and O2 at 1423K. The electrochemical performance of the SOM cell was evaluated by using various electrochemical techniques including electrochemical impedance spectroscopy, potentiodynamic scans, and potentiostatic electrolysis. The effects of Mg solubility in the flux on the current efficiency and the YSZ membrane stability during SOM electrolysis were discussed and examined through experiment and modeling. The electronic transference number of the flux were measured to assess the Mg dissolution in the flux during SOM electrolysis. A negative correlation between the electronic transference number of the flux and the current efficiency of the SOM electrolysis was observed.

Jan 1, 2014

By Wolfgang Van Hooff

Encouraged by a strongly growing and evolving market for granulated products, Paul Wurth continuously improves its granulation and dewatering technologies to provide customers with state of the art installations. Continuously developed know-how about the granulation process of iron blast furnace slag enabled application to non-ferrous materials such as Ni-Slag, Pb-Slag, Blister Copper, Cu-Matte and even TiO2-Slag, which rank among the most difficult materials to granulate. This paper identifies how critical objectives in granulation and dewatering technologies applied to different molten materials with respect to various product quality objectives can be addressed. The differences between hot and cold water granulation systems are explained, including the step from cold runner to granulation water tank. Development of a flow and pressure controlled blowing box is the latest step to optimize the granulation process in order to meet the latest standards in terms of quality, power consumption and environmental protection.

Jan 1, 2006

By Holger Cordes

X-ray diffraction has long been used for qualitative and quantitative mineral analysis but Rietveld data analysis is still an under utilized method for mineral exploration and processing applications. In this full-profile approach the structural parameters of each mineral phase, together with experimental parameters, are refined by least-squares methods to minimize the difference between observed and calculated diffraction patterns. The result is a standard-less, quantitative analysis of the mineral abundance in the sample that is more accurate and considerably faster compared to traditional methods. The TOPAS software package combines a user-friendly interface with a unique approach to resolve overlapping peaks. Automated analysis options are also available and significantly reduce analysis time for routine samples. Several examples on a wide range of naturally occurring rock types are shown that illustrate the capabilities and limitations of the method. The examples include several options for the quantification of amorphous constituents like volcanic glasses.

Jan 1, 2006

By Guomin Jiang

Potassium ferrate is an excellent multifunctional reagent for wastewater treatment, but its preparation is crucial. The improved hypochlorite oxidation method was used to prepare potassium ferrate in this study. Iron nitrate, the preferred iron source, was added into hypochlorite solution and then the stabilization agent was added during the purification process of product. The influence of available chlorine content, iron molecular proportion, reaction temperature and reaction time on potassium ferrate preparation was investigated. The optimal condition for potassium ferrate preparation is 15% of available chlorine content , 0.6 of iron molecular proportion , 30i of reaction temperature , 45min of reaction time. The yield of potassium ferrate is about 67% with high purity (> 99%). The structure and performances of the product was characterized by XRD, EDX, SEM, TG and IR and the results show that the prepared product is consistent with the properties of potassium ferrate(VI).

Jan 1, 2010

By Sergio Neves Monteiro

The efficiency by which an applied load is transmitted through the composite structure depends on the strength of the interface between the matrix and the second phase. In fiber reinforced composites, the interfacial shear stress plays a major role in the composite capacity to support the applied load. This interfacial stress can be obtained by means of pullout tests using the fiber embedded to a certain length in a socket of the matrix material. In the present work, pullout tests were performed to evaluate the interfacial shear stress of ramie, a relatively strong natural fiber, reinforcing polyester matrix composites. The general result permitted to calculate a critical length for the ramie fiber embedded in polyester resin. From this critical length, the value of the interfacial shear stress was calculated. An interpretation of this result together with SEM observation displayed a relatively weak bond between the ramie fiber and the polyester matrix.

Jan 1, 2010

By Hugo Cabrera-Real

This work investigated the chemical and mineralogical properties of CaO-SiO2-CrOx-CaF2- MgO slags. Synthetic slags were prepared and the effect of the slag basicity (CaO/SiO2) and MgO contents on the stability of the mineralogical species formed was analyzed. The morphology and composition of the slags were analyzed by XRD and SEM-EDS, whilst their chemical stability was evaluated by leaching with an aqueous acetic acid solution. It was found that in slags with CaO/SiO2 = 1, the main Cr-compound was MgCr2O4 spinel, which forms octahedron crystals. Small amounts of CaCr2O4 and CaCrO4 were also observed. It was found that increasing the slag basicity from 1 to 2 the compounds MgCr2O4 and CaCr2O4 were formed together with the Cr(V)-containing compound complex Ca5(CrO4)3F which forms hexagonal crystals. The results showed that the highest chromium concentration levels in the leaching liquors corresponded to slags with CaO/SiO2 = 2, probably owing to the formation of Ca5(CrO4)3F.

Jan 1, 2010

By Sergio Neves Monteiro

In the present work, a ceramic foam elaborated with illitic clays was characterized. Properties related to density and compression strength were determined in samples fired at 1300oC, a temperature that permits the clay structure to generate and retain gases that will produce the foamy structure. The microstructure of the ceramic foam was studied by X-ray diffraction, scanning electron microscopy and mercury porosimetry. The results showed that the ceramic foam presents a bulk density of 0.38 g/cm3. The microstructure is formed by large open pores, quartz particles and vitreous phase.

Jan 1, 2006

By Michael P. Sudbury

Non-ferrous slags are granulated and stockpiled as an alternative to pit cooling or transporting molten slag to a dump. The chemical composition of such slag is determined by the pyrometallurgical process in which it is produced, while the size distribution is set by safety concerns or a desire to reduce wear of pumps, pipelines and other equipment. Relatively few operations give consideration to the effect of granulation conditions on other properties of the granulate as the material is typically accumulated on the smelter site. It is becoming recognized that slag has many potential commercial uses and carries much of the energy applied to the smelting operation. This paper outlines the findings of extensive work to identify uses for granulated non-ferrous slag, the importance of preparation conditions on the properties, impediments to more extensive use of granulated slag, the real costs of slag stockpiling and the opportunities for further productive research.

Jan 1, 2006

By Elli Nurminen

In this work the thermodynamics of the metallic sulphate decomposition reactions were studied through thermodynamical calculations and thermogravimetric methods. The decomposition temperatures and mechanisms were determined for cupric sulphate, ferric sulphate and also for industrial flue dust from a copper flash smelting process. The aim was to determine the thermodynamic conditions for sulphate decomposition and to estimate whether the reactions are kinetically likely to take place in the flash smelting process heat recovery equipment. The information is essential in CFD-modelling of the reactions taking place in the boiler and for optimising the process.

Jan 1, 2006

By Esher Hsu

In Taiwan, around 8,000 tons of batteries are consumed per year but only 17% of which were collected and transported to oversea for recovery. The dumping used batteries have become a potential environment problem. How to increase the collection efficiency of used batteries is an important issue for EPA in Taiwan. Besides, some treatment plants are on process to get permission for recovering used batteries. The objective of this study is to estimate the recycling cost of spent consumer battery and explore the feasibility of recovering used consumer batteries in Taiwan based upon the principle of cost-efficiency. The recycling cost including collection cost and recovery is estimated based on a survey. Results would provide some suggestions to Taiwan EPA regarding feasibility of recovering used batteries in Taiwan.

Jan 1, 2006

By Keith S. McIntosh

The fire assay process for the quantitative recovery of platinum group elements (PGE?s) prior to subsequent analysis traditionally is a time-consuming process. Samples derive from various ore types and contain PGE?s at the ppm or ppb levels, making concentration of the elements mandatory before assaying. Traditionally sample turn-around times are of the order of 24 hours. The whole sequence of sample preparation, fire assay and subsequent analysis of PGE?s have been automated by Anglo Platinum. Some of the major challenges on the road to automation will be discussed and the novel solutions that were implemented. The engineered solution included robotic automation of the whole sequence, from sample preparation, up to the final element by element assay. The final system allowed for rapid (less than one hour) and accurate analysis of PGE?s even in streams containing very low levels, such as flotation tailing streams and drill core samples.

Jan 1, 2006