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By A. S. Macfarlane

Western Deep Levels (North) is a deeplevel, longwall gold mine. Severe strata control problems and high rates of elastic closure, resulting in high rates of energy release, are associated with mining at depths of up to 3 500 metres. To assist in controlling these aspects of mine design and safety, a waste backfilling system has been designed and commissioned. The integration of such a system into an existing, producing longwall brings many problems of logistics, organization, planning and control. It is the purpose of this paper to examine these aspects of fill management, and to describe some of the practical problems involved with the integration of this project into the mining environment. Although many of the rock mechanics and soil mechanics aspects of backfilling systems are common there are specific problems involved which apply to longwall systems. Very strict guidelines are required for planning personnel to design their backfilling systems for a particular situation. These aspects are examined, and basic models developed which can be used without the necessity of comprehensive input from rock mechanics. A summary of the financial implications is included, and these are examined with regard to possible future applications and expansion of waste filling.

Jan 1, 1988

NIM reports Report No. 1615 Fluorspar pellets. A survey of the world market and an assessment of future South African production. Report No. 1621 Correction for matrix effects in the analysis of solutions by X-ray-fiuorescence spectrometry. Notices Questionnaire on Technicians The Department of National Education's committee of enquiry into the education, training, utilization, and status of engineering technicians in the Republic of South Africa was established as a result of Resolution 6.3 taken at the Sixth Conference on Engineering Education: The Education and Training of Engineering Technicians. Vraelys oor Tegnici Die Departement van Nasionale Opvoeding se komitee wat ondersoek instel na die opleiding, gebruik en status van ingenieurstegnici in die Republiek van Suid-Afrika is gestig as gevolg van Besluit 6.3 wat geneem is tydens die Sesde Konferensie oor Ingenieursopleiding: Die Opleiding van Ingenieurstegnici. Competition for Student Members of the South African Institute of Mining and Metallurgy Each year the Institute offers a prize (or prizes should the entries warrant it) of up to R100 for the best paper or dissertation on a topic appropriate to the interests of the Institute. The competition is open to all Student Members of the Institute.

Jan 8, 1974

By A. G. Ramsay, P. G. Kahles, L. E. Kun

A method for the clarification of uranium pregnant solutions using a high-rate floc blanket was developed from laboratory scale through pilot-plant testing to full-scale production by the Anglo American Research laboratories. A two-stage clarification process (hopper plus leaf) was commissioned at the Western Deep levels uranium plant in October 1980. The high efficiency of the hopper clarification permitted its use on its own. The leaf clarifiers were therefore taken out of service in September 1981, since when the secondary clarification is achieved by further unaided gravity settling in the semi-clarified and clarified pregnant-solution storage tanks. As a result, a daily 12000 to 17000 t of countercurrent-decantation overflow with a suspended-solids concentration of 500 to 600 mg/I is continuously clarified to a suspended-solids concentration of less than 30 mg/I. Secondary gravity settling reduces the suspendedsolids concentration to under 20 mg/I. The cost of the single-stage hopper-clarification process is RO,O020per ton of liquid treated. The removal of the leaf clarifiers from the circuit resulted in an approximate visible saving of RI00000 per annum.

Jan 1, 1983

Notices TRANSPORTATION AND THE ENVIRO NMENT The 5th Quinquennial Convention of the S.A. Institution of Civil Engineers will take place at the Carlton Centre, Johannesburg, from 20th to 24th August, 1973. ENVIRONMENTAL ENGINEERING A conference on environmental engineering problems in industrialized and developing countries is to be held at the United Engineering Centre, New York, on 19th and 20th September, 1973. RABCEWICZ-COLLOQUY The Austrian Society for Geomechanics is to honour Professor Ladislaus V. Rabcewicz, on the occasion of his 80th birthday, with a meeting in Salzburg Congress Hall on 11th and 12th October, 1973. The themes of the four half-day sessions will be as follows. PYRO MET ALL URG ICAL EVENTS IN 1974 Diisseldorf is to be the venue for the following three events: International Iron and Steel Congress O.F.S. Branch Welkom THE MARCH GENERAL MEETING OF THE BRANCH WAS HELD IN THE ST. HELENA CLUB AT 8.00 P.M. ON TUESDAY, 6TH MARCH, 1973 O.F.S. Branch Welkom MINUTES OF A GENERAL MEETING HELD IN THE ST. HELENA CLUB ON WEDNESDAY, 16TH MAY, 1973, AT 8.00 P.M.

By H. S. Sichel, Kleingeld

A frequency distribution model plays a fundamental role in ore evaluation, especially for the feasibility study of new deep gold mines. The geological complexity of the reefs being mined at present in the Witwatersrand basin poses some difficulties regarding the modeling of the underlying ore-value distribution. This geological complexity has given rise to a need for more applicable distributional models. This paper places the geology of the Witwatersrand basin in perspective and draws some important conclusions from the genesis of the deposition. In addition to the three-parameter lognormal model, two more-general distributional models are proposed. These are the compound lognormal (CLD) and log-generalized inverse Gaussian (LN-GIG) distributions. A detailed, although preliminary, comparative study of these two more-general models with the three-parameter lognormal model is described, and the efficiencies of the estimates and modeling are analysed. It is found that the broad assumption that gold grades follow a three-parameter lognormal law is not always the case, and the need to test for departures from log normality should be emphasized so as to ensure the use of appropriate models.

Jan 1, 1992

By Austin Whillier, Duncan Mitchell

The problem of heat stress underground in the gold mines is approached on the basis of the heat transfer between the human body and the underground environment. Experimental measurements of radiant and convective heat transfer and a theoretical calculation of maximum evaporative heat transfer enable the maximum cooling power of an environment to be calculated in terms of the dry-bulb and wet-bulb temperature, the mean radiant temperature, the wind speed and the barometric pressure. For most underground applications the cooling power can be expressed as a function of wet-bulb temperature and wind speed only. The relative importance of wind speed and wet-bulb temperature can be assessed: in working places where wind speed is low additional cooling of workmen can be achieved better by increased wind speed than by decreased wet-bulb temperature. The wet kata reading proves to be of limited value as an index of heat stress because environments with equal wet kata do not necessarily have the same cooling power. Finally, thermal equilibrium with the environment is possible when cooling power equals or exceeds the rate of metabolic heat generation. The rates of metabolic heat generation for various underground tasks are indicated.

Contribution by G. Narsimhan It was with much pleasure that I went through D.F. Malan's excellent paper. The following explanatory and critical note has been the result of my deep study of the paper. Although by qualifications and experience I have been a chemical engineer, involved over four decades with problems in the modeling and simulation of transport-limited (heat and mass) chemical reactions in multi-phase systems, I have of and on interested myself in challenging problems in extractive metallurgy. This is the first time I have veered of to continuum mechanics, at the age of 71! Author's reply. I thank Professor Narsimhan for his extensive contribution to the paper. It provided me with the stimulus to derive an extended model. However, there are some inaccuracies in his arguments that need further discussion. Professor Narsimhan's main concern is that there is not a good enough fit between the derived viscoelastic Kelvin model and the experimental data supplied by Güler1 (see Figure l1 on page 218 of my paper). I will therefore explain the choice of a viscoelastic model in more detail and also make specific comments on the arguments given in his contribution.

Jan 1, 1996

By Isobel Clark

This paper reviews some of the traditional methods of reserves estimation based on lognormal distribution with or without an additive constant. In the rush to computerize mine planning and grade control generaly, proven estimation methods, such as Sichel's t, seem to have been overlooked. By use of a personal microcomputer, the traditional methods were investigated thoroughly, the results being tested against existing tables and figures. The fitting of a lognormal distribution, including estimation of the additive constant, is discussed, and the calculation of Sichel's t estimator and its associated confidence limits is described in detail. Payability calculations for a lognormal distribution are also covered briefly. The advantages of personal computers, particularly speed and ease of use, are emphasized. This low-cost approach permits detailed investigation of some of the assumptions and approximations inherent in the established methods of calculation. Several disturbing discrepancies are revealed in various factors, and some generalized statements made by previous authors are found to be over-simplistic. Full details are given of acceptable approximations and computer algorithms, and concern is expressed over the possible loss of proven methods under the welter of new, sophisticated computer software.

Jan 1, 1987

By M. I. Brittan

SYNOPSIS The key reactions of the copper segregation process have been studied with a view to establishing the kinetics of the system. The investigation was carried out using two refractory copper ores from the Zambian Copperbelt in a small-scale, fluidized bed, chloridization reactor. The rate of chloridization of the copper in the ores is compared with the rate of volatilization of the cuprous chloride produced and with the rate of reduction of the cuprous chloride to form segregated metallic copper. In conjunction with available data on the rate of production of hydrogen chloride in a segregation system and with due regard to the conditions applicable in a TORCO reactor, it is concluded that the chloridization reaction is the major rate limiting step of the process. Factors influencing the rate of this extraction step and aspects of its mechanism are examined. The findings have confirmed the validity of the existing theory of segregation and provide insight as to the viability of the system of reactions involved in the copper segregation phenomenon. Experimental results which relate to observations made in the course of TORCO plant operation and segregation studies are discussed.

By J. P. Hugo

Nuclear energy - its interactions with mining and metallurgy - PRESIDENTIAL ADDRESS given by J. P. Hugo Pr. Eng., B.Sc (Eng.) (Rand), Ph.D. (Sheffield) Energy is the life blood of the modern technological era in which we live and it was, I think, Benjamin Franklin who said that the manipulation of energy was the basis of all science and technology. This is perhaps an oversimplification, but there can be little doubt that our life today, and the improved standard of living we aspire to, are governed almost entirely by our ability to generate and manipulate energy. This ability has made it possible for Man - each specimen a feeble twentieth of a horsepower - to travel to the moon, to recover valuable minerals from the depths of the earth, to do arithmetic at unbelievable speed, to lessen the drudgery of manual labour. For these and virtually every aspect of our life we are dependent on energy from external sources. It is, therefore, not surprising that the per capita consumption of energy, and more particularly electricity, has become one of the most reliable criteria by which to measure the standard of living and technological advancement of a country.

By A. J. Lynch, N. W. Johnson, D. J. McKee, G. C. Thorne

The behaviour of minerals in sulphide flotation processes, with reference to simulation and control. by A. J. LYNCH, Ph.D., N. W. JOHNSON, Ph.D., D. J. McKEE, Ph.D., and G. C. THORNE, B.Sc. (Hons.) (Visitors) In sulphide flotation processes, there are two mechanisms by which particles are transferred from the flotation pulp to the concentrate: adhesion to air bubbles and natural flotation, and entrainment in the froth. The entrainment mechanism is particularly important for particles of non-sulphide gangue, which do not absorb collector. The importance of controlling the recovery rate of water was illustrated in plant testwork in which selectivity between valuable sulphides and sulphide gangue, and between valuable sulphides and non-sulphide gangue, was altered by manipulation of variables affecting the water recovery rate. The two mechanisms should be recognized in the development of a control system. Most of the control schemes in operating plants have concentrated on reagent additions, which affect the natural flotation mechanism. Although control of the chemical environment is clearly of paramount importance in flotation, plant tests have shown that control of the variables affecting the entrainment mechanism is also important.

Jan 4, 1974

By R. Sun, R. G. Gillies, R. S. Sanders, J. Schaan

The pipeline transport of paste, backfill or thickened tailings slurries is an important component of the tailings disposal process in many mines around the world. These mixtures contain significant fractions of fine (clay) and coarse (sand) particles, causing them to exhibit non-Newtonian flow behaviour and high frictional pressure gradients. There is often economic incentive to operate these pipelines in the laminar flow regime. Irrefutable evidence has shown that coarse particle settling can occur during the laminar flow of these slurries even when static settling tests show no indication of such behaviour. Previously, a ?rule-of-thumb? minimum frictional pressure gradient of ~1.5 to 2 kPa/m was suggested to ensure effective sand transport, based on the results of tests conducted using viscous Newtonian oils. In this paper, we examine the results of laminar flow tests of non-Newtonian, coarse-particle laden slurries conducted with pipeline loops of 50, 100, 150 and 250 mm in diameter. The results indicate that the ratio of the mean wall shear stress to the mean surficial particle stress is abetter indicator of laminar flow settling tendency than frictional pressure gradient.

Jan 1, 2007

By D. Seke

Metal inventories are usually reported in financial statements of mining companies. However, the value of these inventories can be reliable only if the metals in stock are measured within acceptable tolerances. Reliable metal balancing requires accurate mass measurement, sampling, and chemical analysis. Many mining companies are usually unable to validate the accuracy of metals in inventories at the end of their financial year. This is mainly due to poor mass measurement, sampling, and chemical analysis practices. This has an adverse impact on metallurgical accounting and metal valuation. In addition, it puts a lot of stress on external auditors, who have the duty to recommend the approval of the financial statements to the board of directors. Although a full value chain of metal reconciliation includes the accuracy of Mineral Reserve definition and grade control at the mine, this paper discusses the implementation of best practices for mass measurement, sampling, and chemical analysis at processing plants. This is an important aspect of sampling and reconciliation that is required in order to improve the reporting of inventories in the financial statements of public mining companies. Keywords metallurgical accounting, corporate governance, sampling, analysis.

Jan 1, 2014

A banquet, attended by 467 members and visitors, was held at the Wanderers Club, Johannesburg, at 8 p.m. on Friday, 21st March, 1969, to celebrate the 75th Anniversary of the founding of the Institute. Introduction of Dr Carel de Wet R. C. J. Goode (President) Dames en here: Ons het 'n aantal vooraanstaande gaste in ons midde vanaand en mnr Maxwell sal u later meer van hulle vertel. Dit is my aangename plig om u voor te stel aan sy Edele, die Minister van Mynwese, van Beplanning, en van Gesondheid, Dr de Wet en sy gade, mev de Wet. Sy Edele Dr de Wet het geen bekendstelling nodig nie-alhoewel hy ons minister vir slegs die afgelope twee jaar is, het hy reeds talle funksies van ons Mynbedryf bygewoon en het baie vriende gemaak onder ons. Hy het homself baie bemind onder ons gemaak toe hy Wes-Driefontein onlangs besoek het om hulle ondersteuning en aanmoediging aan te bied in hulle uur van nood. The Honourable Dr de Wet was born in the Free State. He is a grandson of that very famous general Christiaan de Wet, who caused so much pain to the British forces and for so many months so successfully eluded them in the Transvaal and Orange Free State. He was educated at both the Pretoria and Witwatersrand Universities. He first practised medicine at Boksburg and then moved to Vanderbijlpark, so you see he has an early association with gold mining on the Witwatersrand, and in moving to the Vereeniging-Vanderbijlpark district he became closely involved in our coal mining and metallurgical industries. South Africa's first steel was poured from a l0-ton open hearth furnace belonging to the Union Steel Corporation in Vereeniging in 1913. Dr de Wet has been mayor of Vanderbijlpark and for several years has been their member of parliament. More recently, the Honourable Dr de Wet has filled with great honour that most important office of Ambassador for the Republic of South Africa in London. At present he wears two hats, in that he is Minister of Planning and of Health, but more important is his cloak, that of Minister of Mines, which I trust offers him the greatest comfort. To fulfill these three arduous tasks must demand of him a terrific devotion to duty, and in doing this he carries on that loyal tradition of service to his fatherland so evident in his grandfather. Dames en here, dit is vir my 'n groot genoeë om Sy Edele Dr de Wette vra om 'n heildronk in te stel op die Instituut vir Mynwese en Metallurgie. Toast to the Institute of Mining and Metallurgy Dr the Honourable C. de Wet (Minister of Mines): Mr President, ladies and gentlemen, Mr President you have introduced me gracefully to this distinguished company and I am appreciative of your remarks. I am fully conscious of the responsibilities that devolve upon me as Minister of Mines in a country where mining makes so vital a contribution to economic progress and development and has, in fact, laid much of the foundation on which our present proud edifice is built. The achievements of the mining and metallurgical industry in its diversified activities arouse feelings equivalent to paternal pride, but let me speedily add that in considering any family relationship that may exist, the Minister of Mines should not be regarded in the role either of a fairy godmother or an indulgent father.

Dr Hanekom I would like to thank Dr Hanekom for a very valuable -contribution; it summarizes careful statistical test work which was an omission from the original paper. Minor manipulative details, the application of a finer measuring graticule and the reproducibility of the procedure are described and the author accepts with gratitude this ready-made answer to the first and second points of Dr Finkelstein's comments. Mr Williamson The author is indebted to Mr Williamson for historical background to early experiments with captive bubbles and it is conceded that the original paper described another avenue to an old flotation goal. The field of application is restricted and we would not work with all the material illustrated by Klassen and Mokrousov.1 The particles in Figure 74(a) are far too large and irregular; material in Figures (b) through (d) could be employed for semi-quantitative work in spite of obvious disadvantages; Figure 74(f) represents ideal conditions. We have studied this mineral-collector association in the size range given and results were satisfactory. For larger pick-up values than that illustrated an induction period of more than 0.01 second was required (actually 90 seconds for a maximum bubble load at pH 7.2 with 25 g/t oleic acid!). REFERENCE 1. KLASSEN,V. I. ANDMOKROUSOV,V. A., 'An Introduction to the Theory of Flotation,' Butterworths, London, 128, Figure 74, (1963). Mr Slander and Mr Kooij Researchworkers in a practical mineral development laboratory may well ask what contribution yet another micro-technique can make to the problems of large scale ore flotation. The obvious answer is that there can be little or no direct translation of results obtained with a static system comprising air bubble and pure mineral concentrate to a dynamic multicomponent operation. However, for the rapid study of one mineral or variable some small scale apparatus must be employed. In the Anglo American Research Laboratory, the described semi-quantitative pick-up technique has filled a niche and requirement. For ourselves, the system represents a definite advance over the contact angle approach in that samples of minerals conventionally prepared in laboratory or plant may be used, which is a desired step nearer flotation. We bracket this pick-up apparatus with the Hallimond tube1,2 and evidence is now to hand that pick-up curves may often be related to flotation recoveries obtained from this tube with pure mineral samples and from the Fuerstenau glass cell3 with the total ore at low pulp densities. We would not wish to push the comparison of pick-up results past this stage for there is much published development work relating the Hallimond and Fuerstenau equipment to flotation on a larger scale. At the Anglo American Research Laboratory for example, a test in a Fuerstenau cell is often the final integrated step in laboratory investigations into the TORCO process. As these contributors rightly point out, pick-up tests can offer nothing towards the determination of optimum reagent dosage for large scale flotation. This is the function of bench-type flotation cells with up to 2 kg batches of ore. At this level, collector performance and consumption and physical properties of the froth are more comparable with large scale operation. The pick-up cell, Hallimond tube and Fuerstenau cell are essentially equipment from which the effect of control parameters can be derived. For the assessment of collector behaviour, the pick-up approach is rapid and economic and we offer here a pick-up contribution towards the flotation of Witwatersrand uraninite with anionic sulphonate collectors (Fig. 1). A large crystal of the local mineral was not available for contact angle measurements and owing to its low concentration in Witwatersrand gold-bearing reef, a small sample was laboriously obtained by tabling, superpanning and heavy medium separation. The pick-up values of a sized portion were determined by the described procedure in the presence of nine petroleum sulphonate collectors. Responses fell into two categories; "normal" curves (dotted lines) and a group of collectors which were very active at low concentration but showed depression of pick-up at the higher levels. The similarity in form of curves for collectors 1 and 3 was apparent and reagent 3 was found to be simply a diluent of 1. Otherwise, collector performance could not be related to either sulphonate content or molecular weight of the active constituent. However, reagent 2 gave the best performance in a bench flotation cell with regard to overall uranium distribution but, as predicted, reagent 1 yielded the best grades. Later pick-up tests with a similar class of collector have suggested that depression at high reagent concentrations may be due to "bubble armouring" whereby an hydrophilic air-liquid interface is produced which rejects mineral attachment. Prolonged investigations with the same mineral sample have not been required except for the study of uraninite which lasted for more than a year. Variation in pick-up response could not be detected over this period during which the mineral was stored under distilled water. The only visible change was a small efflorescence of lead sulphate, readily removed and decanted off after stirring with a glass rod in the sample tube. In its main role as a "trouble-shooter", the pick-up method is applied to fresh mineral samples taken from a flotation plant and soon discarded or from a current run in the ore-dressing laboratory. After production of a concentrate, a solvent cycle, as described in the original paper, may be required to remove heavy organics or other contaminants as when a sample has been taken from circuits containing detergents, grease or return flotation solutions. This solvent cycle will not remove chemisorbed collectors and we prefer not to work with minerals from flotation tailings or with pick-up cell discards. It has been thought preferable to answer the contributors' other apprehensions with regard to sample preparation, activators, depressants and the physical properties of reagents in another paper on offer to this Journal. It covers pick-up investigations relating to the flotation of nickeliferous pyrrhotite at two Anglo American Corporation Mines, which approach seemed the correct orientation for a reply to another contributor to this paper.

By S. M. Graham, G. Mellis

"The determination of the oxidation state(s) of an element present in a solid sample may be required for a number of reasons, including the assessment of the degree of reduction which has taken place during a multi-step production of a metal. In addition, possible flaws in a metal may result from small amounts of oxides included in the solid. The analyte of interest may be present as a major component of a sample of interest, or as a minor impurity - beneficial or requiring removal - in another matrix.Numerous methods have been established for the analysis of species in solution samples - for example, Fe2+ and Fe3+ by titration, Cr6+ by colourimetric means, etc. With appropriate knowledge of the solution being analysed, many of these methods are fairly straightforward, extremely reproducible and accurate. In those instances where the analyte in a solution is known to be in only one form, the analysis is even more straightforward, since it can be achieved instrumentally (by AAS, rCP-OES or rCP-MS, for example).However, the situation with respect to the analysis of solids is not as simple. Various techniques - such as X-ray diffraction - are routinely used by our mineralogists to obtain information about the various minerals present in solid samples, and thus about the oxidation states of the analyte elements present. However, these techniques usually give results that are qualitative, or semi-quantitative at best. They are also usually time-consuming and expensive. One of our colleagues at Mintek, Deshenthree Chetty, has done extensive work in developing a method for the quantification of manganese species in solids using mineralogical methods, and this is no small achievement."

Jan 1, 2014

By A. M. Venter

"SynopsisThe availability of advanced characterization techniques is integral to the development of advanced materials, not only during development phases, but in the manufactured components as well. At Necsa, two modern neutron diffractometers equipped with in-situ sample environments, as well as complementary X-ray diffraction instruments, are now available as User Facilities within the National System of Innovation in support of the South African research and industrial communities. Neutrons and X-rays, owing to their different interaction mechanisms with matter, offer complementary techniques for probing crystalline materials. Both techniques enable nondestructive investigation of phenomena such as chemical phase composition, residual stress, and texture (preferred crystallite orientation). More specifically, the superior penetration capabilities of thermal neutrons into most materials allows for the analysis of bulk or localized depth-resolved properties in a wide variety of materials and components. Materials that can be investigated include metals, alloys, composites, ceramics, and coated systems. In particular, depth-resolved analyses using neutron diffraction complements surface investigations using laboratory X-rays in many scientific and engineering topics. The diffraction techniques can add significant downstream value to the anticipated nuclear industry development activities.IntroductionMaterials characterization is central in understanding the relationship between the structure, properties, and performance in order to engineer materials that fit the performance criteria for specific applications. This is conveniently represented in the form of a tetrahedron, generally known as the material science paradigm (Figure 1).The availability of advanced characterization techniques is integral to the development of advanced metals, not only during development phases, but in the form of manufactured components. At Necsa (South African Nuclear Energy Corporation), modern X-ray and neutron diffraction instruments are now accessible to the South African research and industrial communities. These facilities enable nondestructive investigations of materials and components that could add significant downstream value to the anticipated nuclear industry development activities."

Jan 1, 2015

By T. Mahlangu Mahlangu, T. Fungene, K. C. Sole

"Although oxygen is widely employed as the oxidant of choice in gold leaching by cyanide, its low aqueous solubility presents some drawbacks in practical application; hydrogen peroxide has therefore been considered as a possible alternative. The aim of this investigation was to study the catalytic decomposition of hydrogen peroxide, which generates an oxidizing intermediate species, and to understand its effect on cyanide destruction. Operating conditions that facilitated the effective decomposition of hydrogen peroxide were established by varying the pH and catalyst type and concentration. The oxidizing intermediate, detected using an indirect technique, was found to be the hydroxyl radical (OH?). OH? is commonly generated in acidic solutions, but this work demonstrated that it is also produced at the alkaline pH values necessary for cyanide gold leaching. The effects of free and complexed iron and copper catalysts on the oxidation and consumption of hydrogen peroxide and cyanide were also investigated. It was shown that the cyano complexes of Fe(II) and Cu(I) are also effective as decomposition catalysts. Hydrogen peroxide concentrations above 0.01 M decreased the free cyanide concentration, which was attributed to the probable formation of the cyanate anion (CNO-). Although cyanide consumption increased due to its oxidation in the presence of OH?, excessive cyanide consumption in the presence of copper was attributed primarily to its complexation by the unstable copper(I) cyanide species. Rate constants for the decompositions of H2O2 and cyanide by ferrocyanide and copper cyanide were calculated; the latter was identified as being a better catalyst. IntroductionLeaching of gold from its ores using cyanide has been employed for well over a century (Habashi, 2016). Addition of cyanide converts the gold into a cyanide complex (Au(CN)2 -) that is soluble in water (Wang and Forssberg, 1990). The leaching reaction can be represented as Equation [1]:"

Dec 1, 2018

By I. V. Filippova, Y. Foucaud, M. Badawi, O. Barrès, L. O. Filippov, S. Lebègue

Sodium silicate (Na2SiO3) is one of the most common reagents used in the froth flotation process, in which it is an efficient dispersant as well as a powerful gangue minerals depressant. Due to its high affinity with a lot of minerals, mostly silicates, it adsorbs on their surfaces and prevents the adsorption of the collectors, maintaining them hydrophilic. Hence, Na2SiO3 is widely used in the flotation separation of rare earth minerals, zinc minerals, iron minerals, scheelite, fluorite, apatite, and many other minerals. For decades, authors have demonstrated higher efficiency of Na2SiO3 when it is used in combination with sodium carbonate (Na2CO3), a common pH regulator. Among many well-known depressants, this system presented the best efficiency for many ores, including the Tabuaço scheelitebearing skarn studied herein. However, the mechanisms resulting in these strong positive synergistic effects are not well understood at the moment. Hence, the response surface methodology (RSM) was applied to this ore, considered as a case study, to optimize the depressing conditions and to study deeply the flotation behavior of this system. Strong synergistic effects between the two reagents were exhibited by the RSM, mostly affecting the scheelite, fluorite, and calcium-bearing silicates recoveries. This was attributed to surface carbonation of the minerals by Na2CO3, subsequently leading to a better depression by Na2SiO3. Overall, a 1:1 ratio between the two reagents displayed the best results in terms of WO3 grade and recovery. To gain understanding in the molecular mechanisms responsible for the aforementioned synergistic effects, FTIR studies were combined with state-of-the-art molecular modelling (Ab Initio Molecular Dynamics at 300 K) on fluorite, an archetype of calcium minerals. Keywords: Synergistic effects, scheelite, depressants, FTIR, DFT calculations

Jan 1, 2020

By W. P. Nel

A fuel cell is an electrochemical engine that converts the chemical energy of a fuel, such as hydrogen, and an oxidant, such as oxygen, directly into electricity. The emerging fuel cell industry may represent a major opportunity for the global platinum mining industry. This is because low temperature fuel cell systems use platinum group metals as catalysts. Fuel cell vehicles may become the most important driver of future platinum demand within years of their commercialization. A great number of factors impact on and drive the diffusion of fuel cell vehicle innovation. Such drivers range from energy security to environmental concerns and the technological development of fuel cells and systems. Such factors and drivers of fuel cell vehicle diffusion are combined with the generic ?body of knowledge? on ?technology forecasting? and ?diffusion of innovation? to design a framework that provides a holistic approach to the analysis of this complex enterprise. An attempt is made in this paper to address the following questions: Which types of fuel cells require platinum group metals? Which types of fuel cells will achieve dominant design status? Will fuel cell vehicles diffuse successfully? How big will the impact of successful fuel cell vehicle diffusion be on future platinum demand? How well do fuel cell vehicles compete with incumbent technologies such as spark-ignited and compression-ignited internal combustion engine-driven vehicles? How soon will oil depletion start to drive the diffusion of fuel cell vehicles? How important is hydrogen as a fuel? What impact does the inadequate hydrogen fuelling infrastructure have on fuel cell vehicle diffusion? The paper contains some initial results of a research project that has the aim of producing a schedule of future platinum demand generated from fuel cell vehicles. Keywords: diffusion of fuel cell vehicles, technology forecasting, platinum demand forecasting.

Jan 1, 2004