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By J R. Leeming

The paper describes a technique that has been developed by the Health and Safety Executive (USE) to make an assessment of the effectiveness of Health and Safety (H and S) management at complex sites. The paper then describes how the technique was adapted and used for the first time at a large coal mine. The results highlighted certain deficiencies in the safety management system, allowing directed advice to he given to management.

Jan 4, 1997

By G. G. Barbante

Anode slimes produced during copper electrorefining are a valuable source of silver, gold, selenium and tellurium. The conventional pyrometallurgical process for treating slimes involves preliminary leaching in sulphuric acid followed by smelting in a reverberatory furnace with fluxes, but it is slow and has many recycle streams. The chemistry of the phases and the reactions that occur in slimes smelting are poorly understood and and this prevents major improvements to the process. Laboratory-scale experiments were conducted using unleached slimes, with and without the addition of fluxes and under neutral, oxidising and reducing conditions. Results show that selenium is readily removed as gaseous selenium dioxide and that molten Cu-Ag-Se-O phases form when fluxes are added. Oxidation-refining of these phases by air injection and flux addition can result in the formation of silver suitable for further electrorefining

Aug 1, 1995

During a programme to determine the suitability of the UK site for deep disposal of radioactive wastes, geostatistical methods were used to characterise rock heterogeneity on the basis of seismic and wireline acoustic-impedance data. The data were analysed to yield semi-variogram models that quantified the three-dimensional spatial heterogeneity of acoustic impedance. These models were reconciled with geological interpretations of the area and used to generate simulations of acoustic impedance, with wireline acoustic impedance as conditioning data. The three-dimensional simulated images were compared with actual seismic acoustic impedance. The variography confirmed a vertical zoning effect in the Borrowdale Volcanics, showing that it is caused by preferential clusters of high acoustic impedance values corresponding to regions of relatively low porosity. The method provided realistic three-dimensional models from sparse, one-dimensional wireline data

Jun 19, 1905

By J. H. Morris, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Oxygen isotope analysis indicates that quartz, carbonates and muscovite could all have formed in near-isotopic equilibrium with the mildly saline H2O-CO2 ore fluid at 330 degrees C. Calculated values for O, C and S in the ore fluids imply derivation from a deep, homogeneous source region and are consistent with formation either as a direct or an indirect result of igneous processes. Values for delta-O18 plot a little outside the accepted magmatic range, but have almost certainly been modified by exchange reactions with wall rocks. These reactions were also the most likely cause of deposition of the ore constituents. The chemical and isotopic character of the fluid was similar to that in many Archaean and later mesothermal auriferous vein systems, especially the Mother Lode region of California. If the Southern Uplands-Longford Down accretionary complex conceals an Ordovician arc, the tectonic setting was also broadly comparable

Jun 19, 1905

By L. E. Mordberg, E. N. Nesterova

Geochemical studies of the bauxite deposits show that the primary composition is gibbsitic. Some trace elements were relatively mobile during bauxite formation with the content of Th, U and Zr increasing and that of Rb, Ni and Co decreasing. Y and Pb were relatively immobile during lateritisation; their contents and ratios were inherited from different types of underlying rocks. The supply of Ni and Co took place at the diagenetic or epigenetic stages; their ultimate source was the crystalline basement in the region. The studies support the view that the bauxite was likely to have originated as a result of in-situ lateritisation and not through sedimentary transport and redeposition

Jun 18, 1905

By F. T. Da Silva

Concentrates of titaniferous minerals containing around 30 wt% Ta2O5 are processed hydrometallurgically by hydrofluoric acid leaching and solvent extraction, followed by the precipitation of hydrated potassium heptafluorotantalate. A fundamental study of the thermodynamics of this precipitation and recrystallisation was undertaken to increase understanding of the conditions most conducive to the production of pure, well-crystallised K2TaF7. Activity-pH diagrams for the Ta-K-F-H2O system explained the dissolution of Ta2O5 in fluoride solutions quite well and also the precipitation-recrystallisation of K2TaF7.H2O. X-ray diffraction and scanning electron microscopy confirmed the thermodynamic observations. It was concluded that the best precipitating agent for K2TaF7 from fluoride solutions is KF but a recrystallisation step in a HF environment produces purer, well-crystallised K2TaF7.H2O, eliminating oxy-salts and other impurities

Jun 21, 1905

The reduction of zinc from slags by a molten, carbon-saturated bath was examined in a laboratory study under conditions of continuous slag feeding. The results show that it is possible to reduce the bulk of the zinc from the slag before there is a net reduction of iron. However, the recovery of zinc was not as high as in batch tests performed in an earlier study. Lead in the slag was reduced simultaneously with the zinc to very low levels and was volatilised. Copper in the slag was reduced and dissolved in the alloy. An attempt was made to identify potentially commercial ways of treating zinc slags using an iron bath. The approaches that appear to have the greatest potential are reduction in a batch process using electrical heating and reduction in a continuous process with co- or countercurrent flow of the slag and alloy. In the latter the alloy would be prepared in a separate furnace before being contacted with the slag. The purpose of this would be to superheat and carburise the alloy so that no additional heat or reductant would have to be supplied in the slag-alloy reactor

Jul 1, 1991

By G. S. Camm

Gwynfynydd is a small, high-grade black shale-hosted vein-gold deposit. The Chidlaw Link Zone is the only area being mined and contains 24 000 t ore grading 15.2 g/t gold. Within the Link Zone a complex vein structure occurs consisting of a mother vein up to 5 m thick and narrow (less than 0.5 m) leader veins. The former shows minor variations in dip, strike and thickness, whereas the latter show marked changes in all three. The leader veins are hosted within the footwall zone of the mother vein and both are composed of quartz with galena, sphalerite, chalcopyrite, pyrite and minor arsenopyrite. The vein system is transected by a series of cross-vein and intra-vein dip-slip faults. Pockets of gold occur at vein intersections or branches and within the complex footwall zone and are often related to variations in vein attitude and/or geometry. The Chidlaw Link Zone displays a complex, erratic distribution of gold mineralisation and a multi-stage history of structural activity, fluid flow and mineral deposition

Jun 18, 1905

By J. A. Hudson, D. L. Millar

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993 (original title: Rock engineering system performance monitoring using neural networks.) Synthetic and analytical approaches to objective-based design of rock engineering projects are discussed. Rock masses are considered as complex dynamic systems with components that concurrently interact with each other and their environment. The existence of a rock engineering system canon (i.e. a set of systems governing rules) is proposed. Its possible components are highlighted and an application is demonstrated using a "rock mass automaton" designed to simulate dynamic heat distribution in rock. In the example given, the canon implements the basic result from probability theory applied to the thermodynamics of solids. Rock engineering system performance is reduced to the mapping of the output of a rockmass to varying input (design) options, within the state space of the systems model. The Kohonen Self-Organising Map provides an extremely useful analytical tool to reduce the hyper-dimensionality of rock engineering system behaviour. Further, the hyper-dimensional state vector is mapped "quasiconformally" such that the neural map tends to spatially organise similar input state vectors, facilitating interpretation of rock engineering system behaviour (performance monitoring). Work is reported on the development and validation of the automation as a basis for an internal representation of the rock mass bahaviour. The results are reported of simulations compensating for the uncertainty of the exact mechanisms operating within the rock mass, using additive noise with the input state vector in the training stages of the self-organising map implementation. Initial work on adopting Grossberg's Adaptive Resonance Theory neural network architecture for classification of rock engineering systems behaviour is also presented

Apr 1, 1994

By Xiao Min You, D. R. Swonbourne

Smelting of Cu anode slimes involves the use of a slag to hold the oxidised Cu, but some Ag is also inevitably oxidised to the slag. The solubility of Ag in sodium silicate slags at 1 100 and 1 150 degrees C has now been determined over a very wide range of oxygen partial pressures. Silver was found to be present in the slags both as neutral atoms and as AgO(0.5). The activity coefficient for atomic Ag was a very strong function of slag composition and temperature, whereas that for AgO(0.5) was much less affected by slag composition and was almost independent of temperature over the limited range examined. The results reveal that the dissolved Ag cannot be fully recovered by reduction of the slag with very reducing gases

Jun 21, 1905

By G. W. Harris, J. J. K. Daemen

Slightly shorter, modified version also published in CIM Bull., vol.94, no.1047, Feb. 2001, p.52-55. To minimise ore dilution induced by blast movement in surface mines it is necessary to quantify such movement. This will allow more accurate location of the grade boundaries on the surface of a blasted rock pile before excavation. A method has been developed and tested for measuring accurately the direction and magnitude of subsurface blast movement, using a caesium vapour gradiometer and a real-time, differentially corrected global positioning system to locate the pre- and post-blast positions of magnetically enhanced target objects placed in blastholes inside a bench. The procedure does not necessitate disturbance of the blasted rock and the movement information is available sufficiently quickly to allow for modification of the selective mining boundaries for each surveyed blast. It was found that the maximum depth of target detection was 18 m and the overall accuracy was plus or minus 1 m horizontally and 1.2 m vertically

Jun 21, 1905

By N. Krauland, A. Nystrom, M. Board, S. Sandstrom

Several deep Swedish cut-and-fill mines experience severe ground control problems, including roof collapse and wall sloughing, as a result of variable rock quality and high in situ stresses. A project to examine the problem included two main areas. The first was prediction of mining conditions at depth and the adaptation of cut-and-fill mining to such conditions; the second was the assessment and improvement of support methods at present and future depths. Simple, elastic, mine-scale numerical models were used to optimise stope sequencing and more detailed, stope-scale models to simulate the failure processes around a stope and the interaction of rock mass and support. Kristineberg was chosen for testing and calibration of the predictive methods because of its long history of severe ground conditions and the large base of observational and monitoring data available for comparison. Horizontal cut and fill was found technically suitable to depths beyond 1 000 m and economically viable if ore value covers support costs. Stability can be achieved with the present support technology down to 1 000 m but the 7-strand 15.2 mm cables have poor deformation properties (5% failure strain) compared with rebar rock bolts (17%). Reducing the intervals between levels from 100 m to 50 m will cut support costs and improve production reliability and capacity. Simulation of sill-pillar mining indicated that conditions would be most severe when pillar height was reduced to 15-20 m; mining of a sill pillar has been carried out successfully to the last 3 m, whose extraction is planned for the near future

Dec 1, 1995

By S. P. Mishra, G. R. Chaudhury

The adsorption of Cu2+ ions by Penicillium sp. displayed a dual rate, with an initial faster phase followed by a slower one. The adsorption rate increased with increasing pH due to chemical and biochemical reactions. The Cu-loading capacity of the biomass increased at higher initial Cu2+ concentrations. Above 40 degrees C the adsorption rate decreased which may be due to partial hydrolysis of biopolymers which are essential constituents of the cell wall. Adsorption kinetics followed the Freundlich isotherm and the equilibrium concentration that was calculated on the basis of the isotherm matched the observed value well. A series of theoretical adsorption curves were produced using mathematical correlations between the mass transfer coefficient, the Cu2+ ion concentration at equilibrium and at time t. The correlation between the theoretical and observed adsorption rates for different experimental conditions was good. It was concluded that the results from the study were best explained using a mass-transfer adsorption model

Aug 1, 1995

By L. T. Isaacs, W. H. Traves

A numerical model for analysing the drainage of fill in mine stopes has been described. The model can be used to analyse the process of fill drainage in existing and proposed mine stopes. The validity and potential value of the model have been established by experience with a simpler, 2-dimensional numerical model and by testing the new model against the earlier model. The new model is more useful than the 2-dimensional model because it allows for heterogeneity of fill material within the stope - a factor that has been demonstrated to affect drainage characteristics significantly. The 3-dimensional model is also capable of predicting pore pressures and drainage rates at specific locations in the stope without the need to resort to 2-dimensional generalisations. Such information, integrated with relevant field data as they become available, will provide valuable mine planning information for the scheduling of filling operations and design of fill mixes

May 1, 1991

By M. Moinpour, Y. K. Rao

The catalysed direct reduction of copper sulphide with carbon and lime was investigated in the range 850-1000 degrees C using Cu2S-CaO-C and Cu2S-4CaO-4C reaction mixtures. The effects of the catalytic additives K2CO3, Li2CO3, Na2CO3, NaF, Na2SO3 and the ternary eutectic (K,Li,Na)2CO3 were determined. Potassium carbonate, sodium fluoride and the ternary appear to be the most effective catalysts for the direct reduction process. The rate enhancement of the catalysed carbothermic reduction of copper sulphide in the presence of lime was explained in terms of the catalysis of the Boudouard reaction

Jul 1, 1991

By I. L. Bell

The ironmasters of America had asked the Iron and Steel Institute to visit the USA. The Council decided it was not possible to accept, but Mr. Bell visited; this is an account of his trip. Topics covered include transport, charcoal, coal measures, coal, anthracite, bituminous coal, flux, magnetic iron ore, specular iron ore, limonite, red hematite, clay ironstone, black band ironstone, smelting works, blast furnaces of Pennsylvania, Lake Champlain furnaces, Lake Superior furnaces, Cleveland furnaces, Pittsburg furnaces, Missouri furnaces, and those of the southern states. He goes on to describe Catalan hearths, malleable iron works, Bessemer works, the Blair steel process, and labour.

Jan 12, 1875

By I. R. Hanby

A simple solution to the problem of whether to round the calculated number of trucks up or down to the nearest whole number is to adopt as criterion the minimum cost per unit volume/mass moved, assuming all trucks in the fleet are of the same type. When the effects on journey time of varying haul-road slope are calculated for several rolling resistances, it is shown that the optimum angle of 7.5 degrees is moderately independent of both rolling resistance and height climbed; the lower the resistance, the lower the sensitivity to ramp angle, but if haul-road gradients do not exceed 1 in 10 (5.7 degrees) for safety reasons then travelling time will never be more than 7% greater than its theoretical minimum. Further calculations result in a graph of the maximum payload values to incur the minimum cost, for different values of total effective resistance

Jan 1, 1991

By Evans E. C.

At first sight, the extinction of a mine fire by the action of some such gas as carbon dioxide would appear to be quite a simple and practicable operation. From a consideration of the theoretical aspects only of the question, it becomes evident that the matter is not so simple as it appears to be at first sight. The fire at the Senghenydd Colliery occurred as the result of the disastrous explosion of October 14th, 1913. This explosion was confined to the west side of the colliery; and as a result the timbers in the main intake on this side were set on fire; but these were soon buried beneath falls, and the tire continued under them. Attempts were made to extinguish it with water, with the aid of chemical extinguishers, and by digging it out; hut these had to he abandoned, and ultimately the fire-zone was sealed off by “ bashings” (stoppings). By December, progress in the decrease of combustion was so slow that it was decided to try the effect of inert gas. The installation, control and operation of the carbon dioxide plant and associated water-gauge are described in detail and conclusions drawn for the extinguishing of mine fires by CO2

Dec 1, 1916

By J Parnell, B Manson

Bitumen occurs in the basins in reservoir sandstones, in veinlets close to hydrocarbon source rocks, in veins through lava beds and in sulphide-mineralised veins where it is closely associated with, but predates, the sulphides. The role of organic matter was probably in enhancing metal reduction by creating a low-Eh environment rather than in metal transport. Coeval euhedral quartz crystals or albite in sulphide-bearing carbonate veins provide evidence of an aqueous component to the hydrocarbon fluid

Aug 1, 1995

By C. J. A. Mcewan, C. M. Rice

The Rosita Hills contain rich, vein- and breccia pipe-hosted precious metal deposits. Volcanic activity occurred in two cycles - an early, mainly andesitic cone-building phase that terminated in the formation of a caldera and breccia pipes and a later phase characterised by trachytic lavas and dykes, rhyolite domes and lamprophyre dykes. Alteration consists of weak propylitic and argillic and, locally, intense advanced argillic, K-feldspar sericitic and silicic types. Marked trace-element depletions (Rb, Sr, Zn, Mn) are associated with K-feldspar-sericitic alteration and with advanced argillic alterations, whereas enrichments (Pb, Ag) are associated with K-feldspar-sericitic alteration. Gold distribution is highly localised and is controlled by breccia pipes and a caldera ring fault; it is not related to district scale alteration. In general, the geochemical and alteration patterns are complex, but they are clearly influenced by linear structures, the caldera ring fault and breccia pipes. Pipe-hosted Au-Ag and vein-hosted Ag mineralisation are associated, respectively, with early andesitic and late, post-caldera rhyolitic activity. The pipe-hosted and, especially, the vein-hosted mineralisation show affinities with adularia-sericite-type epithermal deposits

Jan 1, 1991