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By C. F. Gleeson

"I HAVE BEEN ASSIGNED the pleasant task of adding a last word in way of summary to this session. I think that the trend set in having a geochemical session at the CIM Annual General Meeting is a good one and I hope it will continue so that members of the mining fraternity can get together on a regular basis and discuss geochemical problems peculiar to our Canadian scene. A series of interesting papers have been presented on what has been considered by many in the past as not only a problem area for geochemistry but even an impossible one. The papers should help dispel some of these fears. Lack of development of geochemical techniques in the Shield has been due to a variety of factors, many of which have been mentioned. However, I feel that one of the main reasons for this lack of development has been timidness on behalf of many people to get out and do the necessary work which helps produce answers to many of the questions asked. New developments and applications of geochemical methods in the Shield will not be done by the faint of heart but by those who have the curiosity, interest, imagination, drive, resources and, most of all, the intestinal fortitude to stick to it and not give up because results or conditions do not meet with preconceived notions. Another element that will be needed by those who will successfully apply the techniques and who will be responsible for new breakthroughs is the systematic approach to sampling and analysis and the integration of geochemical, geological and geophysical results. Erratic sampling patterns - a sample here and a sample there - generally lead to more problems than solutions."

Jan 1, 1971

By Min-Sung Kang

Excavation and earthmoving equipment mostly operate in accident-prone areas. These areas normally have rollover, confinement, and fall or may be considered harmful work areas due to demolitions and sewage removals. It is inevitable that excavation and earthmoving systems should be developed to secure the safety of operators through unmanned and remote control systems. Therefore, this research proposes a system that enables excavators to be unmanned and remote controlled without any renovation, remodeling, change, or transformation by applying attachable and separable mechanism and modules. Moreover, this research proposes the sensor module to evaluate the dynamic status without processing remodeling or transformation the existing hydraulic drive excavation system by adopting the easy attachable and separable mechanism. The study verifies this proposal based on observed possibility and feasibility through the experiments.

Aug 1, 2013

By Robert G. Boutilier

Mining companies in communities without other large employers often encounter dependent or defiant stakeholder attitudes, sometimes simultaneously. Less often they also see some slip into social dissipation or advance towards sustainable development. This paper presents a four-quadrant framework that shows how patterns of social capital foster these four reactions. The two dimensions defining the quadrants are the social capital levels (a) between the company and each stakeholder, and (b) among stakeholders themselves. Examples from the Antamina mine in Peru illustrate a social capital measurement system that can predict these reactions and help the community chart its path towards sustainable development.

May 1, 2006

By Md. Rashedul Islam

Magnetic data was collected from the Yeoju historical sites using the fluxgate gradiometer through six sites & several grids. We measured the vertical gradient by the FM256 Fluxgate gradiometer. The readings were logged every half meter. The obtained data were processed and treated to introduce a high quality magnetic image. The gradiometer results defined various positive and negative magnetic anomalies, which revealed the existence of several archaeological features of different shapes and sizes. The study of the process magnetic images give us a concept that the subsurface features are caved shape stone chamber tombs, burial mounds, deep room structure, Yeoju mausoleum, pagoda?s square foundation stones, walls etc. All these are superior work of early Goguryeo inheriting orthodox Silla style. So, the study area may have great archeological interest.

May 1, 2009

By Paul Graham

Presentation Focus ? What is LTUG / What do we do? ? History of LTUG ? Examples of Benefits from LTUG Participation ? Encourage Participation What is LTUG? ? An informal gathering of surface mining companies to discuss and work issues of common interest and to share information and best practices around large tires.

May 1, 2008

By R. A. L. Drew, F. Edelmann

Brazing is a low-cost process used extensively in the manufacturing and repair of aircraft gas turbine engines. Components within the compressor stage of the engine experience relatively low temperatures (600-700°C), therefore joints of stainless steels are typically employed. In such joints, a Pd-Ni-Cr-Si-B (PalNiCroTM) brazing alloy is used as a sealant, however brazing procedures are not well understood. The wetting behavior of PalNiCroTM on AISI 347 was evaluated with respect to contact angle. A microstructural evaluation was carried out with variable joint clearances. Microhardness profiles were performed to investigate the presence of hard secondary phases, which were later confirmed by electron microscopy. The results indicated an equilibrium contact angle of 10° within 100 seconds. The average microhardness of the braze layer and base metal were approximately 550 and 205 VHN, respectively. At the interface, a diffusion zone was present containing carbides and borides.

Jan 1, 2004

"An atmospheric process for the synthesis of scorodite(DMSP®)has beendeveloped,in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. Under optimum conditions, the synthesized scorodite (FeAsO4?2H2O) was well crystallizedand the crystals were faceted; the particle sizes were as large as 15 to 20 µm. In thisstudy, iron (II) sulfate heptahydrate (FeSO4·7H2O), arsenic (V) acid (60mass%H3AsO4) solution, and distilled water were used to prepare the original experimental solution (700 ml), in which the contents of Fe(II) and As(V) were 55.9 g/L and 50.0 g/L, respectively. The effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas injectionrate, temperature, and the initial pH of the solution, on the size and shape of the scorodite particles wereinvestigated. From the experimental results, the changes in the shape of the scorodite particles wereclarified for each synthesis condition.INTRODUCTIONDOWA has developed a processfor synthesizing well-crystallized scorodite (FeAsO4•2H2O). Theprocess is named andtrademarked as DMSP® (Fujita et al., 2008; Fujita et al., 2008; Fujita et al., 2009; Fujita et al., 2009; Fujita et al., 2009, Kubo et al., 2010). In this process, oxygen gas is injectedinto a sulfuric acid solution containing large amountsof As(V) and Fe(II). Facetedscorodite crystals as large as 15–20 µm weregeneratedthrough the pre-formation of a gel-like precursor. However, it is known that the synthesized scorodite particles become smaller and more aggregatedwhen the synthesis conditionsdeviate from the optimumconditions.In this study, the effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas flowrate, temperature, and initial pH of the solution, on the size and shape of the scorodite particles were investigated. The experimental resultsclarified the changes in the shape of the scorodite particles for each synthesis condition."

Jan 1, 2016

By M. Ye. Shulgina, M. L. Bolotin, S. A. Prokopev, Ye. S. Prokopev

Iron ores concentration at Russia’s operations is carried out using conventional flow sheets. They comprise the two-four stage grinding followed by one-two stage magnetic separation. This results in the maximum recovery of magnetite to concentrate and the tailings generation. The final concentrate is generated only during the last stage of magnetic separation. Technologically, this flow sheet layout is not effective at recovering the liberated magnetite grains during grinding to the resulting concentrate. Advanced models of magnetic separators do not allow for the selective separation of the tailings and the portion of the resulting iron ore concentrate. Magnetic product which is the ore mixture of the liberated magnetite grains, high grade and low grade intergrowths is directed to the next grinding stage. In this case, regrinding of the liberated magnetite occurs. In addition, the performance of hydrocyclones during classification in closed grinding circuits is poor. Their classification efficiency does not provide the material separation in accordance with the size. In this case, simultaneous separation in accordance with the density occurs. The quartz particles with the size of 300 mm have similar velocity and trajectory like the particles of magnetite with the size of 60 mm. As a result, light and coarser intergrowths report to the overflow and free heavy magnetite grains report to underflow and return to regrinding (“the density effect”). This resulted in a significant increase of a mill circulating load, the decrease in the feed throughput and higher power consumption. In this connection, the development of iron ore concentrate stage recovery with the focus on gradual liberation of the intergrowths is getting much attention. Gravity concentration technique, particularly, spiral separation is effective at solving the problem of stage recovery not only the dump waste product but also high grade magnetite concentrates at the early concentration stages. This can be attributed to a significant difference in magnetite (4.9-5.2 g/cm3) and host minerals (quartz 2.7 g/cm3) densities, which is the principal during gravity concentration. The test work on concentration of various products samples from current operations (the mills discharges, concentrates from various stages of wet magnetic separation and cyclones underflows) was carried out. Spiral separators SV-500 and ShV-500 manufactured by Spirit LLC were used for the test work. High grade iron ore concentrate (69.05% Fe) was generated during primary wet magnetic separation concentrate concentration using a spiral separator. During the concentration of mills discharges the content of iron in the resulting concentrates and middlings of wet magnetic separation II stage was 64.5% and 64.6%, respectively. The recovery of iron to the concentrates of spiral separation was 33.6-42.0%. The studies presented demonstrate that by using spiral separation for iron-bearing ores concentration, you can separate magnetite liberated grains at the early concentration stages, decrease their regrinding and circulating loads in grinding circuits. This process is able to improve the overall recovery and economics of iron ores concentration process.

Jan 1, 2016

By F. Musuka, D. Jenkins, A. Keyes

BHP Olympic Dam operates a Direct-to-Blister copper flash smelting Furnace (DBF) and an Electric Slag Cleaning Furnace (ESCF). Tapping blister copper from these furnaces via tapholes is a routine task carried out by trained personnel. Blister tapping is a high-risk activity with personnel operating in close proximity to molten metal. BHP’s risk management framework has identified taphole integrity as key to managing the potential for loss of molten metal containment and molten metal – water steam explosion, both of which have the potential to cause multiple fatalities. As part of the focus on managing this risk, since 2017, a dedicated Taphole Development Team has been embedded in the operation to run an accelerated improvement program focused on safely and sustainably embedding an improved taphole design with greater integrity. The program of works includes selecting and testing of new materials as well as improving operating discipline by collaborating with tapping personnel to convert their knowledge into codified condition monitoring and operating strategies. Computational fluid dynamics (CFD) is being used to derive critical risk controls, and to develop live-alerts to infer excessive refractory insert wear. To date, improving DBF blister taphole mudgun clay has led to more consistent drilling depths and subsequently reduced oxygen lancing requirements, resulting in improvements in taphole insert service life. On the ESCF, insert performance testing and development of a new taphole condition monitoring strategy, is being used to increase taphole insert tonnages to more sustainable levels. Operations personnel have been closely involved in different phases of the change management, this has led to standardization of tapping practices for both furnaces, and improved ownership of the proposed changes. The paper discusses the maturity in taphole integrity risk management as a result of recent and ongoing developments. It then provides an overview of future taphole developments proposed at Olympic Dam. INTRODUCTION Tapping operations at Olympic Dam and learning from significant events The Direct-to-Blister furnace (DBF) at Olympic Dam was built with a conventional design blister taphole, which was designed for manual oxygen lancing and clay stopper bar plugging tapping operations (Campbell, 2005). Manual tapping is a high-risk activity, where personnel work in close proximity to molten metal, and molten metal personal protective clothing and equipment must be used. Opening tapholes by oxygen lancing is a skilled activity and unintentional damage to the taphole inserts can occur. Since 2008, a Mudgun and Drill unit has been developed and trialled and is now in use on the DBF blister tapholes, to remove personnel from the line of fire when opening and closing tapholes. This has the additional benefit of reducing lancing damage to taphole inserts. A new taphole design labelled the Modular Blister Taphole (MBTH) was developed at Olympic Dam for the Mudgun and Drill operation. The intent of the design was for mudgun clay to fill the entire tapping channel when plugging after a tap. The drill would then drill through this clay plug to open the taphole.

Jan 1, 2019

By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By Laura Kelsey

Contaminant Robust In Situ Water Extractor CRIWE Nafion-based water clean-up Extract purified water from natural extraterrestrial sources In situ water processing for downstream electrolysis Chemically resistant to process contaminants such as acid

May 1, 2013

The quality of refractory bricks and castables could be determined by direct measurements of their material properties such as elastic properties, porosity, density, etc. using conventional static or non-destructive testing (NDT) dynamic techniques. Quality monitoring of refractory linings is much more challenging and complicated. The static methods require undesirable drilling and sample extractions from the furnace structure. A more desirable alternative is the use of NDT techniques for material quality estimation. The Acousto Ultrasonic-Echo (AU-E) technique is a new stress wave propagation approach for monitoring the quality of refractory linings in operating furnaces. In this paper, the conceptual methodology for the AU-E technique is described, the capabilities and limitations are expanded, and the results from two case studies are discussed.

Jan 1, 2005

By Bahri Öteyaka, Ali Uçar, Oktay Sahbaz

"A Jet Diffuser Flotation Column (JDFC) is a newcomer flotation device whose operation principles similar with Jameson cell but it has an essential change in downcomer. By taking into account the hydrodynamic and fluid mechanic principles (Sahbaz et al. 2013) downcomer was changed as a diffuser, therefore turbulence at the end of the downcomer was reduced to provide better aggregate stability and homogenous dissipation of the bubbles in the separation tank. Thus the performance increase has been aimed for the coarse particles.According to theoretical results, obtained by the formula of Oteyaka (1993) showing the relationship between velocity gradient and maximum floatable size for the various contact angles, the d50 of quartz flotation of JFDC is about 240 µm and 310 µm for the contact angle of 50° and 60°, respectively. This result was verified by the experiments. According to the experimental results; d50 which was accepted the maximum floatable particle size of quartz flotation of JFDC was about 256 µm and 300 µm for the contact angle of 50° and 60°, respectively.INTRODUCTIONFlotation is a kinetic process used for separation of hydrophobic particles from hydrophilic particles. There are many different parameters affects the success of the flotation and particle size is one of them. While the flotation is very efficient for intermediate size, the efficiency of the process starts to decrease for both fine and coarse sizes (Trahar, 1981; Muganda et al., 2011). Therefore; researchers have tried to find a solution for the efficiency decrease in fine and coarse sizes by modifying the chemical condition and designing the new devices. For example, Jameson cell is a unique device for the fine particle flotation due to the suitable design and fine bubble producing (Jameson, 1988; Evans et al., 1995; Sahbaz, 2010). Because of this success operation the Jameson cell is applied more than 200 flotation plants in worldwide. On the contrary, the efficiency of the cell decreases for coarse particle flotation due to the turbulence occurred in the separation tank (Sahbaz, 2010; Cowburn et al., 2007). That’s why, new flotation device was designed in loboratory scale by Sahbaz, Oteyaka and Ucar in 2010s and it has been called as Jet Diffuser Flotation Column (JDFC) recently."

Jan 1, 2016

By R. E. Stewart

"Using the concept of economic life and marginal analysis, it can be shown that proper equipment replacement timing can save a mining company many thousands of dollars. To assist management with determining the economic life of mining equipment, a new computer package has been developed. The package, called ERG (equipment replacement guide), incorporates all important economic factors related to equipment usage, such as operating costs, maintenance costs, salvage values, depreciation, volume of work, tax credits, inflation rates, ROJ, etc. The information is used in a series of equations which balance the costs of new equipment against the total cost of old equipment. The solution of the equations determines economic life and the point in time when the old equipment should be replaced. IntroductionIn an operating mine, equipment must eventually be replaced or downgraded for a variety of reasons. Fleets of haul trucks, dozers and other major pieces of equipment deteriorate over time until the mounting costs of maintenance and repair force either a major overhaul or the ir replacement by new and more efficient pieces of equipment.The question of determining the best time to replace old equipment has been approached in many different ways. Various methods, ranging from operating experience, intuition and physical necessity to sophisticated computer models have been devised to help cope with equipment replacement decisions . The best of the se will incorporate the most important economic factors related to equipment usage, such as operating and maintenance costs, salvage values, depreciation, work delivered, the cost of capital, tax credits and, of course, the effects of inflation.Economic TheoryThe fundamentals of equipment replacement theory grew out of the interaction between economics, engineering and finance. The use of annual cost comparisons and rate-of return calculations were helpful in handling situations in which assets with different finite lives were being compared. Later developments bringing together the concept of economic life and marginal analysis helped provide additional refinements to the theory. Taylorui showed that the displacement of an aging asset with a similar, but newer, asset can be justified economically when the marginal cost of keeping the asset one more year exceeds the minimum uniform annual cost equivalent of the proposed replacement."

Jan 1, 1980

By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By Abhilash

Uranium is conventionally extracted using a process that employs strong acid (H2SO4) and an oxidant (MnO2) as leaching agents. This method often creates environmental problems, requires large amounts of energy, and involves a complex operational plant. It is not, however, economically attractive to extract uranium from low-grade ores by chemical leaching. Because the content of U3O8 in the Indian ore is usually below 0.1% by weight, it is necessary to develop an alternative process to enable the efficient and economic recovery of uranium. Uranium ore from the Narwapahar mines, UCIL is a type of vein deposit found in India, which accounts for ~54% in India. The ore (0.047% U3O8), though of Singhbhum area, possess exceptionally different mineralogy due to presence of some refractory minerals and richness of apatite (5%) resulting in a maximum 78% recovery through conventional processing at UCIL, with a very high consumption of sulfuric acid and pyrolusite, besides possible loss of uranium as uranium phosphate. To avoid usage of environmentally non-benign oxidants, remediation of influence of phosphates, and improve the overall process output of uranium; an alternate extraction technology using microbial isolate(s) is worthwhile exploring and the same is presented in the paper. The microbial isolate enriched with Acidithiobacillus ferrooxidans grown from source mine water was employed for bio-leaching of uranium while varying pH, pulp density (PD), particle size, etc. On varying pH at 35oC using 20%(w/v) PD and <75µm particle size, 83.5% and 78% uranium bio-recovery were observed at 1.7 and 2.0 pH in 40 days against maximum recovery of 46% and 41% metal in control experiments respectively. Whereas, it was observed that grinding of ore to finer size actually helped dissolution of uranium. Finer size particles (<45µm) gave a maximum biorecovery of 93% in 40days at 10%(w/v) PD, 1.7 pH and 35oC. The bio-recovery of uranium fell down from 93% to 82.73% and 60% on increasing the pulp density from 10% to 20% and 30% respectively for particles of <45µm size. The higher uranium dissolution during bioleaching at 1.7pH can be correlated with increase in redox potential from 433 mV to 664mV in 40 days.

Aug 1, 2010

By Ming’an Wei, Qifu Duan, Chengtie Wang, Jianmin Wu, Erdenet Mining Corporation, Lusheng Zhou, Wenjian Wu

"The development and industrial applications of magnetic liners have been around for decades. A Swedish company SKEGA first introduced the rubber magnetic liner, and then followed by the Chinese metal magnetic liners. Traditionally, both liners were used in secondary and regrind ball mills, especially for ores containing magnetic materials. Mostly steel balls or equivalent forged balls, usually below 60 mm in diameter, were used as grinding media. With the development of mineral resources over the years, SAG mills and larger ball mills have become the dominating components for comminution circuit design globally. Due to the larger ball mills and thus larger grinding balls (up to 80 mm) especially in non-ferrous metal industry, the application of magnetic liners has been very limited. Based on the new development of materials, the HMR Group Limited has been exploring new designs of magnetic liners which led to the invention of the Nano Steel Magnetic Liner (NSML). Recently, NSML had a successful application in a 5.5m x 6.5m ball mill with 80 mm balls at the Erdenet Copper Mine in Mongolia. Although the first set of liner had a service life of 12 months, the design of the second set was modified and improved to accommodate the operating conditions, which is expected to reach least 24 months service life. The original manganese steel liner only had about 8 months liner life.1. IntroductionMineral processing is an essential operation for the development and utilization of mineral resources. The effective concentration of various useful minerals depends on sufficient liberation of the mineral particles in the ore. The crushing and grinding process such as ball milling are the most common way to achieve proper liberation size. Mill liner is an eternal topic for the operations, not only because it protects the equipment, but also affects the mill grinding efficiency and availability. In recent years, magnetic mill liners have been developed that can easily meet the production targets with numerous benefits, such as zero maintenance, reducing specific energy consumption and improving grinding efficiency."

Jan 1, 2016

By N. Moelans, I. Bellemans, K. Verbeken

In this work, we present a phase field model to simulate the facetted crystallization of Fe3O4 in a quaternary FeO-Fe2O3-Cu2O-SiO2 melt under different partial pressures of oxygen. An important focus in creating more realistic phase field models is the incorporation of the thermodynamic driving forces in multicomponent multiphase-field models by coupling to thermodynamic databases. The diffusion of FeO, Fe2O3 and Cu2O is considered. The ratio of FeO/Fe2O3 at the upper boundary is in equilibrium with the oxygen fugacity of the atmosphere, while conserving Fe. Two-dimensional simulations are performed with different varying oxygen fugacity in the atmosphere. For the considered composition range, the growth velocities of the spinel crystals increase with decreasing oxygen fugacity. INTRODUCTION Crystallization of silicate melts has its applications in geology, pyrometallurgy and glass making. In pyrometallurgy, the solidification of slags influences the freeze lining behaviour (Campforts et al., 2007) and the cooling of slag after tapping (Durinck, Jones, Blanpain, & Wollants, 2008). Modeling of silicate melt crystallization is frequently done on the macroscopic level, using thermodynamic equilibrium calculations to determine the fractions of all phases as a function of temperature. The Factsage software and database package (Bale et al., 2016, 2009, 2002) already proved its usefulness in pyrometallurgical applications, for example to model the phase mixture after solidification of a stainless steel slag (Durinck et al., 2008). Crystallization of phases typically results in complex morphologies on the mesoscale, e.g. dendrites or facetted growth. On this mesoscale, the phase field concept has proved to be a very powerful tool (Moelans, Blanpain, & Wollants, 2008) for modeling crystallizing microstructures, because it can treat arbitrarily complex interface shapes with minimal mathematical complexity. In contrast to macroscopic models, the diffusion profiles and crystallization kinetics can be described as well as the morphology of individual crystals. First, Kobayashi (Kobayashi, 1993) simulated a growing dendrite in a pure undercooled metallic liquid. Then, Warren and Boettinger (1995) simulated a dendrite in an isothermal system considering a binary alloy. The extension to multi-phase systems was done by Steinbach et al. (1996). This was further extended by Tiaden, Nestler, Diepers, and Steinbach (1998) to a framework with coupled diffusion and phase field equations in multi-component systems.

Jan 1, 2019

By S. Castro

Hydrolysis of metallic ions depends on pH and the products of hydrolysis either activate flotation or can lead to inadvertent activation of gangue particles, but can also depress flotation of valuable components. One of the most recently studied topics is the use of seawater in flotation. Seawater is a concentrated NaCl solution (about 0.6 mol/L) that also contains considerable amount of Mg2+ and Ca2+ ions. The hydrolysis products of Mg2+ strongly depress flotation of molybdenite over the pH ranges over which they form in the process water. This effect can be eliminated by removal of hydrolysing ions from the process water or by carrying out the flotation at the pH over which such a hydrolysis can be avoided. The former can be exemplified by prior precipitation of the harmful hydrolysing ions as, for example, in the University of Concepcion Patent. The latter can be exemplified by the use of metabisulfite to depress pyrite in the flotation of Cu-Mo sulfide ores in seawater, the process that is carried out at much lower pH, which avoids formation of Mg2+ hydrolysis products.

Jan 1, 2017

By Mark Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the Autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the Open Pit and Process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of: 1) Electronic caps for more precision and flexibility, as well as for allowing extremely fast shots. 2) Explosives with a higher velocity of detonation (VOD), to provide for improved shock energy. 3) Improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by six tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster ?hard ore? (BWI >17), as well as autoclave ?hard ore? (BWI >15). Approximately six million tons of D2M material is expected be shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

May 1, 2003