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By Maria Agostina Cinellu

Some aspects of the reactivity of the two different kinds of gold(III) oxo complexes [Au2(N,N)2(?-O)2][X]2 [N,N = 2,2'-bipyridine (bipy) (1), 6-alkyl-2,2'-bipyridine (bipyR) (2), R = Me a, CH2Me b, CHMe2 c, CMe3 d, CH2CMe3 e] and [Au2(C,N,N)2(?-O)][X]2 [HC,N,N = 6-benzyl-2,2'-bipyridine (bipyR') (3), R' = CHMeC6H5 a, CMe2C6H5 b] (X = BF4, PF6) have been studied. Treatment with water converts the unsubstituted bipyridine complex [Au2(bipy)2(?-O)2][PF6]2 (1) and the cyclometallated derivatives [Au2(C,N,N)2(?-O)][PF6]2 (3) into the water soluble monomeric hydroxo species [Au(bipy)(OH)2][PF6] (4) and [Au(C,N,N)(OH)][PF6] (5), respectively. These hydroxo species, likely the intermediates in the formation of the oxo complexes, are quantitatively reverted to the latter ones by reflux in anhydrous solvents. Both kinds of oxo complexes react with PPh3 to give OPPh3, the gold(I) complex [Au(PPh3)2][PF6] and the free bipyridine ligands. The reaction of the dioxo complexes [Au2(bipyR)2(?-O)2][PF6]2 (2a, 2b, 2c, 2e) with different alkenes gives the unprecedented alkene complexes [Au(bipyR)(?2-alkene)][PF6]. The styrene adduct [Au(bipyip)(?2- CH2=CHPh)][PF6] (7) (bipyip = 6-iso-propyl-2,2?-bipyridine c) has been characterized, inter alia, by X-ray diffraction analysis. Organic products arising from olefin oxidation are also found in the reaction mixture.

Oct 1, 2003

By E. Rezaei

Glue is an animal protein that is used with other organic agent such as thiourea, in copper electrorefining. The concentration of glue has to be controlled carefully, because the electro-deposition process is often very sensitive to small fluctuation in the operating variable. This additive (glue) prevents rough and nodular copper cathode deposits. The nodular deposits may grow causing short circuits, which results in losses in production. Addition agents are effective in controlling metal growth; they modify the normal nucleation and lattice growth steps and refine the grain structure. In this research glue concentration was determined in an industrial copper electrolysis plant. A non-linear model with high capability was constructed and after optimizing its parameters, the accuracy and precision of the model were evaluated. For determination of glue concentration, electrochemical voltammograms in optimum condition (Differential pulse voltammetry technique, Hpulse=50 my, scan rate=10 mv/s) were plotted. Some information from voltammograms was transferred to the model as inputs and the calibrated model analyzed the information and the glue concentration was determined with high precision and accuracy. In this way there is no need to separate or add agents to remove interferences. This method has been successfully applied at Sarcheshmeh copper complex.

Jan 1, 2007

By Y. T. John Kwong

Abstract - To exploit an ore deposit without unduly impacting the environment is a challenge that can only be met by the concerted efforts of traditionally independent teams working on a mining project. Not only is detailed geology required of geologists to help mine engineers to develop a mine plan that assures generation of the least possible amount of mine waste, but metallurgists also have to select the most environmentally friendly mineral processing schemes, and communicate with environmental engineers with regard to complications that process chemicals may pose on proper mine waste management. Traditional ore deposit models typically emphasize the geological and mineralogical aspects of ore genesis to facilitate exploration for similar deposits. Recent research has shown that potential environmental liabilities such as acid mine drainage and metal leaching can readily be predicted according to deposit types. The choice of mining methods, mineral processing schemes, and decommissioning options are also largely dictated by the composition and setting of an orebody to be mined. Integrating such related information into traditional ore deposit descriptions would lead to the development of comprehensive environmental ore deposit models. The latter would facilitate communication among staff of the varied components of a mine project and aid with the selection of a combination of methods and strategies that would assure minimum environmental risks and impacts, reduce the overall project cost, and enhance sustainable development.

Jan 1, 2003

By J. A. Finch

Samples of feed and product from a closed grinding circuit treating a heterogeneous lead-zinc ore were taken. The feed was subjected to laboratory batch grinding in a rod and ball mill with the objective of simulating the closed-circuit size distribution. It was concluded that the batch rod mill can closely simulate this product if only the over-all size is considered, but mineral-by-mineral large differences occur. If, as is suspected, the mineral sizes are the important factor in flotation, the differences could lead to problems in interpreting flotation results. An example of mineral recovery as a function of size is described to illustrate the potential problems.

Jan 1, 1979

By K. Sun, S. A. Argyropoulos

The assimilation and the exothermic behavior of Zn-Zr metallic powder compacts into molten aluminum was studied by measuring simultaneously the temperatures inside at the centerline of the compact, at its surface, and inside the molten aluminum bath, as well as the net downward force acting on the compact. In addition, the exothermic behavior of these compacts was also investigated in an argon protected atmosphere. The temperature rise inside the compact increases significantly with the mass ratio of zirconium in the compact and to a lesser degree with the aluminum bath temperature. Experimental results on the recovery of these compacts in molten aluminum will also be presented.

Jan 1, 2008

By G. Q. Zhou, H. C. Liang, X. D. Zhao

"This study describes the strain behavior in vertical shaft lining (VSL) embedded in thick soil deposits and its application in assessment of concrete deterioration. The observed strain in VSL continuously decreased companied by a sinusoidal fluctuation due to the influences derived from negative skin friction (NSF) and temperature. The increase in strain increment between peak and trough at each year and compressive strain level as the servicing time continued and VSL depth increased implies that the concrete strength was attenuated, and this attenuation was significantly dependent on the existing compressive strain level in VSL. The reliability of the proposed approach was validated by Schmidt Hammer Technique (SHT) – based concrete strength, and is applicable in concrete assessment and then fracturing prediction of VLSs in thick soil deposits.Concrete strength, Field monitoring, Strain behavior, Vertical shaft liningINTRODUCTIONOver 100 VSLs in Southeastern China subjected to an unpredictable fracturing as shown in Figure1, and there are over 1,000 VSLs embedded in thick alluvium su?ering from challenges of damaging and potential fracturing (Cheng, Yang, Zhou, Li, & Hu, 1993; Zhou, Cui, Lv, Huang, & Chen, 1999; Li & Li,2005). Therefore, a reliable assessment of these VSLs is significant to the normal servicing of mine shafts and the recycle of underground space when these mine shafts were closed.The continuous increasing of NSF induced by the drainage of water–saturated deposits well interpreted such extensive fracturing phenomenon, and it is universally regarded as the governing indicator to determine the VSL stabilization (Cheng et al., 1993; Zhou et al., 1999). Based on this recognition, the fracturing prediction and VSL strengthening according to the field monitoring on hydrogeological characteristics, servicing environments, and mechanical behaviors of VSL were carried out (Zhao, Zhou, Zhong, Zhu, & Liang, 2009; Liang et al., 2009; Xie, Lv, & Wu, 2014). As known, the compressive strain level in VSL and the in–situ strength of VSL concrete were the main factors to perform such fracturing prediction. However, the existing studies in literatures were limited to the strain accumulating or releasing behaviors (Zhao, Zhou, Zhao, Kuang, & Hu, 2017), and lack of considering the VSL concrete strength and its attenuation. In this reported study, the in–situ monitoring data on the strain in typical VSLs and the VSL elevations between 2004 and 2014 were initially analyzed. Then, an observed strain behaviors–based approach was developed to quantitatively evaluate the VSL concrete deterioration."

Jan 1, 2019

By Bill Charbonneau

Lumen, lm The measurement unit of light emitted by a light source 60W incandescent840 lumens 32W T8 linear fluorescent3200 lumens 54W T5HO linear fluorescent5000 lumens 400W metal halide24,000 lumens

Oct 1, 2010

By Ken Musgrave

"A program is described that helps managers and supervisors control maintenance more effectively. Work- order generation, preventive maintenance, repair parts inventory, planning and scheduling, reporting, analyzing costs, printing purchase orders and other functions are covered. Flexibility often permits integration with other programs such as payroll, cost accounting and materials management.The Role of MaintenanceMaintenance provides a service to allow the rest of the operation to do its job effectively. Its success should not be measured by maintenance cost alone, but also by its effectiveness in reducing downtime and maximizing production. It can make sense to spend more maintenance dollars if this results in an even greater contribution from increased production.The Cost of MaintenanceIn mining companies, maintenance costs can be as much as half of operating costs. Maintenance has generally not been given the management attention that an expenditure of this magnitude deserves."

Jan 1, 1986

An optimization process is described that can be systematically applied by mine planners to produce life-of-mine schedules aligned with their strategic targets, while maximizing the net present value of the mining operation. The software tool employed uses heuristics and an evolutionary algorithm to generate life-of-mine schedules of production and development activities. Generating such schedules is typically a very difficult task due to the large number of operational constraints that must be respected, and the vast number of alternative schedules; as a result the value of the mining operation can be compromised. With an expansion at Newmont?s Leeville mine in Nevada, the mine planners were given the task of producing feasible life-of-mine schedules with significantly increased production rates. Their initial efforts indicated that it would be a considerable challenge to generate such schedules in a timely manner. By systematically applying the proposed optimization process, the mine planners were able to generate optimized life-of-mine schedules with the desired production rate.

Aug 1, 2013

By F. Hosseini

Shaping of metals by thixoforming relies on the unusual flow behavior of semisolid slurries containing nondendritic solid phase. The Flow behavior of metallic alloys containing both solid and liquid phases is investigated in the low solid fraction range (, 55%). This behavior depends on both the solid fraction and the shear rate. Four different shear rates is applied using back extrusion technique and flow stress versus true strain in different solid fraction is compared. It is well accepted that the flow stress s of alloys in their semi-solid state obeys to a thixotropic behavior, due to agglomeration and dissagglomeration phenomena during forming. The load-displacement curves produced from the tests may show an initial peak, believed to originate from a skeletal structure which rapidly breaks down under shear. Apparent viscosity obtained from this method is compared with other works and the proper power law of pseudo plastic state is introduced.

Oct 1, 2011

By A. Diaz, Minera Los Pelambres, C. G. Salinas, G. Leinenweber, F. Diaz, D. Rojas, R. Bernal, O. Jimenez

"Los Pelambres Mine (MLP) is located in the IV Region of Chile, a semi-arid region where water plays a key role in operations as a scarce resource and is vital for the sustainability of human life, animals and ecosystem. The conventional flow meters installed on pipes at MLP can fail to provide an accurate measurement due to corrosion and/or fouling on the inner wall or presence of elements in the water such as acids, salts and suspended solids. Conventional flow measurement methods require the inner diameter to be known, however it is not always possible to assess its real value due to scaling, fouling, corrosion, etc. Here we present a novel methodology to solve these problems, which consists of the measurement of flow by a method that does not require the internal area of the pipes: the fluorescent tracer dilution method. In addition, the fluid velocity can be determined by the transit time of a radioactive tracer method. With the flow rate and velocity, the equivalent area is determined and thus the equivalent internal pipe diameter as well. This methodology was applied in a recirculation pump station, for mineral processing from the El Mauro tailings dam.This work demonstrated adequate correlation between measurements from fluorescent tracers and velocity measurements from radioactive tracers, both of which lead to the assessment of the internal diameter of pipes with scaling. The results of both methods disagree with the data provided by the flowmeter installed on the line due to its miscalibration. This information is useful in validating and correcting the information provided by online flowmeters of all water and solutions transport processes in filled pipes.INTRODUCTIONPresently, the need to optimize water resources is increasingly ever important, due to various reasons such as water scarcity, community empowerment, an increased use of water for mining processes and environmental considerations. Taking into account those main considerations, Los Pelambres Mine decided to focus on water conservation to avoid losses of this vital element. They decided to demonstrate that all of the systems that used water (flow meters, pipes, pumping stations, lagoons, etc) were in good condition and that no evitable loses of this important resource occurred. A plan was proposed to conduct a “hydraulic assessment” of fluid flux and water speed at different points and courses at the mine, with the purpose of obtaining hard data to support, verify and correct the information provided online from specific instrumentation dedicated to those purposes. The final goal was to manage the water resource basin in a sustainable way, based on cross-checked information. The chosen points are representative of the processes present in the mine, such as recirculating water stations at different operating conditions and surface water courses, where the fresh water capture systems operate."

Jan 1, 2016

By Sadough vanini Ali

Hot deformation behavior of functionally graded steel (FGS) was investigated via conducting hot compression tests at different temperatures and strain rates. Functionally graded steels consist of ferrite, austenite, bainite and martensite layers that are made by diffusion of alloy elements during the melting process. The zenerhollomon parameter has been used to describe the flow stress variations as a function of temperatures and strain rates. The parameter values for all the layers via using the boundary conditions was determined based on composite graded behaviors. Furthermore by applying the rule of phase mixtures, the whole strain rate applied on composite would be the sum of layers strain rates considering the layers volume fraction, while the layers have the same stress. Consequently the composite flow stress for each strain rate and temperature was determined.

Oct 1, 2011

By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By S. A. Sadough vanini

In this paper the influence of temperature on the flow behavior and rheological characteristics of an A356 alloy in the semi-solid state using backward extrusion process are studied experimentally and numerically. Simulation process is done by dynamic explicit in ABAQUS software for each forming condition. A cooling slope treatment was employed in order to obtain a non-dendritic microstructure. Experiments were performed in 5 temperatures and 4 different wall thicknesses. In the low forming speeds, liquid fraction had time to escape from solid phase forward the samples? wall. This condition was the main reason for the segregation phenomenon seen in the base and walls. Viscosities were determined using the force-displacement graphs obtained form back-extrusion tests. As observed experimentally, in a constant temperature, increase of shear rate resulted in decrease of alloy viscosity exponentially. Raising the temperature increases the liquid fraction hence reduces the semi-solid alloy viscosity. The results of experimental and simulation are compared and there is a good adaptation.

Oct 1, 2011

By C. A. Pickles, K. Mackowiak

Black Thor chromite ore from the Ring of Fire deposit in Northern Ontario was carbothermically reduced in a microwave system to produce a ferrochromium alloy. The as-received ore contained 43.0% Cr2O3, 19.9% Fe2O3, 14.5% MgO, 13.4% Al2O3, and 7.0% SiO2. Activated charcoal was utilized as the reducing agent. Firstly, TGA/DTA and permittivity studies were carried out in order to determine the relationship between the reduction process and the microwave susceptibility. Secondly, microwave reduction experiments were performed on the chromite ore. The variables investigated were; the amount of carbon, processing time, input power and type of atmosphere. A maximum chromium grade of 76.1% and a chromium metallization of 82.7% were obtained for a processing time of 20 minutes, a power input of 800 W, and a carbon addition of 15% in an argon atmosphere.

Jan 1, 2017

By I. B. Lambert

The guide has been developed by officials from resources and environment agencies in the Australian Government and the South Australian and Northern Territory Governments. It elaborates on the Australian Government?s policy that new uranium mines are to be approved subject to world best practice environmental and safety standards. The guide outlines the best practice principles and approaches that apply generally to mining in Australia, before giving more detailed consideration to best practice environmental protection and regulation for ISR mining.

Aug 1, 2010

By G. Tairova, J. Ioffe

Arsenic, selenium and mercury species are common contaminants in mining aqueous streams and present significant environmental and health problems. The objective of this project is to investigate methods to lower the concentrations of these elements in mining aqueous streams. A new composite media for removal of these elements of concern from mining effluents was developed. The results of bench scale and pilot plant experiments, using the media, indicated removal of arsenic, selenium, mercury and other elements of concern below detection limits.

Jan 1, 2014

By Helmer Kraemer

One of the CIM 2003 conference themes is ?Globalization and the impact on mine operations?. In this context, the first official version of the new ?International Rock Excavation Data Exchange Standard? (IREDES) is being released. This new standard is a highly flexible data interface for exchange of information between production equipment and central computer systems. The standard was defined by global players in the mining industry and will soon be used to enhance local operations of global mining companies. Beside the standard definition now other aspects are coming into focus: The question how to design and how to implement IREDES compliant data exchange in practice. Implementation of IREDES covers the following aspects: !" Implementation on in-field production systems !" Communication and networking !" Implementation on databases and commercial IT systems In-field production systems are characterized by a big variety of different automation systems. Therefor, different IREDES implementation philosophies have to apply to those systems. One philosophy uses an integrated IREDES compliant automation system on every machine. The alternative method uses one shared IREDES compliant ?Proxy server? for a number of machines connected to this server using proprietary interfaces. Communication and networking can be integrated openly and independently from hardware infrastructures. The only precondition is that communication and networking has to be Ethernet - TCP/IP protocol compatible. IREDES Implementation on the commercial IT level means to exchange IREDES data sets with databases, simulation software, office packages and special applications. Interfacing is easy as long as the software or the database system provides an interface to the Extensible Markup Language (XML).

May 1, 2003

By Adriana Ramirez, Bradford C. Wesstrom, Blanca Olave

The Freeport McMoRan El Paso Copper Refinery optimizes electrolyte quality using a number of systems. The facility controls copper, arsenic, antimony and bismuth using electro-winning cells within the Tank House and Nickel Carbonate Plant Liberator Circuit (NCP). The NCP manages sulfuric acid content utilizing recycled electrolyte in the slimes autoclave as well as operation of the Acid Purification Unit, APU. The El Paso Refinery removes common sulfates using metal hydrolysis with sodium carbonate. Finally, a Mechanical Vapor Recompression, (MVR), at the water recovery plant removes sodium sulfate generated by the NCP. This paper will provide a summary of these operations. INTRODUCTION In the mid 1920’s Nichols Copper Company, in Laurel Hill, New York, recognized the need for a modern copper refining facility in the southwest. Because of the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the ideal location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Water is a precious commodity in the desert southwest, making conservation of this natural resource an important goal for the El Paso Operations. In the 1980’s, work on the treatment of slimes was improved through the use of pressure leaching of the refinery slimes using an autoclave. Due to the high tellurium content in the leached slimes solution, it was crucial to implement a method for its removal before the solution returns to the tank house electrolyte. A copper telluride cementation operation was installed for tellurium recovery and the ability for the recycle of the leachate and wash water to the refinery electrolyte. In October of 1997, ground was broken for the construction of the water recovery plant using an MVR to reuse process water, reducing water consumption by 25%. In 2002, electrolyte purification was further improved with the installation of an Acid Purification Unit, (APU) (Sheedy, Pajunen, & Wesstrom, 2007). The APU recycles 90% of the acids (both sulfuric and arsenic acids) back to the tank house electrolyte. The solution that passes through the APU is treated with soda ash to precipitate metals out of solution as carbonates and generates a sodium sulfate solution. This sodium sulfate solution is easily processed in the new water recovery plant, where the majority of the water recycles back into the plant as pure condensate. In 2012, the power plant at the refinery upgraded its Reverse Osmosis System to provide RO water to the tankhouse. This insured that the refinery would not have to bleed electrolyte for metals contained in well water such as: calcium, magnesium, iron and sodium chloride.

Jan 1, 2019

By O. Zach, K. Gamweger

"The Process of gas purging in molten Aluminium has been an industrial practise for many years. The melting of alloying elements and their rapid distribution in the bath is very important. To improve the mixing and homogenisation process, at RHI NON FERROUS METALS ENGENEERING GMBH a lot of CFD calculations were done. The so developed new ""purging program"" was tested at Alumino Catalan S.A., Spain. The results of the testtrials were very satisfactory and corresponds very well with the calculated data."

Jan 1, 2004