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By G. E. Rowan

"DURING the dark ages, the cherished dream of chemists was to find a process for converting base metal into gold. Many a wealthy-but-gullible patron lost a fortune in the search. Men who work with metals today are a bit more realistic. I haven't heard of a metallurgist who expects to develop any one alloy that will resist all corrosive media. In the field of stain-less steels, there are about forty different types of alloys that are used where corrosion is a •problem.A stainless product is ordinarily selected because it offers one or more of the following qualities:(1) Resistance to corrosion (2) Resistance to oxidation at high temperatures (3) Good mechanical properties at room temperature (4) Good mechanical properties at high or low temperature (5) Attractive appearance (6) Ease of maintenanceToday we are interested in discussing the stainless steel family of alloys because of their .ability to resist corrosion. We• will not try to explain the Theory of Corrosion. Let us assume that, when surface potential and oxide formations are properly controlled, iron will resist attack in various chemi.cal solutions. The addition of alloying elements to iron does this for stainless steels. The principal stainless alloys used by various Canadian industries are listed in the accompanying Table."

Jan 1, 1959

By T. H. Patching, M. W. Mikhail

"Data from a standardized procedure for measuring methane desorption rates from samples of Western Canadian coals gave a good correlation (0.994) with the percentage of fines (-0.6 mm) found in the corresponding run-of-mine coal. The correlation was independent of the mining method and the top size of the samples. It is suggested that both methane desorption rate and the production of fine coal sizes are functions of the fissuration of the coal being mined.This relationship, in conjunction with established data of degradation by unit process equipment, may be useful in predicting the amount of fines that will be produced from new seams of coal and by planned new washeries. It also could be a valuable guide in modifying existing washery processes to minimize production of fines."

Jan 1, 1980

Cominco began investigations about ten years ago relative to noise abatement in underground operations. As a result of intensive research, this study has advanced so that the practice now has wide application. Automotive mufflers are used on vane-type blasthole diamond drills. Exhaust hoses are attached to longhole percussion drills. Hand-held drills, such as airlegs and stopers, are equipped with mufflers which are either part of the drill, as received from the manufacturer, or are light rubber de-vices developed, fabricated and installed by Cominco. Ear defenders are in general use. The paper reviews details of practices employed, and assesses the success achieved. Noise is generally associated with some of the basic equipment used in mining. About ten years ago, in order to improve on this situation. The Consolidated Mining and Smelting Company of Canada Limited began investigations relative to noise abatement in its underground operations. As a result of intensive research, this study has advanced to the point

Jan 1, 1964

By J. G. Patterson

"The depressive action of sodium cyanide on chalcocite has been investigated and found to be unstable. Flotation results show that with the addition of sodium cyanide to the system chalcocite is initially depressed but rapidly recovers with time, provided there is sufficient oxygen present.lt is proposed that the unstable depression is due to the reaction of cyanide with adsorbed xanthate and copper ions at the chalcocite surface to form soluble copper complexes. When all the free cyanide has so reacted, xanthate anions can then re-adsorb on the chalcocite surface and the flotation will recover. Results are presented to verify the the above mechanism."

Jan 1, 1968

By H. B. Lumsden

This paper is intended to deal merely with the commercial development of some of the principal non-metallic mineral resources in the three prairie provinces- Manitoba, Saskatchewan, and Alberta. Coal is not included in this summary. Building Stone First and foremost, mention may be made of the building stone now being produced at Tyndall, Manitoba. This is a mottled limestone and is declared by experts to be one of the finest building stones in America, both as regards durability and appearance. It has been used very extensively both for exterior and interior work, not only in western Canada, but also in the principal cities as far east as Montreal. The stone is the "'Upper Mottled Limestone", which forms the summit of the Trenton (Ordovician) strata in the Lake Winnipeg basin. Quarries are at present being operated at Garson and Tyndall . The area where this stone is known to be available extends in a north and south direction for a distance of three miles, and the main productive ridge is probably about one half mile wide. The outlook for the future of the industry is extremely promising, as the stone is becoming increasingly popular in Eastern Canada, more particularly for interior work.

Jan 1, 1928

By C. Moreland

Fluidized low-temperature carbonization of coal, a recent development, offers a possibility of reducing fuel costs of coal-burning electric ?generating plants. The Research Council of Alberta have built a pilot plant and are conducting a programme to -develop a carbomzation plant for Alberta sub-bituminous coals which will produce char suitable for use as a .boiler fuel, and tar of a potentially high value as a ?chemical raw material. The economies of the process as a whole, and the value of the tar, have yet to be assessed.

Jan 1, 1958

By C. L. Lewis

"The development of computer process control at the Lake Dufault concentrator is reviewed and the on-stream X-ray analysis -computer system is described briefly. Some applications of the computer in metallurgical process control are described.The computer sequences slurry sample streams to the analyzer and translates the analytical results from voltage signals to elemental percentages. The required flotation reagent flow rates are calculated from analyses and mill-feed tonnage rates and the reagent feeders are set automatically to provide such flow rates. X-ray calibration time has been reduced from about 45 minutes to 15 minutes by the use of a computer program. Metallurgical and operating personnel have acquired the ability to program the computer and have extended the system capability to allow the calculation of recoveries, averaging of mill data, application of ore specific gravity in grinding control, control of oxidized ore flotation and the development of an economic recovery program."

Jan 1, 1971

By R. H. Andrews, F. J. West

"Jones & Laughlin Mining Company, Ltd. operate the Adams mine at Kirkland Lake, Ontario, where they mine approximately 4,000,000 tons of extremely hard iron-formation and 3,500,000 tons of volcanic waste rock annually in order to produce 1,100,000 tons of iron pellets. This paper will discuss the maintenance of the four Model 1600 P & H shovels and the two 50-R drills used to obtain this production. The chief maintenance problems at the mine are due to the hard, abrasive ore and the cold winter weather."

Jan 1, 1970

By D H. Sharp

The Quebec Cartier Mining Company produces iron concentrate for twelve months of the year from Port Cartier. This J>Ort is designed to handle ship varying in size from 3,000 to 100,000 d.w.t., requiring 50 feet of water at low tide. The harbour was built on shore for reasons of economy and layout, after considering many more conventional offshore designs. It provides for heavy oil bunkering, tanker off-loading, a heavy lift derrick and freight handling, besides ship loading and mooring. The weather for the previous fifty years was studied to enable wind and wave conditions to be accurately assessed for design purposes, and to determine probable lost time due to adverse weather conditions through-out the year. The first ship to be loaded was 60,000 d.w.t.; the second, 20,000 d.w.t. The latter entered the harbour after dark, under its own power, following a tug through the partly dredged narrow entrance. Large ships use tug assistance. Ships may leave the loading berth with the other berths occupied.

Jan 1, 1963

By M. Tanaka, H. Narita, T. Fuchikami, K. Morisaku, K. Nagao, T. Yoshida, K. Kuroda

The effect of various N-substituents on the performance of amide-containing tertiary amine compounds in the extraction of Rh(III) from HCl solutions was investigated to optimize the structure of these compounds for industrial use. It was found that N-2-ethylhexyl-bis(N-di-2-ethylhexyl-ethylamide)amine and tris(N-di-2-ethylhexyl-ethylamide)amine, which have long, branched alkyl chains, were suitable for Rh extraction, because they were soluble in a practical diluent (80 vol% n-dodecane?20 vol% 2-ethylhexanol) and stable against highly concentrated HCl/Rh solutions, and showed high selectivity for Rh(III) over Pd(II) and Pt(IV).

Jan 1, 2014

By Esa Peuraniemi, Hanna-Leena Heikkilä

Boliden Harjavalta has been operating a copper flash smelter since 1949. Thus, in 2019, the smelter is celebrating its 70th anniversary of flash smelting. Slag formation is an integral part of the smelting process; currently the processing of slag is based on froth flotation at the slag concentrator. It provides high recovery of copper but restricts slag utilization; the final copper slag is deposited in a landfill. The Harjavalta smelter commissioned a new landfill area for final slag in May 2018. This paper describes the full project from permitting to commissioning of a new landfill area. The permitting process is described comprehensively, including environmental impact assessment together with the environmental and dam safety monitoring. During the environmental impact assessment, observations on rare animals protected on European level were made as well as archaeological findings. Successful completion of the permitting allowed the construction phase to start on time. After six years of intensive work, the new landfill was commissioned in May 2018. The new landfill area provides a sustainable way to store the smelter’s slag for decades to come. INTRODUCTION Slag processing Sulphide based concentrates have always formed the main raw material stream at Harjavalta’s copper smelter. During the smelting and converting steps, the iron included in the concentrate is oxidized and fluxed using a silica-based sand. Originally, the slag was processed by using an electric slag cleaning furnace after which the final slag was water granulated. Froth flotation has been utilized for slag treatment since 1966. In the beginning, the slag was cooled in open ditches. In 1984, controlled slow cooling of slag was licenced to enhance copper recovery at the flotation plant. Today, the slag from both the smelting and converting is tapped/skimmed to slag ladles and treated in the following steps: Slag ladle transportation from the smelter to the cooling area by slag hauler Slow cooling of slag in the ladle to allow mineral precipitation Unloading the slag by tilting the ladle; causing the slag to crush as it drops from the ladle Feeding the crushed slag (-500 mm) by wheel loader to a slag concentrator’s feed funnel followed by a conveyor belt transporting the slag to the concentrator plant Crushing and grinding using lump and pebble mills Froth flotation of the valuables Recycling the slag concentrate back to the smelter feed after dewatering Pumping the final copper slag to the landfill area.

Jan 1, 2019

By Howard W. Tipper, Richard B. Campbell

"The Quesnel Trough is underlain by a thick sequence of mainly Upper Triassic and Lower Jurassic volcanic-clastic and sedimentary rocks that lie between the highly deformed Proterozoic and Paleozoic rocks in the Omineca Geanticline to the east and the Upper Paleozoic Cache Creek Group in the Pinchi Geanticline to the west. Broad areas of the Trough between Kamloops and Williams Lake are covered by Eocene volcanics and sediments and by Miocene-Pliocene plateau lava. Granitic intrusions were apparently mainly confined to two major episodes; one about 200 m.y. ago (coeval with the Guichon batholith) and one about 100 m.y. ago. In addition, the region includes small granitic and syenitic intrusions, some porphyritic, that may be all or partly still younger. Exposures in the region are generally small and scattered, obscured by widespread, not necessarily thick glacial deposits. This, together with the extensive Tertiary cover, makes prospecting difficult. The part of the Quesnel Trough discussed here is the direct northwest-ward extension of the copper-rich Kamloops-Merritt-Princeton region. It contains the Boss Mountain molybdenum mine, related to a breccia zone induced in a batholith of the oldest group by a younger intrusion, and the Cariboo Bell copper deposit in Lower Jurassic volcanic-elastic rocks and syenitic intrusions. The Gibraltar deposit, in a 200-m.y. intrusion, is within the Pinchi Geanticline close to the margin of the Trough. Molybdenum prospects are mainly restricted within or near the 100-m.y. granitic rocks. Copper prospects, on the other hand, are most prominent in the volcanic-elastic rocks and in the 200-m.y.-old granitic rocks, although they can also be spatially related to younger intrusions. Copper thus has a wide potential distribution.The writers believe that the region is deserving of careful and comprehensive exploration by directly applying the knowledge and techniques developed in the important producing areas to the south. All of the major pre-Tertiary geological elements seem to have potential for mineral deposits; none should be ignored. A thorough knowledge of the thickness and distribution of the Tertiary rocks and the development of geophysical methods to ""see through"" them is of particular importance."

Jan 1, 1970

By A. C. Ter-Oganesyants, N. N. Anisimova, G. P. Kotukhova, G. N. Dylko

The process utilized at Norilsk Nickel Polar Circle Division for treating slimes from the electrorefining of copper and nickel was developed in the late nineteen fifties and has survived without any fundamental changes. This technology is a combination of pyro and hydrometallurgical operations to produce PGM concentrates that are sent away for refining. The characteristic feature of the current technology is multiple-stage, extended cycle treatment with significant incomplete production, low labour and automation efficiency and poor hygiene and sanitary conditions. To eliminate all negative aspects mentioned above, specialists of Norilsk Nickel Polar Circle Division have developed a new hydrometallurgical process for treating electrolytic slimes. The main steps of the flow sheet developed are autoclave leaching of the slimes and electrochemical opening-up of a cake from autoclave leaching. The implementation of the new process will allow Norilsk Nickel Polar Circle Division to shorten the process cycle 4-5-fold thus reducing the volume of incomplete production, considerably increase labour efficiency, simultaneously improving working conditions, upgrade the final concentrate, reducing costs and increasing PGM recovery during refining and, ensure higher security of precious metals by employing automated processes and vacuum sealed units.

Jan 1, 2004

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By James D. Bliss, David M. Sutphin

"On the basis of differences derived from genetic, descriptive, and grade-tonnage data, graphite deposits are classified here into three deposit types: disseminated flake, amorphous (microcrystalline), or graphite veins. Descriptive models have been constructed for each of these deposit types, and grade-tonnage models are constructed for disseminated flake and amorphous deposit types. Grade and tonnage data are used also to construct grade-tonnage models that assist in predicting the size and grade of undiscovered graphite deposits. The median tonnage and carbon grade of disseminated flake deposits are 240 000 tonnes and 9% carbon and for amorphous deposits, 130 000 tonnes and 40% carbon. The differences in grade between disseminated flake and amorphous deposit types are statistically significant, whereas the differences in amount of contained carbon are not .IntroductionIndustrial minerals, including mineral construction materials such as sand, gravel, and crushed stone, have historically exceeded metals in global production value. Today, industrial minerals are being used in new and sophisticated ways in response to the late 1980s emerging information- and service-based economies' requirements for less metal and more industrial minerals . Natural graphite is an example of one such mine ral that has been known since ancient times, and is now finding new applications. Graphite was first used as an industrial mineral in Bavaria in 1400 A.D. where it was an important component of crucibles. Traditionally, natural graphite has been used in heavy industries. New applications, such as development of carbon-magnesite bricks a decade ago and the current advancement of alumina/graphite refractories, are increasing its graphite use. Other new uses for natural graphite, such as the use of graphite powder as a thermal blanket for the continuous casting o f steel (Northern Miner, 1987) and the addition of expanded graphite to polyurethane foam where it acts as a flame retardant (Industrial Minerals, 1987), are increasing the demand for this mineral. To meet future demand for graphite and other industrial minerals, knowledge of the characteristics of the deposit types in which they are found is important. A further look at the deposit types for graphite and at construction of descriptive and grade-tonnage models is warranted .The graphite industry recognizes three basic types of graphite , distinguished primarily on the basis of grain size: crystalline flake, lump and chip, and amorphous. These naturally occurring forms of graphite are products of metamorphism and are found in schists of various types, gneisses, and marbles. Temperatures of at [east 400°C are thought to be required for graphite formation (Landis, 1971). Synthetic graphite, also known as artificial or manufactured graphite, is a man-made carbon product and offers higher purity and lower crystallinity than natural graphite. Several authors have written about graphite's unique physical and chemical properties and the uses for individual types of graphite (Krauss et 01., 1988; Graffin, 1983; and Harben and Bate s, 1984)."

Jan 1, 1990

By M. Piche

The western part of the Hauy Formation of the Opemisca Group, occurring near the town of Chapais, is described in this paper. As it has been defined previously, the Formation is composed of a succession of subaerial andesi tic lava flows with some interbedded proximal volcaniclastic sediments. Towards the East, these volcanics yield to coarse grained fluviatile sediments having similar composition to the interbedded lavas. Further east, the composition of these sediments is more arkosic with dioritic and tonalitic fragments. It is proposed that these arkosic sediments are a part of the Stella Formation which has been described by Dimroth et al. (1982).

Jan 1, 1984

By P. E. Fox, R. S. Cameron

"The QR gold deposit lies in the Cariboo plateau region of central British Columbia. The deposit was discovered in 1977 and since then a mineable reserve of 1.3 million tonnes grading 4.7 g/t Au has' been outlined in three separate zones. Soil sampling of glacial tills followed by diamond drilling of favourable host rocks proved to be key exploration techniques.The deposit is situated in the southern Quesnel terrane along the eastern fringe of the Intermontane Belt which here comprises a sequence of basic and intermediate volcanics and a series of stocks of alkaline affinity; generally diorite, monzonite and syenite. Hornfels and epidote-rich ferromagnesian exoskarn and sulphide-rich mantos have developed in a metamorphic aureole formed around a central diorite stock. Gold-rich zones lie along the outer periphery of the aureole where bodies of gold-bearing epidote-rich skarn and auriferous mantos rich in epidote and pyrite have formed in beds of calcareous tuffite lying at the top of a thick basaltic sequence. The deposit is regarded as' a subclass of gold skarn deposits. Diagnostic features are its association with alkalic intrusive rocks in a subvolcanic setting and the presence of oxidized, epidote-rich mineral assemblages.IntroductionThe QR gold deposit lies within the Cariboo plateau region of central British Columbia, 58 km southeast of Quesnel. The deposit, owned by Kinross Gold, was discovered during a regional reconnaissance program by Dome Exploration (Canada) Limited and Newconex Canadian Exploration in 1977. Considerable exploration and development has been done since that time. Mineable reserves of 1.3 million tonnes grading 4.7 g/t Au have been outlined to date in three zones."

Jan 1, 1995

By Frands Jensen, Erik Eriksson

"Haldor Topsoe’s Wet gas Sulfuric Acid (WSA) technology has been proven in a number of industries converting sulfurous gasses to concentrated sulfuric acid. In the metallurgical sector plants have been delivered handling SO2 gasses from copper, zinc, molybdenum, and lead ore. WSA has high energy efficiency and allows autothermal operation from feed gas strengths as low as 3.0% (volume). Recent variants of the WSA process have been developed that allow very high SO2 conversion efficiencies of over 99.9%. This paper describes the technology, its advantages and industrial achievements.The WSA technology is well suited for production of concentrated sulfuric acid of commercial quality from the sulfur dioxide (SO2) gas that inevitably emerges from the metallurgical processes. Some of the features that make the WSA technology attractive for this application are:- High SO2 conversion rates (up to 99.99%)- High energy efficiency leading to a low autothermal point (~ 3% SO2)- No need for gas cooling and drying to produce concentrated sulfuric acid- No production of waste- Very low cooling water consumptionThis paper describes the WSA process principles and highlights features that make this process attractive for handling SO2 gases."

Jan 1, 2014

By Frederick J. Browne

Water, water everywhere, but not a drop (fit) to drink! Trite, but how often only too true? What is there met with in mining which, under various circumstances, may be said to be the most sought-for and highly-prized and also the most objectionable and most feared? Water! What visions that combination of five letters brings to all thoughtful minds? Up to near the end of the eighteenth century water was thought lo be an element but was then discovered to be the result of the combustion of two volumes of hydrogen with one volume of oxygen, and water so produced is chemically pure. Pure water is a clear and colourless liquid when seen under ordinary conditions, but appears bluish when seen through a long tube, and this same bluish tint may be observed in many lakes, especially those of glacial origin. A story often told describes a prospector in the desert who, failing to find water to replenish his canteen, suffers torture and death under fearful circumstances. Then again we may recall the flooding of mines, where water poured in so quickly that there was no opportunity of saving the unfortunate workmen. Instances might be multiplied without number showing that either the lack or excess of this essential fluid has taken heavy toll of human life. In all branches of mining and associated industries water must be dealt with to a larger extent, from an economic point of view, than any other substance, and very often the purity of the water is a matter of considerable importance.

Jan 1, 1925

By Michel Ruel, Ali Soltanzadeh, Benjamin Légaré

High fidelity commercial process simulation packages can be used at different stages of a greenfield project, from initial plant design to operator training in the later stages. However, there are several factors that make the software less attractive for small and medium size brownfield projects, such as the licensing cost and the fact-finding manpower required for model design and simulator maintenance. In this paper a different approach is described. The knowledge gathered from operating personnel was used to implement higher level models based on plant data, operating heuristics, and experience rather than detailed component-level models. The computing platform used was a low-cost, well-established, control system vendor-independent software. Throughout this paper we demonstrate the success of implementing this model-based approach using two industrial examples. The first example is a simulation of the carbon monoxide (CO) distribution system at a metallurgical complex. The purpose of this simulator was to test new control strategies and PLC programs prior to implementation. CO being a toxic combustible gas, validation of the suggested control system changes was necessary for plant safety. Simulation of specific operating conditions helped alleviate concerns and improved plant-wide acceptability of the new operating philosophy. The second example is a boiler simulator at a petrochemical plant. The operator training simulator (OTS) was designed as a platform for experienced operators to practice handling rare or abnormal conditions. A customized medium-fidelity model was developed for this targeted application where the cost of a full scale high-fidelity model could not be justified.

Jan 1, 2016