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By George S. Rice

Foreword Explosion hazards differ widely in the mines of different fields or coal basins. They also differ as between different mines in the same basin or fold, because of variations in gas entering the mines, and because dust conditions and explosion hazards are affected by the mining methods employed and the organization of the work. It is unquestionably true, however, that there are greater differences in explosion hazards in mines of different coal fields or basins than between different mines of the same field or basin. In these respects, the coal fields and individual mines in Alberta are not exceptional. The same conditions obtain in various countries where coal is mined, and are found in single States, as for example in Colorado, where coals are mined ranging in character from sub-bituminous to anthracite, and in attitude from flat horizontal to steeply pitching beds. The U.S. Bureau of Mines, at its experimental mine near Pittsburgh, Pa., has made large-scale tests of the relative explosibility of dusts of coals, ranging in rank from Wyoming sub-bituminous coal containing 19 per cent moisture, to anthracite from Pennsylvania, and including samples from a mine in the Crowsnest Pass district, B.C., and from a Vancouver Island mine. The Bureau has also made similar tests of the dust of coal from a Yorkshire mine which the British Safety-in-Mines Research Board uses as standard.

Jan 1, 1927

By Unknown

With the present-day trend of rising labour costs and a lowering of production efficiency of workmen, it has become imperative that every effort be made to use manpower to the greatest advantage and to mechanize mining as much as possible. During the past few years this trend has gained much prominence in the Porcupine camp. In view of this, the executive of the Porcupine Branch considered that the Mechanical Movement of Muck would be a very timely subject for a Symposium. Accordingly a Committee was formed, with A. K. Douglass, Mine Superintendent for Delnite Mines, Ltd., as Chairman, and the Symposium was held in the Auditorium of the McIntyre Community Building, Schumacher, on March 25th last. Papers dealing with shovel loader and mechanical scraper operation at six of the larger mines of the camp were presented and discussed, and a tabulation was prepared giving data on the machines in operation at a total of eleven mines. The papers and tabulation, reproduced below, will doubtless be of considerable interest to operators of mines in all parts of Canada.

Jan 1, 1948

By I. C. Christopher

Introduction The geology of the Cochen-our Willans gold mine has been described in reports by the late Dr. H. C. Horwood (1) in 1940 and by Dr. J. P. Nowlan (2) in 1947. Information from these and other (unpublished) reports has been incorporated in the present paper, together with some recent ideas regarding structural features which are at present being used to locate ore shoots. Location and History The mining claims of Cochenour Willans Gold Mines, Limited, occupy 705 acres in Dome township, on the east shore of Red lake opposite McKenzie island. Adjoining properties are those of McKenzie Red Lake Gold Mines on the west, Boymar Gold Mines on the north, Marcus Gold Mines on the east, and Martin-McNeely Gold Mines on the south. The claims of the original group were staked by W. M. Cochenour, Dan Willans, and H. G. Young, and the Cochenour Willans Syndicate was formed in 1928. Work was carried out by the Syndicate and several other companies during the next eight years with inconclusive results, due to the irregular occurrence of the ore. In 1936, Cochenour Willans Gold Mines, Limited, was incorporated and production was finally started late in 1939.

Jan 1, 1951

By Guy Demers

"This paper defines the responsibilities and functions of the Maintenance Department, and its organization, physical and human assets, highlighting the unique operating problems. Due to the self-sufficient aspect of the Asbestos Hill Deception Bay project, the Maintenance Department cover-s fields that are numerous and very dissimilar: production, mobile, processing, service, power generation, fire protection, heating, water and sewage disposal equipment. Added to this, buildings, plant and camps, wharves and communications equipment all demand versatility, adaptability and expertise from maintenance personnel. Good maintenance practices are a necessity in this environment and are more critical than at southern locations; that is, high-quality replacement material, complete and well-controlled preventive maintenance, major repairs on a component-replacement basis, updated inventory, efficient training and permanent contacts with suppliers, combined with an equipment improvement program, updated specifications on lubricants, hoses, seals, filters, etc., are mandatory. The seasonal aspect of the operations applies a great deal of pressure on the maintenance team, as the production months do not permit major repairs. Short- and medium range planning and accurate evaluation of equipment conditions highly influence production efficiency. Maintenance control, planning and scheduling do not follow the accepted standard routines, as personnel turnover normally does not permit an accumulation of knowledge of the equipment history and condition by the •individual tradesman."

Jan 1, 1976

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By Kevin J. Melong

"Redpath Canada Limited and joint venture partner Thyssen Mining and Construction Canada have recently completed the sinking of the Scissors Creek service in Saskatchewan through its joint owned company, Associated Mining Construction (AMC). The Scissors Creek service shaft was sunk at Nutrien’s Rocanville mine. The following paper outlines the shaft sinking plant and the methodology related to sinking and shaft lining. KEYWORDS Hydraulic shaft jumbo, Hydraulic shaft mucker, Potash shaft sinking, Shaft lining, Sinking galloway INTRODUCTION The sinking and lining of shafts at mines to access mineral deposits has always been one of the great mining challenges for owners, engineers and contractors. Over the course of history in Canadian mining, the sinking of potash shafts through the notorious Blairmore formation of Saskatchewan has proved to be some of the most challenging shaft sinking projects on record. There is no doubt that today’s shaft sinking business demands the utmost in safety performance while delivering projects within schedule and budget. Given these requisites, Redpath and TMCC (executed under the joint venture company, Associated Mining Construction or AMC), were taxed with developing the shaft sinking system to deliver this program in the safest and cost effective manner, with due regard to schedule and quality. Traditionally the potash shafts sunk in Saskatchewan involved a significant level of manual labour, owing to the methodology of excavation by means of chipping the frozen shaft sections with hand held pneumatic machines, and manually placing tubbing segments or steel liners of the shaft lining system. Most certainly, the AMC team wanted to make a step change from those earlier sinking programs and develop systems for sinking this potash shaft that removed the high level of manual work, thus making this project inherently safer, while endeavoring to sink more efficiently. With that in mind, the team embarked on a design program to improve its overall shaft sinking systems without the requirement for excessive capital and methodology flexibility to adapt to potential changing conditions expected to be encountered during shaft sinking. This was especially important should the new approach be met with less than expected success, and retrofitting of the system was required. The concepts were developed to provide for a much improved work environment, while easing the manual labour burden on the workers with innovative equipment and approach to the work."

Jan 1, 2019

By H. A. Hamza, J. Visman

"This is a report on the combined application of ""long-chain"" flocculants and classifier cyclones in the field of slimes treatment, with emphasis on the simultaneous thickening and clarifying of industrial effluents, at low cost. The principle of the process described below involves: (1) the formation of small floes of relatively great strength, by sequential dispersion and conditioning, with average floe size of about 1501 microns; (2) the floes being of sufficient strength to withstand the shearing forces operating within a cyclone and consequently behaving as solid particles with an equivalent diameter (Stokes) that exceeds the size cutpoint of the classifier cyclone; (3) the removal of flocculated solids by means of a classifier cyclone the size cutpoint of which permits effective separation of these solids from the water. Results of test work to date indicate that a broader use of cyclones in industry is possible with the above types of flocculants because the submicron particles and colloidal material are readily collected and clear water is produced, with the attendant advantages of compact construction and low cost that are characteristic of centrifugal separation. The process generally permits classifier cyclones of medium throughput capacity (e.g. 12-in. diam.) to be used for clarifying effluents that contain minus 10-micron particles."

Jan 1, 1973

By Stephen G. Mlot

Technical Study Work ?Technical study work enables informed decisions: -Obtain a higher price for a quality asset -Minimize expenditure on a project that won?t provide adequate returns -Optimize expenditure on a project to capitalize on the potential return

May 1, 2013

By Ross D. Lawrence

"Comparable transaction analysis is the best known of the market approaches to valuation of exploration-stage mineral properties. The analysis of option and farm-in agreements can also provide useful guidance to valuators. While such approaches can be distorted by incomplete analysis, market-based methods are capable of providing consistent, credible results when carried out carefully with due consideration paid to all factors which buyers and sellers consider when dealing in the real market.RÉSUMÉRoss D. Lawrence graduated from the University of Toronto with a B.A.Sc. (Applied Geology-1956) and an M.Comm. (Mining Finance-1959). As a student and following graduation, he worked across Canada on a variety of mineral exploration projects.In 1962, he was one of the founders of Watts, Griffis and McOuat, and has practiced as consulting engineer since then. For the past 20 years, Mr. Lawrence has headed up the WGM valuation practice, responsible for a group of professionals which has carried out scores of valuations of mineral properties and mining companies. He is a Certified Minerals Appraiser of the AIMA and an active participant in professional affairs.INTRODUCTIONMineral properties without defined resources present one of the most challenging tasks to the mineral valuator. You will hear from others at this conference about the use of cost and income approaches to the problem of valuing exploration properties. This paper will concentrate on market-based approaches. Market based-approaches are based on the principle of substitution and include such techniques as:??Comparable transaction analysis (sometimes referred to as sales comparison analysis).??Farm-in commitment analysis??Rules of thumbAre there any valuation standards available to assist the valuator? In Canada there are none that apply to the valuation of mineral assets or securities. This problem is being addressed, at least in part, by the CIMVal committee of the Canadian Institute of Mining, Metallurgy & Petroleum (CIM)1. Further, the recently established Canadian Association of Mineral Valuators will be giving consideration to the adoption of valuation standards."

Jan 1, 2003

By V. I. Lakshmanan, R. Roy

"Zinc is the fourth most widely used metal in the world after iron, aluminum and copper. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing the steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Process Research ORTECH Inc. has developed an efficient energy-saving sustainable technology for the recovery of zinc from secondary sources such as galvanized steel scrap, dross, dusts etc. The process consists of treating the zinc containing scrap in an alkaline solution to remove the zinc and thereby producing a zinc free steel scrap for recycle. The zinc containing leach liquor is subjected to a solvent extraction process to recover value added zinc oxide as the final product. In this paper, important industrial processes for the recycling of zinc including the PRO process will be discussed. BACKGROUNDZinc is the fourth most widely used metal in the world after iron, aluminum and copper. Global refined zinc output increased by 2.7 per cent to 13.16 million tonnes in 2011 and is expected to increase by an additional 2.4 per cent to 13.48 million tonnes in 2012 [1]. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Other major usages of zinc are in the production of brass and bronze, die casting and zinc-air batteries. The additional demand for zinc could come from its addition to fertilizers to increase crop yield.While the demand for zinc is increasing, many mines are scheduled to close in near future after being depleted of ore. The mines set to close between now and 2015 are Teck Resources’ Red Dog Mine in Alaska, Minmetals’ Century Mine in Australia and Vedanta Resource’s Skorpion Mine in Namibia [1]. The depletion of resources due to continued use and exploitation is becoming a great concern for the zinc industry. As a result, the sustainability of natural resources for continued societal care has become extremely important. Resource conservation and recovery by recycling with minimal environmental impact is a key element for sustainable development. In this paper, important industrial processes for the recycling of zinc including the PRO process are presented."

Jan 1, 2012

By G. A. Bezuidenhout, J. Davis, S. M. Bradshaw, J. P. T. Kapusta, D. K. Chibwe

"This research work forms part of an assessment to complement the feasibility of implementing high pressure sonic injection into relatively small (2.25 m I.D by 3.66 m I.L) Peirce-Smith converters (PSC) used at Lonmin Plc. Work has been carried out to characterize the fluid dynamics of three-phase (air, matte and slag) fluid flow in these converters using Computational Fluid Dynamics (CFD) simulations. The investigation has been done to study the flow pattern of the three phase system at high air pressure injection achieving sonic velocity at the tuyere exit into the converter. The 2-D and 3-D simulations of the three phase system were carried out using the volume of fluid (VOF) and realizable k -e turbulence models to account for the multiphase and turbulence nature of the flow, respectively. These models were implemented using the commercial CFD numerical code FLUENT. A detailed study of the flow pattern has been presented in the form of contour plots and the results obtained are useful for understanding plume extension and velocity distribution, shear wall stress distribution, and phase distribution characteristics in the system. The results provide a basis for further development of sonic injection technology into relatively small industrial Peirce-Smith converters with the ultimate objective of achieving lower energy consumption, improved process efficiency and increased throughput of the converting process. INTRODUCTIONPeirce-Smith converters (PSC) have been used in copper (Cu) and nickel (Ni) making smelters for more than a century for the purpose of removing iron (Fe) and sulphur (S) chemically associated with copper-nickel mattes through exothermic oxidation reactions. This process is commonly referred to as conversion. In principle, conversion is a submerged injection process, where typically air (or oxygen enriched air), at subsonic velocity (typically < 150 m/s), is laterally blown into liquid matte (Cu-Ni-Fe-S system). Oxygen preferentially reacts with Fe and S to produce iron oxide (FeO), which is slagged off, and sulphur dioxide (SO2), which reports to the process off gas."

Jan 1, 2012

By R. I. Kraydenko, A. N. Dyachenko

"The possibility of SiO2 5N production by staged purification of ammonium hexafluosilicate (NH4)2SiF6 is discussed. High-purity silicon dioxide can be obtained with fluoridation of quartz concentrate by solid NH4F at 100 °C, with further sublimation of the product at 320 °C, its dissolution, ammonia hydrolysis, filtration and drying of SiO2•nH2O. This is accompanied by regeneration of the processing reagent - NH4F.INTRODUCTIONProduction of high-purity silica-5N (SiO2 content over 99.999%) is an important and urgent task of the modern chemical industry. This material is used in the manufacture of optical glass, optical fibers for internet cables, silicon for solar power and electronics.Quartz concentrate is raw material for the production of silicon dioxide. The existing technologies of synthetic silicon dioxide were introduced in the mid-twentieth century. These methods are energy-consuming, multi-step and do not meet stringent environmental requirements. In fact, as some conventional technologies became obsolete; it became necessary to develop new methods for the production of synthetic silica. We believe that the fluoride technology of processing of quartz materials by ammonium fluoride is the most promising direction.In industry, silicon dioxide marked ""Silica White"" is obtained by liquid-phase method. The method consists of the precipitation of amorphous silica from sodium silicate solutions with acids. The resulting product is filtered, washed and dried. Depending on the deposition conditions and nature of the coagulant the ""Silica White"" is acidic, neutral or alkaline. The dry product is subjected to grinding. The degree of dispersion and porosity of the particles of Silica White depends on the nature of decomposition agent (a substance that decomposes the silicate) and coagulant, conditions of sedimentation, filtration and drying. During the drying process the silica particles are sintered into aggregates of a few millimeters."

Jan 1, 2012

By O. Lashkari

Manipulation of pouring temperature is an efficient way to produce different microstructural features. In order to characterize the microstructure of rheocast billets due to different superheats of 615-695 °C, the parallel plate compression method was employed. Foundry 356 Al-Si alloy with different morphologies of primary a-Al particles were tested at different initial pressures of 4,8, 11,2 KPa, The resulted strain-time graphs were further treated mathematically to calculate viscosity of SSM billets. The interrelationships of viscosity, the microstructure and primary phase flow during compression are discussed, It is shown that the dendritic primary a-Al structure has the highest viscosity number which is almost three orders of magnitude greater than those for globular morphology, The current research have, for the first time, shown the validity and reliability of "parallel plate compression viscometry" method in characterizing microstructural evolution of Rheocast SSM billets.

Jan 1, 2005

By P. deH. Eastcott

The paper summarizes a slide presentation made during the CIM Mechanical-Electrical Operators&apos; Conference, held at Sudbury. Ontario, January 25-27, 1977. Its scope has been limited to a few specific aspects of modern Canadian hoisting plant practice that are likely to be of interest to operating personnel. It is intended to serve as a brief review of established methods discuss in more detail the present state-of-the-art and suggest trends that will appear as products during the next few years.

Jan 1, 1977

By George P. Demopoulos

In a departure from the traditional domain of hydrometallurgical extraction processes we consider new R&D opportunities for innovative application of solution processing into the advanced green energy and clean technology fields. It would not be an exaggeration if we state that protection of the environment via advancement of clean technologies on the one hand, and harvesting and utilizing renewable energy in a sustainable and cost-effective way on the other hand are clearly among the top pressing global priorities. When hydrometallurgy is approached on the basis of its aqueous chemistry and reactive processing fundamentals, it can indeed provide a highly fertile ground for innovation outside the "box". In this context therefore we will present highlights from our recent research that is directed towards the development of new generation HCl recycling, environmental, and solar energy conversion/storage technologies. In all systems the research is approached via the innovative integration of aqueous process engineering and material chemistry principles. The presentation will include discussion of (i) the development of crystallization-based HCl regeneration technologies; (ii) the supersaturation-controlled production and encapsulation of scorodite that was recently commercialized; (iii) the aqueous synthesis of nano-TiO2 and its electrophoretic deposition into solar cell electrodes; and (iv) the hydrothermal synthesis of nanostructured lithium titanate and lithium iron phosphate materials to make lithium-ion batteries destined for electric cars.

Jan 1, 2014

By J. F. Henderson

Stable mining operations commenced in the Northwest Territories in 1933. Pitchblende from Great Bear lake and gold from the Yellowknife district are the main minerals produced. The value of pitchblende products produced from 1933 to 1941 was nearly $6; 000; 000; data on subsequent production are not available. The first gold was produced from the Con mine at Yellowknife in 1938. Other properties that later came into production include the Negus; Slave Lake; Thompson Lundmark; and Ptarmigan mines. The annual gold production reached $3; 862; 000 in 1942 but due to the war and consequent labour shortage fell to $333; 218 in 1945. The only producing mines at present (May; 1947) are the Con and Negus; but several promising properties are under development; including that of Giant Yellowknife Gold Mines where large tonnages of ore are being blocked out. With the reopening of former producing mines and new production from properties now being developed; gold production should rapidly increase and exceed its former peak within the next few years.

Jan 1, 1954

By T. Schepp, T. Friedrich

"The natural stage of deep mines operation is a closure of unnecessary shafts. It is extremely important to ensure a proper shaft closure to avoid stability loss and the associated damage to surface facilities in the future. For the still active shafts, it can be done by a dedicated shaft closure design, but even then, depending on the shaft closure method, it may be necessary to perform regular shaft inspections. The paper presents a short overview of shaft closure methods and available tools and devices developed in the last time for such shaft inspections. INTRODUCTION The natural stage of deep mines operation, commonly occurring after depletion of the reserves of mined materials, is a closure of unnecessary shafts. All over the world, the number of liquidated shafts grows continuously and the problem of shafts disposal is especially critical for deep shafts. The typical depth of 600 m of currently liquidated shafts in Poland may already be seen as a challenging task. The greater is the challenge of shaft closure in Germany where the last active coal mines for shafts with a depth of up to 1,300 m have been recently closed. It is therefore extremely important to ensure a proper shaft closure to avoid stability loss and the associated damage to surface facilities in the future. For the still active shafts, it can be done by a dedicated shaft closure design, but even then, depending on the shaft closure method, it may be necessary to perform regular shaft inspections. In many cases, it is more important to inspect old, abandoned shafts, where the wall stability or even liner type are not fully known. SHAFT CLOSURE METHODS Abandoning a shaft is a complicated task, as shafts, being the link between the surface and an underground network of workings, disturb hydrogeological and gaseous conditions in the rock mass (Sztelak, 1991). Closure procedures at older mine sites have been carried out in accordance with earlier legislative requirements. For very old shafts (+100 years), it means in many cases only a sealing of the shaft entrances by means of timber or concrete slabs. In the 20th century, the shafts were also closed by means of filling with grainy materials, but even then the retrospective activities at abandoned mine sites were extremely limited and in most cases no further monitoring measures were performed. The possible consequence of an improper shaft closure and lack of monitoring is presented in Figure 1."

Jan 1, 2019

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

By Simon P. Fricker

Gold drugs have been used for the treatment of rheumatoid arthritis since the mid 20th century as disease-modifying antirheumatic drugs (DMARD) class. Methotrexate is often the preferred DMARD, and with the advent of new therapies gold drugs are now used infrequently. Since the introduction of auranofin in 1985 there has been no new clinically approved gold drug. In spite of this apparent lack of progress there has been a great deal of interest in the use of gold compounds for cancer therapy and early promising indications were achieved with a gold phosphine complex [Au(dppe)2]Cl. This compound was not entered for clinical trials, however, due to problems with cardiotoxicity highlighted during pre-clinical toxicology studies. Gold(III) is isoelectronic (d8) with platinum(II) and likewise forms square planar complexes. It is therefore tempting to speculate that such complexes would have similar antitumor activity to cisplatin. In order to stabilise the gold(III) oxidation cycloaurated complexes were synthesised with a single mononegative bidentate ligand, damp, (2-[(dimethylamino)methyl]phenyl), and two monodentate anionic ligands e.g. Cl or acetate. The damp ligand forms part of a five-membered chelate ring. The monodentate ligands are readily hydrolysed and are available for substitution. These compounds had limited anti-tumor activity in in vivo against human tumor xenografts. Mechanistic studies indicated that these compounds had a different mechanism of action to cisplatin. An alternative molecular target for these compounds is biologically important thiol-containing molecules such as the cysteine protease cathepsin B. Modifications were made to the Au(III) damp structure to give compounds with a six-membered chelate ring. These compounds were shown to be inhibitors of cathepsin B. Compounds were also tested for cytotoxicity against a panel of human tumor cell lines. Three compounds were selected for further evaluation against a human colon tumor xenograft. The compounds showed modest anti-tumor activity but with no marked improvement over the parent Au(III)damp complexes. Initial indications are that Au(III) compounds targeted against disease-specific thiol-containing biological molecules have potential as drugs, particularly for cancer. However, further work is required to produce a target-specific drug with a suitable pharmacological activity and toxicity profile.

Oct 1, 2003

By P. C. Patnaik

Performance of industrial gas turbine engines in terms of power output, reduced cooling and efficiency have been continuously increasing in parallel with aero gas turbines due to the advances made in the development of new materials, protective thermal barrier coatings (TBCs) and the advanced diagnostics to monitor service induced problems such as hot corrosion, thermal and thermo-mechanical fatigue and other operational issues, Environmental attack (hot corrosion or high temperature oxidation) is a common degradation mode in the hot section of the gas turbine, Hot corrosion occurs when Na or K bearing compounds in the environment or in the fuel combine with other contaminants such as S and Pb or V to form corrosive sulphates or vanadates thus attacking the protective oxide on the turbine airfoil, These problems pose far more threat to new turbine engine materials such as directional solidified, single crystals and ceramic matrix composites (CMCs). The CMCs due to their increased temperature capability, when used in the combustion chamber, are likely to reduce the peak temperatures attained during combustion and therefore provide the benefits of reduced emissions of oxides of C and N, These issues will be reviewed critically and their impact will be assessed on gas turbine lives. With respect to alternate fuels, past experience has shown that utilization of residual oils and coal derived fuels in gas turbines have resulted in complex deposition and corrosion processes, In recent years biomass derived alternate fuels have been used either through a gasification cycle or through direct firing of the biomass derived liquid fuel with a view to reduce Green House Gases (GHGs) and improve the climatic conditions. In both cases, the resulting high temperature corrosion processes (in the presence of alkaloids in the fuel) are also very complex, leading to premature removal of hot section components, Technology solutions mitigating these fundamental problems will be reviewed and solutions presented.

Jan 1, 2005