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By J. Schmidt

Cold drawing of copper wire rod is usually combined with an in-line annealing process to adjust the ductile microstructure of the wire again. One important key factor for successful annealing is the quality of the copper itself. Rod producers can check the recrystallization behaviour of the rod by different methods: chemical analysis, Spiral Elongation Test (SEN) as well as the Rapid Elongation Test (AR) are some examples of common testing methods. The comparison of the results of these methods does not always show sufficient correlations. The paper introduces firstly the SEN and AR-Tests and their different approaches to the mentioned task. The second step is to compare some results of the SEN-Test with the results of the AR-Test and identify causes of deviations. Thirdly, the effect of pre-annealing is discussed, which is especially common for wire rod with diameters of more than 8 mm.

Jan 1, 2007

By O. -J. Siljan

"Refractory materials are an integral part of aluminium production. One special feature of aluminium making is the prominent role of sodium in all parts of the production process. This presence of sodium inflicts stresses on the refractory materials through reactions and may cause severe damages to the refractory linings. The present paper address possible reactions between sodium and refractories in anode bake furnaces, electrolytic pots and casting furnaces. The discussions presented in the paper points to the importance of selecting materials with excellent alkali resistance in all parts of the aluminium making process, although alkali resistance is not the sole parameter to determine refractory life-time. ""Acid"", i.e. silica-rich alumino-silicate refractories are shown to be the best materials for aluminium electrolysis cell potlinings, whereas high- alumina refractories based on minerals like andalusite seems to be the preferred choice for anode bake furnaces as well as cast house furnaces."

Jan 1, 2004

By Mostafa Benzaazoua, Bruno Bussière, Jean Lelièvre

De nombreuses opérations mimères exploitent et traitent des minerais sulfurés pour concentrer des métaux precieux (Au, Ag ... ) OU des métaux de base (Cu, Pb, Zn ... ), laissant en fin de parcours des tonnages considérables de résidus plus ou moins générateurs de drainage minier acide (DMA) selon leur contenu en sulfures. De nos jours, Jes restrictions en matière de protection de l'environnement obligent Jes opérateurs miniers a trouver Jes solutions Jes plus efficaces pour préserver Jes sites environnants de la pollution due a l'oxydation des sulfures. Cette oxydation cause une acidification accrue du milieu et une mise en solution des metaux toxiques. L'utilisation des recouvrements multicouches est l'une des solutions Jes plus efficaces pour limiter la pollution liée au DMA mais entraine des coilts de construction qui sont souvent considérés par l'industrie miniere comme prohibitifs. Une façon de rendre cette technologie applicable, d'un point de vue économique, est de désulfurer Jes résidus à l'usine de traitement et d'utiliser la fraction inerte comme composante d'un recouvrernent multicouche. Cette opération de desulfuration peut etre réalisée par flottation non sélective des résidus dans le but d'obtenir d'une part un faible volume de concentré de sulfures qui devra être géré convenablement et d'autre part un rejet non générateur d'acide.

Jan 1, 1998

By Robert B. Parsons

"Finance Minister Paul Martin's first budget disappointed almost everyone. The business sector was disappointed at the some what feeble attempt to grapple with the country's deficit. The mining industry was disappointed by tax proposals regarding mine reclamation that fall short of the industry's needs. Has anybody been happy with a federal budget? Federal Budget DisappointsThe federal government's budget papers that were tabled on February 22, 1994, contained a rather bizarre mixture of unrelated tax proposals. The budget signals an unexpected attack on the tax treatment of debt settlements, on certain types of corporate reorgani2ations, and on income earned by foreign affiliates. This is an old style budget, which proposes a pot pourri of technical changes and policy initiatives. Mine ReclamationEffective February 23, 1994, a taxpayer's contributions to a prescribed mine reclamation trust fund will be deductible as a current expense. The budget papers do not provide a definition of what will constitute a ""prescribed"" trust: this definition will surface in due course. However, the budget papers indicate that:• income earned in such trusts will be subject to tax each year;• all withdrawals from the trust (including income already taxed) will be included in computing the income for tax purposes of the recipient;• reclamation costs will continue to be fully deductible at the time incurred; and • contributions, trust earnings, and withdrawals will not be taken into account for the purposes of determining a taxpayer's resource allowance."

Jan 1, 1994

By Denis Landry

"RÉSUMÉAu cours de dix dernières années, la compagnie Maghemite a développé, expérimenté et breveté un nouveau precédé de concentration du minerai de fer à partir de la récupération d'hématite présente au bassin de sédimentation de la Compagnie Minière Québec Cartier.A partir de cette nouvelle technologie de concentration par induction, la compagnie Maghemite produit une poudre d'hématite qui est mélangée avec du strontium carbonate à un ratio de l à 6 en poids. Le mélange homogène est achemine sur un disque d'agglomération, et ensuite incorpore dans la fournaise de la Compagnie Minière Québec Cartier. Le temps de cuisson et la température (l200°C) correspondent exactement aux critères nécessaires pour la fabrication d'aimants de céramique, Grade 5, à partir de la poudre de ferrite.IntroductionMeghemite a débuté sa production de poudre de ferrite au printemps 1986et prévoit une production de 20 000 tonnes par année dans cette nouvelle usine. A très court terrne, une usine sera construite pour la production de cinq à dix millions de Iivres d'aimants permanents par annee et à long terme qu'une usine de fabrication par robotique de moteurs à aimants permanents, utilises dans I'industrie automobile. La poudre de ferrite à base de strontium est une compose ferro-magnétique forme d'une molécule d'oxide de strontium et de six molécules d'hernatite. Ce compose d'hexa fluorite de strontium a une force tres puissante et fournit la source d'énergie magnétique la moins dispendieuse comparée aux autres aimants permanents. L'utilisation des aimants de céramique formes d'hexa fluorite de strontium a connu un croissance phenornenale depuis 1970 pour atteindre un marché de 500 millions de livres par année en 1985.II n'y a aucune autre usine de production commerciale de poudre de ferrite à base de strontium au Canada. Le facteur determinant qui a favorise l'etabilissement a Port Cartier est base sur la réduction de 30% du cout des aimants de cerarnique provenant de notre poudre. Notre debouche majeur se situe aux États-Unis et vise la production des aimants de cerarnique pour les moteurs utilises dans les automobiles, les ordinateurs et les appareils ménagers, L'objectif de cette compagnie est de réduire le prix futur des aimants de cerarnique à environ 30% du prix actuel.L'usine commerciale de production de poudre de ferrite est maintenant opérationnelle. Le financement et la construction de cette usine sont Ie résultat de l'opération d'une usine pilote sur une période de 5 ans afin de récupérer l'hematite d'un haut niveau de pureté provenant de résidus de I'usine de bouletage de la Compagnie Minière Québec Cartier (CMQC) à Port Cartier. La fournaise de CMQC est utilisee pour chauffer les boulettes cornposees d'un mélange de carbonate de strontium et d'hematite d'un haut niveau de pureté en étalant environ 5 tonnes à l'heure de ces boulettes au-dessus du tablier de boulettes de fer dans une des fournaises fonctionnant à environ 450 tonnes à l'heure."

Jan 1, 1987

By Grazyna Zakrzewska-Trznadel

The paper outlines the main objectives of the project that concern the evaluation of the possibility of uranium production from indigenous resources since Poland enters the nuclear program. The best available technologies are considered for uranium extraction and obtaining the yellow cake - U3O8. Liquid-liquid extraction with novel extracting agents, as well as membrane processes for separation of by-products will be tested in course of the project. The technological part will be completed with techno-economical analysis. Acknowledgement The studies were supported by the POIG project, No 01.01.02-14-094-09-00 ?Analysis of the possibility of uranium supply from domestic resources?.

Aug 1, 2010

By Y. Dong, L. Li, L. Yu

Converter slag has become an important secondary raw material. Consequently, vanadium bearing converter slag is of great interest for the recovery of vanadium. Solidified converter slags are made up of three main mineral components: dicalcium silicate, calcium ferrite and wustite. Vanadium in modified slow cooling down converter slag of Magang is found mainly concentrated in a separate mineral phase. The mineral phase with high content of vanadium (24%, wt, V205), concentrating 83% of vanadium, can be separated from the slag for economical vanadium recovery. Some characters of the mineral phase were discussed comparing with dicalcium silicate, one of the typical mineral phases in converter slag studied well.

Jan 1, 2004

By J. Scalise

The paper covers a wide range of topics relative to filtration for continuous cast copper and aluminum. Subjects include system concepts, filtration concepts, system components, filter types, filter media selection, caster water filtration, coolant disposal, and recommended materials of construction.

Jan 1, 2007

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005

By H. M. A. Rice

"The Ainsworth mining camp is on the west side of Kootenay lake; British Columbia; 14 miles south of the town of Kaslo. It is in one of the oldest mining districts in central British Columbia; for mining started there in 1888. Its principal production was between 1905 and 1920. Activity since then has been sporadic. According to available records; some 222; 000 tons of ore had been produced from the camp up to 1942.GENERAL GEOLOGY Bedrock in the district consists of a succession of quartzite, quartz-mica schist, hornblende schist, and limestone of Late Precambrian, Carboniferous, and Triassic age. Most of the hornblende schists are of volcanic origin but some formed from related intrusions. The Nelson granodiorite batholith of Jurassic age borders the camp on the west. There is also a series of basic dykes of much later age."

Jan 1, 1954

By J. P. Mogan, E. D. Dainty

Polynuclear aromatic hydrocarbon (PAH) levels were measured in underground mines in the vicinity of diesel vehicles equipped with several types of emission control hardware. In general, the emission control devices appeared to reduce PAH levels, but the companion mutagen study suggested that the reduction might not always be beneficial. All underground PAH concentrations were below the threshold at which a significant impact on health might be expected, but recent animal exposure studies have indicated that PAHs may not be the primary hazard from chronic diesel fume exposure.

Jan 1, 1994

By K. Madi, E. Yeugo Fogaing, S. Forest, M. Boussuge, L. Massard, M. Huger, Gaultm C.

This study has been carried out owing to the French research program PROMETHEREF, which aims to improve the knowledge of thermal and mechanical properties of industrial refractories at high temperature. In this frame, this paper relates a collaborative study between Saint-Gobain CREE, R&D Centre for Saint-Gobain Ceramics & Plastics in Europe (Cavaillon), the Materials Center P.M. Fourt of Ecole des Mines de Paris (Evry) and the Research Group on Heterogeneous Materials (GEMH) of ENSCI (Limoges). Data collected at high temperatures by using different means (bending tests, ultrasonic measurements,...) allows the identification of the high temperature behavior of two fused cast materials, produced by Saint-Gobain group for the glass manufacturing industry. The results emphasize the importance of the transformation of zirconia and of the viscosity of the glassy intergranular phase on the mechanical behavior. Damage under the form of microcracking caused by thermal expansion mismatch between the phases is also observed during cooling down at low temperature, when the material is elastic.

Jan 1, 2004

By M. Lundström

The Outotec HydroCopper® process is a novel technology, developed and registered by Outotec Technology Oy, for leaching copper from chalcopyrite using cupric chloride solution. The leaching process is operated at atmospheric pressure in a stirred tank reactor, at temperatures near the boiling point of water and pH values between 1.5 and 2.5. During the leaching of chalcopyrite in cupric chloride solution, a reaction product layer forms on the mineral surface. In the present work, the formation and the composition of the reaction product layer was studied in an environment similar to that of the HydroCopper® process. The effect of the process parameters on the reaction product layer was investigated. Electrochemical measurements, including A.C. impedance spectroscopy and microscopic observations were carried out and an equivalent circuit was used to determine the surface parameters, such as the reaction product layer capacitance and the charge transfer resistance. The results suggest that, at low pH, a passivating sulfur-rich layer forms, whereas at high pH, a more porous iron-rich layer was detected. The values measured can give useful information for optimising the leaching parameters of the HydroCopper® process. Cu2007

Jan 1, 2007

By Mario A. Morin

Over the years, several sources have stressed the need to better integrate the underground mine design and planning processes. The belief is that with better integration, better designs and plans will result - designs that are ?optimized?. Some researchers have focused their efforts on data integration, others have looked at closing the loop between production control & monitoring with mine planning & scheduling. In spite of all these efforts, fully integrated applications combining geological modeling, stope design and geomechanics, mine planning and scheduling, rock extraction and material handling system design, mine support systems, economic analysis with production control do not yet exist for the underground hard rock mining industry. There are several likely explanations - some economic, some technical. It is certain that the design and planning processes are interrelated and interdependent and thus are extremely complex to describe and understand. The mining engineer has an appreciation of the complexities involved - but how does he convey this knowledge to a programming team responsible for developing an integrated design & planning system. This paper will focus on software engineering methods, and other possible approaches, to describe and manage the complexities inherent in the underground mine design and planning process and the development of an integrated computerized system.

May 1, 2001

By Xuanxue Mo, Kaihui Yang

"The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Early Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry. The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affInities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental microplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820/0 Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 glt) and recoverable amounts of Au, n, Gd, Ga, Ge, In. A massive sulfide zone, in which lenticular and stratiform orebodies are localized in a sulfide-<:arbonate-silica shale unit or sulfidic tuffIte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulfide zone developed in a subvolcanic intrusion or volcanic sequence. The sulfIde mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite - chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerals occur rarely in the massive ores. The massive ores are generally fme-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and displacement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two distinctive alteration zones have been identifIed: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, tremolite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive model of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

"The ore currently being milled at Delnite is a high pyrrhotite ore with the gold intimately associated with the pyrrhotite. To get maximum recovery of the gold with the lowest reagent cost, it is necessary to keep the pH as low as possible In the laboratory the best results were obtained with a pH of 10 but in the plant it was found that a pH of 11 was the minimum practical pH. With the n1anual control it was difficult to maintain this figure.The Mines Branch had a conductivity probe (see Fig. 1), developed by Dr. G .G. Eichholz that they wished to try out in plant operation.On June 17, 1963, the probe with all necessary control equipment was installed in the regrind circuit (see Fig. 2) at Delnite Mines. Crushed quick lime is fed at this point but it is also necessary to feed hydrated li1ne at two other points in the cyanide circuit in order to maintain the pH close to 11. 0 throughout the circuit. Only the feeding of the quick lime at the regrind mill was controlled in this test.One thing that concerned me with the operation of the probe was whether the reading on the probe chart would correspond to the pH. A look at the graph accompanying this paper will show that except for very minor variations the graphs of the chart reading and the pH reading are parallel. The upper graph shows that the pH reading and the lime titrations also correspond and that the cyanide titrations appear to have little effect on the pH reading.Table 1 gives the results obtained for the two months before and after the instal1ation of automatic control as well as the two months of control. Unfortunately there was a decided change in ore just after the automatic controls were removed. There was much less pyrrhotitc in the ore than usual thus changing the need for lime and cyanide."

Jan 1, 1964

By W. Qin

The nucleation of d hydride in Zircaloy-4 has been studied using electron backscatter diffraction. Hydrides prefer to nucleate at intergranular rather than intragranular sites. (0001) a -Zr//(111) d -ZrHx is the most common crystallographic relationship. The hydride platelets are generally interlinked each other and form a chain-like configuration. Based on thermodynamic model, the formation mechanisms of the hydrides at different sites and the interlinked structure were analyzed. We found that the misorientation of two adjacent grains has a crucial effect on hydride nucleation sites, and the tensile stress near the tips of hydride platelets is a key factor affecting the appearance of interlinked structure.

Aug 1, 2010

By A. Fawceit, B. C. Dyer

"The basis of the tomographic velocity imaging technique is briefly described and an application of the method to detect and image a cross-section through a chromite pod is presented. Using the chromite application as an example, the relative costs of tomographic data acquisition and processing are compared with those of diamond drilling to obtain similar resolution. A number of different tomographic survey configurations and the potential role of the method in surface and underground exploration are discussed.IntroductionThe technique of seismic tomography has been most widely applied in oil industry exploration, nuclear waste disposal, civil engineering site investigations and in the assessment of the condition of mass concrete structures. Although model studies had indicated that tomography would be a useful tool in mineral exploration, relatively few applications have been reported.Essentially the method relies on the determination of the speed with which sound travels through a region within a cross-section of the earth or large body. The speed of sound is determined by the physical characteristics of the medium through which it is passing. In geophysics the speed of sound is generally referred to as the seismic velocity. Due to variations in the formations of different rocks the seismic velocity will vary and so can be used to map geological boundaries"

Jan 1, 1994

By P. J. Foster

Bowtie analysis has recently emerged as a technique of choice that can be used when looking specifically at major hazards in the mining industry. A Bowtie diagram is a graphical means of assessment that focuses on identifying all the specific causes and consequences of major events, from which all the ?pre-event? and ?post-event? control measures can be identified. From this critical control measures can be identified and monitoring/assurance systems can be established. It is this assessment of control measures and their effectiveness that replaces the more traditional evaluation of risk (using matrix-based approaches) based on the fact that risk is a function of control ineffectiveness. This is a major difference with traditional risk assessment where all too often control effectiveness is assumed. This paper summarises the Bowtie analysis process and outlines one specific case study where the technique was used on the unwanted event of a collision of a haul truck and light vehicle in an openpit mine. Although more effort is required in undertaking the assessments, control assurance provided this way will go a long way in ensuring that risk assessments and major hazard management become much more effective in practice.

Aug 1, 2013

By Jeffrey D. Smith, William G. Fahrenholtz, Jose M. Soto

Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy.

Jan 1, 2004