Effects of microtexture on the d hydride formation in Zircaloy-4

The nucleation of d hydride in Zircaloy-4 has been studied using electron backscatter diffraction. Hydrides prefer to nucleate at intergranular rather than intragranular sites. (0001) a -Zr//(111) d -ZrHx is the most common crystallographic relationship. The hydride platelets are generally interlinked each other and form a chain-like configuration. Based on thermodynamic model, the formation mechanisms of the hydrides at different sites and the interlinked structure were analyzed. We found that the misorientation of two adjacent grains has a crucial effect on hydride nucleation sites, and the tensile stress near the tips of hydride platelets is a key factor affecting the appearance of interlinked structure.