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By John E. Pavlick

The availability of concentrated brines rich iodide, bromide, chloride, sodium, magnesium and calcium ions has led to extensive chemical manufacturing operations in Michigan. The brines, ranging 1,000 to 8,000 feet below the earth's surface, are the remnants of ancient oceans which periodically covered and receded over the land area which is now Michigan. After pumping the brine to the surface, iodine and bromine are extracted via an oxidative process. Iodine and bromine find application in catalysts, disinfectants, flame retardants, oil field fluids, film, and gasoline additives. Addition of alkalinity to the brine precipitates magnesium hydroxide, used in high quality refractories needed for steel manufacture. The brines are also the country's primary source of calcium chloride, employed in ice and dust control.

Jan 1, 1984

By Arthur F. Eidson

INTRODUCTION If a uranium mill worker is involved in an accident, analysis of excreta for uranium content and[in vivo] counting methods are used to estimate the extent of the possible exposure and to predict the pattern of uranium distribution among tissues (Spitz, [et al]., 1980). Interpretations of urinary excretion data are based on studies of human exposures to single uranium compounds including U02, U308, U03, UF4, U02F2 and UF6 (Alexander, 1974). Refined uranium ore (yellowcake) is a variable mixture of U03-NH3-H20 adducts (ammonium diuranate, ADU) and their thermal conversion product, U308. The variability in composition of yellowcake (Kalkwarf, 1979; Eidson and Mewhinney, 1980; Dennis, Blauer and Kent, 1981) complicates the interpretation of bioassay data from individuals that might have inhaled any single yellowcake material. A test system would be useful to estimate the dissolution behavior of a particular yellowcake aerosol inhaled by a worker and aid in the interpretation of bioassay data collected before and after an accident. A series of experiments was conducted for this purpose. The objectives of these studies were to: 1) develop specific criteria for comparing [in vitro] dissolution systems and 2) use the criteria to evaluate solvents, methods and experimental temperature and pH conditions used in previous studies. Dissolution experiments were conducted using different combinations of solvents, conditions and methods with a common yellowcake sample. Because little information is available from human yellowcake inhalation exposures to evaluate the [in vitro] results, criteria for evaluation of different tests were derived from a model of yellowcake dissolution in lung constructed from a number of cases in which humans were exposed to single uranium compounds known to be in yellowcake (Mercer, 1975). MATERIALS AND METHODS Materials The powder used in the tests was taken from one lot of yellowcake obtained from a commercial uranium mill. The same powder was previously designated as Mill D in Eidson and Mewhinney, 1980 and Mill 2 in Kalkwarf, 1979. The ammonium diuranate content was measured by infrared absorption to be 25% ± 1% (Eidson and Mewhinney, 1980). Solvents The compositions of the two biological fluid simulants used are compared in Table 1. Simulated lung fluid (SLF) (Kalkwarf, 1979; Dennis, Blauer and Kent, 1981) was chosen to simulate the composition [ ] of lung fluid as closely as practical (Moss, 1979). Simulated blood serum ultrafiltrate (SUF) (Eidson and Mewhinney, 1980) was chosen because of previous successful efforts to model human urinary excretion of inhaled plutonium aerosols (Kanapilly Raabe and Boyd, 1974) and the dissolution rate of 241Am02 in Beagle dogs (Mewhinney and Griffith, 1981). Major differences are that simulated lung fluid contains Mg2+ and a higher Ca2+ concentration than SUF and that SUF contains ammonium ion. Both solvents include protein substitutes; acetate is used in SLF, while amino acids are used in SUF. Both solvents include phosphate but the chelating agent diethylenetriaminepentaacetic acid (DTPA) is included in SUF to prevent possible formation of insoluble uranyl phosphate precipitates that would result in an underestimation of solubility. In addition to the above solvents, modified solvent compositions were prepared to investigate the role of specific salts in yellowcake dissolution studies. Solutions of SUF (Table 1) were prepared without DTPA (SUF-DTPA) and without amino acids (SUF-amino acids). No solution excluded both DTPA and amino acids. The SLF solutions were prepared with DTPA (SLF + DTPA) and without phosphate

Jan 1, 1981

By John A. Ferguson

John Ferguson of Phelps Dodge provides us with a case study of how his company approaches its computing and hardware decisions. Senior management is the target audience for this contribution which discusses computer employment strategy at Phelps Dodge and how it may differ from the practices followed by other companies. The computer professional is well advised to read this subsection also to gain insight into the way in which management looks at computers in support of company operations. The following pages take us through a progression of developments and expectations brought about by the computer: the tremendous versatility of this new tool and its swift development; the widespread changes and problems it introduced; the new and revolutionary management theories it prompted and the widely supported centralized service concept it introduced to information processing. It continues with a discussion of Phelps Dodge's early experience, its ,operating environment, and its strategy development-attention to operating units and later headquarters with stress on service needs of users. It concludes that for computing to be effective it must fit in with the bay in which the company operates and must be sensitive to the needs of the people it serves.

Jan 1, 1979

By A. Pratt, G. Deschênes

This paper quantifies the detrimental effects of pyrite and stibnite on gold leaching kinetics. Means to reduce the effect of these minerals by addition of lead nitrate and oxygen are presented. A significant retarding effect was observed when the pyrite concentration was 20%. A pretreatment with lead nitrate reduced the extent of gold surface coating by Ag, Fe and S. Stibnite, at a concentration as low as 20 ppm, significantly affected the gold leaching kinetics through forming a passivating film of Sb(V) oxide possibly Sb2O5. The most practical way to alleviate the effect of stibnite is to leach the materials at a moderate pH with addition of lead nitrate. A low temperature reduced the efficiency of lead nitrate to counteract the effect of stibnite. The increase of dissolved oxygen is not favourable to alleviate the coating of stibnite on gold.

Jan 1, 2004

By Ron L. Schmiermund

The Ferris-Haggarty underground mine was abandoned circa 1910, and portal discharge has since resulted in degradation of a trout fishery in the receiving waters of Haggarty Creek. Although tunnel discharge varies dramatically in volume throughout the year due to infiltration of snowmelt, compositionally it is a nearly constant low-TDS, pH-neutral, low-sulfate, copper-silicate dominated water. Between infiltration events, components of ARD accumulate in unsaturated, oxygenated environments within upper workings and are delivered to the main haulage level by the subsequent annual snowmelt flush. Mixing with non-ARD mine waters results in neutralization, dilution, and precipitation of amorphous copper carbonate and silicate phases. These mechanisms, combined with variations in the water balance, control the composition of the portal discharge. Understanding the chemical and hydrologic control mechanisms was critical to the design of a passive treatment system to decrease effluent copper concentrations.

Jan 1, 2000

By K. N. Han

The leaching behavior of palladium in ammoniacal solutions was investigated by using the rotating-disk technique in an autoclave. The study included the effects of rotation speed, temperature, oxygen pressure, composition of ammoniacal solutions and catalysts on the overall leaching rate. The dissolution of palladium in ammoniacal solutions was discussed in terms of the thermodynamics and a kinetic model. Even though the Eh-pH diagram suggests that palladium metal can dissolve in ammoniacal solutions at room temperature, it was found that the dissolution was very slow at temperatures below 100 °C but was significantly improved at higher temperatures. It was also found that the rotating speed of the palladium disk had no effect on the leaching rate. The apparent activation energy was found to he 69.7 kJ/mole. Based on the results obtained, it was concluded that the dissolution of palladium is controlled by chemical reaction.

Jan 1, 1999

By Hiroshi Himura, Shoichi Tsushima, Hiromi Goshima

This paper reports the construction of an environmentally-friendly tunnel in sedimentary soft rock near a residential area. The main tunnel, which will be used as the Onmawashi-Koen (Park) Regulating Reservoir, is a large-scale tunnel with a cross sectional area of 254.0 m2 and a lengthof 577.3 m, excavated using such support as shotcrete, rockbolts and steel H-sections. Since the large main tunnel is excavated in sedimentary soft rock, it is necessary to keep the stability of the tunnel face and the crown and to prevent surface settlement. A top heading with a length of 50 m is therefore driven as a pilot tunnel to observe the ground behavior during excavation, and to obtain information on the geological conditions based on which type of support structure is determined with consideration given to the results of field measurements and numerical analyses.

Jan 1, 2001

By K. Hanumantha Rao, K. S. E. Forssberg, B. -M. Antti

Selective flotation of muscovite from a material containing muscovite (15.4%), biotite (13%), and siliceous gangue (quartz and feldspar), using a mixed collector system of sodium oleate and dodecylamine acetate has been described. Muscovite is found to float in preference to biotite, when the pulp is initially conditioned with oleate followed by amine at basic pH values. The results indicate that a product containing 63% muscovite with a recovery of 93% can be obtained, while using 75-150glt of oleate and 96 g/t of amine. The biotite grade and recovery are found to be around 30% and 20%, respectively. A good selectivity between muscovite and siliceous gangue is obtained. A final product containing 95% muscovite with an overall recovery of 75% is obtained when the flotation concentrate is subjected to magnetic separation. These studies indicate the possibility of separating muscovite from biotite by using a mixture of collectors.

Jan 1, 1991

By Harry M. Castrantas

Caro's acid (peroxymonosulfuric acid-H2SO5) is used to destroy cyanides in tailings slurries due to its rapid reaction and low capital and operating costs. Due to its instability, Caro's acid is generated at the mine site using a hot or cold process. The majority of gold mines that use Caro's acid use the FMC hot process. In the FMC hot process, it is not necessary to cool the Caro's acid to minimize decomposition since it is used immediately upon generation. In contrast, the cold process uses a chiller to cool the raw materials and product. This paper will show, using laboratory and field data, that there is virtually no difference in Caro's acid yield between the cold and the FMC hot processes. Caro's acid yield depends on the mole ratio and concentration of sulfuric acid and hydrogen peroxide and is independent of operating temperature.

Jan 1, 1997

By D. A. Saint Don, M. Prueher, S. Barnwell

With the current changes in technology, multiple methods are now available for aggregate resource identification. From Sonic to Coring, Reverse Circulation to Percussive, there are many choices to make regarding drilling technology. The discussion will outline the methods above with focus on aggregate investigation and highlight the new technologies that will make a difference in your search.

Jan 1, 2004

By D. A. Ellis

This paper review s several new applications of solvent extraction developed in conjunction with a research project carried out under the AEC Raw Materials Division by the Dow Western Division laboratories during the last two years. A process for recovery of uranium from ores by contacting the solid directly with organic solvent without a prior aqueous leach and a process for uranium recovery by contacting thick, unfiltered leach slurry with the solvent were studied in an attempt to simplify ad reduce the cost of ore treatment procedures. Processes to produce pure UF4 products at the concentrate mills thus eliminating the production and subsequent dissolution of the concentrate were investigated. Since many of the leach liquors contained vanadium as well as uranium, solvent extraction processes for by-product vanadium were also studied.

Jan 1, 1958

By F. D. Huntley

Raw materials used by the Flat Glass Industry are known in the Industrial Minerals geology sector as Specialty Products. These pro- ducts must meet specification limits usually not the same for all glass manufacturers. Evolving new glass compositions will require mineral concentrates of consistent purity being produced within economic limits that will assure market viability of the resulting glass product. The amount of success the Flat Glass Industry will achieve by developing and maintaining domestic production centers will be determined by many economic factors which affect the costs of doing business. Technological developments by mineral processors must continue in order to achieve more efficient production of high quality glassmaking raw materials.

Jan 1, 1986

By Wolfgang Pietsch

Roller presses were first invented in the middle of the 19th century, for the economical size enlargement of coal fines as fuels. Coal briquettes became quickly accepted for industrial and domestic use giving rise to a large and sucessful industry, particularly in Europe, Japan, and North America. When, towards the middle of the 20th century, coal was more and more replaced by other energy sources, such as electricity, gas, and oil, roller press manufacturers searched for alternate applications of this equipment. In addition to contemporary coal briquetting, in fields such as smokeless fuel and form-coke, it was found that redesigned and modernized roller presses, which are now capable of exerting high forces, are versatile machines for many tasks in mineral processing. Today they are used for: - the "classic" pressure agglomeration and - the "new" high pressure comminution. In pressure agglomeration, the characteristics of fine minerals are improved by forming briquettes or granulated products from compacts. During size enlargement with roller presses briquettes are directly obtained while granular materials are produced by crushing and sizing of compacted sheets. The processes are carried-out essentially dry and often do not require binders other than those inherently contained in the feed and "activated" by the high forces and/or elevated feed temperatures (e.g. hot briquetting). Therefore, no foreign materials (impurities) are added. Another advantage of the technology is, that wide particle size distributions are acceptable or desirable as feed materials, including millimeter or even centimeter sized particles. Plastic particles deform and brittle materials are crushed during pressure agglomeration. A relatively new application of roller presses in mineral processing is the utilization of the crushing effect when brittle materials pass the nip area between the rollers. It was found that this crushing mechanism is very efficient thus saving energy, particularly in grinding circuits handling large capacities. The paper introduces the fundamentals of the process and describes the design as well as applications of modern roller presses in mineral processing.

Jan 1, 1995

By Terence H. Fisher

The use of more productive mining equipment, the tendency to longer development and the advent of new mining methods have introduced new challenges to the ventilation practitioner in Western Australia. These new and more productive mining methods have presented specific ventilation problems, that if not properly addressed, present additional hazards to miners. Factors influencing the increased hazards are larger diesel units, the use of series ventilation systems and an increasing incidences of long (single entry) development and production headings where miners could be trapped in a fire emergency. This paper discusses these new ventilation safety challenges, how they have been and are being addressed, and the legislation changes that take cognisance of technological developments.

Jan 1, 1995

By A. D. S. Gillies, A. Haghighat

"A study has been undertaken at the Missouri University of Science and Technology (MS&T) limestone Experimental Mine to determine new fans set up and wiring options.to install additional mine ventilation capacity. Selection for main fans has been undertaken according to the mine’s required performance specifications and fan characteristics. Available fans for ventilating the mine are Joy and Alphair axial fans each of 24 kW each and two Spendrup booster fans of 12 kW each. The installation of main mine fans on the surface and underground entails numerous considerations. Design of a ventilation network for the Experimental Mine incorporating surface and booster fans has been accomplished using Ventsim Visual program software. The ventilation network has been separated into two segregated parts. A main surface fan and a booster fan have been used in each segregated part of the network. The mine has had a vane axial Joy fan in place for many years. The Alphair 4800 VAX 1800 full blade adjustable pitch vane axial fan was selected and installed as the other surface fan and eventual replacement for the Joy fan. Main surface fans have been connected individually to booster fans in series. The Alphair main surface fan has been installed vertically. Four different wiring options and related cost estimations for addition of the new main fans to the ventilation network have been considered. The analysis resulted in an innovative steel frame design used to allow the fans, when necessary, to be moved to the side of the shaft so that blast pressures do not damage the blades. INTRODUCTION Main fans are the heart of a mine’s ventilation network and play a key role in supplying required airflow (Haghighat, 2014). The Missouri S&T Experimental Mine has been developed in uniform limestone with few stratigraphic features. The mine floor is approximately horizontal and water drains well. A study has been carried out on MS&T Experimental Mine. Selection of main fans has been undertaken according to the mine’s required performance specifications and fan characteristics. Ventsim Visual computer simulation has been used to assist in design of the ventilation network. Wiring circuits, fan foundations and flexibility have been considered as the three main parameters for surface fan installation at the Experimental Mine. Two surface and two underground wiring options and three surface set up options and related cost estimates for the new surface fan system were investigated. Frequent use of explosives in the mine occurs throughout each year. Flexibility in changing the position of a surface fan is important. A number of options have been considered for the location of a vertical main fan positioned on the upcasting shaft. The mine is used for a variety of purposes and flexibility has a high priority amongst design considerations."

Jan 1, 2015

By Daniel Hodouin, Claude Bazin, Sami Makni

SCOTT COULTER: Thanks, Eric. Thank you all for coming. Our first speaker today is Claude Bazin. Claude received a degree in metallurgical engineering in 1980 from Laval University in Quebec. He worked for a short time in a mineral processing plant and then returned to Laval to complete graduate studies in the field of process modeling and control. He obtained his master's degree in 1983 and his Ph.D. in 1990. In 1987 he joined Brunswick Mining, New Brunswick, as research metallurgist and subsequently process control engineer. In 1990 he joined Helzfield Mines, New Brunswick, as senior metallurgist. In 1991 he accepted a position of professor at the department of mining and metallurgy at Laval University, a position he is still holding. He's a member of the CIM, TMS, and the Society for Mining, Metallurgy, and Exploration. Claude's topic today is "On-Line Material Balance for Flotation Plants." INTRODUCTION CLAUDE BAZIN: During the last two decades, the on-stream analyzer (OSA) has gained the stat& of key instrument for the control of flotation plants. The OSA is currently used in almost every sulphide flotation plant (Leroux and Franklin 1994), and its application to oxide mineral flotation plants is increasing. The OSA assays are sent to the flotation operators via an operator console or to control loops of various degrees of complexity (McKee 1991) implemented in a distributed control system (DCS). Operators and/or controllers take control actions based on these assays to ensure an adequate operation of the plant. Although this application pays off very rapidly for the purchase of the OSA, one could ask, "Could we get more from the OSA?" Some plants reported the use of OSA measurements for process optimization (McKee 1991). The optimization strategy is based upon economic indices calculated from metal recovery using the 2-product formula (Wills 1992, p. 124). The 2-product formula is sensitive to measurement errors in the assays and can lead to considerable scatter in the calculated indices (Hodouin et al. 1993). Least squares algorithms provide a robust alternative to filter out measurement errors (Spring 1992). This paper presents some applications of a recursive least squares algorithm that provides real-time estimates of the mass flow rates within a flotation plant using OSA and mass flow rate measurements.

Jan 1, 1998

By K. S. Narayanan, Marcia L. Bartges, K. S. Venkataraman

The starting powders' physicochemical properties and consistency are essential for technical ceramic products to meet their performance specifications. The need for finer and more consistent powders has opened new technologies for synthesizing powders from atoms and molecules. However, submicron and near-micron powders obtained from conventional comminution and classification techniques are still competitive. This paper shows several examples from electronic ceramic applications of how we can use powder characteristics for micromanaging by design the ceramic properties such as the green and fired densities, slurry rheology, shrinkage during sintering, and the microstructure of the sintered bodies. The cross-disciplinary nature of the technology requires that the researcher not only should have a firm grip on the fundamentals of one or more disciplines, but also should be generally aware of the intricacies of other disciplines as well.

Jan 1, 1992

By David J. Dunn

Materials related problems at mines can be big ones - like a newly completed 1 -m (3.5ft) water pipeline burst during initial filling, grinding ball consumption at double the typical norms on startup of a new semiautogenous grinding (SAG) mill circuit or 30 open-pit haul trucks in the shop for new bed liners after less than a year’s service. Materials engineering provides solutions to these kinds of equipment problems by selecting good materials and designs, by trouble-shooting service failures and by maintaining high quality in vendor-furnished materials and components. Materials with good properties, correctly made and fabricated, correctly installed in mining and processing equipment, produce ore and final products reliably and efficiently. Materials engineering, applied during design phases, specification writing, and receipt and installation of materials, ensures that equipment will have the best possible shot at performing up to expectations. Good calls on materials properties - specifying state-of-art materials produced by competent manufacturers - help mine managers to reduce downtime and mining and processing costs. Materials that are improperly made or specified can make a mining operation less efficient or, possibly, uneconomical.

Jan 1, 1992

By Corale L. Brierley

Bacteria have long been used for the extraction of copper during dump leaching of sulfide minerals and in the recovery of uranium from mined-out areas. However, bacteria can also be used in extraction of trace metals from copper ores and waste materials. Molybdenum, tungsten, nickel, cobalt, gold, silver, and other strategic metals can potentially be released from ores and wastes by biological processes. The chemistry and biology of these reactions, the potential for using the processes, and the state-of-the-art of the technology will be discussed.

Jan 1, 1983

By Harry R. Asche, Manfred K. Lechner

The Cross City Tunnel comprises 2km of a new underground traffic route in Sydney, Australia. The route is very complex, involving some six separate tunnels and three underground Y-junctions. For almost 200m the six tunnels run parallel at different level sunder William Street, Sydney. Almost all of the route runs adjacent to the City Business District of Sydney and adjacent to or below many major buildings and services. The planning and design of this project is described. The geometric arrangement is achieved with a strong dependence on 3D road design packages. Road alignment constraints include land acquisition and proximity to existing tunnels and basements as well as maintaining separation from the other tunnels in the scheme. Geotechnical and hydrogeological studies are described. Findings discussed include the high horizontal stress field in the Sydney area and investigation of incised palaeochannels on the route. Methods of design for the tunnels and Y-junctions are described, as well as methods of settlement prediction for the buildings and services. The latter includes the settlement assessment for more than 200 buildings, many in excess of 20 storeys, as well as services including all of the city railway lines in Sydney.

Jan 1, 2003