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By HASAN SERKAN GOKCEN, SERKAN CAYIRLI

Manufacturers have improved various stirred mill types to be well adapted to fine and ultrafine grinding applications. These stirred mills, which are operated in wet or dry conditions, may be classified as horizontal — such as AHM-horizontal agitated media mill, IsaMill and Drais mill — or vertical — such as tower mill, Vertimill, Maxmill, Stirred Media Detritor and ATR vertical agitated media mill. The main difference between vertical and horizontal structures is in their operational variations. Additionally, the scaling-up of mills is also an important parameter for selecting the suitable orientation [1]. The purpose of this study was to investigate the dry grindability of calcite powders in a vertically and horizontally orientable laboratory batch-type stirred mill. The experimental results were evaluated using stress intensity analysis. The results showed that the d50 values decreased with increasing stress energy down to a certain point and then increased for both milling orientations. Even though the optimum stress energies for both vertical and horizontal orientations were in the range of 1 × 10−3 to 5 × 10−3 Nm at 750 and 1,500 kJ/kg energy consumption, the product size was finer for the horizontal orientation at the same stress energy value.

By P. Venkatasubramanian

The selection of a mining method for a mineral deposit is a complex decision problem. Human judgment, based on experience with mineral deposits and geologic conditions, remains the single most important input of the decision-making technique. If the use of artificial intelligence, in particular the developments in expert systems, is taken to its logical conclusion, the experience of the domain experts could be incorporated into a decision-support expert system. A knowledge-based decision support system for mining method selection for ore deposits has been designed whereby the domain knowledge is represented as production rules and organized in a semantic tree representation. This model is written in the PROLOG language. While the verification difficulties of expert systems models are recognized, an example of the model's decision on the mining method for a given ore body is presented and shown to be consistent with the decision made by human experts. In addition, plans, for further verification of the model are delineated.

Jan 1, 1992

By Edward C. Dowling

The advance of science and technology influences the modern economy in countless ways. Older industries must adapt to changes in the marketplace, while new industries are born by applying new technology to meet consumer needs. In light of declining head grades and increased unit costs in the US minerals industry, new technological developments in the production environment are paramount to maintaining a competitive footing in the international marketplace. Micro-engineering research provides the transition between the knowledge base and the application of new technology on the production level. Economic considerations The primary goal of technical development in the production environment is to reduce unit operating costs. Simply stated, this is accomplished by improving operating efficiencies and productivities on the production level. The goal of micro-engineering research in the production environment is to evaluate promising technologies and develop the criteria necessary to apply them in operations. As such, this process is the first step toward innovation and discovery. Generally, the micro-engineering research is followed by macro-engineering development. In the production environment, there are generally more development projects than can be accomplished in a timely manner. Usually, this is the result of financial and human resource limitations. Consequently, it is necessary to prioritize the work such that the most beneficial projects are accomplished first. By performing a discounted cash flow analysis and using benefit-cost ratios (for non-mutually exclusive alter¬natives) or net present value criteria (for mutually exclusive alternatives), the projects can be rated from best to worst. In this way, the financial and human resources can be best allocated to first complete those projects giving the highest returns before moving on to other activities. Moreover, this information is a prerequisite for management to justify additional financial or human resources.

Jan 1, 1992

By Kenneth S. Johnson

Iodine, a grayish-black nonmetallic element, with a density of 4.9 g/cm3, is a solid at ordinary temperatures. It is a member of the halogen family, along with fluorine, chlorine, bromine, and astatine. Iodine melts at 114°C. and at 184°C it is volatilized to a blue-violet gas that has an irritating odor. It does not occur as an element in nature, but occurs as iodates, iodides, or other combined forms. It is the 47th most abundant element in the earth's crust. Iodine was discovered by Bernard Courtois in 1811. He observed an unknown substance in the crude soda ash that results from the burning of seaweed. Samples of this unknown substance were identified to be a new element, and in 1813 Gay-Lussac named the substance iode, from the Greek word for violet color. The world production during 1989 and 1990 [(Table 1)] is estimated to be about 16 million kg per year (Lyday, 1991), of which about 30% is consumed in the United States. GEOLOGY AND MINERALOGY Compounds of iodine are minor constituents in seawater and brines, in certain marine organisms, and in minerals of the Chilean nitrate deposits. Seawater contains approximately 0.05 ppm iodine, and certain marine organisms, such as seaweed, sponges, fish, and some brown algae, are able to further concentrate iodine (Lyday, 1989a). Some seaweed can extract and accumulate iodine up to 0.45% of their weight, on a dry basis. The northern Chilean nitrate deposits, in the Atacama Desert, contain the following iodine minerals: lautarite, Ca(I03), (calcium iodate); dietzeite, CaJIO,), (CrO,) (calcium iodate-chromate); and bruggenite, Ca(I03), . H20 (Erickson, 1981). Various subsurface brines also contain iodine compounds. Some gas-field brines in the United States and Japan locally contain 30 to 1 300 ppm iodine. Several coals in Germany also contain iodine compounds. Iodine has been recovered from brines mainly in Japan and the United States, but also in Java, Indonesia, Italy, England, and the former USSR. Iodine has also been recovered from seaweed in Ireland, Scotland, France, Japan, Norway, and the USSR. Seaweed was a major source of iodine for the world in the first half of this century, and it remains as a large resource. The reserves and future resources of iodine are large, even excluding the resources in seaweed and seawater, and are shown in [Table 1]. Analysis Iodine as the free element can be detected by the characteristic blue color it gives to a starch solution. Quantitatively it is determined as the free element by titration with standard thiosulfate solutions using starch as an indicator. Colorimetric methods are also applicable. PRINCIPAL PRODUCING COUNTRIES Major iodine-producing nations are Japan, Chile, the USSR, and the United States, with lesser amounts being produced in China and Indonesia ([Fig. 1; Table 1]). Annual world production in 1989 and 1990, respectively, is estimated at 15.6 and 16 million kg. In Japan and Chile, the production of iodine depends on production of other materials, such as natural gas or nitrates, respectively, whereas in US operations (in Oklahoma) iodine is the major product recovered from natural brines. Chile was for a long time the principal world producer of iodine from its nitrate-fertilizer operations, but in recent years Japan has become the world leader with increased production of natural gas and associated iodine-rich brines.

Jan 1, 1994

By J. Brent Hiskey

INTRODUCTION Metal electrodeposition processes are of fundamental technological importance to a number of fields. Electrorefining, electrowinning, electroplating, and electrogalvanizing have all been the subject of intense study for over a century. More recently, electrochem- ical deposition has played a critical role in advances in microelectronics and lately has been an enabling technology for the production of certain nanostructured materials. Electrometallurgists have most frequently been concerned with the structure and morphology of massive deposits. For example, in metal recovery steps such as electrorefining and electrowinning, deposits demonstrating adherent coarse-grained characteristics are most desirable. In the case of electroplating, a bright fine-grained, tenacious and strongly adherent deposit is required. The fabrication of microelectronic devices and the production of nanoscale structures such as nanoparticles, nanowires, and nanorods requires a keen understanding of early stage deposition effects. The initial stages of metal deposition, usually referred to as electroclystallization, are fundamentally linked to nucleation and growth phenomena. Early stage deposits are typically very ordered. Whereas, bulk metal deposition structures are much more ran- dom. In both cases, the discharge of a metal ion at an electrified interface is represented by simple cathodic reduction as follows: [ ] Me(H2O)xn[ ] is a hydrated metal ion residing in the bulk solution and Me is the metal atom occupying a crystallographic lattice position. A similar reduction reaction can be

Jan 1, 2005

By J. Herbst, H. B. Treweek, V. R. Degner, G. Poling

Current mineral industry trends toward handling the high tonnages of lower grade ore and tailings retreat lead to a continuing need for large volume flotation cells. The benefits which accompany the larger cell flotation circuit include reduced capital cost, less mill floor space, reduced operational complexity, and less maintenance, provided the metallurgical performance and solids suspension capability of the cell are not compromised. This study reviews development considerations pertinent to large mechanical air induction type flotation cells from the standpoint of cell internal hydrodynamic characteristics and metallurgical performance. While the importance of process related factors such as chemical usage, pH control, solids size and loading, and circuit arrangement cannot be denied, this study will emphasize the relationship of cell size (volume), mechanism geometry (impeller diameter), and mechanism operating conditions (rotor speed and submergence), to air transfer, liquid circulation, liquid "rise velocity" and mechanism power draw. Specific hydraulic performance maps for large capacity 300 and 500 cu ft flotation cells will be reviewed in terms of the relationship between the operational variables and the air and liquid flow conditions within the cell. Metallurgical results, obtained under plant operating conditions for 300 and 500 cu ft cells, are included to illustrate the metallurgical performance similarity of flotation cells which follow hydrodynamic scale-up criteria set forth in this investigation.

Jan 1, 1976

By H. C. Juvkam-Weld

R. Michael Craig Mr. Juvkam-Wold's article is a timely and much needed presentation of the method of depressurization to reduce ground-water inflow into mine shafts. The article is very informative and discusses the effects of depressurization upon shaft inflows adequately. However, the article omits a discussion of another important benefit of depressurization: the reduction of potential for artesian burst or, as it is also called, floor heave. Confined aquifer systems (artesian aquifers) can contain water under several hunder pounds per square inch (psi) of pressure. For example, water levels at elevations of 455 m (1500 ft) or more above the top of the Westwater Canyon member of Reply by H.C. Juvkam-Wold In general, Mr. Craig's comments are useful and accurate regarding the potential benefits of aquifer depressurization. However, two of his points require further explanation since they may lead to a misunderstanding of my paper and its predictions. These refer to his comments regarding failure to account for storativity and to non-artesian conditions. Equation 5 is indeed Darcy's steady state equation. However, as a careful review of the appendix in this paper will reveal, I have used this equation to represent semi-steady state conditions. In other words, steady state conditions are assumed at any instant of time, but conditions may change gradually from

Jan 2, 1983

By Terry M. Hertel

The chemistry of waters processed by Acid Rock Drainage water treatment plants can affect the Total Suspended Solids quality of the plant effluents. The sulfate ions in the ARD water will combine with the calcium ions from the lime that is used to adjust pH to form calcium sulfate. When the sulfate content of the waters to be treated is greater than about 1400 parts per mil­lion, the resulting calcium sulfate concentration will be approx­imately 2100 parts per million. This concentration is above the saturation point for calcium sulfate, and the salt will drop out of solution until the concentration falls below the saturation point. This "salting" phenomenon affects the total suspended solids of the treatment plant effluents by virtue of the fact that the salts will report to the filtration apparatus used for the analy­sis. This scenario is exacerbated as an effluent sample ages. Zortman Mining's water treatment plant effluent was being affected by "salting" during the spring and summer of 1995, and it seemed as though the effluents were exceeding the TSS lim­its; for no obvious reason. A testing program was initiated to verify an observation that "salting' was taking place. Treatment plant samples were collected and allowed to age, with TSS analyses being performed every day that the samples aged. Synthetic solutions were also prepared to study the "salting" phenomenon.

Jan 1, 1996

By K. A. Natarajan, Abha Kumari

In this paper, electroleaching and electrobioleaching of ocean manganese nodules are discussed along with the role of galvanic interactions in bioleaching. Polarization studies using a manganese nodule slurry electrode system indicated that the maximum dissolution of iron and manganese due to electrochemical reduction occurred at negative DC potentials of -600 and -1,400 mV(SCE). Electroleaching and electrobioleaching of ocean manganese nodules in the presence of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans at the above negative applied DC potentials resulted insignificant dissolution of copper, nickel and cobalt in IMH2S04 and in sulfuric acid solution at pH 0.5 and 2.0. Mechanisms involved in electrobioleaching of ocean manganese nodules are discussed. Galvanic leaching of ocean manganese nodules in the presence of externally added pyrite and pyrolusite for enhancement of dissolution was also studied. Various electrochemical and biochemical parameters were optimized, and the electroleaching and galvanic processes thus developed are shown to yield almost complete dissolution of all metal values. This electrobioleaching process developed in the laboratory may be cost effective, energy efficient and environmentally friendly. Keywords: Ocean manganese nodules, Electroleaching, Electrobioleaching, Galvanic interactions

Jan 1, 2003

By A. Foscolos

Land reclamation and rehabilitation of depleted coal mines in the wider area of Ptolemais-Amynteon is practiced by the Division of Mines of the Public Power Corporation of Greece in order to conform to the concept of environmentally sustainable economic development of its operations. Detailed chemical and mineralogical studies were performed on reclaimed soils and their crops in order to evaluate the results of land reclamation and rehabilitation while similar studies were undertaken in adjacent, regularly cultivated, soils. Results indicate that trace element concentrations as well as concentrations of elements of environmental concern to be higher in regularly cultivated soils than the reclaimed ones. However, the concentration of the elements in wheat grains harvested from both, regular and reclaimed, group of soils is the same. The reason for this behavior is the very low water solubility, of the elements in the soils, due to their high pH values and the nature of their occurrence. As a result, wheat crops produced from reclaimed-rehabilitated soils developed on depleted lignite mines in the wider area of Ptolemais-Amynteon do not pose any health problem on either humans or animals when consumed.

Jan 1, 2003

By J. E. Gebhardt, P. E. Richardson

External control of the electrochemical potential of a bed of mineral particles was investigated by the US Bureau of Mines as a method for controlling particle interaction with organic collectors and, thus, flotation response. A cylindrically shaped, 200- to 300-g bed of sulfide mineral particles was used as the working electrode in an electrochemical-flotation cell. In a pH 9.2 sodium tetraborate buffer, chalcocite floated with ethylxanthate at applied potentials [=] - 0.25 V (versus the standard hydrogen electrode) ; pyrite floated at potentials [=] 0.15 V. Differential separation of a chalcocite-pyrite mineral mixture was obtained by controlling the potential, but the flotation response of the mixture did not follow the behavior predicted from measurements on the individual mineral beds. Chalcocite dissolution products had a deleterious effect on chalcocite-pyrite separation by activating pyrite so that it floated below the potential (~ 0.13 V) at which xanthate is oxidized to dixanthogen. A pyrite bed activated with a copper(II) sulfate solution exhibited a flotation response with a potential dependence between that of chalcocite and pyrite. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1988

By Zhuang Jianming, Liu Qinxia, Yuan Mingliang, Mei Xiangong, Chen Jin

Up to now, the leaching of manganese carbonate ore is usually performed at high temperature of 363K and the leaching rate is lower than 90%. Although in laboratory test, the leaching rate is only 90%. This paper introduced an improved method for leaching of manganese carbonate ore. Certain ammonium salt was added to the pulp to raise the solubility of Mn2+ and reduce the adsorption quantity of Mn2+ on the ore surface. Experimental results show that a leaching rate over 95% can be obtained at the temperature >273K. The activation energy is calculated to be 7.15 KJ/mol and is lower than that of normal leaching technique. The effects of the parameters, such as particle size, pulp density and initial acid concentration on the process results are investigated. A leaching rate higher than 95% can be obtained under the following conditions: particle size below 0.25mm, leaching time 60 min, stirring speed higher than 960 r.pm. H2SO4:MnCO3>1 .2, pulp density 105-205 g.L-l. A kinetic model was deduced, verifying with actual experiments. It showed that the model can describe the leaching process successfully.

Jan 1, 1995

By J. Sharp, R. Arnold, P. Rusin, T. Young, N. A. Sinclair

Many oxide silver and molybdenum deposits remain undeveloped because chemical extraction yields poor recoveries or is environmentally unacceptable. Bioreductive leaching of such ore samples at MBX resulted in high extractions of silver and molybdenum. When baseline, three-day, cyanide bottle-roll tests were conducted on manganiferous-oxide silver ore, 13.7% of the silver was extracted. In contrast, 86% of the silver was microbially solubilized into the organic growth medium by bioreduction with 99.8% dissolution of manganese. A followup cyanide bottle-roll test yielded an additional 8.5 % silver dissolution, for a total extraction of 94.5%. Baseline, three-day, acid bottle-roll tests of the iron-oxide molybdenum ore Yielded 1.8% molybdenum. However, bioreduction solubilized 93.3% of the molybdenum into the growth medium. An additional 0.3% molybdenum was solubilized during the followup acid bottle-roll test. Microbial treatment of refractory oxide ores with bioreductive bacteria resulted in higher extractions of silver and molybdenum than conventional chemical leaching. The bioleaching process occurred at a near-neutral pH at ambient temperatures. The bacterial solubilization of silver and molybdenum was achieved without the use of cyanide or sulfuric acid.

Jan 1, 1993

By Aaron Archer, James Parkes

This paper presents design considerations for the major underground elements of the pending BCRUA Phase 2 Raw Water Delivery System Project. These elements include two Lake Taps; an 8,800 LF, minimum 10-ft OD intake tunnel; a suction chamber with 6 Pump Shafts; a 30-ft diameter, 300-ft deep Main Shaft; a 2,600 LF Transmission Tunnel with 78-inch steel liner; and a 130-ft deep shaft on the Transmission Tunnel. The tunnels and shafts will be excavated through the Glen Rose limestone. The design development included consideration for technical requirements, easements, third party commitments, previous local project experience, and constructability based on contractor outreach.

Jun 13, 2021

By W. R. Boehme

The test work was done in two parts. In Part I, five 6 x 16 mesh activated coconut shell carbon samples made by four different manufacturers were evaluated as to their gold loading rate and total gold loading. The five carbon samples tested are not identified by manufacturer and are simply designated as Types A through E. Then from the carbons tested, a suitable highly active carbon was selected for subsequent studies on impurity effects upon loading, Part II. Test Procedures The procedures and tests descriptions are given for the ultimate gold carbon loading tests and the dynamic gold carbon loading tests.

Jan 1, 1983

By N. S. Margaris

The vegetation of Mediterranean ecosystems is distinguished by its resistance to adverse environmental conditions, and that is the reason for examining the possibility of growing species of this flora in waste disposal sites (WDSs). The survival and growth of vegetation established at a waste disposal site is dependent to a large extent on the qualitative and quantitative characteristics of the material used in the final soil cover. In the Ano Liossia WDS, where extensive remediation work is under way, three areas were examined, which met certain criteria in relation to the age of the underlying waste and the existence of impermeable material in the final soil cover. Laboratory analyses have determined soil parameters and nutrient and heavy metal content. Alongside this, at all three sites a network has been installed to monitor the qualitative characteristics of the gaseous phase of the soil cover material. The results showed the existence of a soil material containing few nutrients and the prevalence of oxygen-poor conditions, accompanied by large concentrations of CH4, CO2 and H2S, at depths of up to about one meter.

Jan 1, 2002

INTRODUCTION Automatic controls are devices that assist operators by performing routine tasks faster and better than they could alone. Great strides have keen taken in the development of new processes and bigger machines to improve productivity, but these developments created the need for increased protection of machinery and labor. The new production-line techniques, or continuous processes developed, resulted in routine and, frequently, demoralizing jobs. The human race is not constituted mentally to perform routine operations. Devices were needed also to gather information automatically and perform routine functions. High-capacity plants incorporating large equipment

Jan 1, 1985

By Albert E. Ketler

The techniques for fire monitoring of conveyor belts in underground coal mines have been revolutionized by the advent of sensitive carbon monoxide sensors and computer monitoring systems. These new systems are rapidly replacing the previous thermal (fixed-point temperature) sensors that have been shown to be considerably less sensitive for early fire warning. CO is generally an excellent indicator of spontaneous combustion. However, the most recent non-flammable conveyor belt materials have been shown to "burn" with dense smoke, but without sufficiently high temperatures to produce much carbon monoxide. To cover this fire detection void, a smoke detector was developed to augment CO sensing for these new conveyor materials. However, computer monitoring provides the flexibility for handling this and other additional instrumentation as fire monitoring techniques evolve. CO, smoke and temperature sensing may eventually be advocated for complete fire monitoring.

Jan 1, 1987

By D. S. Holmes

Biological processes for metal solubilization and ore beneficiation are in widespread use today. There are also some promising new applications of biotechnology in the areas of metal concentration and toxic metal cleanup. Recent progress in genetic engineering promises both to revolutionize the existing biological process and to expedite the adoption of the new biological applications. But before it can do so effectively, progress must be made in many areas of fundamental research and in biochemical engineering. These issues are addressed with special reference to the biotechnology of semi-enclosed containers (bioreactors), dumps, heaps, in situ and under- ground leaching, and with respect to the biotechnology of metal concentration. Finally, certain biological considerations for bacterial strain improvement are discussed.

Jan 1, 1987

By Y. Guan

The dissolution behavior of silver in ammoniacal solutions with cupric ammine as an oxidant has been investigated using a rotating disc electrode. The rates of dissolution of silver were determined by an electrochemical means as well as a direct measurement of silver ions reported in the bulk solution as a function of time. The variables investigated included stirring speed, temperature, concentration of lixiviants, and pH of the solutions. The rate of dissolution under the conditions studied' was found to be controlled by an electrochemical reaction at the liquid/ solid interface with an apparent activation energy of 48.07 kJ /mole. The rate was found to be a half order with respect to the, concentration of cupric tetra-ammine, Cu(NH3)l+.; The results were explained in terms of a mixed' potential theory.

Jan 1, 1994