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By J. D. Dixon

The Bureau of Mines investigated the principles of support-rock interaction, based on structural matrix methods which permit mathematical formulation of the problem and computer solution. The principles are given under two main sections: the first discusses the idealization of the tunnel support structural system for matrix analysis; the latter discusses the analysis procedures necessary for carrying out the solution. A general frame matrix computer program and a medium-size computer should be sufficient for carrying out the procedures involved. The example problem consists of a circular tunnel support which is subjected to a uniformly distributed vertical load, Three wall thickness-radius ratios are studied in combination with four support-rock modulus ratios. This problem illustrates the main procedures of the support-rock interaction analysis involved, and examination of the results reveals the influence of the relative rigidities of the support and the rock.

Jan 1, 1971

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing clay mining, crushing and grinding methods, and costs at various clay-mining operations throughout the United States. These papers are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. Although the publication of total production costs might not be advisable in some instances, yet a knowledge of operating costs is essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to-this distinction between total and operating costs in order that no misunderstanding of the cost tabulations shall ensue. The following report deals specifically with the methods employed by the Dennison Sewer Pipe Co., Dennison, Tuscarawas County, Ohio.

Jan 1, 1936

By J. A. Eisele

The Bureau of Hines conducted a bench-scale investigation of a concentrated H2S04 reaction for recovering and separating rare-earth elements, barium, and strontium from a bastnasite ore and byproduct. Barium and strontium were dissolved in the concentrated acid and precipitated as a mixed product by water dilution. Separation of strontium from barium was effected by reaction with Na2C03 solution, followed by a dilute acid leach of the SrC03 formed. After removing the barium and strontium from bastnäsite are, the rare-earth elements were roasted to water-soluble sulfates. The rare-earth sulfate solution was subsequently processed by solvent extraction to produce rare-earth oxides low in lead and magnesium.

Jan 1, 1974

By Martin Hertzberg

The concept of limit burning velocities is being used to formulate a quantitative theory of flammability limits. Competing and complicating processes dissipate power from a combustion wave and quench propagation at some characteristically low limit velocity. Two earlier reports dealt with process (a), natural convection (RI 8127); and with process (b), conductive-convective wall losses (RI 8469). This report considers process (c), radiative losses, and process (d), selective diffusional demixing. The limit burning velocity for radiative losses is [(SU)c ~ e cp] It is normally not a significant process for premixed gas flames; however, for laminar flame propagation in a gravity-free environment, it is the only loss process present. Accordingly, limit velocities at zero gravity should be much lower than on earth, and premixed gases should be flammable over wider composition ranges. For highly emissive dusts, soot, or ash-forming flames, radiative losses are significant even under normal gravity conditions. Selective diffusional demixing is a complication that manifests itself in the form of cellular flame structures and wide gaps in composition between upward and downward propagation limits. It induces a burning velocity shift (?Su)d, causing the flame to behave as though it were richer or leaner than its initial composition, depending on whether the fuel or the oxidizer mole¬cule has the higher diffusivity. A simple pertubation analysis shows that the process generates stable cellular flames whenever [dsu] > 0, where ci is the concentration of the reactant with the higher diffusivity. The same analysis indicates that at the opposite stoichiometry, where [dcu] < 0, laminar structures are stabilized. A simple formula for the diameter of cellular flames is derived, which predicts that dcell should vary inversely with the product of the diffusivity difference Di -DJ, and the burning velocity slope [dc ]. Those predictions are in good agreement with the available data. Buoyancy forces for upward propagation induce flame front curvature, and hence buoyancy and selective diffusion are mutually supportive in upward propagation. Thus large gaps in composition between upward and downward limits are present in those composition domains where cellular flames are stable.

Jan 1, 1981

By K. O. Bennington

[Thermodynamic properties of two amphibole asbestos minerals were determined by the Bureau of Mines. The enthalpies of formation were determined by the hydrofluoric acid solution calorimetry method. Heat capacity measurements were made with an adiabatic calorimeter over the range of 5 to 315 K. High-temperature enthalpies above 298 K were determined with a copper-block drop calorimeter to 852 K for amosite and to 902 K for crocidolite. Thermodynamic data determined for amosite of the composition Fe5+2.2766Mg1.5209 Fe+03.12Mn0.0825) Si7.9163Al0.0837022.0363)(OH)1.9637 are: S°298 = 168.8 ± 5 cal/deg-mole; ?Hf°298-15 (elements) = -2419.24 ± 2.95 kcal/mole; ?Hf298.15 (oxides) = -30.92 ± 2.47 kcal/mole; and ?Gf° -2260.1 kcal. Corresponding data found for s3 ,1s = crocidolite of the composition (Na1.9Ca0.1)(Fe2+.024Fe2.5 01Mg0.475) (Si7.9713024Fe+2 2.501Mg0.475) (Si7.971 Al0.029022.095) (OH)1.905 are: S2.98-15 - 161.1 ± 4 cal/deg-mole; ?Rf° 2 298.15 (elements) = -2433.56 ± 2.99 kcal/mole, 10298.1s (oxides) = -87.69 1.70 kcal/mole, and ?Gf°298.15 = -2269.8 kcal.] Calorimetric values from this investigation were combined with other data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of the measurements. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature both from the elements and the constituent oxides.

Jan 1, 1978

By James H. Russell

The Bureau of Mines, U.S. Department of the Interior, in cooperation with the Department of Energy, has attempted to increase the activity of nickel catalysts for converting synthesis gas, derived from coal, to a substitute natural gas. This report describes the effects of low-level additions of B, Ca, Ce, Co, Mn, Mo, Pd, Re, Ti, Y, Zn, and Zr on the methanation activity of Raney nickel. The methanation rate at 320° C and the resistance to poisoning by 2 ppm H2S were used to compare catalysts. The effects of the additions were small, and the experimental variances were large, necessitating the use of statistical methods to identify significant effects. Co, Ti, Y, and Zn improved the resistance to H2S poisoning, but only Co improved the methanation rate In some individual catalysts containing Ca, Mo, or Mn, both the methanation rate and resistance to H2S poisoning were improved.

Jan 1, 1980

By D. A. Paice, A. B. Shimp

A test program was conducted to determine the adequacy of molded case circuit breakers for dc electrical systems in coal mines. Mine electrical system parameters and the most severe operating conditions to be expected were determined. Tests of the interrupting capabilities of several molded case breakers were made under the worst conditions to be expected. Continuous and pulsed current carrying capability of the breakers was also investigated. Breakers from two different manufacturers passed all tests successfully. Based on the results of these tests, a set of guidelines for applying molded case breakers to dc systems has been prepared.

Jan 1, 1975

By Richard A. Thomas, Michael J. Sapko, Gary L. Mowrey, William D. Monaghan, Michael A. Trevits

Over the years, more than 20,000 mine seals have been erected in underground coal mines in the United States. Seals are used extensively in underground mines to isolate worked-out areas, active mine fire zones, and to control water inundations. Seals are most often built directly in the mine and can be fabricated from blocks made of wood or cementitious material. Recently, several explosions occurred within sealed areas of underground U.S. coal mines. These explosions, believed to be initiated by lightning strikes on the surface, destroyed numerous seals and caused considerable damage external to the sealed area. The National Institute for Occupational Safety and Health is conducting research to develop design guidelines, to investigate noninvasive techniques to characterize seal strength properties, and to evaluate seal test methods. As part of this work, a 30-ft wide, 16.1-ft tall and 4-ft thick seal was built in an underground experimental mine using cement and foamed water. Two types of noninvasive techniques are currently being investigated, namely the Schmidt Hammer for measuring compressive strength and ground penetrating radar (GPR) for detecting the presence of anomalies (e.g., voids, discontinuities) within the seal. Once these noninvasive tests were completed, the seal was subjected to destructive explosion testing. This study presents the results of the Schmidt Hammer tests, GPR scans, and the characteristics of seal failure during explosion testing.

By R. V. Ramani, K. Bode

"IntroductionIn part 1 of this paper, the results of the experimental work in a wind tunnel under controlled conditions were presented. To understand the spatial and temporal behaviour of airborne dust under mine conditions, experiments were performed in the Lake Lynn Experimental Mine of the US Bureau of Mines. The mine airway experiments were designed to study the variations of ambient concentrations along the length of an airway, and the deposition rates and deposition velocities in an airway cross section. Other objectives of the study were to investigate the spatial and temporal behaviour of airborne dust with regard to air velocity and particle density, the size distribution of the airborne dust cloud as it travels in the airway, and the size distribution of the dust particles deposited along the airway. Other objectives of the study were to compare wind tunnel results with In-Mine results, whenever appropriate.Experimental ProcedureLocationA complete description of the Lake Lynn Laboratory Mine of the US Bureau of Mines (USBM) can be found in the US Bureau of Mines Information Circular 8911 (Mattes et al., 1983). This mine provides excellent facilities for dust experiments. The airway dimensions are similar to those of a coal mine airway. The mine has a drift (D Drift, see Figure 1) that extends almost 500 meters without interconnecting airways, stoppings, or bends. The D drift measures approximately 6m in width and 2,25m in height.The Lake Lynn Laboratory Mine· is ventilated by a variable speed, 75 kW (100 hp), 28,3 m3/s (60 000 cfm) blower fan installed on the top of the ventilation shaft. Air velocities of 1, 1,3 and 1,8 m/s, respectively, could be obtained in the D Drift. However, the temperature changes at the surface can cause small variations in air quantities and velocities underground. The low background dust level in the mine reduces the problem of sample contamination from other sources of dust. Extended periods of uninterrupted data collection can also be scheduled. Mine airway parameters which are important for the analysis include the dimensions of the airway and the ventilation data such as the air velocity, and the pressure loss in the drift. All these data were acquired during altimeter surveys which were conducted prior to each of the experiments."

Dec 1, 1995

By A. Sainato, S. J. Kravits, G. L. Finfinger

This Bureau of Mines report describes and compares the procedures, capital investments, and operating costs of rotary and in-hole motor drilling techniques used to drain methane gas from the Pittsburgh Coal- bed in an underground mine located in southwestern Pennsylvania. A timestudy was conducted during the drilling of each of two boreholes, and the data were collated to serve as a base for comparing drilling procedures and operating costs. Findings indicate that drilling with an in-hole motor offers four advantages over rotary drilling; namely, an increase in drilling productivity, fewer worker-hours required, ease of maintaining vertical and horizontal bit trajectory, and less expensive drilling cost per foot of borehole.

Jan 1, 1985

By Warren E. Morrison

Demand for energy in the United States in 1965 was stimulated by the continuing expansion of the economy. A gain of 5.9 percent in gross national product for the year was accompanied by a 4.4-percent rise in energy consumption. Domestic energy resources met about 93 percent of the nation&apos;s requirements. The remaining 7 percent consisted of imported fuels, mainly of crude petroleum and residual fuel oil. The major fossil fuels-natural gas, crude petroleum, and coal, in that order-contributed 96 percent of all commerical energy utilized, with the balance of 4 percent being primary electricity from hydropower and nuclear power plants. Production was up for all of the major mineral energy resources in 1965, with the single exception of anthracite, output of which continued to decline. Bituminous coal output for the year was 512 million tons; marketed production of natural gas, 16,039 billion cubic feet; and crude petroleum output, 2,848 million barrels. Among the secondary products processed from primary energy resources, the most significant gains were in coal carbonized for coke which increased 6.7 percent to 95 million tons, and in the output of liquefied gases from natural gas which rose 4.8 percent to 11,257 million gallons (268 million barrels). Within the latter category, the off? take for petrochemical feedstocks continued to rise at a very rapid pace.

Jan 1, 1967

By C. H. Elder

Coal degasification boreholes drilled from the surface have been success-fully hydraulically stimulated to increase the flow of gas from the coal. This Bureau of Mines report describes the hydraulic stimulation procedure for a coalbed, the equipment required, and design criteria for the treatment. Three examples of stimulation treatment show from fivefold to twentyfold increases in gas production. The tests were conducted in the Pocahontas No. 3 coalbed, Buchanan County, Va., the Pittsburgh coalbed, Washington County, Pa., and the Mary Lee coalbed, Jefferson County, Ala. Two sites where the coal was hydraulically stimulated and exposed by subsequent mining show no adverse effect on mining operations through the treated zones. The induced vertical partings were confined to the coalbed and did not in any way affect either roof or floor rock.

Jan 1, 1975

By David C. Byrne

From an engineering perspective an ideal industrial noise control solution focuses directly on the actual source of the poise. Eliminating the noise-generating mechanism altogether obviates the need for other noise contra l treatments or hearing protection devices. However, in cases where attenuating the source is not feasible engineering controls must be oriented toward blocking the path that the sound waves travel toward employees. Acoustical enclosures are commonly used as sound path treatments to contain the noise from a machine: alternatively a control room/booth or equipment operator&apos;s cab may be used to isolate the worker from the noise. Anyone who has successfully used acoustical enclosures knows that the design procurement, and installation process is deceptively simple. Alt too often First-time efforts fait to account for many of the constraints that can render the enclosure essentially useless. Things that cannot be overlooked include: providing convenient worker access (physical and visual): allowing for proper machine operation/product flow; and supplying fresh air or preventing undue heat or contaminate build-up inside the enclosure. All of these factors must be given careful consideration, otherwise the enclosure will not perform adequately.

By Neil B. Young

Carbonate minerals constitute a major fraction of the oil shale in Colorado&apos;s Green River Formation. Quantification of carbonate minerals is important for the characterization of oil shale, particularly because of their thermal activity in production of oil from shale. The carbonate minerals found in this oil shale are nahcolite (NaHCO3), dawsonite [NaA1(OH)2CO3], dolomite [(Mg1-xFx)Ca(CO3)2], calcite (CaCO3), and ferroan [(Mg1-xFex)CO3]. Although carbonate minerals can be removed by acid extraction from the balance of the oil shale, direct determination of carbonate minerals is complicated by the occurrence of the same cations in more than one mineral. A method for assigning the acid-soluble cations to the individual carbonate minerals was developed from two assumptions based on oil shale geochemistry: (1) Calcite and ferroan do not occur together, and (2) the ratio of iron and magnesium is the same in dolomite and ferroan. These assumptions were tested by the Bureau of Mines by applying the technique for assigning cations to 219 samples from the saline section of the formation. The reported carbonate mineral amounts were compared statistically with X-ray diffraction peak heights, verifying the cation assignment method.

Jan 1, 1975

By Joseph Cervik

This Bureau of Mines report deals with water infusion of coalbeds, which can control methane emission at face areas during developmental mining and which may sometimes suppress dust. Studies show that water infused into the coalbed flows through the fracture system and displaces the methane in the fractures and prevents migration from the solid coal. Displaced gas migrates away from the face area that has been water infused and enters the return ventilation airways. A gradual decrease in methane emission is observed from the start of infusion until the infused zone is mined through. Depending on the permeability of the coalbed, infusion pressures ranged from 300 to 2,200 lb/in2. Face emissions in the Upper Kittanning coalbed were reduced by 89 pet; reductions of 38 to 79 pet were measured in the Pittsburgh coalbed depending on the relationship between the face cleat direction and mining direction. Respirable dust levels were reduced by about 75 pct on a longwall section in the Pocahontas No.3 coalbed and by about 50 pct on a development section in the Upper Kittanning coalbed, but no statistically reliable reduction was found in the respirable dust levels in the Pittsburgh coalbed.

Jan 1, 1977

By Daniel Edelstein

Demand for arsenic trioxide dropped markedly during 1983, primarily as a result of a 27% reduction in cotton planting. As an oversupply of arsenic trioxide developed, prices declined for both domestic and imported material. Domestic Data Coverage.-Commercial-grade arsenic trioxide and arsenic metal were produced by only one U.S. company, which voluntarily reported its production to the Bureau of Mines. To prevent disclosure of proprietary data, the production data have been withheld.

Jan 1, 1984

By Bernadette Michalski

Although hydrocarbons accounted for more than 60% of Bahrain&apos;s income and more than 80% of export earnings, this island nation sustained one of the more diversified economies in the Gulf Region. The availability of low-cost natural gas for electric power has fostered the development of a significant aluminum refining and manufacturing industry with emphasis on vertical integration. The Bahraini iron pelletization plant, closed since 1986 due to financial problems, was scheduled to reopen by early 1989. Commodity Review Metals.-Aluminum.-Aluminium Bah-rain Bsc (Alba) attained record high production levels in 1988 taking advantage of favorable aluminum prices, which averaged over $2,000 per ton as compared with less than $1,500 per ton in 1987. Net aluminum production was nearly 13,000 tons over design capacity. Fewer standard ingots (52,081 tons as compared with 79,685 in 1987) were produced as Alba concentrated on higher value added products such as rolling ingots (42,324 tons as compared with 32,125 tons) and extrusion billets (60,934 tons as compared with 46,618 tons).

Jan 1, 1990

By L. B. Pankratz

Low-temperature heat capacities, high-temperature enthalpy increments, and the enthalpy of formation at 298° K were determined calorimetrically for vanadium subnitride (VN0.465). The low-temperature investigation gave S°298.15 = 6.379 ±0.005 cal/deg mole, and a combustion calorimeter investiga¬tion provided ?Hf°298.15 = -31.80 ±0.60 kcal/mole. The two quantities were combined with the high-temperature data to give standard values of enthalpies of formation and free energies of formation above 298° K. These and related thermodynamic functions were tabulated to 1,800° K. Similar data are included in the range of 298° to 1,600° K for the mononitride, VN.

Jan 1, 1971

"INTRODUCTIONMany of the facilities and much of the equipment available to the Generic Mineral Technology Center for Respirable Dust are highly specialized and therefore, unique to the universities associated with the Center as illustrated in FIGURES 30 through 39.For example, a sample bank of 1300 U.S. coal specimens housed in the Coal Research Section, Deike Building of The Pennsylvania State University has been characterized for physical, elemental, mineralogical and maceral compositions. The results of this research have been used to initiate a study of the relationship between pneumoconioses and coal properties. Selected samples from this bank have been used in animal (primate) studies at the Milton S. Hershey (Penn State) and West Virginia University Medical Centers. These laboratory facilities for research in the medical and biological disciplines is state-of-the-art and includes a primate colony where dust research is currently underway. The Materials Research Laboratory and the Rock Mechanics Laboratory at PSU, and the Mechanical Systems Design and Control Laboratory, the Rock Mechanics Laboratory and the Mine Electronic System Laboratory at WVU are equipped for fundamental research on dust generation and characterization. While the majority of respirable dust research projects fall into these two categories, dust generation and characterization and interaction of dust and lung, there are other laboratory facilities available to the Center which are unparalleled in the type of equipment and expert personnel that they contribute to the program. The Mine Particle Laboratory located at the University of Minnesota and the Diesel Engine Laboratory at Michigan Technological University are examples. They house equipment and instrumentation that is unique to these facilities. much of it having been developed specifically for dust research by the research scientists there. The dust collection equipment and the fine particles measurement, characterization and analysis apparatus are essential to research in the areas of dust collection, particle characterization and diesel particulates. In addition to university laboratories, the research facilities of the National Institute for Occupational Safety and Health (NIOSH) are available to the Center through its relationship With West Virginia University."

Aug 31, 1989

By Leon W. Dupuy

"INTRODUCTION Scheelite occurring in tactite at the Black Rock tungsten mine, near Benton in Mono County, Calif., was investigated by the Bureau of Mines in cooperation with the Geological Survey as part of their search for additional sources of supply of strategic minerals authorized under the Strategic Materials Act. 3/4/The work accomplished by the Bureau, and the assays of samples taken are described in this manuscript. The ore found aided materially in prolonging the operating life of the mine during the recent national emergency, supplying much-needed tungsten for war use. ACKNOWLEDGMENTSIn its program of investigations of mineral deposits, the Bureau of Mines has as its primary objective the more efficient utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, under the direction of Lowell B. Moon, chief, conducts preliminary examinations, performs the actual development work, and prepares the final report. The Metallurgical Division, under the direction of C. C. Ralston, chief, analyzes samples and performs beneficiatibn tests."

Mar 1, 1948