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By A. M. A. Mohamed, F. H. Samuel, S. Valtierra, H. W. Doty, A. M. Samuel

"The influence of Fe, Mn, Cu and Mg alloying additions, Sr modification and grain refinement on the microstructure of as-cast and solution heat-treated Al-10.8% Si alloys was investigated using optical microscopy and EPMA techniques. The results showed that the modification effect of Sr diminished with increasing Cu and Mg additions, due to Sr-Cu-Mg interactions. Strontium caused segregation of AlzCu in areas away from eutectic Si regions, and altered the precipitation sequence of the a-Ah5(Fe,Mn)3Siz iron intermetallic from post-dendritic to pre-dendritic, with the phase observed within the a-Al dendrites. Depending upon the alloy Fe and Mn content, a coarser variation (""sludge"") of the a-Fe phase occurred, in the form of polyhedral shaped particles. The AhCu phase dissolved almost completely during solution heat treatment, while Al5Cu2Mg8Si6, sludge, and a-Aln(Fe,Mn)3Siz phases persisted in all alloys, particularly at high Mg and Fe levels. The f3-Al5(Fe,Mn)Si phase dissolved partially in Sr-modified alloys, the dissolution becoming more pronounced after solution heat treatment."

Jan 1, 2006

By S. R. McCutcheon, D. R. Lentz

"Abstract - The 12.1 Mt Brunswick No. 6 Zn-Pb-Cu-Ag massive sulfide deposit (New Brunswick, Canada) lies between two subaqueous felsic volcanic formations near the base of the Middle Ordovician Tetagouche Group. The footwall comprises rhyodacitic pyroclastic rocks (Nepisiguit Falls Formation), whereas the hanging wall comprises a sequence of rhyolitic flows, breccias, and hyaloclastites (Flat Landing Brook Formation), with an age difference of less than 3 m.y. The Brunswick No. 6 deposit is a proximal autochthonous deposit with a well-zoned massive sulfide body and a basal Cu zone that, at depth, develops into a stockwork stringer sulfide (feeder) system. The massive sulfides are capped sharply by a layered magnetite-chert unit that extends regionally beyond the deposit. The deposit has a keel shape (sheath) formed by the F1F2 interference pattern. The heterogeneous ductile deformation and upper greenschist-grade regional metamorphism has transposed many of the epigenetic stockwork structures and alteration within the host sequence. Hydrothermal alteration is much more extensive, both vertically and laterally, in the footwall (a few 100 m) than in the hanging wall (<100 m). Anomalies farther up in the hanging wall sequence seem to be associated with independent alteration systems related to the rhyolite domes. The least-altered footwall units exhibit keratophyric alteration (albite or adularia) and weak Mg enrichment (chlorite). More intense micaceous (sericite and Mg-rich chlorite) alteration occurs around the footwall sequence. The transposed stockwork stringer sulfides are typically composed of Fe-rich chlorite (± sericite, ± silica) with pyrite, pyrrhotite, chalcopyrite, arsenopyrite, and sphalerite. The (Fe2O3T+MgO)/(Na2O+K2O) and base metal alteration indices are the best practical lithogeochemical vectoring tools at this deposit. Sommaire - Le gîte de 12.1 Mt de sulfures massifs de Zn-Pb-Cu-Ag Brunswick No.6 est localisé entre deux formations volcaniques felsiques sous-marines situées près de la base du Groupe de Tetagouche d’âge Ordovicien Moyen. Le mur consiste en roches pyroclastiques rhyodacitiques (Formation de Nepisiguit Falls) tandis que le toit consiste en une séquence de coulées, de brèches et d’hyaloclastites de composition rhyolitique (Formation de Flat Landing Brook); la différence d’âge entre les deux est de moins de 3 m.y. Le gisement Brunswick No. 6 est un gîte autochtone proximal comprenant un corps de sulfures massifs clairement zoné ainsi qu’une zone cuprifère basale qui passe progressivement à un stockwork de filonnets de sulfure en profondeur (feeder). Les sulfures massifs sont abruptement surmontés d’une unité laminaire de chert et de magnétite dont l’extension par delà le gisement est régionale. Le gisement affecte la forme d’une quille (fourreau) résultant d’un patron d’interférence F1F2. Plusieurs des structures épigénétiques du stockwork et des patrons d’altération de l’encaissant ont été transposés par la déformation ductile hétérogène ainsi que par le métamorphisme régional au faciès des schistes verts. L’altération hydrothermale est beaucoup plus importante, tant verticalement qu’horizontalement, dans le mur (quelques 100 m) que dans le toit (<100 m). Les anomalies situées plus haut dans le mur semblent être reliées à des systèmes d’altération indépendants associés aux dômes de rhyolite. Les unités les moins altérées du mur une altération kératophyrique (en albite ou en adulaire) ainsi qu’un faible enrichissement en Mg (chlorite). Une altération en mica (séricite et chlorite magnésienne) plus intense est présente autour de la séquence du mur. Les sulfures du stockwork de filonnets transposés consistent typiquement en chlorite ferrifère (± séricite, ± silice) accompagnée de pyrite, de pyrrhotite, de chalcopyrite, d’arsénopyrite et de sphalérite. L’indice d’altération (Fe2O3T+MgO)/(Na2O+K2O) et l’indice des métaux usuels sont les outils d’exploration les plus appropriés dans ce gisement."

Jan 1, 2006

By Tyler Roberts

New Afton mine is an 11,000 tonne per day block caving operation, located 8 km west of the city of Kamloops, British Columbia. Due to the nature of block caving and the weak rock mass at New Afton, the mine has faced and overcome many blasting challenges during its ramp-up to commercial production. As New Afton Mine continues to grow the demand for drill and blast precision has continued to grow as well; any misstep incurs delays in achieving full production capacity. The block cave mining method used at New Afton employs single-shot draw-bells, fired with very little void and blind undercutting, allowing little margin for error. New Afton has made continuous improvements to its blasting strategy by reacting quickly to real-time problems and employing sustainable, repeatable solutions to overcome its unique blasting requirements. Examples of these solutions include: increasing blast hole diameter, casing production drill holes, developing pre-loading procedures and developing strategies for remotely blasting under-broken remnants in both draw-bells and undercutting. Increasing the blast hole diameter has alleviated initial problems with hole plugging in the highly jointed rock mass at New Afton. This has reduced drill-cleaning time significantly and enabled New Afton to meet blasting targets. PVC hole casing was trialed when blasting in extremely fractured ground, where drill holes continually plugged. The casing allowed the drill holes to remain open long enough to load and blast. Calculations were carried out in order to achieve the same explosive energy in the cased holes as a typical blast. Results were generally positive, but more testing is required. Production flexibility and scheduling reliability have been maintained at New Afton by developing a pre-loading procedure for the production undercutting. In doing so, New Afton has been able to keep productivity high by having a flexible production schedule that is not reliant on a specific piece of equipment or production drive to remain productive; this flexibility is because the mucking of undercut material can occur at any stage of the drill/blast/muck cycle. New Afton has developed a strategy for blasting remnant under-break in its draw-bells and undercutting by remotely drilling holes near to the under-broken section and then loading the toes of these holes with emulsion, the remainder of the hole is then filled with grout. The holes are grouted in order to prevent damage to permanent pillars between draw-bells (where the majority of the recovery holes need to be located). Several critical areas were recovered using this technique with little to no damage to the remaining permanent pillars. Innovative blasting solutions have allowed New Afton to overcome obstacles in order to become a producing operation. Moving forward, New Afton looks to continue its trend of innovative drilling and blasting techniques when faced with out of the ordinary situations.

Aug 1, 2013

By G. W. Sparkes

The use of CR-39 plastic polymer as a solid state nuclear track detector in the textural analysis of radioactive minerals in geological samples was first described by I.R Basham in 1981. CR-39 autoradiographs provide a detailed, high-resolution image of the in situ distribution of the radioactive minerals within geological samples on both the macroscopic and microscopic scales. This technique is an inexpensive and effective means of obtaining detailed textural information that provides insight into the style of mineralization, its relationship to primary and secondary structures in the host rock, and its association with particular geological features or mineral phases. Although this technique does not provide any information on the identity of the minerals responsible for the radioactivity, the resultant autoradiographs can be used to select regions for further detailed analysis such as petrography, microprobe analysis, or SEM imaging. This paper summarizes the procedure and outlines the appropriate time and materials required for both the exposure and etching of the CR-39 with respect to the intensity of the radioactivity emitted by the geological samples.

Jan 1, 2013

As part of the Australian Mineral Industries Research Association (AMIRA) P9 project, methods of characterising both the ore and the machines in flotation circuits have matured considerably over the past 15 years. Machine characteristics include gas dispersion measurements, such as bubble size, gas hold-up and superficial gas velocity. Ores can be characterised in terms of floatability parameters on a size and mineral basis. Measurements have been performed on various copper plants in many countries around the world over the last 5 years. This paper outlines the cell and ore floatability characteristics of each copper plant and provides a discussion on the differences between these plants. In general, most porphyry copper ore bodies are processed at high tonnage through several parallel banks of cells at each stage of flotation. The floatability parameters of these copper ores are very similar in terms of rate of flotation and proportion of fast, slow and non-floating material. The cell characteristics are also similar, with superficial gas velocity, bubble sizes, and gas hold-up values being of similar magnitude. Investigation of the similarities and differences of the modem copper flotation circuits has allowed an increase in understanding of the particularities of copper flotation. Comparison against other copper circuits provides a benchmark and opportunities for future optimisation.

Jan 1, 2007

By T. H. Peters

The historical development of this program, dating from the construction of Nickel Park at Copper Cliff in 1917 to the various current projects carried out in the Ontario Division&apos;s program, is reviewed. Practices used to grow vegetation on stressed areas, the beneficial aspect of the improved aesthetic appearance of company properties from the point of view of public relations and the improved approach to the workplace by the employee are discussed. The revegetation of the tailings area and its gradual transformation into a Wildlife Management Area is reviewed.

Jan 1, 1978

By A. van As, J. McGaughey, M. J. Mol, R. Tosen

Geotechnical monitoring is a key element of the successful management of a block cave mine. The interrelationships between production and various monitoring datasets are often not realized due to a lack of data integration and appropriate 3D visualization. Timely delivery of information to ensure best cave management practices is only possible with an integrated cave management system. At Rio Tinto, a state-of-the-art cave management system (CaveCAD) has been designed and developed in cooperation with Mira Geoscience to integrate and analyze vast datasets and report this as instructive information regarding the current \u201cstatus\u201d of the cave.

Jan 1, 2014

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Dialkyl dithiophosphinates are a unique class of collectors used in the flotation processing of Cu- Au, complex polymetallic, and precious metal ores. They are known to exhibit higher selectivity and flotation rates for Cu sulfides, galena, and precious metal values in the presence of other gangue sulfides, than the traditionally used collectors such as dialkyl dithiophosphates and xanthates. They also have an attractive HSE profile. Historically, for most reagents used in flotation, practical methods of chemical usage have preceded detailed scientific understanding of how they work; this applies also to dithiophosphinates. Recently, however, the research community has shown significant interest in this chemistry, and numerous studies have been conducted to understand the fundamentals of interactions of dithiophosphinates with several base metal sulfides and precious metals. A critical overview of fundamental studies, laboratory ore flotation, and plant practice of dithiophosphinates is given in this paper. The findings from these studies are rationalized by drawing on concepts and insights from coordination chemistry. A comparison between the interactions of dithiophosphinates and dithiophosphate analogues with various minerals and metals is also made throughout. We believe that such a critical analysis/overview will be invaluable in identifying gaps in knowledge regarding this important set of compounds, which in turn may provide a basis for the design of studies that can advance understanding of their flotation performance. INTRODUCTIONDialkyl dithiophosphinates are an important member of the class of thiophosphorus compounds that are widely used in flotation beneficiation of base metal sulfide and precious metals ores. Ore flotation studies and plant practice experience have demonstrated their unique properties compared to the traditionally used sulfide collectors such as dialkyl dithiophosphates (their closest analogues) and xanthates. The predominant dialkyl dithiophosphinate used in the industry today is sodium diisobutyl dithiophosphinate (a.k.a. DIBDTPi; AEROPHINE® 3418A1 introduced by American Cyanamid in the late 1970s; Figure 1). The widest application of AEROPHINE 3418A is found in complex polymetallic ores of Cu-Pb-Zn-Ag, Pb-Zn-Ag, and Cu-Zn where it has demonstrated improved recoveries (and flotation rates) of sulfide minerals of Cu, Pb and Ag and selectivity against sphalerite, iron sulfides, and penalty elements (Mingione, 1991). More recently, it has also been used as a collector in the processing of Cu, Cu-Ni, and Ni ores (Guitard et al., 2015) and Cu-Au ores (Dunne, 2005). In general, it is considered to possess the collecting power of xanthates together with the selectivity (against pyrite) of dithiophosphates (Hope et al., 2003a, 2003b), while requiring lower dosages than those reagents (Guitard et al., 2015). AEROPHINE® 3418A has also found an important place in several targeted formulations to improve flotation performance. Other benefits of this reagent include higher flotation rates, having a better HSE (health, safety and environmental) profile2 compared to xanthate, and exhibiting resistance to hydrolysis and oxidation (Guitard et al., 2015). Compared to diisobutyl dithiophosphate (DIBDTP), which is known to contribute significantly to frothing (often leading to over-frothing), AEROPHINE® 3418A is observed to be froth neutral (i.e. it does not alter the existing froth characteristics). As is the case for other flotation reagents, the design and application of AEROPHINE® 3418A has preceded understanding of its behavior at a fundamental level. Recently, there have been numerous fundamental and application studies designed to develop a better understanding of its interaction with sulfide minerals and precious metals. This should help in optimizing its application in flotation and provide a basis to better rationalize its unique selectivity and activity characteristics. Past studies on the interacti"

Jan 1, 2016

By S. Mathieu, R. Mennillod-Blondin, P. Cousin, N. Valle, H. Bouzahzah, P. Marion

The gold deposit of the Lapa mine has a complex mineralogical gold state with coarse and fine native gold, aurostibite and submicroscopic gold within arsenopyrite. A specific mineralogical characterization of the refractory fraction was conducted combining various techniques such as optical microscopy, electron microscopy, electron microprobe and secondary ion mass spectrometry. In parallel, the mineral processing behaviour and the recovery of the refractory gold were studied by pressure oxidation and cyanide leaching. This paper presents the mineralogical methodology developed to characterize the refractory gold distribution within arsenopyrite. These results are presented and interpreted in order to plot gold recovery versus sulphide oxidation. The comparison of the metallurgical behaviour yields predicted from the mineralogical data and the one calculated from leaching tests shows a good agreement and allows mineralogical explanations of the gold metallurgical behaviour.

Jan 1, 2011

By J. G. Phillips

Introduction Throughout the Great Plains region (the provinces of Manitoba, Saskatchewan, and Alberta), numerous clay deposits of widely varying composition and character are to be found. These may be classified into two general types: (1) surface clays, and (2) shales. The surface clays consist of a heterogeneous mantle of silts and clays interspersed with grave! and sand deposits, and may belong to any of the following groups: (1) lake clays: (2) river-terrace or flood-plain deposits; (3) delta deposits . In most cases, the water from which these deposits were &apos; laid down was derived from the melting ice of the continental glaciers. These surface clays, in general, possess certain characteristics in common, being all more or less calcareous, often silty, and showing a tendency to &apos;check&apos; in air-drying. The shales found in this region are of Cretaceous and Tertiary age. These deposits have a wide extent, but there is frequently such a heavy covering of drift material that the clays are accessible chiefly along the walls of stream valleys, or along the escarpments of uplands.

Jan 1, 1929

By C. O. Aksoy, H. Kose, K. Ozfirat, T. Malli, A. Gonen, S. Gurgen

In selecting mobile mining equipment, factors including availability, useful economic life, maintenance and operating costs, and spare parts availability are considered. Given these factors, trucks and shovels with different capacities are selected. Optimizing equipment for pit and hillside quarry cases, where 8% and 10% ramps are commonly in use, were examined; the effect of other mining activities such as drilling and blasting on unit cost were considered. In principle, 20 m to 25 m high benches should be economical for downhill haulage, and 7 m to 10 m low benches economical for uphill haulage. However, practice of both mining styles favours 10 m to 15 m bench heights. Hence, the analysis here was carried out with the field experience bench height range. In the study, a truck-shovel optimization was based on the movement of 5 to 20 million cubic metres (in 2.5 million cubic metre increments) of overburden stripping at the Eynez open pit mine in the Soma region of Turkey. The outcome showed that low-capacity shovels were unfavourable due to high production expectations. High-capacity shovels were also unfavourable due to health and safety issues causing high instances of impact vibration on trucks during the loading cycle and a decrease in foreseeable unit lifetimes. The number of shovel passes required to load a truck ranged from three to six. Trucks with high-capacity bodies were deemed uneconomical due to high investment and operating costs.

Jan 1, 2005

By M. J. Bunyard, I. Mullany

"The pressures on mine operators are varied and constantly increasing, declining ore grades, more remote locations and increasing environmental concerns. The challenge facing the mining industry is to find new ways to process ores which are more efficient and less costly and to control them better. This requires a fundamental rethink in the way in which projects are developed, it is no longer good enough to just copy what has been done before. The process starts with the surfacing of the primary underlying constraints for the project and the establishment of new design principles to address these. The generation of new design criteria and processing options follows the well-established path of brainstorm, focus, brainstorm, refocus and economic evaluation. The aim is process intensification, doing more with less, as early as possible and better use of plant data. The methodology requires a complete geometallurgical understanding of the orebody to facilitate the evaluation of viable processing options. Examples of early stage processing considered are blast optimization and ore sorting to reject waste and reduce processing costs. Mine to mill integration, which starts with the optimization of blasting for separation, offers another way to significantly reduce operating costs and increase efficiencies.VALUE MODEL The mining industry has, over the past decade, experienced an unprecedented cycle of increased commodity prices and investments in new mining and processing capacity followed by a market collapse and fall in prices and confidence. Whilst there are now some signs of a return to investment in new capacity, the metals and mining industry is still wrestling with eroding margins and investor demand that companies achieve the full value of their assets. Metals and mining companies must work on all available levers to deflate their costs back to more manageable levels and capture the full value for their products. Levers include optimizing external spending, re-thinking make vs buy trade-offs, debottlenecking, improving availability and operating time of key equipment, more accurate and agile planning processes, value-in-use optimization, and tighter performance management. Figure 1 is a diagrammatic representation of a company’s value model. The three goals of a successful mining enterprise are social acceptance, environmental acceptance and sound financial returns to shareholders. Some of the KPI’s used to measure the success or not of achieving these goals are shown in the translation layer."

Jan 1, 2017

By Malcolm Black

Introduction Before beginning to write this paper, I decided that I should first find suitable definitions of the words Sample and Sampling. The dictionary gives: "Sample.-A portion indicative of the whole"; and according to Baillie (1), sampling is "That process whereby a representative and comparatively small portion of material is selected from a large bulk, and preserved under such conditions as shall prevent contamination or avoidable alteration, with a view to the formation of valid conclusions regarding the suitability of the bulk for specified purposes". These comprehensive definitions are alike in substance, and indicate that unless a truly representative portion is taken, it is not a sample. Ore &apos;as mined&apos; generally varies a good deal in composition, and, in crushing, segregation takes place. Some of the minerals present, due to differences in hardness and friability, break into smaller pieces than others, and, on reaching the bin, the coarse particles roll away, leaving the fines behind. The result of this segregation is generally quite noticeable on the conveyor feeding the mill, especially when the bin is nearly empty and the crushing plant shut down. Should the sampling period synchronize with either the coarse or the fines, the sample obviously would not be representative. I agree that this is rather far fetched, but I maintain that such a condition is possible. Assuming that a representative sample may be procured from the feed conveyor, the method of cutting it down for assay has considerable influence in maintaining the original condition of the sample. The finer the material is ground after each cut, the more uniform the sample will remain. To illustrate this point, let us take a quantity of fine sand and add, say, three grains of rice to represent metallic particles. We may mix this sample by any of the known methods, then cut it into four equal portions. It is obvious that at least one of the portions will be without a rice grain. But let us grind the three grains of rice into flour and proceed as before. Now there will be a much greater chance of including some of the rice in each portion.

Jan 1, 1935

By J. Seo

We propose a dynamic biomechanical simulation method that uses motion capture to evaluate the risk of Work-related Musculoskeletal Disorders (WMSDs). Statistics show that WMSDs accounted for 33% of all non-fatal occupational injuries and illness in construction in 2009, and were a leading cause of temporary and permanent disability. Present methods rely largely on self-reports from workers, observational techniques, and direct measurements of motion and muscle activity to assess awkward postures, physical loads, repetitiveness, and the duration of exposure. While these methods have helped to prevent WMSDs in construction work, they may not be suitable for estimating the internal tissue loads associated with WMSDs. We propose a dynamic biomechanical simulation method to estimate internal forces and moments at each body joint of construction workers with motion capture data. Particularly, we explore the biomechanical loads by simulating active 3D musculoskeletal models based on measured postures and movements. To demonstrate the feasibility of this approach, we studied a ladder climbing task using a portable ladder under controlled laboratory conditions. Postures and motions were determined with a commercial motion capture system (e.g., VICON). The results were analyzed to investigate the feasibility of identifying risk factors based on biomechanical simulation. The results show that the proposed approach allows us to determine the biomechanical basis for WMSDs, and to identify postures and movements associated with excessive physical demands on each body joint. When combined with marker-less motion capture which is our ongoing work, the proposed approach has the potential to assess an individual?s motions and to provide personalized feedback for the purpose of reducing biomechanical loads and WMSD risk in real workplaces.

Aug 1, 2013

By Paul Guliov

Preliminary investigations of stone resources were conducted in the La Range, Johnson Lake-Pelican Narrows-Deschambault Lake and Creighton-Amisk Lake regions of Saskatchewan. The work identified a rich variety of accessible, attractive and technically promising stone resources. Ordovician dolomites in various combinations of red, buff, yellow, grey and purple are very dense and take a very good polish. These are classified as marbles in the industry and some rival the famous marbles of Verona, Italy. A wide variety of attractive granites have been identified. Among these is a jade green stone (charnockite) and ornamental banded granites (gneisses). A dark greenish to black stone (amphibolite) with white and red veining resembles the well-known Verde Antique variety of Vermont and Italy and surpasses it aesthetically and in engineering properties. Some of these stones have been displayed at Canadian and United States expositions where they received an enthusiastic response from the international stone industry. More detailed evaluation and test quarrying of promising deposits are required. Such work could be rewarding to the industry as some stone varieties in the province have the potential for gaining international markets.

Jan 1, 2001

By David G. Meadows

During the last decade Antofagasta Minerals? Los Pelambres Mine has dramatically increased its ore throughput following the fast initial phase ramp up through a series of planned incremental expansions. The original 85,000 mtpd, two SAG line plant was commissioned in 1999 and rapidly exceeded nameplate tonnage in only a few months. Following this, the inclusion of a pebble crushing circuit resulted in throughputs in excess of 114,000 mtpd and a recent, final third line SAG and ball mill addition have taken the plant to over 175,000 mtpd even with increasing ore hardness and changing ore feed characteristics. The progressive changes are described in this paper together with how the technical challenges have been met.

Jan 1, 2012

By Jesus Garcia Iglesias, Jorge Loredo

"Abstract -The Asturian fluorspar district consists of vein and stratiform deposits where mineralization is controlled by a combination of lithological and tectonic factors.It is postulated that these fluorspar deposits have been formed under disequilibrium conditions created during circulation of ascending hydrothermal solutions along faults and other high permeability conduits. Mixing of solutions is inferred from fluid inclusion studies. Cavity filling and replacement processes are very important in localizing the ore deposits and in determining their morphology.Permian volcanic rocks in the area yield a regional positive geochemical anomaly in fluorine implying that Permian vulcanism may be a possible primary source of fluorine.On a regional scale a relationship can be established between some of the ore deposits and important tectonic lineaments. The stratiform deposits preferentially occur within a calcareous-detrital facies located at the margins of basins. These basin margins are related to important synsedimentary faults.Fluorite is the only economic mineral in these deposits. Quartz, carbonates, barite and pyrite are common minerals accompanying fluorite. Other minerals that may occasionally be present as minor components are: marcasite, chalcopyrite, fahlore, sphalerite, galena and related supergene minerals."

Jan 1, 1994

By J. A. Brown, F. P. Kerr, M. A. Archer

Extensive testwork on Global Atomic’s Dasa Project in Niger has been conducted at SGS Minerals laboratory in Lakefield, Ontario. Much of this testwork has focused on a two-stage counter-current leach as a means of improving leach efficiency and decreasing reagent consumption. The ore contains uranium mineralization requiring relatively high sulphuric acid concentrations during leaching to achieve acceptably high extractions. Excess free acidity in the leach solution may be utilized by recycling the high acid solution and contacting it with fresh ground ore. The resulting pregnant leach solution (PLS), now higher in uranium concentration and depleted in free acid, is forwarded on to uranium recovery by solvent extraction. The first stage residue proceeds to the second stage leach where fresh acid and oxidant are provided to leach the remaining uranium. This paper presents the results of the testwork conducted on both a Master Composite and Variability samples.

Jan 1, 2020

By E. Hardwick, K. C. Sole, Y. Jurrius

"The Luilu cobalt plant at Kolwezi, Democratic Republic of Congo, has been operating since the late 1950s, using a conventional precipitation flowsheet for removal of impurities from the cobalt process stream. Most impurities are, however, incompletely removed using this technology. Copper and zinc, both of which quantitatively deposit at the cathode in the cobalt electrowinning process, are two of the main impurities contaminating the cobalt metal product. Ion exchange offers a modern approach to removing these impurities from the cobalt advance electrolyte.Following a laboratory testwork programme to identify a suitable ion-exchange system, an on-site pilot-plant trial, treating 1500 to 3000 L/d of electrolyte, was operated for a period of six weeks to optimise the operating conditions and to determine full-scale design criteria. Copper removal was carried out using a fixed-bed lead-polish configuration with the Lanxess iminodiacetic acid resin, TP 207. Zinc removal was subsequently carried out in a similar configuration using the Lanxess aminophosphonic acid resin, TP 260. The optimised system proved capable of removing both copper and zinc from 20 to 30 mg/L to <1 mg/L from plant electrolyte containing ~20 g/L Co. Selective elution allows co-loaded cobalt to be returned to the main circuit and value to be obtained for the copper impurity. The process shows operational and economic advantages over the traditional flowsheet. Full-scale implementation of the developed process is in progress and some design considerations are discussed."

Jan 1, 2014

By Pan Zhao, Yan-Nan Wang, Fei-Long Liao, Can Cai, Kai-Song Wu

"What are the basic physical parameters and main geometric parameters that are capable of representing the microscopic characteristics of rock? How can these parameters be used to accurately describe the macroscopic mechanical behavior of rock? With such questions in view, and based on the microcosmic structure analysis of rock slices, this paper presents a rock skeleton-pore structure model, holding that rock's mechanical behavior depends on the properties of rock skeleton materials and the form, size and distribution pattern of pores. According to rock stress and deformation behaviors, and in line with the skeleton-pore structure model, an essential mechanics theory for rock is advanced. The assumption that the skeleton materials are incompressible in volume and an introduction of logarithmic strain, generate the relation between porosity and apparent strain. Then, the notion that positive damage and negative damage are represented in terms of porosity is put forward; threshold value of porosity is derived by the damage threshold value of apparent volume strain; a general damage variable of rock is obtained; eventually, with the skeleton-pore model as the groundwork, a global damage constitutive equation is developed, which, with definite physical significance and material parameters to be easily determined, is convenient to apply. It has been proved that the results calculated with this new equation are well in agreement with experimental results.INTRODUCTIONRock is a form of material that contains pores, cracks and skeletons. Skeletons are composed of particles and cements. Pores or cracks within rock actually undermine the assumption of material continuum in solid mechanics. Hence, grave errors — or even false results — are inevitable if some solid mechanics theory is quoted in the discussion of rock mechanics. Many researchers in the field of rock mechanics have attempted various remedies, but the outcome is far from satisfactory — a mechanics theory for rock, in its true sense, has not been established."

Jan 1, 2015