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By D. Xia

Pt-Bi intermetallic Nanoparticles was prepared by the polymer-anchor method. The electron micrographs shows that the dimensions of particles sharply distribute in the range of about 3-6 nm. The elemental ratio of Pt/Bi in the bimetallic particles is estimated by the electron probe microanalysis method. Pt-Bi intermetallic Nanoparticles shows a higher activity for the ORR than pure Pt. No significant dependence of the oxidation currents on the rotating speed of the electrode could be observed in the presence of methanol. This clearly indicates that the Pt-Bi is inactive to methanol.

Jan 1, 2005

By A. Kraly, M. Complojer, P. Paschen, K. Gamweger, H. Antrekowitsch

Increasing quality of aluminium alloys and continuous optimization of the production process leads to an improvement of the gas purging systems. The application of porous plugs for the treatment of liquid aluminum is nowadays not widely used in the aluminium industry especially in Europe. The Department of Nonferrous Metallurgy and the Christian Doppler Laboratory of Secondary Metallurgy of Nonferrous Metals intensified the research and development of refining and alloying processes by gas treatment during the last years. CFD-modeling supports these experiments, which should lead to lower hydrogen content, lower suspended particles and a better distribution of alloying elements in the melt. Different parameters such as temperature, bubble size, gas amount and which kind of gas is used influence the quality of the products.

Jan 1, 2006

The Rabbit Lake In-Pit Tailings Management Facility contains frozen layers of tailings due to subaerial deposition during the coldest periods of winter. Thawing is required to ensure full consolidation of the tailings and to regain disposal space presently occupied by ice. Electric resistance heating has been used to heat soil for bitumen extraction and remediation of volatile contaminants. A preliminary evaluation of the application of electric resistance heating to thaw about 0.3 cubic metres of frozen tailings was conducted using tailings frozen at about -2 oC. Visible thawing of the tailings mass was observed after 25 hours, demonstrating the feasibility of this approach.

Aug 1, 2010

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By Simon D. Handelsman, Malcolm Scoble, Marcello Veiga

"Abstract - In many mining areas, potentially profitable mineral projects can be at risk because local people do not trust their governments and mining companies on many issues, including human rights. Projects will continue to be vulnerable to potential failure, delays, and higher costs. This paper suggests that geoscientists need to be aware of the global challenges they face from issues of corporate social responsibility, sustainable development, and human rights. These are not areas in which geoscience education has traditionally focused.This paper examines the types of conflict concerning human rights that are encountered by geoscientists involved in mineral exploration and development. It provides a background to human rights issues and presents a classification of the types of issue encountered. It reports on a survey of case studies that provide examples of the breadth, complexities, and consequences of such issues. The paper then concludes by outlining the development of codes and standards to improve performance, and suggests approaches for positive, practical engagement."

Jan 1, 2003

By J. Beddoes

The various microstructural factors that influence the creep resistance of y-titanium aluminides are presented and discussed. Titanium aluminides have potential for a variety of intermediate temperature applications in both gas turbine and reciprocating engines. While it is well established that the 'fully lamellar' titanium aluminide microstructure offers superior creep properties, the particular influence of lamellar morphology, third phase precipitation, and grain boundary structure in controlling both the primary and tertiary creep behaviour is presented. The results are primarily based on tensile creep experiments undertaken using several titanium aluminide intermetallic compositions processed via powder metallurgical techniques, investment casting and Bridgman directional solidification. The results indicate that lamellar structure and precipitate formation have a major impact on primary creep, while microstructural degradation through both lamellar and precipitate coarsening influence on the onset of tertiary creep leading to fracture. The results are used to design a creep resistant microstructure produced by directional solidification and the effectiveness of this designed microstructure is demonstrated through 10,000 hour creep tests.

Jan 1, 2004

By R. D. MacEchern, M. C. Rockwell

"This paper describes the research and tests carried out to recover the readily available barite from the tailings produced by the Nystone Chemical Ltd. operation at Debert, N.S. The tailings comprised 70-80% of the original feed and contained about 20-25% Baso4 .The objective of the research, undertaken during 1982, was to produce a barite concentrate which would meet the American Petroleum Institute (API) barite requirements for use in drilling mud. Samples from the tailings pond were examined and analysed to determine the tailings characteristics.Preliminary test work was performed on the tailings samples using a Haultain Superpanner, Wilfley tables and Humphrey's spirals. The grade of the barite concentrate retrieved did not satisfy the API barite requirements.The fineness of the tailings and the fact that approximately 80% of the barite was contained in the -200 mesh (0.074 mm) size fractions, indicated that flotation of barite from the tailings might be successful."

Jan 1, 1984

By Lindsay A. Robertson

The long term management of acid generating tailings at mine closure is a common issue, however, management of ARD is significantly impacted by local conditions, including climate. Acid generating tailings, over time, will produce acid rock drainage (ARD) if left exposed to water and air, which both contribute to the sulphide oxidation process. The long term closure of tailings storage areas is a concern from both environmental and engineering perspectives, with long term acid generation and dam stability the main risks. Several approaches can be taken to minimize ARD from tailings facilities using cover systems. Three tailings facility cover case histories, in areas of net positive water balances, were investigated using unsaturated flow modelling software to determine the long term potential for limiting ARD by increasing saturation of the tailings and decreasing oxygen ingress. Each case study demonstrates the importance of integrating the tailings dam engineering into tailings cover closure design. Model predictions are compared to measured saturation levels to assess the accuracy of the calculations.

May 1, 2011

By J. Bhattacharya, S. K. Mukhopadhyay, S. K. Pal

"While time and again many authors have categorically stressed the restoration of the environment, very little effort has been made in the mineral industry to develop the economy of environmental control. There are many abatement procedures that search a maze of variants. Among them pricing environmental damage seems to be more logical and easily implementable.IntroductionMining as an operation has a severe impact on the Earth's natural resources. While economical environment control is much sought after, solutions are often varied and complex, and can differ in the problems of single or multiple mine sites.Determination of Optimum use LevelsIn “mining environmental control"" it is required to strike a balance to find optimum use levels. The solution is to find where the welfare benefits equal the cost involved to curb the degree of environmental damage (Fig . I) . In the mining industries this can be done by modifying the production/extraction process itself. For most pollutants, the marginal costs of control will exceed the benefits from further reduction of damage long before the zero pollution damage point is reached (Fig. I). From an economic perspective the optimal alteration of environment by mining would occur at z; pollution continues to be caused by ""zy"" control units, but it would be inefficient to pursue the redemption efforts further because the marginal cost involved would exceed marginal welfare benefits."

Jan 1, 1992

By Sheila E. Daniel

"Since 1989, the Mine Environmental Neutral Drainage Program (MEND) has sponsored research into ways of reducing the environmental impact and financial liabilities associated with Acid Mine Drainage from tailings and waste rock. Toward this overall objective, Kilborn was contracted to review the use and applicability of passive treatment systems for acid mine drainage.Experimentation using passive systems to treat acid mine drainage has been ongoing since the early 1980's in North America. Passive treatments are generally considered an attractive alternative to active lime treatment, since they require minimal human involvement, no power, and only seasonal or periodic care and maintenance after establishment. Most attractive is that initial capital cost to implement a passive treatement system is generally low to moderate. Ongoing operating costs are similarly low when compared to active treatment systems.Passive treatment systems currently used, or under investigation to treat acid mine drainage include: anoxic limestone drains, aerobic wetlands, reed bed wetlands, compost wetlands, microbial systems and bioabsorption systems. These wastewater treatment systems utilize the chemical, biological and physical removal processes that occur naturally in the environment to improve wastewater quality, including: oxidation, reduction, coagulation, adsorption, absorption and precipitation; microbial activity; and, gravity aeration and dilution. The rates at which these processes occur determines the loading which can be treated and the effectiveness of the system.The results of our literature review will be summarized, and insight provided into the applicability of passive systems to treat acid mine drainage from Canadian Mines."

Jan 1, 1995

By Zia Pirzada

"Time is of the essence" and "Time is money" These are powerful and true statements during a project life cycle and have far-reaching implications on the success and failure of the project Time and progress management is crucial to the project success. Project delays may increase the cost to an unacceptable level and may render the project as economically unfeasible. On the other hand, if the project is completed on time or earlier than as planned, it may generate economic benefits greater than what had been envisioned To take advantage of the financial opportunities and to improve the cash flow as well as Return On Investment (POI), project schedule can be accelerated to complete the project earlier than planned Project schedule acceleration can be achieved by using analytical tools, such as "Schedule Optimization", "Schedule Reduction", "Schedule Compression" or a combination of any of these concepts along with the "Planning for start up". Schedule optimization does not entail any extra cost, however, other acceleration methods, such as Schedule Reduction and Schedule Compression, may require extra expenditures from the owner. Based on the forecasted early start of the revenue stream, the extra expenditure could become a worthwhile venture with a very high rate of return To accelerate the schedule, all aspects of the project should be reviewed with acceleration costs calculated. All risks and opportunities should be evaluated and taken into consideration to determine if the acceleration is feasible and advisable and will provide definite financial advantages Sometimes schedule acceleration may be desired to prevent the company from paying liquidated damages. This is especially true when the project is not expected to complete on the contractual completion date and when the cost of acceleration is less than the liquidated damages that may accrue against the company.

Oct 1, 2010

By D. Milne

Laser profilometers exist for obtaining very accurate two and three dimensional profiles of joint surfaces. The application of this technology is not commonly applied to the collection of field data on discontinuity surface roughness. Rugged and portable field devices are not commonly used and the value of the possible field data that can be collected has not been well recognised. This paper reviews commonly used field techniques for assessing discontinuity roughness, discusses the value of this data and presents a new laser profilometer design for field application.

May 1, 2009

By D. Laguitton, D. Cimon

"BILMAT is one of the most powerful algorithms in existence for material balance computation in mineral processing flowsheets. It is based on a hierarchical decomposition coupled with the Lagrange multipliers method widely reported in the literature. Flowrates can be calculated optionally for pulp, solid or water. Assays are adjusted for a variety of subnetworks, such as assays of the solid as well as assays of fractions of the solid called level 4 data (l: pulp, 2:solid and water, 3:assays of solid, 4:assays of classes of solid).BILMAT4 is a new implementation of BIU1AT that operates in a new microcomputer environment and makes the method more accessible than ever. Its main features are a full-screen colour editor allowing graphic flowsheet drawing and data entry with automatic error checking. Mass balance equations are automatically generated by analysis of the graphics and corresponding data, thus relieving users from the error-prone definition of networks. Sensitivity analysis is performed to assess confidence intervals of computed flowrates and adjusted assays.BILMAT4 incorporates an option for gold leaching circuits where the element to be balanced appears in both the solid and liquid phases with negligible effect on the mass flows of solids. Recoveries are computed in all streams. This program is currently released by CANMET as part of the CAMP collection for Computer Aided Mineral Processing. A complete sample run of the program is discussed."

Jan 1, 1989

By Patricia Dillon

EHS Management Standards Communication and Reporting (8) ! Establish processes for internal and external communications ! Designate responsibilities for communication with COI ! Report as defined by senior management ! Report annually to employees, shareholders, COI on EHS and social performance Community Rights and Public Consultation (9) !Identify COI?s and establish process to hear concerns !Acknowledge and respond to complaints !Support local communities !Plan for closure and conduct public consultation !New projects include identification of COI?s, concerns to be considered in design

May 1, 2004

By M. Takebayashi, M. Shingu, H. Nagai, T. Nakai, S. Asano

The Toyo Smelter and Refinery, owned by Sumitomo Metal Mining Co., Ltd. (SMM) is located in the coastal zone of Saijo City and Niihama City, Ehime Prefecture, Japan. The refinery has been producing copper, sulfuric acid, and precious metals such as gold, silver, and PGMs. Previously, the process of precious metals recovery was a combination of pyrometallurgy and an electro-refining process with the conventional cupellation for around 400 years. However, this process had some major problems such as non-efficient recovery of valuable metals, high environmental risk by pyrometallurgy, high cost for maintenance of equipment and so on. In order to solve these problems, a thorough hydrometallurgical process for precious metals refining using chlorine leaching technology was originated and developed by Sumitomo and thereafter commercialized in 2004 at Toyo Copper Smelter and Refinery. This new process enabled shorter-term recovery of gold and manpower saving, and occupational safety and working conditions have also been improved. Superiority over the existing hydrometallurgical processes was also confirmed, for example by the achievement of 99.99% pure silver production without an electro-refining process. This paper summarizes the hydrometallurgical technologies for precious metals recovery such as chlorine leaching of copper anode slime for silver recovery, solvent extraction (SX) for gold recovery, and ion exchange (IX) for PGMs recovery. It also presents a unique silver purification process. INTRODUCTION Sumitomo Metal Mining Co., Ltd. (SMM) produces copper, precious metals and rare metals as by-products at the Toyo Copper Smelter and Refinery, and nickel and cobalt at the Niihama Nickel Refinery. Precious metals contained in nickel ore are also separated and refined at the Toyo Refinery after concentration. SMM has been refining precious metals using the pyrometallurgical method. In recent years, we have revamped the separation and refining process of precious metals dramatically by making use of advanced hydrometallurgical and engineering technology developed in the company. In this paper, we introduce the history of development and techniques of this process, and also introduce in detail the technologies of gold refining, PGMs recovery, selenium recovery, and silver refining which have been particularly difficult to achieve.

Jan 1, 2019

By Xianglin Yang, Hong Zhong, Jingjing Xiao, Guangyi Liu

"The selective adsorption of a flotation collector to a mineral plays a crucial role in enhancing the hydrophobicity of targeted mineral particles for attaching air bubbles in pulp. The recent progress of the structure-reactivity relationship of flotation collectors, the characterization methods for mineral surfaces with adsorbed collectors and their commercial application are reviewed in this paper. Particular emphasis is placed on the density functional theory (DFT) for understanding the reactivity of new collectors, the surface analysis techniques including time-of-flight secondary ion mass spectrometry (ToF-SIMS), in situ scanning electrochemical microscopy (SECM) and atomic force microscope (AFM) to characterize mineral/collector interface, and the flotation technologies for optimizing recovery of valuable minerals. Especially, the recently developing collectors such as Gemini, alkoxyalkylthiourea, dithiourea, amide-hydroxamate and oximido-thiol surfactants, and their specificity to given minerals are evaluated. Based on this crucial review, it is evident that the structural modification approaches for minerophilic or hydrophobic groups, and combined surface analysis approach for further understanding the adsorption mechanism of collectors on mineral surfaces will lay a solid foundation for the future development of flotation collectors. INTRODUCTIONIn mineral processing, flotation is the main process for separation and recovery of valuable minerals from the ores contained them (Fuerstenau et al., 2007). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by collector adsorption so that these mineral particles can preferably attach to air bubbles in a slurry or pulp (Fuerstenau et al., 2007). Flotation collector is a kind of functional surfactant, which is composed of polar and non-polar groups (Somasundaran, & Wang, 2006). Non-polar portion, commonly being linear, branch or ring hydrocarbon group, is termed hydrophobic group. The polar portion, exhibiting strong affinity to mineral surfaces, is known as minerophilic group (Nagaraj, 1988). According to mineral types including saline, oxide and sulfide minerals, flotation collector divides into sulfide and oxide mineral collectors. For efficient recovery of valuable minerals from the refractory complex ores, insights into the adsorption mechanism, hydrophobic model and subsequent flotation approach of flotation collectors have been regarded as an indispensable issue in mineral processing."

Jan 1, 2016

By M. J. King, D. A. Van den berg, R. Fukuzawa

"Mercury bearing ore bodies are often treated for the production of copper, lead, zinc, gold, and silver. The mercury deports either to tailings or is collected during various stages of the extraction process. This paper reviews the relationship between various mercury collection processes and the subsequent management of the mercury by-product or waste. It focuses on mercury removal sequestration including cementation, sulphide precipitation, bulk neutralization, and carbon adsorption. Long term mercury management strategies including third-party stabilization, stabilized mercury co-disposal, secure storage, and mercury recycle are also evaluated. INTRODUCTIONMercury is produced in North America as a by-product of non-ferrous metals processing and from recycling of products such as dental amalgam, fluorescent lamps, and thermometers. Its toxicity is recognized to have significant negative impacts on the environment and human health. As a result, many countries are adopting regulations limiting mercury use and its uncontrolled release.The European Union banned mercury exports in 2011 and the United States will do so in 2013. The export bans aim to prevent mercury use in developing countries for activities such as artisanal small scale gold mining. However, by-product mercury production from the non-ferrous metals industries continues.These factors contribute to an oversupply of mercury and the need to find suitable treatment methods for the long term management and storage of mercury and mercury bearing materials."

Jan 1, 2012

By George P. Demopoulos

In a departure from the traditional domain of hydrometallurgical extraction processes we consider new R&D opportunities for innovative application of solution processing into the advanced green energy and clean technology fields. It would not be an exaggeration if we state that protection of the environment via advancement of clean technologies on the one hand, and harvesting and utilizing renewable energy in a sustainable and cost-effective way on the other hand are clearly among the top pressing global priorities. When hydrometallurgy is approached on the basis of its aqueous chemistry and reactive processing fundamentals, it can indeed provide a highly fertile ground for innovation outside the "box". In this context therefore we will present highlights from our recent research that is directed towards the development of new generation HCl recycling, environmental, and solar energy conversion/storage technologies. In all systems the research is approached via the innovative integration of aqueous process engineering and material chemistry principles. The presentation will include discussion of (i) the development of crystallization-based HCl regeneration technologies; (ii) the supersaturation-controlled production and encapsulation of scorodite that was recently commercialized; (iii) the aqueous synthesis of nano-TiO2 and its electrophoretic deposition into solar cell electrodes; and (iv) the hydrothermal synthesis of nanostructured lithium titanate and lithium iron phosphate materials to make lithium-ion batteries destined for electric cars.

Jan 1, 2014

By Alan S. Lock

Large scale feasibility studies for the establishment of oil-seed and cellulose producing crops on mine tailings have been successfully conducted over 1 growing season with the purpose of these crops to be used as feedstock to the biofuels industry. An acid sulphide tailings impoundment in Copper Cliff, Ontario and a near neutral pH goldmine tailings impoundment in Timmins, Ontario were both tested by amending half hectare plots to approximately 1 m thick with residual biosolids from the pulp and paper industry and growing canola and corn on these plots. Full scale agricultural equipment was used to cultivate seed and harvest the plots to prove the full scale feasibility of farming on these biosolids. The vegetation development, growth, yield, quality and composition were assessed to identify the best species that would maximize biomass development for feedstock to the biofuels industry and carbon credits for the mining industry. Groundwater, biosolids and tailings chemistries were investigated to identify potential deleterious impacts of degrading organic matter on tailings metal mobility. Preliminary hydrologic investigations using moisture sensor profiles elucidate potential conservation of water in amended plots. Tailings amended with biosolids have the potential to provide the mining industry with carbon credits and supply feedstock to this new industry while reclaiming brownfields to a new level, utilizing industrial and municipal organic waste material.

May 1, 2009