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By X. B. Wang, Z. Q. Guo

Slagging coal gasification process became a highlight of coal chemical industry in China during the last decade. Refractory lining's life of slagging gasifiers is one of the most critical factors for a cost-effective operation. The paper introduces current status of coal gasification in China, lining structure of slagging gasifiers and performance of refractory lining. It also summarizes the major factors impacting on refractory wear in slagging coal gasifiers in four Chinese chemical plants, based on ten years of industrial experience. The utilizability is discussed in terms of cost-effectiveness of high chromia refractories and possibility of the alternatives.

Jan 1, 2004

By James A. Deeks

"Motor failures and equipment bearing failures are responsible for reduced productivity.With the introduction of computers and data acquisition systems, users are now able to monitor, report and trend deteriorating conditions and take corrective action before a critical shutdown occurs.This paper discusses the monitoring and trend analysis of' motors, and motor and equipment bearings. With today's digital electronics technology users are now able to monitor their equipment, detect deteriorating or abnormal conditions quickly, alarm the condition locally and or remotely, and decide if immediate corrective action is necessary or if it can be delayed until the end of a work Shift. All of this can be done long before any damage is done to the equipment.Monitoring Trend AnalysisIt is no longer necessary to compromise in selecting products, since state-of-the-art designs allow the adjustment in such small increments that the users are able to detect minute changes in a system's performance.Monitoring and trending of motors and equipment bearings is now available in economical packages which can be expanded as a system grows. Simply select the information you need, set the parameters, choose the scan time, and decide on the degree of reporting.Buffer storage of short-term monitoring of a number of analogue channels permit the user to view the recent history of motor data such as: motor average load, unbalance, motor current, ground fault, reserve thermal capacity, plus all of the settings of the protective device.A decision can be made to freeze the stored information after the motor stops or after the motor starts. Then the user is able to recall the conditions and diagnose the performance and the cause of the abnormal condition. Typical scan times range from ¼ second to 5 seconds ."

Jan 1, 1992

By M. D. Quinn

THE sand and gravel used for backfilling at the Hollinger mine is obtained from deposits in a low range of hills some three miles north of the mine, where the Company owns a number of claims. The material is transported to the mine by aerial tram. Shipments from these deposits to the Hollinger mine commenced in June, 1927, and since May, 1936, sand has been supplied also to the McIntyre mine. During 1942, Hollinger requirements were 1,700 tons per day, and 900 tons per day was delivered to McIntyre. For the past seven years production has averaged 900,000 tons annually, and total deliveries to the end of 1942 were 13,129,022 tons, of which 11,075,339 tons went to Hollinger and 2,053,683 tons to McIntyre. Some years ago, when the original pit was approaching exhaustion, new workings were opened on claims east and south of the tramway terminal. It soon became apparent that the sand varies considerably in character from place to place. The weight per cubic foot was found to range from 85 to 130 lb., and the water percolation rate from 2 to 50 inches per hour. As the mine requirement is a sand with percolation rate of 6 inches or better per hour, it was evident that in certain parts of the deposits the material was not suitable for use as backfill. As a consequence, it was decided to carry out a programme of systematic sampling of the claims in order to select the areas containing suitable material for back-fill and at the same time estimate the tonnage available.

Jan 1, 1944

By L. A. Homeniuk, R. Bonnar

"The Athabasca Basin has been the scene of an intense exploration effort since the late 1960s, resulting in the establishment of this area as one of the major uranium districts in the world.The A thabasca Group is of Helikian age and unconformably overlies metamorphic rocks of Aphebian and Archean age. Most of the known uranium deposits have a close spatial relationship with the unconformity, graphitic meta-sediments, major northeast-trending structures and the basin edge. It should be noted that, in regard to the latter, some of the Cluff Lake deposits are exceptions.The pre-Helikian rocks underlying the Athabasca Group have been divided into six Iithostructural domains. The known uranium deposits are concentrated in the Wollaston and Mudjatik domains in the southeastern portion of the basin.The orebodies typically have a narrow high-grade portion below the unconformity and a broader, lower-grade disseminated zone in the overlying sandstone. Over-all grades average over 1% U3O8 and our estimate of known reserves totals more than 400 million pounds of contained U3O8. Some of the deposits have high concentrations of other metals, including nickel, arsenic, cobalt and gold. Ubiquitous chlorite and clay alteration is characteristic of the orebodies.Other Proterozoic basins in Canada of similar ages and having analogous geological settings to the Athabasca have received far less attention. Although little of the known uranium mineralization in these basins is related to the Helikian unconformity, there may be an exploration potential for deposits similar to those of the Athabasca basin.IntroductionThe Athabasca sedimentary basin is located within the Churchill Structural Province of the Canadian Shield in Northern Saskatchewan. The basin is elliptically shaped and is approximately 800,000 square kilometres in area.The objective of this paper is to summarize the various elements in the genesis of the unconformity-type uranium deposits of the Athabasca Basin and to evaluate the comparative potential of other Proterozoic basins to host similar unconformity-type deposits."

Jan 1, 1982

By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By L. Tapia

The main disturbance for stability in primary grinding using SAG mills is related to continuous changes in the ore being fed to the plant, such as size and hardness. Searching for stability is the first step to accomplish, before trying to maximize the mill throughput. The time variability in the characteristics of the ore being fed from the mine to the plant must be known or inferred to perform adaptive changes in the grinding process control. In day to day operation, such information is not available in real time. Transport times and inventories between the mine and the plant complicate the situation. Under this scenario, Minera Los Pelambres implemented a grinding optimization strategy, based on the real time analysis of certain process variables, such as ore size, mill current consumption, pebble generation and throughput. As a result, both grindability and stability indexes are inferred. This is equivalent to inferring the ore characteristics by knowing its effect on the grinding behavior. These two indexes permit control of the SAG mill total charge level and hence, allow optimization of throughput by means of an expert control system.

Jan 1, 2007

By W. Kempson

"Mining Companies have producing assets in increasingly diverse portions of the world. It is not uncommon that the owner, the design team, the mine contractors and the operators are all based in different countries. While these assets are always subject to the regulatory requirement of those countries there have not been international standards available to review and evaluate these assets. This becomes particularly important when considering safety critical items such as tailings dams, vertical shaft systems and autonomous vehicles to highlight a few. The work currently being completed in ISO ensures these standards will be available and will be generated by and subscribed to on an international basis, thus removing the potential for patriotic partisanship and ensuring safe and predictable systems are installed. This paper will discuss the benefits of the international standards, the structure of the teams and working groups who are generating these standards as well as the process by which the standards are generated. This will allow insight into the creation of the standard and will aim to demonstrate the “neutral” and technically strong manner in which the generation of these standards is achieved. In addition, the paper will discuss the standards which have been produced in the last five years as well as the current standards which are in place. The finale will discuss upcoming work and the timelines in which it is anticipated these will be completed. INTRODUCTION Mining Companies have producing assets in increasingly diverse portions of the world. While these assets are always subject to the regulatory requirement of those countries, there have not been international standards available to review and evaluate these assets. This becomes particularly important when considering safety critical areas such as vertical shaft systems, tailings dams and autonomous vehicles to highlight a couple. The work currently being completed in the International Organization for Standardization (ISO) ensure these standards will be available and will be generated by and subscribed to on an international basis, thus removing the potential for patriotic partisanship and ensuring safe and predictable systems are installed. The ISO/TC 82 – Mining was founded in 1955. This was an active committee until it was thought that the standards at the time were adequate and the Technical Committee was put on “Care and Maintenance”. In 2012 countries lobbied ISO to pull this committee from dormancy and restart it, this happened in in the same year."

Jan 1, 2019

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

Caterpillar Inc The world's largest manufacturer of construction and mining equipment, diesel and natural gas engines and industrial gas turbines. Technology leader in logistics, construction, transportation, mining, forestry, energy and electric power generation.

Aug 1, 2013

In the last 30 years numerous mining plants have been developed in North America but only a handful of these have required freezing the area where the shaft was sunk. The most recent mine shaft to be sunk using this technique is located on an island off the coast of Louisiana. The project required the input and skills of numerous people in several companies, including the owner, engineers and contractors. The Cote Blanche installation is one of several mines in the area which extract salt from a dome which extends under the Gulf of Mexico. The geology of this area is, however, markedly different from others in the region because there is approximately 460 ft of water logged soil above the salt dome. Because it is not possible to sink a shaft in ground that is this soft, the overburden where the shaft is located must be frozen before excavation can take place. The Cote Blanche mine is a producing facility which was built in 1958 by the Carey Salt Company. The original facility included a 14 ft diameter production shaft and a 7 ft-8 in diameter service/ventilation/escape shaft. This system was installed by The Cementation Company. In 1996 the owner decided to improve both the mine ventilation and production hoisting system by installing a third shaft. This shaft would be designed to extract 650 tons per hour from a depth of 1600 ft and provide 500,000 cfm of ventilation to the mine at a maxium design pressure of 4 in WG. These parameters resulted in a requirement for a 16 ft finished inside diameter concrete lined shaft and a headframe designed as a pressure bulkhead. Because the mine would operate from one level only, the most efficient hoisting system for the application was determined to be a ground mounted koepe running on rope guides. With these criteria fixed Cote Blanche embarked on a program which would see construction start in June 1998 with the first salt produced in February 2001 at a cost of $US18M. The major players in the design and construction were G.L. Tiley & Associates Ltd., BLM Bharti Engineering, Freezewall Inc., Phillips Mining, Geotechnical and Grouting Inc., Don Hart Consulting and Dynatec International.

May 1, 2002

By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005

By Jochen Petersen, Caroline Muzawazi

The technical feasibility of ammonia leaching of PGM bearing Platreef flotation concentrates was investigated as an alternative method for the recovery of base metals prior to precious metal recovery. The composition of the concentrates includes 2.02% Cu and 3.17% Ni, and the major base metal minerals are chalcopyrite and pentlandite. Optimal leaching conditions were initially established in shake flask experiments to be a solution containing 4 M NH4OH, 4 M (NH4)2CO3 and a pH range between 9 and 10. These were used as base case conditions in column and batch stirred tank reactor tests, where the effects of total ammonia concentration and operating temperature were explored further. At optimal conditions nearly 100% Cu and Ni extraction were obtained in the batch stirred tank reactor, and 95% Cu and 60% Ni extraction was obtained in columns. The activation energy for chalcopyrite and pentlandite was 36 kJ/mol and 16 kJ/mol, respectively, in both reactors, indicating different reaction pathways for the two minerals. Gas-liquid mass transfer appears to be the limiting reaction step in columns much more than in tanks, and the degree of ammonia loss to air is significant. This initial test work indicates the feasibility of using ammonia leaching for this and similar materials as an alternative route to conventional smelting and refining prior to PGM recovery, but a number of technical challenges still need to be overcome.

Jan 1, 2014

By Frank Martonhegyi

"The objective of this paper is to review the coal basins in the Canadian part of the Western Cordillera to aid their understanding, and to aid in finding and proving places of economic coal mining potential. Coal occurs in eugeosynclinal basins in the Western Cordillera which evolved through three stages: -from systems of volcanic arcs in the Late Jurassic to mid-Cretaceous; -through an intermediate stage with deposition in increasingly restricted successor basins in Jurassic to Early Tertiary; -to a continental stage by the Eocene. Minor coal seams occur usually in late volcanic arc stage sediments bur they can be locally thick as they are on Queen Charlotte Islands. Successor basins usually show a marine-paralic-limnic evolurion. Signijicanr coal deposits occur in the tarter two sequences in the Whirehorse (Tantalus) and Bowser (SkeenaSusrur) basins. Currenr activities are intensive in the more accessible Bowser Basin, for example at Telkwa, Susrut River and on the Groundhog coal field. On Vancouver Island major coal seams occur in cyclic sediments, but the more accessible deposits are mined our. Exploration renewed recently in the less accessible northern part of the Island, for example Quinsam, for surface mineable coal. The Western Cordillera is a mosaic of allochtonous tectonic blocks. They originated from the south and were displaced northward by several hundred kilometres. Many Tertiary coal basins are related to strikeslip transcurrent faults along which the later part of displacement took place, for example the Dawson coal area in the Tintina Trench. Tensional and dipslip normal faulting also created or enhanced sites for thick peat accumulation. For example at Hat Creek 280 m of coal occur in a 550 m section. Secondary structures are often better exploration targets than the main fault zones. Pluvial and alluvial fan environments away from the main drainage are usually the favourable sites for thicker and cleaner coal deposition."

Jan 1, 1985

At 14%, the representation of women working in the mining industry is the lowest among primary industry categories in Canada1. With reference to mining operations and senior leadership, the gap in the industry is even more pronounced. In an effort to narrow the gender gap, recent industry, education, and policy efforts have been made to increase the number of women entering the industry through career awareness and early career recruitment strategies. These strategies implied that by increasing the numbers of women entering the industry there would be a natural progression of women into the hierarchies of organizations. Efforts to retain women in the industry have focused around removing career barriers such as reviewing flexible work practices and programs directed at work life balance. At this time, these efforts have resulted in negligible fluctuations to the gender gap within the industry. This research investigates the under-representation of Highly Qualified Women (HQW), and the interaction of workplace culture on their career advancement and retention within the industry. HQW (women with a bachelor?s degree or higher) are the focus of the work as they represent an essential source of leadership and technical capacity for mining organizations. This paper is based on the results of a survey of 170 HQW working in the Canadian mining sector. The findings from this research suggest that HQWs careers in mining are stalled, despite a strong indication by respondents of interest in their professional career advancement. With regards to workplace culture, respondents indicated that blatant forms of gender discrimination have been reduced in mining workplaces; however, exclusion from informal networks, implicit bias and subtler forms of workplace discrimination persist. Utilizing a framework to assess the workplace culture for women in attracting and retaining their employment, respondents provided detailed information on the aspects of workplace culture that are most problematic in relation to women?s career development in mining. Women consistently identified problematic workplace culture as a significant barrier to the career advancement and retention of women within the industry. The representation of women within the labour force will likely remain stagnant until the industry addresses workplace culture within the industry, and makes strategic efforts to develop inclusive cultures throughout mining and supportive organizations.

Aug 1, 2013

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011

By Darryel Boucher, Thomas W. Leadbeater, Raymond Langlois, Joshua Sovechles, McGill University, Zhoutong Deng

"Spiral concentrators are used to upgrade ore based on the density difference between their component minerals. This simple flowing film gravity separator is of interest for the processing of large amounts of material, as found in the iron ore industry. Addition of wash water at different points on the trough of the spiral affects the grade and recovery of the valuable concentrate by affecting the flow of particles within the thin slurry film. This paper shows how radiolabelled hematite (-355+300 µm) and quartz (–1,180+1,000 µm) tracers were used to determine the particles’ behaviour within the slurry film with and without the addition of wash water. The results presented provide a detailed particle flow pattern around a wash water addition point and its effect on the trajectory and velocity of the particles. This information is of interest in building knowledge about spiral wash water injection parameters such as injection location, direction, flow rate and nozzle orifice type (affecting jet shape and velocity).INTRODUCTIONSpiral concentrators are density based separation devices. They are extensively used in the upgrading of iron ore, fine coal and minerals sands (sources of ilmenite, rutile, zircon and monazite) (Wills & Finch, 2016). A spiral unit is composed of a channel of specific profile formed as a helix of 3 to 7 turns around a central structural post. The feed pulp is composed of 15 to 45% solids with particle size from 75 µm to 3000 µm (Wills & Finch, 2016). Throughput of a single spiraling trough can be up to 8 ton per hour and multiple trough unit (up to four trough) can process up to 30 ton per hour for a footprint of around 0.7 m2 (Palmers & Vadeikis, 2010). They are low cost concentrators considering manufacturing of their trough via polymer reverse molding. The energy intensity of a spiral plan is notably small considering the throughput and is mostly related to pulp pumping and final concentrate dewatering."

Jan 1, 2016

By S. N. Kalyakin, D. S. Flett, M. A. Mulagaleeva, N. V. Gudkova, S. S. Serdyuk, V. I. Kuzmin, Institute of Chemistry and Chemical Technology SB RAS, O. A. Logutenko, V. N. Kuzmina, V. G. Lomayev

"The Chuktukon niobium-rare earth elements ore deposit is located in Siberia (Russia). Weathered carbonatite crusts are the basis of the ore deposit. The deposit itself is 3.5 km in length, about 800 to 1400 m in width and up to 200–300 m in thickness. The ores are composed of iron-manganese oxides (hydrogoethite, hematite, psilomelane, pyrolusite) and contain 3–7% of rare-earth phosphates (florencite, monazite) and 0.5–1% of niobium oxide (pyrochlore). The ore is completely finely dispersed and consists of oxide particles formed of compact, dense aggregates which makes ore dressing as well as leaching of the rare and radioactive elements very difficult. Several options for processing of these ores have been considered: 1) reduction of the iron oxides to magnetite followed by beneficiation with magnetic separation to produce a rare metal concentrate; 2) processing of the rare earth elements (REE) containing minerals by direct alkaline-acid treatment; 3) processing of the ores using nitric acid leaching in an autoclave.INTRODUCTIONThe Chuktukon niobium-rare earth metal ore deposit is located in Siberia, in the Krasnoyarsk region, 110 km from the Boguchan hydroelectric power station which has recently been commissioned. This mineral raw materials is capable of providing impetus for the modernization of the Russian rare metal industry because of its qualitative and quantitative characteristics. The deposit is located in a region of promising industrial development and is a part of the territoriy where the Russian Federation’s Program “Complex Development of the Lower Angara Region” is currenly being realized. The main program directions are creation and development of industrial activities in sectors such as power, metallurgy, oil and gas, gold, rare-metals, and timber. The program will aid the development of the niobium and rare-metal resources of the Lower Angara and neighbouring regions as well as increase the national production of REE and therefore import substitution (Lapin, 1997; Lomaev & Kuzmin, 2003; Lomaev & Serdyuk, 2011; Serdyuk, Lomaev, & Kontorovich, 2000)."

Jan 1, 2016

By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004