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By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By Rod Abbott

High Definition Scanning (laser scanning) is a proven technology that is accurate to within 6mm in 50m (¼? in 150?). It can capture in excess of one million 3D point measurements in an average 2 hour scan. It has numerous applications including brown-field retrofits, bridge measurement and analysis, verifying as-built conditions, and crime scene investigation. We most commonly use it for plant design to capture current site conditions, so as to prevent interferences and problems before construction begins. All vital information is captured in the first site visit, which limits the need for extra field trips.

Oct 1, 2010

By Subagyo, Geoffrey Brooks, Ken Coley

The generation of droplets and their subsequent reaction in the emulsion is critical to the overall kinetics of oxygen steelmaking. High temperature experiments have been performed at McMaster University to study this behavior. The results from this work and other previous studies has formed the basis of a number of physical and chemical models that attempt to describe the critical aspects of droplet behavior in Oxygen Steelmaking. These models include semi-empirical models for predicting droplet generation rate, droplet size distribution and droplet residence time as a function of blowing parameters.

Jan 1, 2004

By R W. Drybrough

The program to increase production at Sherritt Gordon's Lynn Lake property, which began in 1956, included increasing the rope speed and the horsepower of the ore hoist at the "A" shaft. Because of the limited power sup-ply from the two 7,000-hp. hydroelectric plants, and the ? 3,600 hp. predicted for the combined hoisting requirements of the three production shafts, it was considered desirable to lessen the impact of this type of load on the relatively small power system by equipping all future hoisting arrangements with Ward Leonard direct-current drives. The manually operated 8-by 4-ft. hoist at the "A" shaft had a rope speed of 1000 f.p.m., and was driven by a 385-hp., 380-r.p.m. wound rotor motor with liquid rheostat control. This A.C. drive was replaced by a semi-automatic Ward Leonard direct-current drive with a 515-hp., 566-r.p.m., shunt wound motor, providing a rope speed of 1,500 f.p.m. During several months preceding the con-version, all possible preparations were carried out to keep the changeover period to a minimum, and this resulted in a total shutdown time of twelve days. The capability of the "A" Shaft hoist was increased from 109 tons per hour to 134 tons per hour, and both mechanical and electrical maintenance were reduced considerably. The total cost of the conversion amounted to $130,000. The hoistmen who had been required for the manual A.C. drive were transferred to the new Farley shaft, and the reduction in operating labour costs of the "A" Shaft hoist

Jan 1, 1965

By Eugene Barsky

"At present, theoretical concepts of gravitational separation processes are mainly limited by the study of the interaction between a flow and a solitary particle. Then the main conclusions of this analysis are applied to a mass process. However, this analysis is absolutely insufficient, because some elementary phenomena such as the ingress of coarse particles into the fine product output and vice versa cannot be interpreted from its standpoint. It is also impossible to predict the results of the classification of a material with a specific granulometric composition on a specific apparatus on its basis.In the present paper, an extended model of the process is suggested. The model is based on the behavior of all the particles of a specific narrow size class, and not on that of an individual particle. Similarity criteria of the process, which were empirically derived previously, are obtained from the analysis of this model.INTRODUCTIONIn case of gravitational separation, a part of solid phase moves, as a rule, vertically upwards with the flow, while another part settles against the flow. This flow is extremely complicated and chaotic due to various random factors. Among these factors are mass interactions of particles with each other and with the apparatus walls, non-uniform character of concentration and velocity fields, turbulent vortices and local fluctuations, real particles shape difference from spherical one, etc.Particles rotation results in a transverse force (Magnus' effect). At the motion of a non-rotating particle in a non-uniform velocity field, a transverse force also arises (Saffman's effect).A great number of publications have been devoted to the account for all these factors in two-phase flows in recent decades. Very complicated models have been developed, but the problem has not been completely solved as yet [1, 3].At the same time, simplified models of the behavior of a solitary particle in a flow are being developed. Despite their schematic nature, such models often prove to be useful for establishing general laws of the process and its similarity criteria [1]."

Jan 1, 2016

By Qing-hua Tian, Li-then Cheng, Xue-yi Guo

In order to recycle valuable metals from silver separated residue, a novel method using alkaline smelting at low temperature was proposed. The main factors affecting the main metal recovery such as the smelting temperature, smelting time, liquid-to-solid ratio and alkali addition were investigated comprehensively. The behavior of the main metal elements, such as Pb, Sn, Sb and Bi in silver separated residue was also discussed. The results indicated that amphoteric metals such as Pb and Sn can be smelted into the melt, while other metal elements, such as Sb and Bi were left in the residue.

Jan 1, 2011

By C. Carrasco

Caletones Smelter, Division El Teniente of Codelco Chile, has used Teniente Converter (TC) as the only smelting unit since November 2000. The modernization project considered the shutdown of the last reverberatory furnace, the installation of the fourth Teniente Slag Cleaning Furnace, the installation of a new fluidized bed dryer and the modification of the concentrate injection system into TC. The modernization project and related investments allowed for the increase of the smelting capacity up to 1.25 million t of concentrate annually.Next stage of the smelter expansion in the year 2004 considered the increase of the smelting capacity up to 1.44 million t/year. The expansion required technology modernization and the installation of the new equipment, such as concentrate injection system, oxygen plant, fluidized bed dryer and storage bin. Currently the annual smelting capacity is about 1.35 million t of copper concentrate, being limited by sulphuric acid plant treatment capacity. This paper presents the technology and production evolution in the Caletones Smelter in the years 2000 - 2006, demonstrating the potential of development and competitiveness of Teniente Converter as world-wide recognized smelting/converting reactor.

Jan 1, 2007

By Forrest A. Kerr

Introduction During recent years the work of the Geological Survey in northwestern British Columbia has been in the nature of reconnaissance and exploratory mapping, largely for the purpose of gaining knowledge of the potential mineral-producing zones known to occur along the eastern side of the Coast range, and also to gather such data as might facilitate their exploitation. Commencing with fairly detailed mapping in the more accessible parts, the work has been continued and expanded until now an understanding has been gained of the more general features of a continuous section along the range for a distance of about two hundred miles. Geographically, northern British Columbia is more or less isolated. It is cut off from the central part of the Province by a rugged and mountainous country which, except for the telegraph line and a rarely travelled trail along it, is not penetrated by any developed routes or lines of communication. To the west, it is cut off from the Pacific by the Coast range, an extremely rugged area sixty to eighty miles in width which, except along the few navigable rivers cutting across it, cannot be readily traversed. Politically, it is further isolated in this direction by the narrow strip of south-eastern Alaska which borders the coast and extends inland to the axis of the range.

Jan 1, 1931

By C. A. Pickles

Microwaves are being applied industrially in a number of fields and possess a number of potential advantages that could be applied in extractive metallurgy. Microwave heating has a number of unique characteristics, which distinguish it from the conventional heating methods. In microwave heating, the absorption of energy occurs at the molecular or atomic level and therefore the heat is generated within the material itself. In conventional heating, the exterior temperature is usually higher than the interior, but with microwave heating, the temperature gradient is inverted and thus the interior temperature can be much higher than that of the surface. The energy densities in microwave systems can be relatively high and this in combination with the low thermal conductivities of oxide ores, can lead to very high internal heating rates. In this research, the application of microwave energy for the reduction of a nickeliferous silicate laterite ore has been investigated. The real and imaginary permittivities are the two fundamental properties which determine the microwave absorption characteristics of a material and these were measured for the ore, both with and without carbon additions using the cavity perturbation technique. The microwave heating and reduction experiments were performed in a 0 to 2 kW CTC microwave system. The effects of power input, processing time, sample mass and charcoal additions on the microwave absorption were investigated. Then reduction experiments were performed and the nickel grade of the magnetic concentrate and the nickel recovery in the concentrate were determined.

Jan 1, 2005

Agenda ?Introduction ?Geology ?Mining ?Metallurgy ?Process, Layout ?Environmental Background ?Kinross Gold Corporation owns the Lobo-Marte gold property, located in Region III of northern Chile. ?The property is close to two other Kinross mines, Maricunga 50kmto the south and La Coipa 60km to the north, plus a regional office in Copiapo and district level operating synergies are expected. ?Lobo and Marte were discovered in the early 1980s and are intrusion-hosted, porphyry-type precious metal deposits, typical of the Maricunga District. ?The Marte open pit heap leach mine was in commercial production in late 1988, but was suspended in February 1992 as it did not meet forecasted production levels and recoveries. ?Kinross plans to recover ore from the Lobo and Marte deposits through an open-pit, heap leach47,000tonne per day operation.

May 1, 2010

By D. R. Keck

"SINCE the .Canadian Chemical Company has no direct connection with mining operations, and I have had no experience with mining, there is little I can tell you that you do not already know. However, we have had considerable experience with certain types of metallurgical problems and I would like to discuss with you some of these problems and their solutions by our metallurgists.In order to acquaint you with the type of plant and processes to be employed at Edmonton, I would like first to take a few .minutes to trace briefly the history -of the Canadian Chemical Company's affiliate, The Celanese Corporation of America. In the early •part of the twentieth century, two young Swiss brothers, Camille and Henri Dreyfus, received their P.h.D. degrees in chemistry. They were extremely interested in work which was being carried on at that time to find a suitable synthetic fiber that could compete with natural fibers, both quality and price-wise. Early man-made fibers were both coarse and hard to dye. The Doctors Dreyfus• poured all their earnings into research and ultimately developed cellulose acetate filament. During World War I, the Dreyfus brothers were invited to the United States to produce cellulose acetate 'dope' for airplane wing coverings. Dr. Camille Dreyfus built the first American plant for fiber production at Cumberland, Maryland, in 1924.Due to resistance of textile mills to the new fibers, Celanese was forced to set up its own dying, weaving, and finishing mills to prove the new materials. Through the years, however, this operation has •been retained primarily for fabric development purposes,.. with the majority of the acetate being sold to other textile mills."

Jan 1, 1953

By G. A. Moruzi

Two sulphide dust secondacy explosions have occurred in the mines of the SUdbury operations of Falconbridge Ltd. during the past 18 months. 'Ihe main similarity between the occurrences is that they both happened in vertical crater retreat blasthole stopes. A relatively high p:,v.tier factor was noted in both instances. other details are enumerated and examined, as well as some results of tests done by Noranda Research on company ore samples.

May 11, 1988

By L. M. Wang, G. P. Jiang, Y. Jiang, Liao. W. S.

ABSTRACT The authors measured porosities and permeabilities for cores from a low-permeability sandstone uranium deposit in Inner Mongolia. Features studied included fine pore structure, mineral composition, cation exchange capacity, granule appearance, and cementing features. In general, grading of the grains was relatively poor, which decreased the radii of the pore channels. The pore throat distribution was significantly heterogeneous. Pore channels ranged from small to large, but the lack of large pore channels led to low permeability. Cementation by calcite and clays, including montmorillonite, chlorite, and kaolinite, resulted in pore channel narrowing, further decreasing the permeability of the formation.

Jan 1, 2014

By N. Katsikaros, A. Lewis-Gray, P. Richards

"To optimize gold recovery in complex leach-to-electrowinning processes, Gekko Systems developed the Gekko resin exchange column (G-REX) as an intermediate step, using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin. Operational experience has been gained at the Castlemaine Goldfields Ballarat gold mine. In near-continuous operation since 2008, the Ballarat plant treats unclarified concentrate leach solution. The extension of this technology to higher throughputs and more complex chemistry is discussed.RÉSUMÉ Afin d’optimiser la récupération de l’or dans des procédés complexes impliquant la lixiviation suivie de l’extraction électrolytique, Gekko Systems a développé la colonne Gekko de résines échangeuses d’ions (G-REX) comme étape intermédiaire, à l’aide d’une résine hautement sélective pour la récupération de l’or qui permet d’isoler les métaux contaminants. Gekko détient la licence exclusive pour la résine AuRIX®100 produite par Purolite, et la colonne G-REX a été spécifiquement conçue pour cette résine. C’est à la mine d’or Ballarat de Castlemaine Goldfields que l’expérience opérationnelle a été acquise. L’usine de Ballarat, en exploitation quasi-continue depuis 2008, traite une solution concentrée non clarifiée de lixiviation. L’extension de cette technologie à des capacités supérieures et à une chimie plus complexe est examinée."

Jan 1, 2017

By Riggin P. R.

"IntroductionIndustrial Relations combines two very important relationships - employee relations and union relations.Employee relations always come into play when people are hired to perform tasks. Because mineral processing plants cannot be operated successfully without people, at least not yet, if they ever will be, employee relations must exist in an operatingplant.If the employees choose to be represented by a union, then a relationship with the union as an institution also comes into play. It is very important to note that unionization does not mean that the employee relationship is replaced by a relationship with the union. The latter is superimposed on the former, but it does not replace it. Similarities and overlaps in the two relationships will be present, some of which are of fundamental importance. Nevertheless, they are two different relationships and the reader should bear this in mind when reviewing those parts of this chapter which discuss unionization, collective bargaining, collective agreements, and work stoppages.These two important relationships, which we have chosen to combine and call industrial relations, have crucial roles to play in the social system which interrelates people performing the necessary tasks involved in the operation and maintenance of a plant. The technological organization - equipment, process layout and so forth - and this social system are interdependent and complementary. This chapter attempts to show that the potential level of effectiveness of both the technological organization and the social system depends on the recognition and nurturing of this nexus between them.Occupational health and safety and training are subjects for another chapter. But, both of these have been critical and longstanding employee relations topics . They are destined to take on added importance in the future. As issues in collective bargaining, they are also attracting increasing attention in all union relations. It is hoped that the reader will not isolate from industrial relations those topics which are being dealt with in another chapter. They are very much a part of it and we cannot refrain from making some reference to them."

Jan 1, 1989

By S. M. Grillo, Fiori. M., R. Bornioli, C. Marini, S. Fadda

Abstract - The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temper- ature, the composition of the albitizing fluids was modified by an influx of meteoric or other waters.

Jan 1, 1996

By S. M. Grillo, M. Fiori, R. Bornioli, C. Marini, S. Fadda

The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temperature, the composition of the albitizing fuids was modified by an influx of meteoric or other waters. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum.

Jan 1, 1997

By R. W. Thompkins

MINE operators are concerned with temperature conditions in their mines, particularly the effects of high temperatures on the l1ealth and efficiency of tl1eir employees. This paper is written to focus attention on the variables of heat transfer between rock and air. It illustrates the difficulties of predicting the manner, and the extent, of heat transfer from theoretical concepts, prior to actual operation of a mine airway. There are ~1any sources of heat in mines. The most important is that of the rock surrounding the airway. This heat, in turn, is a product of the age of the rock, faulting, proximity to recent igneous activity, oxidation of sulphides, hot ground waters, etc. The sources of heat may be constant for any one mine, but they are far from constant when dealing with various mining districts or e1•en with a number of mines in the same district. A second source of heat is that produced by machinery in operation. Practically all the waste

Jan 1, 1962

By Ben D. Thompson

Cemented Paste Backfill has proven to be of critical importance to the operation of a number of Canadian mines, primarily due to the rapid backfilling rate this method permits. In order to improve the efficiency of this backfill system (i.e. optimize binder contents, fill fence design, and the employment of two stage filling strategies) there is a requirement to better understand its geomechanical behaviour. In response, in-situ experiments have been conducted in long-hole stopes to quantify the evolution of total earth pressures and pore pressures at a series of instrumented points within both the core of the backfill and close to fill fences. The deflection of fill fences as a result of paste loading has been measured and additional instrumentation has also been employed to measure cement hydration, negative pore pressures, and blasting induced vibrations within fresh and cured paste backfill. Installing geotechnical instrumentation within an open long-hole stope can be an extremely complex procedure and this paper details the methods that have been successfully employed. Preliminary results are presented, and the pressures induced by backfill with differing binder contents, at a number of different in-stope locations are considered.

May 1, 2009

By G. Bylapudi, K. Mondal, J. Hirschi

ABSTRACT: Rock bolts are the main form of defence against rock falls in mines. Conditions under-ground are conducive to corrosion. A perception exists about American coal mines that bolt corrosion is not an issue, especially when bolts are fully grouted. This perception is not necessarily accurate due to the formation of micro-cracks as the resin sets and to subsequent rock movement that breaks the resin column’s continuity. Corrosion should be considered when designing rock bolt support in long-term excavations. This paper explores the problem of corrosion, outlines a method to determine the corrosion potential of bolts, and suggests ways to mitigate such effects.

Jan 1, 2010