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By Donald J. Olson, Thomas J. Lutzenberger, John Ramage

The North Shore Inline Interceptor, Phase IA tunnel is a 8,550-meter (28,000-ft) interceptor tunnel currently being constructed by Traylor Bros./Frontier-Kemper, Joint Venture, using a 9.8-meter (32-ft - 4-in) diameter Robbins tunnel boring machine (TBM). This tunnel is being driven in Silurian age dolomite approximately 91.5 m (300 ft) below ground surface. Significant water inflows were encountered when the tunnel drive penetrated the thinly-bedded Waubakee Formation. Flow increases approaching 0.75 cu m per min per 30 m of tunnel (200 gpm per 100 ft) have occurred in this formation. After driving approximately 2,285 m (7,500 ft) of tunnel (200 m full face in the Waubakee Formation), total flows exceeded 12 cu m per min (3,200 gpm) with about 5.7 cu m per min (1,500 gpm) entering the tun¬nel from the 200 m (600 ft) of exposed Waubakee Formation. Additional water control measures consisting of increased pumping capacity, increased water treatment capacity, surface grouting ahead of the tunnel, grouting ahead of the tunnel face and panning to improve the working environment for installation of tunnel support, were implemented to deal with the large water inflows. Currently (January 24, 1989), 3,400 m (11,000 ft) of tunnel has been driven, total water inflows are in the range of 11.7 cu m per min (3,100 gpm) with only 6.8 cu m per min (1,800 gpm) inflow from about 1,220 m (4,000 ft) of tunnel driven full face through the Waubakee Formation.

Jan 1, 1989

By E. Poeck, R. Garvey, U. Ozbay, K. Zhang

"A coal bump is characterized by the sudden failure of one or more pillars and an associated release of kinetic energy. Although the geologic conditions surrounding coal bumps are often similar, their occurrence and magnitude are difficult to predict. This paper presents the development of an approach to assess the potential for coal bumps in room and pillar mines through the use of energy concepts and special consideration of the interface properties between the coal and overlying rock. Back analyses were performed on the widespread collapse of a room and pillar mine with an associated 3.9 local magnitude seismic event. Pillar and mine-scale models were constructed using the distinct element method to simulate the mining stages leading up to the collapse. A variety of loading conditions, material properties, and interface properties were evaluated for their effect on unstable failure of single pillars, and the mine-scale model was used to study the evolution of failure during progressive mining. The extent of unstable failure was quantified in these models by calculating the total kinetic energy released during each mining stage. Through the parametric analysis of single pillar models, it was found that softening parameters in either the coal or the coal/rock interface can individually facilitate unstable failure of pillars, but the combination of the two in a single model produced a much higher release of energy during failure. The results of the mine-scale model further illustrated the trend as the combination of softening parameters in the coal and coal/rock interface produced a series of failures which most accurately reflected the collapse event at the mine. The method of room and pillar stability analysis demonstrated in this study effectively explores the potential for large coal bumps. INTRODUCTION The analysis of coal pillar behavior is challenging because natural variability in geologic conditions requires estimation of material strengths and predicted loads for a given mining situation. Large width-to-height (w/h) ratio pillars and deep overburden present an additional challenge, as the failure behavior of such pillars is more complex and may involve unstable, sudden collapse. Empirical methods have improved the success of coal pillar design for a wide range of conditions, but for deep cover and squat pillar geometries, less accuracy has been achieved in predicting pillar performance (Mark 2000). As with any empirical approach, more back analysis and the consideration of new variables may help improve understanding and accuracy of future designs. This paper presents a study of pillar stability through the back analysis of the Crandall Canyon Mine collapse, which occurred in August of 2007. Pillar-scale models are utilized for the calibration of material properties and assessment of potential instability under varying conditions, and mine-scale models are constructed in an attempt to reproduce widespread failure and correlate with observations at the mine. Special consideration is given to the properties of the coal and the coal/rock interface, and kinetic energy is calculated throughout the course of the simulations to gauge the level of instability when pillar failure occurs. Models were constructed using the Universal Distinct Element Code (UDEC) (Itasca, 2014)."

Jan 1, 2016

By Remo Grandori

"INTRODUCTIONDouble Shield TBMs were introduced in the market in the early seventies with three main targets:• Increase the TBM performances in term of advance per day thanks to the ability to erect a segmental lining simultaneously with the excavation phase.• Be able to advance through unstable and disturbed rocks under the protection of the shields• Provide a finished tunnel by installing a precast lining as the TBM advance.In 2003 SELI developed the design of the Double Shield Universal (DSU) TBM as an evolution of the original Double Shield TBM design.This new TBM design was targeted to improve: the TBM capability to advance through squeezing/converging rock formations under high cover, the telescopic joint design (allowing by such to operate the machine in double shield mode in very weak rock), the capability of the TBM to investigate and treat the ground around and ahead of the tunnel face.In the same lapse of time Single Shield TBMs, originally utilized for soft ground tunnelling, extended progressively their range of application to mix rocks and finally to hard rock tunnelling with increasing performances.This also thanks to the substantial reduction in the installation time of the segmental lining ring that contributed to minimize the TBM stand by time between two consecutive boring strokes.Today the choice between the two types of TBMs needs to be carefully evaluated project by project since one type of TBM may “prevail” in certain geologies and diameters and vice versa.THE VISHNUGAD PIPALKOTI TUNNELThe Vishnugad Pipalkoti Tunnel is part of the 444 MW Vishnugad Pipalkoti Hydro Electric Project (VPHEP) on Alaknanda river in Uttarakhand (India).The Owner is the Indian electric company “Tehry Hydro Development Corporation” (THDC) and the World Bank finances the project.The Headrace Tunnel total length is 13.4 Km and a section of about 12,3km will be excavated by TBM by SELI Overseas (Italy) in subcontract to HCC (India) the General Contractor for the project. The TBM will be delivered ex workshop in March 2016 and it is foreseen to start boring in the second half of 2016.Figure 1 below shows the location of the project and the following Table 1 summarizes the geometrical characteristics of the TBM tunnel."

Jan 1, 2016

By D. H. White

The term "block caving" as used in this text includes panel caving and mass caving as described by Julin and Tobie (1973). This method reportedly was conceived in 1895 when a block of ore ranging up to 200 ft (61 m) in width was undercut at the Pewabic Mine on the Menominee Range in Michigan (Bucky, 1956). Over the years this method has evolved largely as a consequence of trial and error in which operators became acutely aware of what nature would allow and what it would not. Today block caving remains somewhat of an art rather than a science where experience often dictates what needs to be done. With the plunging prices of base and specialty metals in the early 1980s caving mines sought to reduce operating and development costs in order to return to profitability. For some this became an impossible task given the design, grade and operating costs of the day and closure became the only alternative. One lesson learned from the experiences of the 80s is that survivability depends on cost competitiveness and this implies the efficient use of resources and technology. To this end applied rock mechanics serves as a useful tool. The purpose of this paper is to show how Geomechanics can be used? in block caving to facilitate sound decision making and how this equates to dollars saved. Features of mining method selection, design and operation are discussed as related to this theme.

Jan 1, 1990

By William Gleason

"What will the mine of the future look like? Will it resemble the current operations that supply the world with the products it needs to function, or will it be something totally different? How will the demands from the communities that are most affected by mining operations shape the mine of the future? How will technology and innovation be used to help miners reach deposits that are getting harder to access, and what are the dangers of this new world? Who will work at the mine of the future, and what will that work look like?These are questions that do not yet have definitive answers, but they are questions that need to be asked for the mining industry to move into a future that is as filled with uncertainty and challenge as it is with promise and opportunity.On Feb. 16, the 2015 SME Annual Conference and Expo and the 117th CMA National Western Mining Association conference began with a keynote address, "The mine of the future: Forecasting opportunities and challenges for the global mining industry." Panelists from five sectors of the mining industry participated in the session, which was followed by the conference and expo, that in large part, were also trying to answer the question of what the mine of the future will look like.In coming months, Mining Engineering will continue the discussions and answer some of the questions submitted by members of the 2,000-person audience during the keynote address in a monthly feature called, "Predicting the Mine of the Future," and in Thought Leaders Podcasts with the panelists and other industry experts."

Jan 1, 2014

By M. Gorman

The Mineral Park Mine is an open pit copper-molybdenum mine located in northwestern Arizona, approximately 74 miles southeast of Las Vegas, Nevada. The property has been owned by the Duval Corporation, Cyprus Mining Company and Equatorial Mining of Australia. Mercator purchased Mineral Park from Equatorial in 2003. Mineral Park commissioned a 25,000 tpd copper and molybdenum concentrator in November and December of 2008. The process includes two stage milling (SAG and Two Ball Mills) fed by primary crushed ore. Metals are recovered in a copper-molybdenum flotation circuit consisting of mechanically agitated roughers and cleaners. The copper- molybdenum flotation concentrate is thickened and further processed in the molybdenum flotation circuit which separates the copper and molybdenum minerals into salable concentrates. The molybdenum circuit also uses mechanically agitated cells. This paper describes the plant and some of the highlights of the commissioning process.

Jan 1, 2010

By M. M. Botz, F. W. DeVries

Discussion by F.W. DeVries Comments on natural cyanide attenuation. The paper by Botz and Mudder in the November 2000 issue of Minerals and Metallurgical Processing had one disappointing aspect. Table 1 (p. 229) failed to include a significant species - neutral copper cyanide (CuCN). This compound has been most trouble-some in many plant-scale cyanide cleanup processes, includ- ing acidification-volatilization- reneutralization (AVR), hy- drogen peroxide cleanup and air/SO2 cleanup. It has also plagued many pilot efforts to use ion-exchange (IX) resin technology. This author elucidated the concept that, under some conditions, copper cyanide failed to precipitate out of treated effluents and appeared to exist as a filterable colloid that reported as copper and cyanide, with the latter measured as WAD (weak-acid-dissociable) cyanide in that analytical method. The concentrations measured were very near the levels of 0.2 ppm, often the regulatory limit for WAD cyanide. The copper concentration, using the 1 : 1 ratio for this com- pound, would then be more than 0.4 ppm, which could also be unacceptable. We discovered that it was unsafe to assume that the Cu(CN),- would surrender both cyanide ions simultaneously and allow cupric copper to be removed subsequently as, say, cupric ferrocyanide (Hatchett's Brown). This compound could be ignored as safely as the "iron blues," as essentially an inert solid, stable in geologic time if not exposed to sunlight. Under poorly controlled oxidation of the cyanocuprite ions (copper with four, three or two cyanides complexed to the copper), CuCN could well be formed and could not be assumed to precipitate out as a solid. The authors of the paper, by failing to include the CuCN species in their model, may have left users of the model prone to ignore the possible occurrence of the colloidal(?) form in the discharge, thus finding an effluent that failed to meet regulatory limits. (See addendum below.) This somewhat ephemeral material may well have been responsible for some large-scale failures of cyanide destruction technology to succeed at sites in North America and elsewhere. Two specific references alluding to this occurrence may be found: Griffiths et al., 1987, "The detoxification of gold-mill tailings with hydrogen peroxide," Journal of the South African Institute of Mining and Metallurgy, September, p. 282. DeVries, 1989, "Improved understanding in detoxification of cyanide leach liquors using peroxide" Rand01 Gold Conference, Sacramento CA, p. 15 1. It is advisable for workers in this area of cyanide removal or recycle to avoid assuming that CuCN will, with certainty, precipitate out of solution, or that the dicyanocuprite ion will part simultaneously with both cyanide ions and allow cupric copper to be dealt with by other reactions. One further piece of work may be incomplete. That is, a definitive study of the long-term behavior of CuCN that does precipitate when exposed to other compounds present in neutralized tailings. Addendum. The extremely complex reaction of cupric ion on cyanide- which, of course, results in oxidation of cyanide to cyanate, probably through the intermediate stage of forming cyanogen [(CN)2] from oxidation of HCN with its hydrolysis to cyanate and cyanide ion - involves two cyanide moieties and the reduction of the cupric ion back again to the cuprous state. This, then, can form the CuCN potential "solid" that was already the undesirable species. In cyanide cleanup, with either air/SO2 or hydrogen peroxide, copper is generally employed as the catalyst, so it is unclear what happens when the CU(CN)2-1 is ultimately exhausted. Certainly, the field evidence is quite clear that all

Jan 1, 2002

By D. Carr, C. Anderson, M. Deal, C. Larson

"Construction of the OceanaGold Haile operation’s process plant in Kershaw, South Carolina is currently under way, with ore through the mill expected in late 2016 and commercial production expected in early 2017. The process is designed to treat 6,350 tonnes per day with minor upgrades required to achieve 8,270 tonnes per day. Plant optimization during detailed engineering, combined with a focus on de-risking the process, has resulted in numerous process changes since the initial design. This paper describes the plant optimization and de-risking, it also presents a proven commissioning strategy modelled after OceanaGold’s Didipio operation, whilst identifying potential expansion opportunities. INTRODUCTION Haile Gold Mine is located in Kershaw, South Carolina, approximately 50 miles south of Charlotte, North Carolina. Gold was first discovered at the site in 1827, and the property has been through several operating periods since. The last operation employed heap leaching from 1985 through 1992. Since then, the property has been closed and fully reclaimed. Romarco Minerals acquired the property in 2007, and began an exploration program that delineated 2.02Moz. of gold in reserve at an overall grade of 2.06 g/t. OceanaGold acquired Romarco Minerals and the Haile Operation in October of 2015. OceanaGold operates under a risk management philosophy in all aspects of operation, both corporately and at each individual business unit, and has implemented numerous process changes to eliminate or mitigate risks identified in the initial design of the processing circuit, and provided increased opportunity for optimization and expansion. This paper describes the plant optimization and de-risking, it also presents a proven commissioning strategy modelled after OceanaGold’s Didipio Operation, and identifies potential expansion opportunities. INITIAL PROCESSING CIRCUIT DESIGN An extensive metallurgical test work program was undertaken by Romarco Minerals and third party laboratories during the initial design phase of the Haile project [1]. This preliminary test work provided the technical information as a basis of plant design. The initial flow sheet for the Haile processing circuit is shown in Figure 1 (see APPENDIX). The plant is designed to process 6,350 tpd (7,000 stpd) on an annualized basis. The process begins with a jaw crusher followed by a SAG and ball mill grinding circuit to reduce particle size to P80 74 µm. A flash flotation cell treats 50% of the cyclone underflow in the ball mill circuit. Grinding circuit product is sent to a rougher flotation circuit to recover gold-bearing pyrite. The flotation concentrates from flash and rougher flotation are reground to P80 13 µm using stirred media detritors (SMD’s). The rougher flotation tail is pumped to the carbon-in-leach (CIL) circuit for gold recovery. The reground concentrate is pre-aerated prior to being pumped to the CIL circuit. The CIL circuit is a hybrid circuit with eight tanks. Tank 1 leaches the pre-aerated concentrate only, and tanks 2 through 8 leach the combined flotation tailing and tank 1 discharge. The carbon strip circuit is a standard pressure Zadra system, followed by electrowinning, and refining using an induction furnace. CIL tailing passes through a cyanide recovery thickener prior cyanide destruction and then pumped to the tailing storage facility (TSF)."

Jan 1, 2017

By D. C. Torre

Since the early 1960s, there have been efforts to develop and produce reliable continuous haulage systems capable of taking the full output of a continuous miner and transporting it, in one continuous flow, from the face to the tipple. The majority of the successful continuous haulage systems were placed in operation in the early 1970s. These were all of the bridge conveyor type. They usually consisted of bridges and mobile bridge carriers (MBC) attached at the inby end to the continuous miner and at the outby end to the panel conveyor itself. These successful bridge conveyor continuous haulage systems are either of the belted or chain type. The most successful belt type continuous haulage systems are those manufactured and marketed by the Long-Airdox Co. Until early 1977, Jeffrey Mining Machinery Division manufactured and marketed the most successful chain conveyor type haulage sys¬tems. In 1977, Long-Airdox reentered the market with a chain-type system to complement its belted system. The original bridge-type continuous haulage system was introduced to the coal mining industry in the early 1960s by the old Long Co., a predecessor to the current Long-Airdox Co. These original units were of the chain conveyor type. In the early 1970s, there were also developments in continuous haulage, employing different material handling media. These in¬cluded the Serpentix, a flexible type belt, introduced by the Joy Manufacturing Co. There was also a serious attempt to introduce hydraulic-type continuous haulage by Consolidation Coal Co. and Conoco Research. Despite some startling successes, particularly with the bridge-type haulage systems, the general and widespread application of continuous haulage has eluded the mining industry. Some of the problems are related to underground conditions; others to people, both management and labor. One of the greatest obstacles to universal success continues to be the difficulty of accepting the philosophy as well as the machinery of continuous haulage. Nevertheless, efforts continue to spread the success of commercial and viable systems in the industry. There is also effort to improve on these systems, and on methods for their successful use. In addition, efforts continue, with private and public support, to develop new types of continuous haulage equipment and systems. Bridge Type System Developments Because they have already been successful in some US and overseas mines, new developments in bridge-type systems will first be touched on. The Long-Airdox Co. has continued to improve both its belted and chain continuous haulage system. In the belted system, the company recently introduced a new design that will be mainly applicable in higher coals and in noncoal mining applications, as shown in the accompanying figure. This new system is equipped with 305-mm-diam (12-in.-diam) pulleys in the bridges and mobile bridge carriers, in place of the 150-mm-diam (6 in.-diam) pulleys in the standard system. The modification is designed primarily to improve belt life and keep belt problems to a minimum. An operator, the Clinchfield Coal Co., a Division of Pittston Coal, developed the detaching of the bridge-type continuous haulage system from the miner by placing a mobile bridge carrier at the head of the string. However, Long-Airdox and Jeffrey have now made this an option to their at¬tached-type system. In the US, there are many chain type haulage systems detached from the miner with an extra MBC at the head. There are two such belted systems

Jan 7, 1982

By R. Haecker, S. Gupta, P. Somasundaran

Rock disintegration processes are usually inefficient and costly operations in mineral beneficiation, mine development and oil well preparations. Thus, there is a strong need for improving the energy efficiency of unit operations such as drilling and comminution. The effects of selected cations and anions on drilling efficiency in a hard rock formation (Dakota Sandstone) were studied. The zeta potentials and the tensile strengths of the drilled samples were measured under similar chemical conditions. The chemicals tested included MgCl2, Na2CO3, AlCl3, NaCl and Dodecylammonium chloride. The results indicated that drilling rates can be enhanced or retarded depending on chemical conditions such as the solution pH and the type and concentration of reagents. Drilling data are correlated with mechanical (tensile strength) and interfacial (zeta potential) properties of the rock formation. The mechanisms involved are discussed in light of Rehbinder's and Westwood's theories.

Jan 1, 2000

By M. Li, J. K. Thompson, A. S. Azman

"Powerful mining systems typically generate high-level noise that can damage the hearing ability of miners. Engineering noise controls are the most desirable and effective control for overexposure to noise. However, the effects of these noise controls on the actual hearing status of workers are not easily measured. A tool that can provide guidance in assigning workers to jobs based on the noise levels to which they will be exposed is highly desirable. Therefore, the Office of Mine Safety and Health Research (OMSHR) of the National Institute for Occupational Safety and Health (NIOSH) developed a useful tool to estimate the hearing loss due to occupational noise exposure in a systematic way and evaluate the effectiveness of developed engineering controls. This computer program is based on the ISO 1999 standard and can be used to estimate the loss of hearing ability caused by occupational noise exposures. In this paper, the functionalities of this software are discussed and several case studies related to mining machinery are presented to demonstrate the functionalities of this software. INTRODUCTIONPeople regularly exposed to noise can develop hearing loss at different levels of severity depending on a number of factors. The resultant hearing loss can affect one’s ability to understand speech, learning, acoustic signal perception, or appreciation of music. Hearing loss caused by overexposure to noise has long been recognized in literature. However, it still does not get serious attention by those working in noisy environments because the loss of hearing ability is a gradual process and workers are often unaware until the damage becomes an apparent problem. In the United States, occupational hearing loss is one of the most common work-related illnesses. Depending on the definition of exposure and impairment, in 2012 the National Institute for Occupational Safety and Health (NIOSH) estimated that there are between 5 and 30 million workers in the U.S. who are exposed to noise levels at work that put them at risk of hearing loss.4 In the mining industry, noise-induced hearing loss (NIHL) is particularly severe due to the fact that heavy-duty machinery is widely used to improve production efficiency, and this machinery can generate much higher-level noise than the permissible level defined by regulation. As a result, the mining sector has the highest prevalence of hazardous workplace with high noise exposures (76%) among all industrial sectors."

Jan 1, 2015

By K. N. Han, H. C. Cho, R. Kim

"A comprehensive analysis of the effect of OH- on various cations in hydrometallurgical systems has been investigated. Cations chosen for this analysis included groups 1A and 2A, rare-earth elements and other common transition metal ions such as Cu2+, Fe2+, Fe3+, Mn2+, Ni2+, Co2+, Ag+, Cd2+, U4+, UO2 2+, Hg2+, Al3+ and Zn2+. The Newton-Raphson technique was used to calculate and plot various metal species over a wide range of pH. This study has clearly shown that by adjusting the concentration of OH-, the separation of Fe from Mn, U from V, Ce and Eu from other rare-earth elements, and In from Sn is possible. The effects of hydrated metal ions on the separation and removal of various metals from each other under various conditions is discussed.IntroductionThe primary purpose of hydrometallurgical processing is to extract, remove and purify various metals from diverse sources. Hydrometallurgists are frequently preoccupied by the extraction of cations in metallic form, but overlook the important role anions play in such processes. A proper choice of anions can determine the fate of successful extraction, removal and purification of metals (Esmaeili et al., 2005; Brbooti et al., 2011; Wei et al., 2005; Jeppesen et al., 2005; Al-Tarazi et al., 2004), and also separation (Farha et al., 2011; Sevenich and Fritz, 1983; Rashid, 1974) of cations from various solutions.In this study, the authors have examined some of the effects that anions play in various solutions. The anion considered in this study was the first hydroxide, OH-. Other anions, such as Cl-, Br-, I-, and CN-, will be dealt with in the second part of the series of two papers."

Jan 1, 2015

By C. B. Manula

This paper presents the results of an application of the PSU/USBM Open Pit Materials Handling Simulator (1) to a large stripping mine in the Southwestern Coalfield. The specific objective of the study was to demonstrate the application of the simulator to a complex multi-pit operation, with emphasis on simulating short term and long term production plans recommended for the mine by Theodore Barry Associates (2). Mine Description The mine is located in the Southwestern Coalfield, which encompasses parts of the states of Utah, Arizona and New Mexico. The lease area presently covers 121500 x 103 m2 (30000 acres) in a strip 37.007 x 103 m (23 miles) from north to south and up to 1609 m (1 mile) in width, located at an elevation above 1525 m (5000 ft). Three gently dipping coal seams are present, of which the upper seam (#3) averages 0-5.5 m (0-18 ft); the intermediate seam (#2) averages 0-1.2 m (0-4 ft); and the lower seam (#1) averages 0-2.4 m (0-8 ft). Overburden is mixed sand, gravel, calcareous clay, caliche and sandstone, with calcareous shale and sandstone burden between seams. Where the seams are covered by less than 6.1 m (20 ft) of overburden, they are generally weathered and oxidized and are not extracted. Stripping ratios have ranged from 3.5 to 6.0 with an average of 5.4. All future plans were based on a stripping ratio of 5.3.

Jan 1, 1979

By J. W. Leonard

By using physical and chemical method to increase the bulk density of newly mined coal, the productivity of a mine can be significantly increased. Greater amounts of coal can be placed in fixed volume shuttle car by increasing bulk density. This can increase mine productivity by about 15%. Small, easy to achieve changes in mining operations are required to obtain the increased productivity. This article deals with chemical methods used to increase coal bulk density, the results and discussion are based on experiments performed in the laboratory.

Jan 1, 1992

By Basil S. Fee

INTRODUCTION Probably the most important family of chemicals used in mineral processing today is a category of basic commodity chemicals loosely denoted as pH regulators. Typical chemicals which are referred to as pH regulators include lime, magnesium hydroxide, soda ash, caustic soda, ammonia, sulfuric acid, and hydrochloric acid. These chemicals are often used in very significant amounts in almost all of the major mineral processing operations such as flotation, hydrometallurgy, etc. (in dosages up to ten pounds per ton of feed ore treated). While cheaper in cost per unit weight of chemical than more specific chemicals such as collectors, frothers, extractents, etc., the overall cost to the mill operator is generally higher with pH regulators per ton of ore processed than with any other given processing chemical. For example, a rough rule of thumb in sulfide mineral flotation is that the cost of lime is double that of the collector(s) used. The symbol pH is used to designate hydrogen ion concentration. When acids, salts, and bases are dissolved in water, individual molecules are dissociated into their constituent radicals or ions. The strength of an acid or a base increases with the extent of such dissociation or ionization. An alkaline solution is one in which the number of Qydroxyl ions (OH ) exceeds the hydrogen ions (H ). In an acid solution, the hydrogen ions predominate. In either case, both ions are always present as water itself ionizes to a limited extent, that is: [ ] The pH scale is logarithmic and the pH value is the negative of the logarithm (base 10) of the molar concentration of hydrogen ions per liter of solution. For example, a pH of 5 means that the molar concentration of hydrogen ions per liter is 0.00001 (1 x 10-5). Likewise, a pH of 9 means that the molar concentration of hydrogen ions per liter is 1 x 10-9. Normally, the relationship between hydrogen ion and hydroxyl ion concentration is based on the relationship: Concentration of H ion x concentration of OH- ion = constant. Eq. (1) In dilute and/or moderately concentrated solutions that are normally used in mineral procygsing processes, the constant at 25°C is 10-14. On the pH scale, the value of pH equal to 7 represents the hydrogen ion concentration of a neutral solution. pH values lower than pH 7 indicate increasing acidity and higher values than 7 indicate alkalinity. Table 1 shows the nature of the pH scale at 25°C. Temperature affects the extent of ionization of dissolved acids, salts, bases, and water so that the hydrogen ion concentration (hence pH) of a solution is also affected by temperature. As a means of demonstrating this dependency, Table 2 shows the change of the exponent of the constant (base 10) in Eq. 1 and the pH value corresponding to neutrality as a function of temperature. It is also important, for example, that alkalinity or acidity expressed by pH not be confused with total alkalinity or total acidity. For example, total alkalinity is commonly determined by titration with a standard acid solution (usually HC1). pH is a measure of the hydroxyl ion concentration of an alkaline solution, whereas titration is a measure of an alkaline solution's acid neutralizing capacity. Thus, if one takes a series of various alkaline solutions prepared using different chemicals but all of exactly the same pH (and temperature) and then subsequently carries out a titration on each solution with a standard acid, it would be observed that the various alkaline solutions would neutralize entirely different amounts of acid. As an example, 0.08 grams of caustic (NaOH) , 6.32 grams of soda ash (Na2CO3), and 8.17 grams of ammonium hydroxide (NH4OH) all have a pH of 11.3 at 25°C. One liter of each of the above solutions neutralizes 0.073, 4.348 and 8.496 grams of HC1, respectively. Therefore, depending on the specific use of any given pH regulator, special tests need to be run by the mill operator to determine factors such as: the specific technical goals to be accomplished by

Jan 1, 1986

By F. M. Doyle, K. Osseo-Asare, E. Peters

With the aid of molecular orbital theory, a discussion is presented of the relationship between the electronic structures of ions and molecules, and the elementary steps involved in homogeneous electron transfer reactions. An electronic theory of the reactivity of oxidants and the mechanism of action of oxidation catalysts is then presented, with emphasis on the oxidative decomposition of metal sulfides. For model oxidants, two molecular reagents: O2 and Cl2, and two ionic reagents: Fe3+ and CU2+ were selected; silver (1) was chosen as the model catalyst. The reactivities of these reagents are rationalized in terms of constraints on orbital overlap, the availability of unoccupied d orbitals, and the rearrangement of electronic configurations.

Jan 1, 1993

By G. Swartz, R. J. Brison, R. A. Wyman, J. P. Vandenhoeck, S. E. Khalafalla

Magnetic fluids are commonly composed of ultrafine submicron particles of magnetite (Fe3O4) dispersed in either a kerosene or a water carrier medium with oleic acid as a protective colloid. The unique property of these fluids is that when the magnetic particles are attracted to a magnet the carrier medium moves along with the particles so that the liquid also appears magnetic. The availability of a fluid whose gross behavior changes sharply in a magnetic field without affecting its rheologic characteristics is becoming critical for many technologic applications. About two gener¬ations ago suspensions of relatively large, micron-sized ferromagnetic particles in oil proved useful in clutches, brakes, and dashpots. These were called magnetic clutch materials, and their viscosities were highly dependent upon the applied magnetic field, in contrast to true mag¬netic fluids which retain their fluidic characteristics under all applied fields and field gradients. While the term "ferrofluid" was used by Rosensweig and Kaiser&apos; to designate a magnetic colloid composed of a dispersed magnetic ferrous material, the more general term, "mag¬netic fluid," is preferred. This is because these fluids may contain ferro- or ferrimagnetic substances, such as cobalt, nickel, gadolinium, dysprosium, or magnetic ferrites in carrier liquids, such as hydrocar¬bons (kerosene), silicones, water, fluorocarbons, etc. Preparation of Magnetic Fluids Magnetic fluids were first prepared by Papell and Faber, at the NASA Lewis Research Center, Cleveland, Ohio, by tumbling ferrite materials for several weeks in a carrier medium (such as kerosene) and a dispersing agent (such as oleic acid) with steel balls. Rosensweig et al.1 compared the stability of their ferrofluids obtained from both metallic iron and the magnetic oxides of iron, Fe3O4 and yFe2O3. They found that, although the saturation magnetization of iron is 3.5 times greater than that of magnetite, its colloidal solutions deterio¬rated much more rapidly. The iron particles were undoubtedly rapidly oxidized to a nonmagnetic state due to the enormous surface area of these colloidal particles. Because the properties of these fluids are highly dependent on particle size and may acquire opposite characteristics by small incre¬ments in that size, more controllable methods of preparation have been developed recently by Khalafalla and Reimers.6 In one method metastabilized pyrophoric wiistite is ground to colloidal size in a kerosene oleic acid mixture, and then it is disproportionated to colloi¬dal magnetite and iron at temperatures just below the eutectoidal temperature of wüstite stability (570°C); thus, t < 570°C 4 FeO t > 570°C Fe + Fe30, (1) Because of its antiferromagnetic characteristics, the precursor wüstite is much easier to grind than magnetite. Another method3 avoids grinding entirely and utilizes a peptiza¬tion technique from ferrous materials in the molecular state of aggrega¬tion. This latter procedure has resulted in preparation of strong fluids at considerable savings in cost.

Jan 1, 1985

"With a longstanding reputation for engineering expertise, Weir Minerals continually develops solutions and technology to better serve the mining industry. Recognizing that throatbush wear rate has a major impact on the overall efficiency of slurry pumps, Weir Minerals has developed superior rotating and axial adjustment technology.In many applications, the pump’s throatbush is the component that has the shortest life compared to the impeller and liners, with considerable variability.Adjusting the gap between the throatbush and the impeller front shroud reduces hydraulic recirculation in the pump. This prevents localized wear on the throatbush, improves hydraulic efficiency and lowers the total ownership cost for the operator. To avoid impacting the plant’s production, these adjustments are often performed while the pump is operating. However, this can have safety implications for individuals working at the front of the pump unit.“Manually adjusting an alloy throatbush on a large pump requires several people and is laborintensive. It requires mechanical tools to adjust the four pusher bolts, one at a time, in order to reduce the gap between the throatbush and impeller. We wanted to find a safer and quicker way to extend the wear life of the pump with regular adjustments, which led us to development of this technology,” said Marcus Lane, global product manager for centrifugal pumps for Weir Minerals.“Our automated throatbush adjustment solutions are available for pumps fitted with either rubber or alloy throatbushes on Warman slurry pumps used in the most arduous applications, and have been designed with our customers’ safety and pump operation in mind. By mechanizing the adjustment procedure, personnel are removed from the line of fire, and the accuracy of axial movement is increased,” said Ron Bourgeois, director of slurry pumping technology group for Weir Minerals."

Mar 1, 2019

By Tony Dunn

FMC Corp. achieved a significant cost reduction at its Green River, WY soda ash operations using a new proprietary solution-mining and processing technology. In phase one of the program, trona ore is dissolved, recovered and processed with the new technology. It is then fed into an existing refining plant, replacing dry mined and calcined trona ore. Phase two produces a final high-purity product. It also increases capacity by 635 kt/a (700,000 stpy). Both phases were completed under budget and ahead of schedule. This $120-million expansion project uses a new process and a new team to derive soda ash in a more cost-effective and environmentally friendly manner. The team successfully introduced solution-mining technology - with a liquid solution injected into previously mined sections of the mine. This shift in techniques signified a new era for soda ash production. The project is an example of teamwork at its best. For it to be successful, FMC had to work within several different areas inside and outside of the company. Engineers, contractors, mechanical operators and technical people were needed who could blend in with FMC&apos;s existing in-house team.

Jan 1, 1999

By K. N. Han, J. J. Kellar, Y. Guan

The adsorption of zinc species onto silica in ammoniacal solutions was studied. The adsorption isotherms indicated that the adsorption of zinc increased with increasing pH. The adsorption density increased as the zinc equilibrium concentration increased up to =3.5x10-4 M. Above this concentration, the adsorption density was independent of the equilibrium concentration, and a maxima adsorption density was reached. Temperature had no significant effect on the adsorption density.

Jan 1, 1995