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By W. R. Lindsay

Considerable attention has of late been given to the blasting of large amounts of ore in one operation, on account of the saving in labour and explosives and consequent low cost per ton, and also on account of the additional safety to employees. The blast here described, at the Hidden Creek mine. at Anyox, B.C., is not necessarily unique either in size or methods employed, but some interesting p10blems were encountered and the solutions of these may be of interest to others engaged in similar work. The ore consisted mainly of old scope-bottoms and sill pillars, although there also were some braces and parts of vertical pillars included. Some of the stope-bottoms were overlain by caved waste, and one of the problems was to break them in such a manner that the maximum amount of ore could be recovered without serious dilution with waste. The ore blocks, designated as the 385 silt and the 7 A-103 blocks, were under preparation for blasting for over a year, as conditions permitted. This work consisted in drilling long machine drill holes, varying in length from 14 to 20 feet. These holes were drilled with the Numa detachable bit, made locally, starting at 2~-inch diameter and bottoming at 2 inches for the longest length. The long hole drilling was used in the thinner sections of the area. For the stronger, thicker portions, powder drifts (3 ft. by 4 ft. in section) were driven for the powder charges. Reference to the plan and sections (Figures 2 co 8 inclusive) show the relative location of these, as well as the long drilling. The amount of explosives used in the powder drift charges averaged 0.25 pounds per ton of estimated burden, varying from 0.2 to 0.3 pounds per ton.

Jan 1, 1934

By G. W. Poling, J. R. Hoffert

"A common practice in preventing gravity-fed tailing pipeline from plugging due to sanding is to add lime at relatively high dosage rates. The lime affects the rheology of the slurry ""vehicle"" which transports the coarser particles in a heterogeneous flow-regime. This paper describes a study of the effect of lime on the critical deposition velocities and friction head losses of Highmont Mining Company's mill tailing. Testwork using an extrusion viscometer was related to the surface chemistry changes brought about by the high lime additions. Lime additions which typically increased the tailing pH from 8.4 to 11.5 reduced the critical deposition velocities from approximately 3.2 to 1.7 m/sec.IntroductionCommon practice, at least in base metal concentrators in British Columbia, is to use high lime additions in tailing slurries when the pipeline becomes partially plugged with sands. Some concentrators, such as the Highmont Mining Co. Ltd. plant, add lime on a continuous basis during low tonnage periods and during startup/shutdown transition s. Although such high lime additions often solve temporary plugging problems, the effect of lime on slurry rheology has not been well understood.Slurry pipelines are designed to transport solids in suspension with a minimum of wear and without particle deposition. These two objectives are in opposition because the velocities required to maintain solid suspension can sometimes cause high head losses in the pipeline, as well as wear problems. Thus, the optimum velocity for a long distance slurry pipeline is in the range that provides just enough turbulence to keep coarse particles in suspension."

Jan 1, 1985

By M. Clotilde Apua, A. F. Mulaba-Bafubiandi

"The efficiency of hydrochloric acid (HCl) leaching of gold from low grade gold-bearing material has been investigated in the presence of sodium hypochlorite (NaOCl) to produce in situ chlorine gas which is an oxidizing agent able to oxidize gold metal to its soluble forms. The effect of concentrations of HCl, NaOCl, and mixtures of HCl + NaOCl was sought. Iron and potassium present in the feed were leached and consumed all the HCl. Gold found as inclusion in pyrite was not exposed to the lixiviant. Therefore, leaching of gold from low grade gold-bearing material in aqueous chlorine solution is not an effective process for now.INTRODUCTIONHydrometallurgy of gold is commonly based on cyanide leaching solution. Due to the environmental concerns related to cyanidation and mercury processes, and inefficiency of cyanide gold leaching to dissolve refractory ores, sustainable alternative lixiviant systems, capable of generating gold (I) and gold (III) complexes must be studied. Amongst non-cyanide gold lixiviants there is the chloride/chlorine system (Hilson and Monhemius, 2006; Senanayake, 2004; Pilsniak and Trochimczuck, 2007; Wang et al., 2007; Reeves et al., 1999; Khodadad et al., 2008).In practice, the most oxidizing agents utilized for the leaching of gold as chloride, are chlorine (Cl2) or hypochlorite (HOCl) which are either generated in situ by suitable reaction or added in solution (Adamson, 1972). The dissolution of gold concentrate using hydrochloric acid, sodium chloride and sodium hypochlorite (Cl-/HOCl system) were studied (Puvada and Murthy, 2006). The effect of NaOCl and NaCl concentrations were also investigated. The leaching was performed under the following conditions; time: 4h, solid–liquid ratio = 1:4, at room temperature. It was found that the increase of the NaOCl concentration from 25 to 75 g/L did not have any meaningful effect on the recovery of gold which was about 30% (experimental conditions; S/L ratio = 1:4, NaCl concentration: 25 g/L, HCl concentration: 0.35 M). It was also found that from 25 g/L to 200 g/L NaCl, the recovery of gold rose from 30% to 40% (experimental conditions; S/L ratio: 1:4, NaOCl concentration: 25 g/L, HCl concentration: 0.35 M)."

Jan 1, 2012

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

By T. Hidayat

The distributions of minor elements between slag/metal and slag/matte in equilibrium with tridymite in the Cu-Fe-O-S-Si-Al-Ca system have been investigated in the range of conditions of interest to the high- temperature copper production, refining, and recycling processes. An improved experimental methodology has been used involving high temperature equilibration in controlled gas atmospheres, rapid quenching, and quantitative microanalysis techniques using Electron Probe X-ray Microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrum (LAICPMS). The effect of oxygen partial pressure on the distributions of minor elements between slag/metal and slag/matte has been accurately measured. The effects of slagging components (Al2O3 and CaO) on the distributions of minor elements between slag/metal have also been experimentally determined. The present study is a part of a larger integrated experimental and thermodynamic modelling research program in the systems relevant to high-temperature copper processing. INTRODUCTION In the high temperature processing of copper, minor elements are distributed between different phases, i.e. liquid slag, liquid matte, and liquid metal. From a processing perspective, it is desired to have the valuable minor elements distribute predominantly in the metal and matte phases rather than in the slag phase, and to have the non-valuable minor elements distribute predominantly in the slag phase rather than in the metal and matte phases. Knowledge of the distributions of minor elements between phases in the smelting, converting, and refining processes is required if the distributions of minor elements between phases in these processes are to be optimized.

Jan 1, 2019

By K. E. Waters, N. Brodusch, R. Gauvin, H. Demers

"Rare earth elements are becoming increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. The characterization of the composition, morphology and volume fraction of the various phases that have valuable rare earths in the ores are needed to find the optimal industrial process to extract the ores containing the rare earths. Rare earth-bearing minerals contain many elements with the M-and L-lines overlap, requiring a high degree of resolution, pushing the boundaries of scanning electron microscopy quantitative analysis. Enhanced microscopy at a high spatial resolution with improved x-ray quantitative analysis enables the accurate determination of the distribution of the desired rare earths in various mineral phases. INTRODUCTIONRare earth elements are becoming increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. From batteries (lanthanum and cerium), to magnets (dysprosium and neodymium) and lighting (yttrium), the rare earth elements are crucial to the advancement of technology, and to energy saving devices (Crow, 2011). The goal of this project is to characterize the composition, morphology and volume fraction of the various phases that have valuable rare earths in the ores in order to estimate the economical VALUES (of the ores and to find the optimal industrial process to extract the ores containing the rare earths. High spatial resolution imaging and x-ray microanalysis are needed to reach this goal. In this work, the results obtained with a cold-field-emission scanning electron microscope (FE-SEM) and a silicon drift detector (SDD) energy dispersive spectrometry (EDS) detector at low accelerating voltage are compared to experimental conditions typically used with electron probe microanalysis (EPMA) instrument.With this improvement, a detailed scientific analysis of the composition of these, and other, ores will become possible with a SEM/EDS system. This will help to better understand how such ores were formed, hence assisting in finding them, and to better understand how to process them in preparation for high end industrial applications, namely through mineral processing."

Jan 1, 2012

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By M. T. Shehata, R. W. Revie, M. Elboujdaini

Environmentally assisted cracks in linepipe steels are initiated either as a result of stresses in combination with environmental effects, as in stress corrosion cracking (SCC), or as a result of trapped hydrogen in the steel, as in hydrogen-induced cracking (HIC). To understand better the mechanism of the crack initiation process, key metallurgical and environmental elements that can affect the cracking phenomena were investigated and are reviewed in this paper. The complexity of both cracking phenomena results from the dependence of SCC and HIC on multiple metallurgical, mechanical, and environmental parameters that may all influence both crack initiation and propagation; e.g., composition, microstructure and non-metallic inclusions in the steel, applied stress, water chemistry in the field, and ionic concentrations in the groundwater near the pipe surface to name a few for SCC. In addition, for HIC phenomena, one can add the concentration of H2S in the fluids transported in the pipe as well as concentration of CO2, pH, etc. In this paper, cracking of linepipe steels is analyzed critically, with particular attention to the crack initiation process. The paper is divided into two parts: The first part covers SCC and the second covers HIC.

Jan 1, 2005

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012

By J. P. Harrison, M. Grenon

"This paper summarizes the results of numerical studies on drift stability in moderately jointed rock masses. It investigates the relative pertinence of geomechanical factors such as joint orientation, spacing and stress regime. This is undertaken using a distinct element model and a series of parametric studies. IntroductionIn evaluating the stability of drifts in jointed rock, it is often necessary to compromise by employing models that capture the complexity of the rock mass, but which are still simple enough to allow for their routine implementation. The distinct element method can arguably provide an eloquent method to accomplish this. This paper explores the applicability of the method by means of a parametric study aiming to identify the dominant factors that influence the stability of drifts in moderately jointed rock. To this end a commercially available 2D distinct element numerical model was used. A series of techniques are presented in an effort to quantify the results of any instability predicted by the model.This paper also demonstrates a case study where a 3D joint network model was integrated into the distinct analysis software package. The advantages, as well as the current limitations of this approach, are discussed."

Jan 1, 2001

By T. G. Joseph, A. Sharma

ABSTRACT: Ultra-class haul trucks operating in oil sand face operational and maintenance issues as a result of soft underfoot conditions (Joseph, 2002). With exposure to frequent high g loading events, tire life is reduced due to sidewall belt fexure and frequent ground contact. Therefore, an improved under-standing of the interaction between tires and oil sand is needed. This paper examines the outcomes of a series of static and cyclic loading tests, performed using a scale tire on rigid, sand, and oil sand surfaces. Geometric predictions are made regarding the footprint area and vertical deformation of an ultra-classtire on similar surfaces.

Jan 1, 2011

By Ian Ewart, Trevor Bergfeldt, Gourab Satapathy, Ajay Patel

"Conventional electrowinning (EW) of nickel from sulfate electrolytes is complicated by several factors including the requirement for a diaphragm cell to separate the anolyte and catholyte and the need to minimize nickel mist emissions. Developed and commercialized by emewCorporation, this novel process electrowins high purity nickel cathode (99.5%) from copper refinery bleed streams using the proprietary emew vortex EW technology. The emew nickel process incorporates high flow rate in an enclosed cylindrical EW cell operating at high current densities that overcomes the challenges of conventional nickel EW and completely eliminates the risk of nickel mist emissions. The tubular cathodes are easily harvested and mitigate the effect of plating stresses inherent in nickel EW. The present paper describes the emew nickel process and its most recent application to copper refinery bleed streams at full-scale.INTRODUCTION To meet the stringent demand of customers, nickel producers are giving prime importance to production of high purity nickel cathodes. The major challenge for refineries is to improve cathode quality and appearance despite fluctuating electrolyte impurity levels. The basis of achieving good quality cathode includes the control of electrolyte impurities and consistency of specific process conditions. The commercial operation of emew nickel technology has been successfully implemented and has demonstrated the ability to produce high quality nickel cathode from refinery bleeds. This paper emphasizes the importance of upstream impurity removal to achieve the required nickel emew feed composition by evaluating the benefits of using selective precipitation as a purification scheme with the aim of improving the overall nickel recovery while ensuring suitable nickel concentration in the advanced electrolyte is achieved. Nickel electrowinning is similar to other electrowinning processes that employ insoluble metal anodes & cathodes. It requires the passage of direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. For the recovery of nickel from solution, the most common methods are electrowinning and hydrogen reduction. Electrowinning usually occurs from sulfate, chloride or mixed sulfate/chloride electrolytes. In sulfate electrolytes, nickel electrowinning cells are normally designed to achieve specific criteria as outlined below (Robinson & Tuppa, 2002):"

Jan 1, 2017

By T. Mulpeter, G. Deschênes

Sadiola Gold Mine is an open pit operation located in Mali and owned by Anglogold Ashanti Ltd, Iamgold Corporation and the State of Mali. A conventional cyanidation process (cyanidation/CIP) treats 15,000 tpd (of a mixture of oxide and sulphide ores) at an average grade of 3 g/t Au. In 2002, the increasing tonnage of sulphides caused an increase in production costs and a decrease in gold extraction (from 95% to 70-76%). Because of the short retention time of the leach circuit (18 hours) and the refractory nature of the sulphides, gold leaching kinetics are critical. A laboratory investigation was initiated to evaluate actual plant practice and identify a means of improving the gold leaching rate. The study was conducted on a "soft" sulphide gold sample containing 4.96 g/t Au, 0.4 g/t Ag, 2.5% pyrite, 1.2% arsenopyrite, and 0.2% pyrrhotite with a P80 of 74microns. Pre-leaching significantly influenced the gold leaching rate. A short pre-leach (2 hours) performed at pH 8, a DO of 8 ppm, and with 300 g/t lead nitrate added at the start or the end, produced the preferred conditions. Pre-leaching for more than 2 hours was detrimental to gold extraction. The cyanide concentration had to be maintained at 450 ppm NaCN to reach a maximum gold extraction within the retention time of the circuit. A maximum extraction of 81.3% Au was obtained in 20 hours (leach residue at 0.97 g/t Au). A high level of dissolved oxygen in the pre-leach was not of any benefit. Extension of gold leaching beyond 20 hours indicated that all leachable gold had been extracted by that time. Plant modifications were made to allow leaching of oxides and sulphides in separate circuits. Treatment of oxide ores is now performed at a higher rate. Sulphides are processed at a lower throughput, with 300 g/t lead nitrate, to allow a retention time of 22 hours. Combined throughput remains the same, and total gold recovery has increased from 76% to 80% for an additional gold production of 16,000 ounces per year.

Jan 1, 2005

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from both primary and secondary sources having various compositions. Vanadium pentoxide and vanadium trioxide are the most available and known sources of vanadium oxides. In this paper, an overview of leaching both oxides has been reported. The problem of vanadium pentoxide leaching under acid conditions is the low solubility of the dissolved vanadium. This was investigated and then supplemented with further studies of leaching at mildly basic pH’s as well as under acid reductive leaching conditions (to form vanadium (IV)). Atmospheric oxidative leaching of vanadium trioxide was investigated using oxygen and ferric ion as the oxidant. It was shown that the leaching of vanadium trioxide using oxygen is very slow; however, ferric ion can dramatically increase the kinetics and leach efficiency.

Jan 1, 2014

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By F. Mackay, S. A. B. da Fontoura

"The theoretical solution for a viscoelastic well was presented by Gnirk and Johnson in 1964. From this an exercise was executed to validate the numerical simulation of a cemented salt well. The exercise comprised the geomechanical behavior through time of a cemented salt well, this was achieved using a finite element commercial software. This simulation showed the accuracy of the theoretical solution for viscoelastic materials such as salt rock. The theoretical solution presented elastic and viscoelastic analytic equations for the tangential and radial stresses. The equations for the elastic material (casing and cement) and for the viscoelastic material (salt rock) are presented here: Where equations 1a & 1b are the radial and tangential stresses of the elastic material; equations 2a & 2b are the radial and tangential stresses of the viscoelastic material; and a, r and b are the geometrical parameters explained in Figure 1. These equations are function of Pb, a stress time dependent factor that comes from the Burgers model of viscoelasticity. This is well explained in Gnirk and Johnson (1964) and for the sake of simplicity is not disclosed here. Po is the stress at section A-A’ dependent of the depth h."

Jan 1, 2015

By D. D. Macdonald, G. Engelhardt

The accumulation of damage due to localized corrosion [pitting, stress corrosion cracking (SCC), corrosion fatigue (CF), crevice corrosion (CC), and erosion-corrosion (EC)] in complex industrial systems, such as power plants, refineries, desalination systems, etc., poses a threat to continued safe and economic operation, primarily because of the sudden, catastrophic nature of the resulting failures. Of particular interest in managing these forms of damage is the development of robust algorithms that can be used to predict the integrated damage as a function of time and as a function of the operating conditions of the system. Because complex systems of the same design rapidly become unique, due to differences in operating histories, and because failures are rare events, there is generally insufficient data on any given system to derive reliable empirical models that capture the impact of all (or even some) of the important independent variables. Accordingly, empirical models have generally failed to provide a robust basis for predicting the accumulation of corrosion damage in complex systems under realistic operating conditions. The alternative prediction philosophy is determinism, in which the development of damage is described in terms of valid, physico-electrochemical mechanisms with the output being constrained by the natural laws. The differential damage is then integrated along the corrosion evolutionary path for the system (i.e., over the future operating "history") to yield the desired integrated damage, which is the quantity that is most useful to an operator. In this paper, we review the theory of predicting corrosion damage within the framework of Damage Function Analysis (DFA), with particular emphasis on the pitting of aluminum in chloride solutions and on the accumulation of damage from SCC in Type 304 SS components in the primary coolant circuits of Boiling Water (Nuclear) Reactors (BWRs). These cases have been selected to illustrate the various phases through which localized corrosion damage occurs.

Jan 1, 2005

By M. Reda

Because of the adverse environmental effect of Chromate, Molybdate ions had been investigated as replacement for Chromate and the results had shown not to be encouraging. Film deposited from peroxopolymolybdate (from reaction of Molybdenum meta, with excess Hydrogen Peroxide), are more robust than that deposited from molybdate solutions. This was shown to be due to higher fraction of Mo (IV) and Mo (V) that form from Mo (VI) in the peroxopolymolybdate deposited film than the film deposited from Molybdate solutions. The peroxopolymolybdate film contains 40% un-hydrated molybdic acid, tetraperoxodimolybdate and tetra peroxo tetra molybdate. The protective properties of peroxopolymolybdate were shown to be due to the effectiveness of the un-hydrated molybdic acid.

Jan 1, 2010

By L. J. Han, Y. J. Zong, S. Y. Wen, J. J. Wei

"Stress strain curves characteristics, deformation and strength properties, and failure process and characteristics of sandstone samples under different stress states were analyzed through triaxial compression tests carried on using TAW-2000 microcomputer control electro-hydraulic servo rock triaxial test system. The experimental results reveal that peak strength, residual strength, elasticity modulus and deformation modulus increase linearly with confining pressure, and failure models transform from fragile failure under low confining pressure to ductility failure under high confining pressure. Macroscopic failure forms of samples under uniaxial compression was split failure paralleling to the axis of samples, while macroscopic failure forms under uniaxial compression was shear failure, the shear failure angle of which decreased linearly with confining pressure. There were significant volume dilatation properties in the loading process of sandstone under different confining pressure, and then based on acoustic emission damage and volumetric dilatation damage the damage evolution properties of samples were analyzed, and damage constitutive model were established, realizing the real-time quantitative evaluation of samples damage state in loading process. INTRODUCTIONDamage is a phenomenon that micro defects in material under monotonic loading or reloading will lead to progressive decrease of the cohesion and damage of volume units. Many scholars at home and abroad have carried out systematic researchers on damage evolution characteristics and constitutive model of rock, and have achieved a series of remarkable results in this field. Lu Y.D. (2004) studied the complete stress-strain curve’s characteristics of marble under triaxial compression, and established the bilinear elastic-linear strain softening-residual ideal plastic damage constitutive model. Ren J.X. (2001) studied the damage evolution laws of coal and rock mass by computerized tomography triaxial loading system, realizing the quantitative evaluation of damage state. Zhang Z.L. (2011) studied the deformation and failure mechanism of strong weathered sandstone by triaxial compression test, and analyzed the damage evolution processes and established the damage evolution equations based on the density method. Li X.J. (2012) studied the microscopic damage characteristics of siltstone under triaxial compression by scanning electron microscope and digital image technology, and analyzed the statistical distribution characteristics of cracks azimuth angle, length, width. Zhou J.W. (2012) studied the strength, deformation and fracture damage characteristics of sandstone by uniaxial cyclic loading and unloading tests, and defined damage variable based on linear damage mechanics theory and acoustic emission (AE). Cao W.G. (2006) established a new damage model and a statistical damage constitutive model of rock under specific confining pressure according to the force of damaged part and undamaged part in rock on the base of statistical damage theory. Li S.C. (2014) studied the damage evolution characteristics in the whole uniaxial compression process of sandstone by electrical resistivity and AE, and proposed a status qualitative criterion for rock damage."

Jan 1, 2015

By M. Sukhram, S. A. Argyropoulos

"In the aluminum and steel processing industries there is a need for velocity sensors to measure the flow characteristics of liquid metal. This paper will present a sensor and an inverse heat transfer technique to determine the direction of velocity in flowing liquid aluminum. Experimental research work with the sensor involving liquid aluminum was conducted, using the Revolving Liquid Metal Tank at the University of Toronto, which rotates 50 kg of liquid aluminum with velocities up to 0.35 m/s. Experimental data for various magnitude of velocity demonstrate that the sensor records different thermal profiles under different fluid flow conditions. Using the transient temperature information and the inverse technique, the direction of velocity of the molten aluminum flow field can be inferred. INTRODUCTIONOur research at the University of Toronto has focused on developing invasive sensors to determine the velocity of high temperature liquid metals. High temperature in this setting is defined at VALUES (in excess of 660 °C. The discussion which will persist in this manuscript involves detecting the direction of flow in liquid aluminum using an inverse heat transfer technique. We first reported on the sensor which is used in this article in the following two publications (Sukhram and Argyropoulos, 2011a; Sukhram and Argyropoulos, 2011b). The motivation to perform this research is due to the lack of sensors available to characterize the conditions within a high temperature liquid metal reactor/vessel. A report conducted by The Minerals Metals and Materials Society (TMS Energy 2011) has suggested that the introduction of sensors into molten metal processing environments has the potential to increase process efficiency up to 15%. Such sensors will aid in the understanding of high temperature liquid metal processing operations with the goal to implement more efficient process design and practice."

Jan 1, 2012