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By Nobuhiro Ishikawa

The in-situ observation of the effect of impurities on the reduction process of iron oxides by C in TEM was carried out. A few wt% of CaO or AbO, was used as impurities in FeO was prepared. Some precipitates grew into the C layer expect for using 3.0wtCa. The reaction between FeO and carbon was much different from using pure FeO at about 800-1 lOOK. The rate of reaction became much slower including Ca and almost no reaction was happened with the concentration of CaO up to 3.0wt%. On the contrary, AbO, had ahuost no effect on the reaction. The results indicated that Ca suppressed the reaction and the effect of Al was much less. The precipitates which grew into C layer accompanied almost no Ca and AI. Only Fe was detected in the precipitates.

Jan 1, 2008

By Burkhard Seeger et al.

The oxidation of copper sulfides can be highly accelerated in the presence of nitrous gases (NOx) as reaction catalysts. Sulfur and sulfate are simultaneously produced in this highly exothermic reaction. This process, carried out in sulfuric acid medium, is performed at an approximately normal pressure and at a temperature of around 110 °C, in a closed container, adding either oxygen or air. The oxidation is automatically controlled through a computer. The process covers the following steps: Catalytic oxidation, filtration and crystallisation of the hot concentrated liquid, electrowinning, mother liquor treatment through jarosite formation, recovery of dissolved copper and zinc and regeneration of industrial water, and non-soluble residue treatment with extraction of sulfur and recovery of silver and gold. No combustibles are needed. No air is contaminated, and no waste water is produced. Solid residues are in a stable, non-toxic and non-corrosive state of equilibrium. Risk of accident is low. Investment costs are small compared to those of the comparable pyrometallurgical process, and production costs are competitive.

Jan 1, 1999

By J. R. Budden

The growth and oxidation characteristics of any bacterial culture are ultimately determined by the nature of the sample being treated. The most important parameters in the application of bio-oxidation are bacterial cell number, growth rates, oxygen uptake and rate of oxidation. Cells present in the solution of an established culture were counted directly using a microscope, related to a protein value, and then used to determine the total cell number (in solution and on the solids). Protein determination of total cells enabled the growth rates on slurry to be calculated. The cell number and culture growth is related to the iron and sulphide contents of the sample. To illustrate these considerations a moderately thermophilic culture was used to treat ore and concentrate samples obtained from Australian mines.

Jan 1, 1990

By Tobias Pröll, Bernhard Kronberger, Joachim Rohovec, Werner Hölt, Hermann Hofbauer

"As this is only a first draft, more precise explanations as well as detailed schemes, figures and plots will be included in the final draft. The description og the 100 kW test rig will also be mor detailed as construction is ongoing and will be finished during the summer. Furthermore simulations are to be finished shortly; so details on combustibles and gas concentrations will also be included in the final draft.AbstractOxyFuel combustion is a key technology for the efficient separation of CO2 from fuel combus¬tion (especially coal). Since coal plays a minor role in the Austrian energy mix the application of OxyFuel towards other fuels (biomass, waste fuels) is interesting to reduce greenhouse gas emissions from Austrian energy sector. The investigation of OxyFuel technology for alter¬native fuels is also interesting from a strategic point of view in order to generate knowledge for operation of capture ready cofiring and waste/sludge-incineration plants. OxyFuel uses a synthetic mixture of 02 and recycled exhaust gas where the 02 content may vary. This supplementary degree of freedom allows improved operation especially for low calorific fuels. Heavy fuel oil addition for low calorific combustibles can be omitted when using OxyFuel combustion. Application of alternative fuels (wood, waste wood, municipal waste, sewage sludge) in a 100-kW CFB plant is investigated in combination with process simulation.IntroductionOxyFuel combustion is discussed as one of the key technologies for the efficient separation of CO2 from combustion of fossil fuels (especially coal). Since coal plays only a minor role as primary energy source in Austria, the broadening of the scope towards OxyFuel of other fuels like biomass or waste fuels is necessary to reduce greenhouse gas emissions from Austrian energy sector. The investigation of OxyFuel technology for alternative fuels besides the large coal-oriented projects is interesting also from the strategic point of view. The presented project aims at the generation of knowledge in order to design and operate capture ready cofiring and waste/sludge incineration plants."

Jan 1, 2008

By V. T. Taniguchi

A process for large scale chromatographic separations using a continuous chromatography technique is described. The process combines the advantages of large scale batch fixed column displacement chromatography with conventional analytical or elution continuous annular chromatography (CAC) to enable large scale displacement chromatography to be performed on a continuous basis (CDC). Such large scale, continuous displacement chromatography separations have not been reported in the literature. The process is demonstrated with the ion exchange separation of a binary lanthanide (Nd/Pr) mixture. The process is, however, applicable to any displacement chromatography separation that can be performed using conventional batch, fixed column chromatography.

Jan 1, 1989

By Luis G. S. Sobral, Gabrielle N. Bard

Copper sulphides Concentrates, from the flotation process of copper primary ore; contain, commonly, small amounts of precious metals, such as gold and silver. During the smelting process of those concentrate all gold and silver are practically in the blister copper, which is cast into anodes. Those copper anodes are electrorefined in an electrolytic system, where the electrolyte is an acid copper sulphate solution, where a high purity electrolytic copper is produced (>999,9/1000). The slime when submitted to an oxidative leaching process, using sodium hypochlorite and hydrogen peroxide as oxidizing agents, turn those metals into solution. This research practical work, apart from concentrating effort on the digestion of the anode slime, aims at evaluating the efficiency of the cementation process of the metals of interest for the separation of them to take place. 141

Jan 1, 2008

By Jouko Kallionen

Advanced Flotation Technology is the application driven design of flotation cells to achieve the optimum performance for each type and grind of flotation. This can be applied to roughers, scavengers, cleaners and specialty cells such as those to float hydrocyclone underflows in both primary and regrind circuits in order to reduce overgrinding. Standard, engineered, components are matched to provide mechanism design and cell dimensions for each case according to feed parameters and flotation type. Advances in process control have been achieved with high level controls and operator information data. This has gained a higher degree of understanding of cell operation and ore type being processed. Excellent results of this Advanced Flotation Technology in large scale porphyric copper ore have been achieved and designs through 7000 cu ft (200 m3) are currently available for high capacity concentrators. This paper will detail how flotation cells are more responsive to the exact requirements of the duty specified.

Jan 1, 1999

Most of the world's zinc metal is produced via the roast- leach-electrowinning (RLE) process. The process is well established, but most of the sulphur in the sphalerite concentrates reports in the acid, which has to be stored and/or sold. There are significant incentives to develop a simpler process with much reduced acid generation. Ferric ion is a well known oxidant for most sulphides, in particular sphalerite, and it converts the sulphide to elemental sulphur. Based on stoichiometry, however, the amount of ferric ion needed to achieve acceptable zinc extractions is prohibitive for downstream zinc recovery from the leach solutions. The process suggested here makes use of less-than-stoichiometric ferric sulphate additions because the ferric ion is regenerated by sparging SO2/O2 mixtures. This regeneration can be effected in-situ in the leach vessel or outside the leach vessel. An example of the application of this new process is presented for a Canadian sphalerite concentrate assaying 60% Zn. The effects of temperature, ferric concentration and ferric ion regeneration are presented. Options to recover zinc from the leach solution are also briefly discussed.

Jan 1, 2000

By Henry Salomon-De-Friedberg

Quebrada Blanca has had to overcome numerous challenges in achieving design throughput. The paper reviews how actual practice has evolved from the original design. The major challenges that were encountered from heap leaching to solvent extraction, the tankfarm and through to electro winning are discussed. The eventual solutions to some of the key issues are presented.

Jan 1, 1999

By Nicola Baldo, Marco Pasetto

"The paper discusses the results of a laboratory study, aimed to evaluate the suitability of the bottom ash from Municipal Solid Waste Incineration (MSWI), obtained from different Italian plants, to be recycled in the lithic skeleton of bituminous mixtures, for base layers of road and airport pavements. The research involved a preliminary study of the physical and geotechnical properties of the bottom ash by itself; it was followed by a mechanical characterization of the bituminous concretes. The traditional Marshall methodology was used to identify the optimum bitumen content; the mixtures were also mechanically checked by means of the stiffness modulus test, repeated load axial test and fatigue test. Because the requisites for acceptance in the Italian Specifications and Standards have been satisfied and given the positive mechanical performances, it has been verified that the MSWI bottom ash can be used as substitution of the lithic materials in the road bases, also with very high contents (up to 81% on the weight of the aggregate). Introduction The incineration of Municipal Solid Wastes (MSWs) provides for by-products which can be mainly classified as bottom ash and fly ash. The first one, corresponding to the 25% on the weight of the wastes to be incinerated, so resulting the principal product of the process, is mainly composed by Silica (Si), Iron (Fe), Calcium (Ca), Aluminium (Al), Sodium (Na) and Potassium (K) oxides, so presenting a composition similar to that of different natural materials. Its metallic fraction can be recovered; the remaining part is usually stocked in dumping or, less frequently, recycled. Bottom ash can be re-utilised in the construction of new infrastructures, especially in bitumen bounded mixtures, because of the inert properties of the binder which covers the grains with a subtle film, that prevents the release of heavy metals. The paper describes a study aimed to design new bituminous mixes for flexible road and airport pavements, realised with the highest content of 4 types of bottom ashes, deriving from different MSWI plants of the Northern Italy. The ashes will be named as BA1, BA2, BA3, BA4 respectively (the origin cannot be specified)."

Jan 1, 2008

By T. R. A. Davey

It is often important in the study of a process to determine whether the limitations are governed by equilibrium or kinetic considerations. Sometimes it is possible to devise a design of the process or the equipment so that the apparent. limitations set by equilibrium considerations are overcome. In this paper, detailed consideration is given to the lead refining processes of sulfiir-decoppering and of vacuum dezincing to illustrate this, and possible implications for other refining processes are indicated.

Jan 1, 2000

By Jimsher Aneli

The investigation of some peculiarities of conductivity dependence on filler type and amount in the polymer composites has been conducted. It is established, that conductivity of composites based on phenolformaldehide resin essentially depends on proportion of double fillers: graphite + carbon black, graphite+ andesite, contained in composites. It was shown, that these composites characterized by synergetic effect ? non additive influence of fillers concentration on the conductivity of composites. Some other properties of composites contained binary fillers (effect of temperature and pressure on the conductivity) have been investigated.

Jan 1, 2006

By Nexhmedin Lohja

The production of high-carbon ferrochromium in a submerged electric furnace based on double-level technology has some advantages compared to close-type furnaces with one tap hole. These advantages include the reduction of the specific energy consumption for the overall process, good separation of ferrochromium from slag, an effective treatment of raw materials including lean chrome ores (low percentage of Cr2O3) etc. An outline of the operation of this furnace along with the production line of briquettes from fines of chrome ore by using organic and inorganic binders, will be followed by a description of the recent work carried out to improve the energy consumption in this furnace through a pre reduction process of Cr2O3 ores by the off-gas energy recuperated from the furnace and the use of SiC in the feed. A short theoretical analysis of the new work will also be given.

Jan 1, 2006

By Hee Dong Jang, Hong Yong Sohn, Miguel Olivas-Martinez

"Tetramethylorthosilicate (TMOS), a precursor of silica nanoparticles, is prepared from the waste silicon sludge, followed by the synthesis of silica nanoparticles from the TMOS by flame spray pyrolysis. A two-dimensional multiphase computational fluid dynamics (CFD) model for the flame spray pyrolysis process (FSP) for the synthesis of silica nanoparticles has been developed. The model incorporates the governing turbulent equations of overall continuity, momentum, energy and species mass transport to represent the gas phase and the population balance model (PBM) to account for the silica nanoparticles. The model has been validated with experimental data in terms of gas temperature and average particle size. Introduction Silica (SiO2) nanoparticles are used in various industrial applications, such as catalyst, pigments, thin film substrates, electronic and thermal insulators, and humidity sensors [1]. They are also used as additives in plastics and rubbers to improve the mechanical properties of elastomers, and in liquid systems to improve their suspension behavior. These applications rely on the particle morphology, average particle size, particle size distribution, and phase composition [2]. Silica nanoparticles can be synthesized by wet chemical processes such as sol-gel methods and high-temperature processes such as flame spray pyrolysis (FSP). The FSP process provides a unique control of particle size and crystalline structure and it can also produce high-purity, thermally stable particles continuously with minimal further treatments. The sizes of the flame- made particles range from a few to several hundred nanometers, depending on the operating conditions [1]. The synthesis of silica nanoparticles from organic compounds that contain silicon by the FSP process is of interest because it generates no harmful by-products [1, 3]. Several compounds such as tetraethylorthosilicate (TEOS) and tetramethylorthosilicate (TMOS) can be used to synthesize silica nanoparticles, but most such compounds are expensive. Thus, it is desirable to prepare the precursor compounds from waste materials. In the present study, TEOS and TMOS synthesized from silicon sludge were used as precursors of silica nanoparticles [4]."

Jan 1, 2008

By T. J. A. Smith

This paper provides an overview of some of the key issues in design of smelter gas handling systems, with particular reference to smelter smelting plants. In both primary smelting and converting, gas handling and treatment systems often represent the major capital cost component. There is also ample evidence that poor system design can be a major cause of smelter down time, lost production and unforeseen high maintenance costs. The paper discusses these issues and offers guidance for improved design.

Jan 1, 1992

By Mingchun Lu, Zhijia Liu, Xueqi Zhang, Jianliang Zhang

"In order to solve the problem of shortage of scrap, especially high quality scrap, a new substitute for scrap or DRI has been developed. The decarbonization mechanism of granular pig iron has been analyzed and the technical process and decarbonized granular pig iron have been evaluated in this paper. The research result shows that this new process is superior to direct reduction process in product quality, construction investment, operation flexibility, production efficiency etc. Decarbonized granular pig iron (DGPI) not only can be used as conventional scrap but also can be charged into EAF as high purity .burden equivalent to heavy scrap:IntroductionIn the past years, with the universal application of continuos casting technique in China, the amount of scrap generated inside steelworks has been reducing continually. On the other hand, the EAF steel proportion is increasing and this gives to the obvious change in structure of steel product. At present, the requirement on both scrap quantity and scrap quality is being paid more and more attention. Because China is a country which is devoid of scrap and poor in resource (nature gas and high grade iron ore) for developing direct reduction iron (DRI) so that sponge iron can not be produced cosmically in China and has to be mainly imported. Instead of part of scrap, some cold pig iron in cold state has been charged into EAF in China. However the high carbon content in pig iron has limited its proportion in EAF metal burden. Because the price of pig iron is lower than that of imported DRI in China, the technique of granular pig iron decarboniztion is hopeful to become effective way to produce substitute for scrap or DRI."

Jan 1, 2000

By V. A. Bryukvin

A hydroelectrochemical technology has been proposed and experimentally proven for processing metallic gold- and silver-containing concentrates on the basis of copper and copper alloys obtained as a result of preliminary physico-mechanical upgrading of electronic scrap. The proposed technology is based on hydroelectrochemical leaching of scrap using reversible electric current and diluted nitric acid solutions, containing complexing agents, permitting complete separation of gold from the nonferrous matrix without involving gold in the process, and dissolving copper, zinc, lead and tin virtually without any emission of nitrose gases.

Jan 1, 2006

By B. Yalamanchili

Gerdau Ameristeel Beaumont presents its systematic approach for upgrade decisions that has developed over 30 years of ongoing capital projects for quality and cost improvements. This system serves to identify product needs, select process improvement strategies, justify them, and assist multi-department communications and decision-making. This is illustrated with Beaumont mills? last Stelmor upgrade and leads to a discussion of the need to consider Life Cycles of both products and technologies as we move to answer the challenges of the future.

Jan 1, 2006

By Florian Kongoli

While calcium ferrite slags have been successfully used in continuous copper converting for the last 30 years, ferrous calcium silicate slag was proposed about 8 years ago as an additional alternative for copper smelting. Although both slags are normal extensions of each other their phase relations have not been completely clarified. In this paper the liquidus relations of both slags have been quantified at various areas that cover both of them. The existing experimental data have been first reviewed and discussed in relation to the solidification procedure. An original physical model is then used to predict various diagrams of the liquidus surface of both slags. It is shown that the ternary liquidus diagrams normally used for FeOx-SiO2-CaO system are not suitable for industrial slags. The new model diagrams of Fe/CaO versus SiO2 and Fe/SiO2 versus CaO as well as Fe/CaO versus Temperature and Fe/SiO2 versus temperature are proven to be much more convenient for ferrite and ferrous calcium silicate slags. Based on these diagrams the effect of SiO2 and CaO on the melting temperature is quantified. The effect of Cu2O is also quantified through the model. Some Fe/CaO versus Cu2O and Fe/SiO2versus CaO at various copper contents are predicted and the results show good agreement with the experimental data. It is also shown that in the presence of liquid copper, Cu2O is dissolved in the slag depending on the oxidation degree of the system and might lower the liquidus temperature. Some discussions are also presented taking into account plant observations and important conclusions are drawn for copper smelting and converting

Jan 1, 2006

By Dariusz Kopyci ski, Józef Dorula

The study proves that by introducing the iron powder and disintegrated steel scrap to low-sulphur cast iron still before the inoculation carried out with a conventional graphitising inoculant, the mechanical properties similar to those obtained during the inoculation treatment carried out on cast iron with the recommended high sulphur content are achieved. The said operation increases the number of crystallisation nuclei for dendrites of the primary austenite. In this case, the iron particles act as substrates for the nucleation of primary austenite, due to a similar crystallographic behaviour of the regular face centred cubic lattice The more numerous are the dendrites of primary austenite, the less free space is available in the interdendritic spaces for the formation of graphite eutectic grains, which makes the structure more refined (more eutectic grains) and the mechanical properties higher.

Jan 1, 2016