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By D. Tahija

"Carbonic acid prepared on-site from carbon dioxide gas is widely used in water treatment and increasingly in some industrial applications. It has not seen extensive use in mineral processing but is an attractive alternative to sulphuric acid for pH control, with the need to counteract high pH levels caused by cemented backfill of particular interest. The fundamental chemistry of carbonate solutions as applied to flotation and flocculation circuits is described as well as plant-scale application. A project to introduce use of carbon dioxide for pH control at the Hecla Greens Creek lead-zinc-silver-gold operation is planned to begin operation in the first half of 2015. INTRODUCTION Flotation pH Control and Backfill Most sulphide flotation circuits are run at pH values ranging from slightly acid to strongly basic, with slightly basic pH the most common. Lead sulphide circuits are typically run at values from 7.5 to 9, with zinc circuits running at higher values of 9.5 to 10.5. This has been the case with ores that produce a natural pH in the circumneutral range, so that the pH needs to be raised. Although lime [Ca(OH)2] is the cheapest reagent in use to raise pH, soda ash (Na2CO3) or caustic soda (NaOH) are also employed where sodium ions in solution are preferred to dissolved calcium, or, in the case of soda ash, the presence of carbonate is desired. The use of soda ash for pH control in lead circuits has been widely recommended for many decades (1). The situation is necessarily different at operations where cemented backfill is used in underground mines (2). Backfill, whether emplaced as rammed paste or pumped slurry, is composed of mill tailings mixed with around 10% Portland or similar cement. When later mining occurs near or adjacent to previously backfilled areas, a considerable amount of old backfill is inevitably mixed with new ore and shipped to the mill. Depending on orebody geometry, mining methods etc., the amount of backfill in mill feed can easily approach 20%, with periods of higher content not unheard of. The presence of so much backfill, with its high cement content, produces results largely indistinguishable from adding a large amount of lime to run-of-mine feed: mill pH in the grinding circuits can range above 11 and high concentrations of calcium ions are present. The need to raise pH disappears; the problem becomes to lower it."

Jan 1, 2015

By John R. Marks

In April 1990, the Homestake Gold Mine embarked on a five year, $US 23 million underground drifting and drilling program to explore promising ore targets north of the current mine. This paper describes the ventilation and air-conditioning system that was installed for the 4m x 4m x 5.2 km (ultimately) drift, which is being driven at about 8m per day in 48OC (118.5 F) crystalline rock. Design parameters are described first. Differences in South African, Canadian and U.S. drift ventilation and civil tunneling techniques proved interesting. Details are then given on equipment selection, installation and performance. Costs are included. Special note is made of safety considerations for a long, dead-end drift.

Jan 1, 1991

By Roy A. Koski

This paper describes variations in feed characteristics, preparation techniques, response to induration and product quality in pelletizing magnetite concentrates, earthy hematite ore fines, and specular hematite concentrates in grate kiln systems. The Cleveland-Cliffs Iron Company manages plants processing these various materials on the Marquette Iron Range in northern Michigan. The operations include the Humboldt Mining Company, Marquette Iron Mining Company, Empire Iron Mining Company and the Pioneer Pellet Plant. The combined output of the operations is approximately 9,000,000 long tons per year. The Humboldt Mining Company, owned by Ford Motor Company and Cliffs, produces pellets from a specular hematite concentrate. The Empire operation, which processes magnetite ore, is owned by Inland Steel Company, McLouth Steel Corporation, International Harvester and Cliffs. The Pioneer operation, which processes earthy hematite ores, is a joint venture of Republic Steel Corporation, McLouth Steel Corporation, Bethlehem Steel Corporation and Cliffs. The Marquette Iron Mining Company, owned by hones and Laughlin Steel Corporation, International Harvester, Wheeling-Pittsburgh Steel Corporation and Cliffs, produces pellets from specular hematite concentrate at the Republic Mine and Eagle Mills Pellet Plant. With the exception of the Eagle Mills plant, the operations employ the grate-kiln pelletizing system. Descriptions of the Empire, Pioneer and Republic operations, which have a combined capacity of 7,200,000 tons per year, are given in the paper.

Jan 1, 1969

By G. F. Joklik

Although the mineral shortages of twelve to eighteen months ago have given way to oversupply, their memory lingers on. These problems were man-made: booming demand throughout the industrial world, political and industrial unrest and the oil embargo all contributed. But in the minds of many, the shortages conjured up visions of the depletion of the world's mineral resources, a disaster that could be staved off only by drastic curbs on consumption and therefore, curbs on economic growth. A little historical research shows that fears such as this are not inventions of the 1970's. A hundred years ago, for example, the imminent exhaustion of the world's coal supplies was being predicted in Great Britain. The English economist, John Stuart Mill, who was usually more perceptive, wrote a few years earlier that "it is only in the backward countries of the world that increased production is still an important object". And later there was Franklin Roosevelt who said in 1932, "Our industrial plant is built; the problem just now is whether under existing conditions, it is not overbuilt". His concern, in other words, was not with the discovery and exploitation of new natural resources, but with the administration of known resources and with seeking foreign markets for surplus production. In light of copper prices at the time -- just under 6¢ a pound -- that was understandable. These instances illustrate how, throughout the world's industrial history, concern about surpluses of raw materials has alternated with alarm about the adequacy of supplies and with calls for restricting growth.

Jan 1, 1975

By J. Potter, A. Anani, C. Antonio

This research aims to test the hypothesis that the low retention rate of women in the mining industry is caused by workplace culture and policies established due to gender segregation. A quasi-experiment is developed to determine the cause-and-effect relationship between gender segregation-inspired culture and the retention of women. The experiment considers the impact of the job type and the operational environment. The analysis provides information on factors that cause low retention of women in the industry, the extent to which gender segregation plays a role, and insights that allow actionable and measurable changes in the industry.

Feb 1, 2023

By Hasan Ali Taner, Vildan Onen

One of the problems in flotation is mechanical entrainment and the other is the presence of complex gangues (especially clay minerals). In the present study, it was aimed to determine the effects of clay types (kaolinite, illite, and montmorillonite) on mechanical entrainment parameters (total flotation recovery, real recovery, mechanical entrainment recovery, and water recovery). Effects of clay types and clay amount on chalcopyrite flotation were investigated by flotation experiments. Interaction mechanisms between the clay minerals and ore were characterized using SEM–EDS analyses. Experiments were carried out with and without a collector using the mixture of clay minerals and ore under certain experimental conditions. While the clay mineral most affecting the chalcopyrite grade was montmorillonite, the highest mechanical entrainment recovery and the lowest real recovery values were obtained in the presence of illite. While illite is stated as the least problematic clay mineral in the literature, it was determined that illite among three clay minerals used in this study caused significant mechanical entrainment. In contrast, it was determined that increasing the amount of kaolinite did not have a significant effect on mechanical entrainment. This study’s findings will guide in determining of clay minerals’ effect on gangue entrainment in flotation.

Dec 29, 2023

By Jonathan G. Price

Silver-copper-lead deposlts in Precambrian, Permian, and Cretaceous red-bed sequences near Van Horn, Texas, have the following features In common: (1) mineralization controlled by steeply dipping fractures in sandstones, (2) lack of ore In overlying and interbedded limestones, (3) absence of igneous intrusions, (4) sulfide ores without typical hydrothermal gangue minerals, and (5) associated arsenic, molybdenum, zinc, and cadmium but not gold. Ore was probably deposited along fractures by reaction between low-temperature, oxidizing, metal-rich ground waters and sulfide-bearing waters or rocks. Detailed mapping and studies of fracture patterns indicate that mineralization occurred during Basin and Range extensional deformation, thereby postdating major Trans-Pecos igneous activity.

Jan 1, 1983

By R. N. Gow

EH-pH diagrams are useful tools in understanding how mineral surfaces react in solution and particularly how aqueous conditions can be changed to enhance mineral leaching processes. However, successful application of these diagrams requires several things be kept in mind to prevent what others have termed ?gross errors? in their calculation and use. The aqueous Cu-S system is used as the basis for explaining the mass-balanced method of calculating EH-pH diagrams with the thermodynamic equilibrium software, STABCAL. This includes a breakdown of the Gibbs? Phase Rule and how it is employed in STABCAL to modify the diagrams. This methodology was then applied to the aqueous Cu-As-S system and resulting diagrams are compared against examples of those generated using the predominant-ion method. The resulting mass-balanced diagram for enargite (Cu3AsS4) is noted to compare well with spectroelectrochemical measurements using Raman spectroscopy and cyclic voltammetry.

Feb 23, 2014

By Ahmad Rahbar-Kelishami, Zahra Karimi

When alumina is extracted from bauxite ore, one of the environmental pollutants created is known as red mud (RM). This study clarifies that the RM obtained from the Iran Alumina Company has a significant proportion of iron oxides (24%), alumina (19%), silica (17%), and calcium (21%), as well as trace amounts of other minerals. The elements in the RM can be removed and utilized again to reduce environmental pollution. Acid leaching is one of the best ways to selectively exclude some minerals from the RM. In this research, the RM is exposed to different inorganic acids, including HCl, HNO3, H2SO4, and H3PO4, and their binary mixtures. By comparing the results obtained from XRD, EDX, and SEM, it was discovered that CaSO4 crystals are formed by exposing the RM to sulfuric acid. Besides, phosphoric acid was only able to destroy the surface of RM particles. The XRD analyses of acid-washed residues demonstrated that except for the residue of HCl 5 N, all residues contain hematite, showing that inorganic acids cannot easily extract hematite from the complex phases of red mud. While the dissolution of RM with HCl or HNO3 will remove most of the calcium content of RM texture, increasing its iron oxide percentage, which may subsequently be utilized to make colors and pigments.

Mar 29, 2024

By M. J. Virnig

A flowsheet for the recovery of nickel and cobalt from laterite ores has been developed which involves acid leaching followed by hydroxide precipitation of the metal values and then releaching of the hydroxide cake with ammonia. Investigations of the chemistry of extraction of nickel by LIX® 84-1 and a developmental reagent, XI-84-IT, along with the physical properties of the organic phases are described. Based on these investigations, suggestions with regard to design of a solvent extraction plant and operating conditions are made.

Jan 1, 1999

By Edwarde R. May

The Flambeau volcanogenic massive sulfide deposit located in northwestern Wisconsin occurs within the southern lobe of the Canadian Precambrian Shield. The steeply dipping tabular body occurs in a complex pile of cyclic schistose intermediate to felsic fragmental volcanics. No chloritic alteration pipe is recognized but adjacent rocks have undergone magnesia metasomatism and subsequently were metamorphosed to the upper greenschist and lower amphibolite facies. Although modest in size the deposit is of special interest in that it has an extensive and well preserved supergene enrichment blanket. Economic minerals found within a pyritized quartz-sericite schist are chalcocite and bornite overlying primary chalcopyrite.

Jan 1, 1976

By Alafara A. Baba, Yakubu A. Dallatu, Kehinde I. Omoniyi, Shemang Y. Chindo, Edith B. Agbaji

As a result of the rise in global demand for pure copper, there is urgent need to consider the processing of low-grade chalcopyrite ores. Ammoniacal leaching solutions have been reported as an effective and efficient leachant for the dissolution of chalcopyrite. This work reports different parameters that influence the leaching kinetics of a Nigerian chalcopyrite-rich siderite ore obtained from Wase Local Government Area, Plateau State, Nigeria, and assayed as 11.30 wt% of Cu. At the optimum leaching conditions (0.4 mol/L NH3-( NH4)2SO4 leachant concentration; 75 °C reaction temperature; 45 μm particle size), the extent of chalcopyrite ore dissolution reached 87.4% within 120 min. The dissolution rate was affirmed to conform to the diffusion control mechanism with the activation energy, Ea, of 38.84 kJ/mol and a reaction order of 0.661 for the leachant concentration being established. The leaching mechanism was affirmed by characterizing the raw ore and the leached product by XRD and SEM-EDS analysis. Ascertaining optimal leaching conditions for copper using alkaline leachant is advantageous from the environment and economic points of view.

Jan 6, 2023

By K. KAKLIS, O. SAUBI, Z. Agioutantis, R. JAMISOLA

Three-point bending (TPB) tests were conducted on prismatic Nestos marble (Greece) specimens. The specimens were instrumented with piezoelectric sensors, and comprehensive recordings of acoustic emission (AE) signals were obtained. Machine learning in the form of artificial neural networks (ANNs) was then applied in an effort to investigate whether specimen load evolution can be predicted as a function of AE signals. A number of ANN models were developed, and the optimum model was selected based on the highest coefficient of determination (CoD) value as well as the lowest root mean square error (RMSE) value that was calculated for each model. The best performing ANN model exhibits accuracy above 99% with an RMSE value below 4%. It can be concluded that ANNs can potentially be applied to predict rock behavior under load especially when such loads lead to failure.

Sep 7, 2022

By Yiming Zhang, Yunpeng Li, Chun Feng, Ruyang Cao

In the past, the selection of the number of empty holes between blast holes heavily relied on the subjective experience of practitioners, leading to unsatisfactory blasting results. The number of empty holes between blast holes is particularly important for the perforation of explosive cracks. In order to determine the optimum number of empty holes for inducing the propagation of explosive cracks, a two-dimensional numerical model of two-hole blasting was established based on the continuous-discontinuous element method (CDEM) using polymethyl methacrylate (PMMA) as the medium, and numerical simulation of various working conditions was conducted; the simulation results are basically consistent with the PMMA model test. Through the analysis of blasting parameters, the optimal number of empty holes with a certain hole spacing is fitted. The following conclusions are drawn: (1) There is a threshold for variable x. When x exceeds 50, the presence of empty holes cannot lead to the perforation of explosive cracks between the blast holes. (2) When x is below 50, the optimal number of empty holes inducing the propagation of explosive cracks can be determined through fitting an empirical formula. By adjusting the number of empty holes between blast holes, a significant spacing between adjacent blast holes was achieved, allowing for effective penetration, so as to effectively “induce” the direction of the fracture zone and make full use of the energy of explosives. The research results of this paper are conducive to the research of directional blasting technology and provide certain references for the optimization of precision blasting parameters.

Dec 19, 2023

By T. A. Doyle

Column and batch test methods are used to simulate and model the leaching of various mining by-products. Batch tests are simpler, while column tests more intuitively represent the field conditions to be simulated. Projects that have included different types of leaching tests illustrate the strengths, limitations, and associated uncertainties of each. Column and batch tests have been used to evaluate arsenic solubility in leachate from treated copper smelter flue dust, to simulate the leaching of pit wall rock from a proposed gold mine, and to simulate the release of uranium from aquifer materials.

Jan 1, 1998

By Courtney Black, Paul F. Ziemkiewicz, Eberhard Werner, Matthew Daly, Joseph J. Donovan, Jeff Frazier

Injection of alkaline waste-lime slurry was performed at a West Virginia surface coal mine site, to attempt neutralization of acid springs by an alkaline recharge method. Deep trenching (>5 m) using an excavator yielded the most effective injection into the aquifer. Water from two springs, 90 m from the deep trench, showed 70%-80% reduction in acidity in response to injection. Neutralization persisted >170 days after treatment, with pH between 5.1-5.7 and metal acidity from 25-60 mg/L. A minor fraction of lime introduced was consumed. The sustained neutralization is attributed to reaction of acid water with subsurface lime, entrained below the wafer table by macropore infiltration. Characteristics of groundwater transport are critical in determining recharge structure location.

Jan 1, 2000

By Victoria Vaccarezza, Corby Anderson

The demand for rare earth elements for everyday technology and applications has initiated much research into the extraction and recovery of these rare earth elements. An otherwise unknown group of minerals, eudialyte is a zircon silicate consisting of rare earth oxides (REO), contained in a unique mineral structure and represented by a complex chemical formula. Research into extraction and recovery of rare earth elements involves various beneficiation and hydrometallurgical techniques. The goal of beneficiation being to efficiently liberate and upgrade the REO content, followed by hydrometallurgy to extract the desired elements. This overview will discuss previous research on treating eudialyte group minerals via different mineral processing and extraction techniques.

By P. G. Vikre

Several factors have caused less emphasis to be placed on geologic mapping in mineral exploration in the last 15 years. These include opportunities for "easy" discoveries of near surface gold and silver deposits in developed countries, and of base metal deposits as well in less developed countries, a decline of emphasis on geologic mapping in many universities, and a decline of useful mapping by government agencies in many areas. Geologic mapping is simply a way of recording geologic observations on volumes of rock larger than can be seen from one place. Since most geologic processes involve systems larger than this, mapping is also essential to understand the significance of observations made on smaller volumes of rock, such as thin sections and sample taken for chemical or isotopic analysis. To be useful, the observations recorded through geologic mapping are then interpreted to arrive at an understanding of the 3D geometry and geologic history of a volume of rock, which is used to direct mineral exploration, or any number of other purposes.

Jan 1, 1995

By K. N. Han, J. J. Kellar, Y. Guan

The adsorption of zinc species onto silica in ammoniacal solutions was studied. The adsorption isotherms indicated that the adsorption of zinc increased with increasing pH. The adsorption density increased as the zinc equilibrium concentration increased up to =3.5x10-4 M. Above this concentration, the adsorption density was independent of the equilibrium concentration, and a maxima adsorption density was reached. Temperature had no significant effect on the adsorption density.

Jan 1, 1995

By W. H. Stahl

The continuous vacuum filtration is the solid-liquid separation process that is nowadays most frequently used in the beneficiation industry all over the world. After a development time of several decades, the various filter types such as drum filter, disk filter, plate filter and belt filter can be consideres as a sound functional design ensuring a trouble-free operation. Nevertheless, the vacuum filtration does no longer meet the present and future technological requirements. The moisture content of filter cakes is too high. Their thermal secondary drying is too expensive (coal, ores) and may bring about undesirable material changes and the filter cake conditioning with water-binding substances for dumping purposes is too costly.

Jan 1, 1983