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By Fathi Habashi

Extraction by organic solvents is a chemical process in which metal species in the aqueous phase react with an organic reagent to form an organometallic com- plex, thus, the metal species leave the aqueous phase and enter the organic phase from which it can be stripped back in the aqueous phase to obtain a pure and a concentrated solution. The metal in the organic phase is not bound to carbon atoms as in organometallic compounds but to oxygen, nitrogen, sulphur, or hydrogen by a co-ordination (dative) bond (Habashi, 1999).Solvent extraction was used for the first time in hydrometallurgy in connec- tion with the special and urgent materials requirements of nuclear energy during World War II. A plant was constructed in the United States for the preparation of high-purity uranyl nitrate solution. In this plant, the yellow cake (a high-grade sodium or ammonium uranate) was dis- solved in HNO,, and uranium was selec- tively extracted by ether then stripped by water to give a concentrated solution of pure uranyl nitrate. This was gradually followed by developing methods for other high-priced metals such as plutonium, thorium, niobium, tantalum, zirconium, hafnium, boron, beryllium, and molybde num. The second step took place in the 1960s when solvent extraction was applied for the first time to extract a rela- tively cheap metal-copper. At present, solvent extraction technology is wide- spread, well accepted, and highly efficient. Solvent extraction had its origin in the discovery, by Christian Friedrich Bucholz (1770-1818) in 1805, that uranyl

Sep 1, 1999

By Nabeel Khan

Annual oil production from the Canadian Oil Sands in Northern Alberta has been rising for several decades, and more ore and overburden are excavated each year from an increasing number of open pit mines. Overburden meeting certain specifications will be used to dam tailings and fill open pits, but the remaining material must be stored in overburden storage structures (OBSS). Well-designed overburden storage structures are more stable and cost less in the short- and long-term. The purpose of this paper is to explore OBSS designs that will be stable yet economical in the short- and long-term. The geological background of the site is briefly discussed, including the effect of each of the main geologic layers (recently deposited till and muskeg, Clearwater Formation clay shales, McMurray Formation oil sands, and the Devonian limestone) on the slope stability of the OBSS. Cost is considered in the analysis when balancing between minimizing costs (steeper slopes) and acceptable factors of safety (flatter slopes), all the while considering the financial consequences of failure. Potential failure planes are identified and probabilistic analysis is conducted on the critical failure surface. The variations in the factor of safety caused by varying pore water pressure, friction angle, and cohesion, are plotted and discussed.

Jun 1, 2012

By L. W. F. Mackenzie

The influence of rolling temperature and annealing on the recrystallization and texture of magnesium AZ31 has been investigated. 100x125x6 mm AZ31 plate was cast in a permanent steel mould and then homogenized at 380°C. As-cast and homogenized microstructures were then characterized, and 35x30x6 mm specimens were machined from the homogenized material. Specimens were rolled up to 40% at temperatures between 25 and 350°C; selected specimens were subsequently annealed at 400°C. Following rolling, the microstructures were compared. The influence of rolling temperature on as-rolled texture has been demonstrated, and texture evolution has been evaluated following annealing. The recrystallization behavior has also been characterized. Optical microscopy, scanning electron microscopy and electron backscattered diffraction (EBSD) were used to characterize the microstructures of the alloys. X-ray texture analysis was used to investigate the texture in as-rolled and annealed specimens.

Jan 1, 2006

By J S. Kermeen

This paper deals with drilling and blasting techniques at the Phoenix mine, near Grand F1nks, B.C., which is now operated by The Granby Mining Company Ltd. The difficulties of open-pit mining through former underground workings are unique to this operation. Rock types are related to drilling conditions, and the methods used, or contemplated, to overcome the several difficulties are outlined. The equipment used is also mentioned. Finally, blasting techniques and costs are reviewed. Introduction T HE Granby Mining Company operates on open-pit copper mine and concentrator at the site of the original Phoenix mine, near Grand Forks in south-central British Columbia. The pit is a side-hill cut measuring approximately 1,000 by 2,000 ft., and covering a vertical range of from 4,550 to 4,950 feet above sea level. The mill is currently operating at 1,900 tons per day. A 4.5 to 1.0 waste to ore ratio necessitates the removal of some 15,000 tons of ore and waste per working day. Mining conditions at Phoenix are extraordinary in that all the ore zones currently being

Jan 1, 1965

By G. A. Davidson, P. G. Williams

"New developments in centrifugal slurry pump technology are discussed in relation to their importance for improving pump operation and reliability.Experimental data obtained by measuring the velocity of liquid flows in a slurry pump casing using Laser Doppler Velocimetry are presented. This demonstrates the importance of selecting pumps with the proper hydraulic design to provide optimum efficiency, maximum part life and minimum operating cost.The paper also discusses the use of new wear resistant materials, such as ceramic/metal composites, which can significantly improve the life of parts exposed to abrasive media. The results of laboratory attrition tests are presented. IntroductionCentrifugal slurry pumps are of primary importance for the hydro transport of abrasive and corrosive media in the mineral processing industry. As for all process equipment, slurry pumps must be carefully selected and operated to provide optimal performance. To achieve this, it is necessary to select equipment which will provide efficient and reliable operation for the specific service conditions and incorporates the best materials available to obtain maximum parts life.Abrasive wear of liquid end components is the most important aspect that distinguishes the design and application of slurry pumps from other types of pumps. It is therefore necessary to have a fundamental understanding of the mechanical interaction between pump components and the media being handled, as this will impact significantly on hydraulic design, mechanical reliability and selection of wear resistant materials. Recent advances in computational approaches'» have greatly improved the prediction of wear rates in pump casings by facilitating the solution of complex equations which describe the wear mechanisms mathematically. In conjunction with this, new experimental techniques allow researchers to measure flow fields in pump casings using non-invasive devices such as Laser Doppler velocimeters."

Jan 1, 1992

By J. Bensabat, B. Figueiredo, A. Niemi, J. Rutqvist, C. F. Tsang

"A hydro-mechanical model was developed to study the interaction between mechanical deformation and fluid flow in the fault zones during CO2 injection and storage at the Heletz site which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The potential reservoir for CO2 storage at the Heletz site consists of three sand layers separated by lowpermeability shale layers. The potential consequences caused by fault reactivation, focusing on the shortterm integrity of CO2 storage, are evaluated. The difference in the results obtained by considering the three-layer as an equivalent layer storage formation is analyzed.INTRODUCTIONLarge-scale storage of CO2 in deep underground reservoirs may cause considerable pore-pressure perturbation as well as flux migration and concern has been raised over whether shear slip displacements may be induced in nearby faults, as a consequence of their reactivation. A state-of-the-art review can be found in Rutqvist (2012), which describes the various possible effects resulting from CO2 injection into a deep sedimentary basin, including those involved in reservoir stress–strain changes, micro-seismicity, caprock sealing performance, and potential fault reactivation. Moreover, several studies have recently shown how CO2 injection may produce seismic events both on major faults (i.e., large faults with large initial shear offset) (Cappa & Rutqvist, 2011a, b, 2012), and on minor faults that might have gone undetected during the site characterization, e.g., faults less than 1 km long and without detected initial offset (Mazzoldi et al., 2012).The present paper is concerned with the Heletz formation which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The Heletz site located at the southern Mediterranean coastal plain of Israel and the structure is an anticline fold with a crest of about 4 km by 2 km. The structure is gently dipping to the east, truncated by a pinch-out line to the west and subdivided into a number of blocks by transversal normal faults with small displacements. The water table is located at 300 m below the land surface. An areal sketch of the site with the elevation of the caprock and the location of the borehole that has been chosen for the CO2 injection experiment is presented in Figure 1."

Jan 1, 2015

By E. Essadiqi, P. Poruks, D. Boyd, D. Emadi, I. Yakubtsov, T. Turi

This paper reviews the results of an extensive study of microstructures and mechanical properties in bainitic linepipe steels. The research was carried out as a collaborative project between Queen's, Stelco and CANMET. Basic studies of phase transformations and mechanical properties in these steels established important relationships between processing schedule and microstructure evolution, and between final microstructure and mechanical properties. The best combination of strength and toughness properties is obtained with a microstructure comprising a matrix of intragranularly-nucleated bainite (`acicular ferrite - AF') and small (~ 0.5 µm) dispersed particles of martensite (`M/A'). We describe this as a dual-phase AF+M/A microstructure. An experimental study on 15-mm thick plate determined the window of steel composition and processing parameters which gives the dual phase AF+M/A microstructure. The minimum strength and toughness properties for Grade 621 (X90) linepipe steel can be achieved by either a lean steel composition (0.04C-1.77Mn-0.04Cr¬0.32Mo-0.31Ni-0.29Cu-0.08Nb) with extreme processing parameters, or by a higher alloy composition (0.04C-2.07Mn-0.50Cr-0.51Mo-0.04Nb) with a more industrially realistic processing schedule. It is proposed how this approach could be extended to obtain higher strength linepipe grades.

Jan 1, 2005

By Benoit Taillon

Contenu de la presentation 1. Le projet QMM et son contexte 2. Gérer la biodiversité 3. Résultats obtenus QMM QIT Madagascar Minerals S.A. ? JV: Rio Tinto (80%) et Madagascar (20%) ? Trois gisements: Mandena (en cours d?exploitation), Ste-Luce et Petriky (total 6000 ha) ? CapEx : USD 940M (Installations minières + port, énergie, routes, logement, écoles, cliniques, etc.) ? Technique par dragage des sables minéralisés et de concentration de l?ilménite (FeTi02) ? Exportation de l?ilménite pour son traitement.

May 1, 2011

By D. M. Baird

Copper mineralization occurs at several places along the shore of Notre Dame bay, Newfoundland, and at one time formed the basis of a considerable mining industry. The sources of the mineralizing solutions and the structural settings of some of the deposits have not been clearly understood. This paper reports new investigations into the origin and structure of the deposits between Bett's cove and Stocking harbour, in a strip about ten miles long and two miles wide along the western shore of Notre Dame bay. The most complete previous descriptions of the area are those of Snelgrove (1929, 1931, 1938), Douglas, Williams and Rove (1940), and the writer (1947). The discovery of the Bett's Cove deposits took place about 1860, soon after the discovery of the well-known Tilt Cove deposits to the north. Several other small prospects were found between Bett's cove and Stocking harbour between 1880 and 1910. At Bett's cove, active mining began in 1875 and a small smelting plant was built near the mine in 1877. .Mining operations came to an abrupt halt in 1883 after a major cave-in. In 1900, and again in 1906, attempts were made to drain the old workings and reopen the mine but were abandoned long before completion. Total production amounted to about 130,000 tons of hand-picked copper ore which averaged about ten per cent copper, and 2,450 tons of pyrite (Snelgrove, 1938, pp. 52-55).

Jan 1, 1948

By F. J. Alcock

The Appalachian region of Canada comprises the three maritime provinces; Nova Scotia; New Brunswick; and Prince Edward Island; and that; part of the Province of Quebec lying south and east of Logan's fault. This; major thrust runs in a gently curving line from lake Champlain to Quebec; city and thence down the valley of the St. Lawrence to pass between Anticosti; island and Gaspe peninsula. To the northwest lies the St. Lawrence; Lowland division of the Interior Plains geological province; a region underlain; largely by early Palxozoic strata; which for the most part lie horizontal; or with low dips; where faults occur they are predominantly of the normal; type; and only locally are the beds cut by intrusive rocks. To the southeast; on the other side of the fault zone; an entirely different set of conditions is; encountered. There; Lower Devonian and older strata stand at high angles; are sheared and thrust faulted; and are intruded in many places by granitic; igneous bodies. The present paper is designed to outline briefly the geological; and structural history of this geological province and to emphasize; the part that structural conditions have played in connection with mineral; deposition.

Jan 1, 1954

By Garth D. Kirkham

The Problem The Don deposit is a series of two sub-vertical zones that pose a number of challenges with respect to modeling and interpolation. The first challenge is that, based on data and observations, the mineralization and, more importantly, the grade is layered or banded and is stratigraphically controlled. The second challenge is that, due to the undulations of the deposit and extreme changes in dip, using a standard oriented ellipse to guide the estimation process is not appropriate and does not result in an estimate that is representative on a local scale. In order to solve this problem an adapted methodology of relative elevation modelling, has been devised to effectively model and estimate deposits faced with these challenges. Relative Elevation Designed for bedded seam and gridded surface With variable dip and vertical grade variability

May 1, 2013

By Oberlando Gonzalez, Claudia Serna, Andrea Alzate, Esperanza López, Maria Holuszko

This paper presents a systematic approach on gold recovery from electronic waste (e-waste) using ammonium persulfate. This process was developed as a response to the lack of hydrometallurgical systems capable of separating gold from its metallic substrate without material grinding, with minimum formation of pollutants, and achieving a lower reaction time. Computer memory boards, electronic processors and electronic pins and contacts were analyzed to determinate base metals (Ni, Fe, Cu) and gold (Au) using microwave plasma atomic emission spectroscopy (MP-AES). An aqueous commercial grade ammonium persulfate with oxygen and pressure was used to produce the persulfate anion (S2O82-) and the oxidative sulfate ion (SO42-), which partially oxidized and leached the base metals breaking the Au-Ni-Fe-Cu bonds and allowing gold to be recovered in its original non-leaching state. The influence of the oxidative parameters was evaluated using full factorial (FF) and central composite designs (CCD) with response surface methodology (RSM) and first and second order models were developed. Using RSM allowed to obtain a faster recovery of gold, minimizing the agent consumption. The findings presented suggest that optimized quantities of ammonium persulfate, oxygen, pressure, temperature and liquid solid ratio could be used for selective oxidization of the base metals and to extract more than 96% of gold from e-waste.

Jan 1, 2017

By V. Schwinn, P. Fluess, N. Cauderlier, J. Bauer

From a strategic and economic point of view, the development of fine grain high strength steels for long distance pipelines is intensified world wide to satisfy the demand for natural gas in the future.The project related property profiles based on strength, toughness, crack arrest and sometimes resistance against HIC at defined design temperatures require an effective structural refinement using advanced steelmaking and processing in the rolling mill. The microstructure of modern line pipe steels ranges from ferritic pearlitic to ferritic-bainitic and structures where bainite is the dominant component, possibly upgraded by secondary phases. This paper illustrates microstructures and properties of recent orders on line pipe steels both for onshore and offshore application using different processing routes in the plate mill. Examples will be given for SAWL 485 offshore grades, X65 HIC and X70 HIC onshore grades, respectively. Finally, production results of a recent X80 order will be presented.

Jan 1, 2005

By Suzie Poulin, N. Geoffroy, G. P. Demopoulos

Most metallurgical industries generate toxic waste that must be treated prior to being released to the environment. However, in a lot of cases, the waste materials are poorly characterized or the analytical results are not well interpreted. These shortcomings often result in the development of inefficient industrial procedures, thus causing economic waste and difficulty meeting environmental regulations. Fortunately, a wide range of analytical techniques are available to guide researchers and engineers into making sound process development decisions. In this work, an industrial selenium and mercury removal process is used as an example to illustrate the application of X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) coupled with Energy-dispersive X-ray spectroscopy (EDX) and powder X-ray diffraction (PXRD) on solid waste. Furthermore, samples of analytical results are presented and interpreted and the modifications to the industrial process that resulted are explained. Finally, a brief description of the advantages and limitations of the aforementioned analytical techniques is given with an emphasis on industrial solid waste material.

Jan 1, 2011

By B. D. Frater

Geometallurgy or process mineralogy is an integrated part of the scoping, pre-feasibility and feasibility phases of a project as well as an existing operation. A well planned and executed geometallurgical testwork programme during the early phases, will result in a more accurate decision making process during the selection phase. The better this integration between geological, mining and metallurgical data gathering during the early phases, the more accurate the predictions will be with regards to throughput and recovery during modelling and process and equipment selection in later phases. This will enhance and improve the mine and process scheduling and subsequent NPV. Geometallurgical information gathered during plant operation and testwork can for example be used to statistically model the pit optimisation, plant throughput and optimise the plant for certain feed material (characterised by statistical models).

Jan 1, 2017

By B. Skrotzki, E. Augenstein, C. Rockenhäuser

"The aluminium alloy 2618A is an Al-Cu-Mg alloy with additions of Fe and Ni, which is designed for long-term operation at elevated temperature in transportation and aerospace industries. The alloy degrades due to coarsening and dissolution of GPB zones and coarsening of S-Phase precipitates (Al2CuMg). This work investigates the overageing process at the application relevant temperatures of 190 °C for durations ranging up to 25,000 h. The nm-sized precipitates were selectively imaged along the <001>a direction of the Al matrix using dark-field transmission electron microscopy. The resulting images were then evaluated and allow the statistically relevant determination of radii distributions and the average radius of the precipitates dependent on temperature and heat treatment duration. Ostwald ripening of the S-phase does not describe the ageing process adequately. Instead, the evolution of GPB zones during the initial ageing regime needs to be considered in addition to the coarsening process of the S-phase. DSC measurements were performed to determine the presence of GPB zones in different ageing states. This will allow a quantitative description of the ageing process and a comparison to samples aged under external load.INTRODUCTION Alloy 2618A is an Al-Cu-Mg alloy, which is part of the 2XXX series of aluminium alloys. It is used in aerospace and transportation industry due to its desirable material properties for long term operation at elevated temperatures (Polmear, 2006). Fe and Ni are added to form intermetallic compounds, which retain microstructural stability at elevated temperatures (Bergsma, Li, & Kassner, 1996; Elgallad, Shen, Zhang, & Chen, 2014; Oguocha, Yannacopoulos, & Jin, 1996; Wang & Yi, 2006). The size and distribution of the nm-sized S-phase formed from the supersaturated solid solution (SSSS) during heat treatments mainly controls the strength (Khan, Starink, & Yan, 2008; Liu, Zhang, Ding, Sun, & Chen, 2003; Parel, Wang, & Starink, 2010; Shih, Ho, & Huang, 1996; Wang, Starink, & Gao, 2006). The S-phase has the composition Al2CuMg and is orthorhombic under equilibrium conditions (Heying, Hoffmann, & Pottgen, 2005; Perlitz & Westgren, 1943). Early experiments proposed the following decomposition of the S-phase sequence during heat treatments (Hardy & Heal, 1954; Silcock, 1961):"

Jan 1, 2018

By M. M. C Jiménez, J. A. S Ténorio

For the recovery of valuable materials and for the protection of environment, recycling process of printed circuit board is an important subject of study. Moreover, the popularization of the computers and its technological evolution has generated a large number of waste electrical and electronic equipment. This paper presents a study of synergistic solvent extraction of copper, nickel and zinc from a sulfuric leaching liquor of printed circuit boards (PCB’s). The percent extraction of copper, nickel and zinc from dilute aqueous sulfate media besides synergistic effect of mixture of the .extractants Cyanex 272 and D2EHPA have been studied. Furthermore, different conditions such as temperature, pH of the feed solution have been examined. The results suggest that the synergistic effect of the .extractants mixture enhance the extraction efficiency of nickel.

Jan 1, 2014

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By E. Ghali, W. Zhang, M. Robichaud, G. Houlachi

"The performances of six mesh and one plate dimensionally stable anodes have been investigated in the zinc electrolyte at 38oC and compared to conventional silver-lead alloy anodes. The electrochemical behaviour of these anodes was studied by cyclic voltammetry, galvanostatic, potentiodynamic, open circuit potential and electrochemical noise measurements. It was observed that at the end of 24 h of galvanostatic polarization at a current density of 50 mA/cm2 in the zinc electrolyte at 38oC, the mesh V had the lowest potential followed by mesh III, mesh VI, plate-V, mesh IV, mesh I, and mesh II electrode. When the potentials for mesh I, mesh III, mesh IV, VI and plate-V, mesh V were compared with that of the Pb-0.7%Ag anode (1920 mV/SHE), they were found to be 6%, 16%, 7% 10%, 17% lower, respectively.After 16 h decay following the 24 h polarization, the mesh III had the lowest corrosion rate (51 mS/cm2) among the seven specimens, followed by the plate-V, mesh V, VI, IV, I and II (221 mS/cm2). For the fresh surface as received, after two hour open circuit potential measurements, mesh I had the most positive (noble) potential (1382 mV/SHE) among the seven electrodes followed by the plate-V electrode, mesh V, mesh IV, mesh VI, mesh III and mesh II (751 mV/SHE). After consecutive series of electrochemical testing, mesh V, mesh III, mesh VI had lower corrosion rates (~ 343± 6 µA/cm2) than that of mesh IV, mesh I, plate-V, and mesh II (~ 644± 143 µA/cm2).INTRODUCTIONThe continued use of lead based anodes in the electrowinning process has been mainly due to their relatively low cost as compared to other materials (Msindo, Sibanda, & Potgieter, 2010). They have good electrical conductivity, stability during electrolysis, very good corrosion and wear resistance (Ivanov, Stefanov, Noncheva, Petrova, Dobrev, Mirkova, Vermeersch, & Damaerel, 2010). However, lead-based anodes give their high energy consumption and low corrosion resistance for electrowinning. To overcome these problems, Dimensionally Stable Anodes (DSAs) has been chosen (Msindo et al., 2010). Comparing to the traditional lead anodes, the DSA anodes have many advantages: (1) no contamination; (2) no loss of anode material, pure electrolyte; (3) lower gas bubble effect through special anode designs; (4) use of higher current densities (Msindo et al., 2010). The success of DSA anodes has been attributed to their chemical stability that allows them to maintain nearly constant dimensions during the life of the anode even when operating in environment with low pH values. Due to their stability, the consumption rates of DSA are as low as 1 mg/amp.y (Alfantazi & Moskalyk, 2003)."

Jan 1, 2016

To date, improved thickening of clay mineral dispersions presents major technological and environmental challenge to mining and mineral processing industry worldwide. Flocculant-assisted dewatering processes currently employed during thickening are far from being efficient, requiring further development and process optimisation for dramatic improvement. In this paper, recent studies carried out to modify (i) pulp chemistry, (ii) flocculation performance and (iii) particle interactions to significantly improve the dewatering behaviour of flocculated, model and plant smectite and kaolinite clay dispersions are presented. It is shown that pulp pH-mediated hydrolyzable metal ion hydrolysis and specific adsorption in tandem with high molecular weight flocculant and shear may synergistically act to significantly enhance the dewaterability of both clay mineral pulps. Furthermore, polymeric flocculant structure type is demonstrated to show clear links with floc shear sensitivity, and hence, flocculation performance and pulp dewaterability. The implications and relevance of the findings plant clay mineral waste tailings thickening operations are drawn.

Jan 1, 2006