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By M. J. King, D. A. Van den berg, R. Fukuzawa

"Mercury bearing ore bodies are often treated for the production of copper, lead, zinc, gold, and silver. The mercury deports either to tailings or is collected during various stages of the extraction process. This paper reviews the relationship between various mercury collection processes and the subsequent management of the mercury by-product or waste. It focuses on mercury removal sequestration including cementation, sulphide precipitation, bulk neutralization, and carbon adsorption. Long term mercury management strategies including third-party stabilization, stabilized mercury co-disposal, secure storage, and mercury recycle are also evaluated. INTRODUCTIONMercury is produced in North America as a by-product of non-ferrous metals processing and from recycling of products such as dental amalgam, fluorescent lamps, and thermometers. Its toxicity is recognized to have significant negative impacts on the environment and human health. As a result, many countries are adopting regulations limiting mercury use and its uncontrolled release.The European Union banned mercury exports in 2011 and the United States will do so in 2013. The export bans aim to prevent mercury use in developing countries for activities such as artisanal small scale gold mining. However, by-product mercury production from the non-ferrous metals industries continues.These factors contribute to an oversupply of mercury and the need to find suitable treatment methods for the long term management and storage of mercury and mercury bearing materials."

Jan 1, 2012

By A. Varma

Successful technology commercialization occurs when a company is focused on creating shareholder value by providing a reliable product at a price point attractive to the market, while at the same time maintaining strict control of its internal cash burn rates. Developing a technology platform and a market platform are equally important in the commercialization of new technologies such as fuel cells. This paper will discuss some of the key barriers that may prevent successful market entry for emerging and disruptive technologies, such as: R&D priorities, supply chain / manufacturing issues, materials, cost reduction strategies, customer needs, developing a market pull strategy, institutional barriers such as existing regulatory/approvals processes and/or current design/purchasing practices, product reliability and resilience, and finding the right path to market. SDTC is an arms length foundation that aims to financially support the successful market entry of emerging and disruptive technologies that can provide significant environmental benefits to Canada. The fuel cell industry, which represents one such technology, is at a critical point in its evolution where market receptivity and the technology platform are converging to potentially create significant customer advantages for fuel cell products being developed today. Since its inception in 2001, SDTC has received over 850 business cases from which it has identified successful strategies to overcome the noted barriers to commercialization. While maintaining commercial confidentiality, the SDTC database will be mined to: Identify specific success stories that have overcome various barriers and discuss their strategy; Identify specific fuel cell related industry experiences that hinder successful market uptake. The general attributes and trends of successful technology developments identified in this paper will hopefully provide guidance to technology developers and prepare them to successfully tackle the next set of hurdles on the path to commercializing their technology, once they have proven their technology works in the laboratory.

Jan 1, 2005

By H. W. Manley

SULPHUR, like the minerals of coal, iron and petroleum, is one of the essential materials in our modern expanding industrial civilization. Before discussing the salient features of the production of sulphur from the Canadian sour gas, it seems appropriate to outline the historical past and probable future utilization of sulphur. The ancient Greek writer Homer spoke of its "pest-averting sulphur" and the "divine purifying fumigation". Ancient alchemists found sulphur to be a fascinating and baffling material. The discovery of gun powder in the year of 1250, and its application to the art of war a, century later, made sulphur an important commodity in the progress of mankind. The initial manufacture of sulphuric acid in the year of 1736 by the Englishman Joshua Ward, established the basis of a chemical industry that today utilizes 80 per cent of the consumption of elemental sulphur. Commercial production of the chemical soda ash ( N a2C03) discovered in 1787 by the famous Leblanc Process, in-creased international demand for the element sulphur and marks the birthday of the Sicilian sulphur industry.

Jan 1, 1961

By William D. Gallant, Thomas M. Barczak, Carol Tasillo

"This paper describes the results of full-scale testing of several multi-layered wood crib configurations that were tested in the Bureau of Mines mine roof simulator in cooperation with the Cape Breton Coal Research Laboratory and Cape Breton Development Corporation of Sydney, Nova Scotia. Nine different crib configurations currently being used as wood packwall supports for advancing longwall applications in Canada were evaluated. Configuration parameters understudy included the aspect ratio (height-to-width relationship) and percentage of solid material used in the crib construction. Test results and generalized wood crib behaviour are discussed in detail. Recommendations are made concerning crib constructions to maximize strength and stability. A cost benefit analysis of multi-layered wood crib configurations is made. A comparison of laboratory results and underground observations of several wood packwall supports in the Sydney coalfield suggest in situ load capacity is less than that measured in laboratory testing. Reasons for the apparent decrease of in situ load bearing capability are described.IntroductionA cooperative effort was undertaken by the U.S. Bureau of Mines with the Cape Breton Development Corporation (CBDC) and the Cape Breton Coal Research Laboratory (CBCRL) to evaluate the behaviour of gateside packing materials used in advancing longwall mining applications in the Sydney coalfield. As part of this effort, full-scale tests were conducted on wood packwall supports in the Bureau's 3-million pound (13.3 MN) active load frame.Nine different pack configurations were evaluated as part of this study. The wood packwall supports were multi-layered crib constructions from 6 in. (0.15 m) by 6 in. (0.15 m) cross section timbers using timber s 30 in. (0.75 m) and 60 in. (1.5 m) in length . The percentage of solid material in the crib constructions varied as illustrated in Figures 1 and 2. A summary of crib constructions is provided in Table 1."

Jan 1, 1991

By N. M. Steven, J. M. Moore, J. L. Kuyper

Abstract - Mineral exploration and research has led to the identification of four types of tungsten mineralization in the NE-trending, largely ensialic, inland branch of the late Proterozoic/early Paleozoic Pan-African Damara Orogen. The mineralization (mainly scheelite) occurs in a terrane (the Central Zone) that is characterized by multiple deformation, greenschist/amphibolite-facies metamorphism and numerous peraluminous S-type granitic and pegmatitic intrusions. The four major types of scheelite mineralization are (in ascending stratigraphie order of host rock): (1) thin (5 cm to 2 meter) quartz+ plagioclase+ diopside ± scapolite cale-silicate granofels with finely disseminated scheelite (scheelite-bearing granofels; SBG) developed as discontinuous intercalations within the cale-silicate rocks of the Khan, Spes Bona, Oberwasser and Kuiseb Formations (Nosib and Swakop Groups); garnet+ pyroxene ± vesuvianite + scheelite ± fluorite replacement skarns hosted by Okawayo, Karibib and lower Kuiseb Formation marbles in the aureoles of late tectonic, unmineralized leucogranites; metaturbidite-hosted scheelite- (and possibly wolfrarnite-) bearing tourmalinites, both stratiform and crosscutting, in the Kuiseb Formation located in the 'cleavage fronts' of late tectonic granitoids; scheelite-bearing vesuvianite +quartz+ garnet skarnoid rocks (several hundred meters in length) in the calcareous metaturbidites of the upper Kuiseb Formation. These scheelite occurrences were discovered by the follow-up of a large number of tungsten anomalies located during a regional stream sediment sampling program. Detailed mapping, ultra-violet surveys and rock sampling proved to be the most effective surface exploration techniques for locating mineralization; soil sampling and geophysics were of almost no use. The largest, continuous scheelite-bearing skarn of economic interest, Otjua, has a drill-indicated reserve of 250 000 tonnes at 0.53 wt% W03 and 8 wt% CaF2.

Jan 1, 1994

By D. Moronkeji, R. Maharidge, D. A. Curry, B. J. Davis, U. Prasad, J. Franquet

"Proper shale characterization is crucial in shale gas drilling, exploration, completion and production. Unlike porous sandstone and carbonate reservoirs, the challenge with shales comes from their micro- to nano-darcy permeability ranges and the anisotropy of their mechanical and hydraulic properties. Most porosity-dependent logs are not sensitive enough to capture the true behavior of shales. Consequently, mineralogy and other strength and stiffness-related properties must be determined to characterize magnitudes and variances in shale mechanical and flow properties. In addition, these properties must pass quality assurance/quality control (QA/QC) practices to give confidence in their use in subsequent log calibrations, during geomechanical modeling, or in fracture design models. This paper presents a technique to integrate shale properties that are measured by various methods, and a methodology to perform QA/QC on the data before application.Shale properties originate from various sources, including downhole and laboratory measurements. Physical samples for laboratory testing are usually limited to a few depths. Lab tests are often costly, and replicating in-situ conditions can be difficult or impossible. In addition, results frequently show wide scatter, reflecting inherent depth variability and lateral heterogeneity. Wireline logs provide nearcontinuous data, but rarely yield direct measurements of rock strength properties. Although geomechanical and fracture models use log data, calibrating it with reliable and previously verified lab-measured properties is important. This paper presents a process to perform QA/QC on lab-measured data using various crossplots.Ten mechanical, microstructural and physical properties are graphically displayed to visually characterize shale strength behavior in ambient and in-situ conditions, whether measured or modeled statically or dynamically. These properties are often sourced from different departments. The properties are integrated but are individually subject to the previously mentioned uncertainties. Pairs of property values are crossplotted and compared with correlations from the literature or previously established with qualified data from related formations. Conformance with these correlations gives confidence in the data, whereas outliers are flagged as questionable. Repeating the process with questionable data crossplotted against other parameters for the same depth highlights the property with the greatest uncertainty. The determination of its value is investigated to locate the source of the inconsistency and establish a more reliable value. Where this is not possible, the user has a rational basis for rejecting that property value."

Jan 1, 2015

By P. E. Fox, R. S. Cameron

"The QR gold deposit lies in the Cariboo plateau region of central British Columbia. The deposit was discovered in 1977 and since then a mineable reserve of 1.3 million tonnes grading 4.7 g/t Au has' been outlined in three separate zones. Soil sampling of glacial tills followed by diamond drilling of favourable host rocks proved to be key exploration techniques.The deposit is situated in the southern Quesnel terrane along the eastern fringe of the Intermontane Belt which here comprises a sequence of basic and intermediate volcanics and a series of stocks of alkaline affinity; generally diorite, monzonite and syenite. Hornfels and epidote-rich ferromagnesian exoskarn and sulphide-rich mantos have developed in a metamorphic aureole formed around a central diorite stock. Gold-rich zones lie along the outer periphery of the aureole where bodies of gold-bearing epidote-rich skarn and auriferous mantos rich in epidote and pyrite have formed in beds of calcareous tuffite lying at the top of a thick basaltic sequence. The deposit is regarded as' a subclass of gold skarn deposits. Diagnostic features are its association with alkalic intrusive rocks in a subvolcanic setting and the presence of oxidized, epidote-rich mineral assemblages.IntroductionThe QR gold deposit lies within the Cariboo plateau region of central British Columbia, 58 km southeast of Quesnel. The deposit, owned by Kinross Gold, was discovered during a regional reconnaissance program by Dome Exploration (Canada) Limited and Newconex Canadian Exploration in 1977. Considerable exploration and development has been done since that time. Mineable reserves of 1.3 million tonnes grading 4.7 g/t Au have been outlined to date in three zones."

Jan 1, 1995

By Lucien Piché

"IN any opportunity such as I am now given, I suppose that one should not fail to say that what the world has to offer to this year's graduates in science and in engineering is the greatest promise ever held out. High-ranking new scientists and engineers -particularly those with the Ph.D. degree -find themselves in an apparently delightful situation; the glow of attention that surrounds them and the dazzling starting salaries that are offered to them may indeed be turning their heads a bit and the attitudes of some of them are sometimes expressed with a smugness that can find its equivalent only in freshmen. On the average, however, the new graduates are, without any doubt, the best trained ever, or at least they have been the most expensive to train in the universities.There appear to be exciting opportunities for competent, well-trained and educated scientists and engineers far beyond the numbers that can be annually produced, and the demands for excellence in depth as well as in breadth of training probably will continue to increase for many years to come. The problem is visible all around us in Canada that there is much more money to buy brains than there are brains to be bought."

Jan 1, 1966

By Shuji Owada

Scrap electrical and electronic appliances, so called "E-waste", are not a present target to be collected and recycled under Japanese regulations. This material, however, contains considerable amounts of base, precious, and rare metals and it is necessary to recover these elements for maintaining stable supply and establishing "the society of environmentally-sound material-cycle". This paper describes recent trends of rare metals recycling in Japan and technological approaches to achieve the above objective. Also a research work to concentrate rare metals from the printed wiring boards by combining brand new comminution and physical separation methods is discussed.

Jan 1, 2011

By D. Campbell

Mining activity is increasing in northern boreal and subarctic regions of Canada. This is the case in the far north of Ontario, especially in and near the Hudson Bay Lowland (HBL). De Beers Canada opened the Victor diamond mine in the centre of the HBL in 2008, and advanced exploration and impact assessments are occurring to the west in the ?Ring of Fire? for ferrochrome, nickel/copper, iron/ vanadium and platinum-group elements, making it one of the richest mineral finds in Canada in recent years. However, the HBL is also a near-pristine, sensitive environment. Its peatlands forms the third largest wetland in the world and are globally important stores of terrestrial carbon. Human populations in the region are sparse, consisting almost entirely of First Nations communities. Local First Nations also have a strong land ethic and greatly influence mining developments. Through formal agreements, they have insisted on a gold standard for environmental management, including a small mine footprint and the return to representative native ecosystems after mine closure. However, knowledge on the revegetation of subarctic and northern boreal ecosystems is limited. Here, we are conducting research at the Victor mine to develop gold standard protocols for the revegetation of disturbed peatlands and mine waste uplands and present a summary of results. We first tested existing protocols for peatland restoration from southeastern Canada. We collected peat-forming plants from nearby muskeg, spread them sparsely over disturbed peatlands and applied a light phosphate fertilizer, but unlike southern protocols, no mulch appeared to be required to produce a representative cover of peat-forming plants within three years. A bigger challenge is the reclamation of uplands made of mine waste back to representative ecosystems. We first characterized reference conditions for uplands in the HBL, which are scarce in the region. Nearby natural uplands were divided into two classes, interior uplands and uplands along river valleys. Multiple parameters were examined at these sites including soil development, bulk density, soil chemistry in the rooting horizons, plant cover by stratum, plant species composition and dead wood. The mean condition and, more importantly, the range of these parameters allow us to set broad targets for progressive reclamation, which will facilitate success. Finally, we characterized local upland plant species through their functional traits to determine their likely abilities to colonize, grow and contribute to ecosystem processes. A classification of species by these simple functional attributes will help restoration managers to select candidate species to meet different goals at different successional stages (i.e. good versus poor dispersers or establishers). Research into these protocols remain in the early stages, but show promise that gold standards can be achieved to ensure that mining wastes can be reclaimed to productive ecosystems.

Aug 1, 2013

By J. G. Whellock, J. W. Matousek

"In spite of their importance to the economics of many metallurgical projects, the values and technical aspects of precious metals losses in smelting operations are relatively undeveloped subjects. This paper attempts to provide a condensed overview of precious metals losses in pyrometallurgy, using some of the limited production and experimental data available. It is intended for three general groups of metallurgists - operators attempting to improve recoveries, cost-accounting engineers making estimates of metal losses in new or modified smelting plants, and research engineers and students.Distribution coefficients of precious metals, the ratios of metal or matte assays to slag assays, are convenient means of comparing smelting processes and the tendencies of the different metals to enter the slag. For silver in lead blast furnaces this ratio is approximately 250;for gold and the platinum group metals in submerged-arc, electric furnaces it is 900. The ratio for gold and PGMs in converters varies with the degree of oxidation of the charge. The over-all cycle-average for industrial installations is tentatively estimated to be 35.IntroductionThe magnitude of precious metal s losses in pyrometallurgical operation s is difficult to assess. The primary producers are generally reluctant to discuss the subject. The by-product producers (the large sulphide smelters o f copper , nickel, and lead) might be more willing to disclose information, but these have precious metals in their feeds in such dilute quantities that accurate accounting is extremely difficult. It is not until numerous processing steps have been taken t hat the precious metals become sufficiently concentrated to permit acceptably accurate sampling and analytical procedures to be followed. Thus, knowledge of the precious metals contents o f the intermediate mattes and slags may simply be unavailable."

Jan 1, 1990

By Jochen Petersen

This paper gives an overview of the various strands of postgraduate and undergraduate training offered in the Department of Chemical Engineering at UCT. Since 2003 the Department is offering a formal postgraduate MSc programme in hydrometallurgical engineering aimed especially at graduate work-based engineers, with 5 weeks of intensive course work plus a research dissertation on a work-related project. This programme has now run 5 times over the years and produced some 20 degrees. The paper reflects on the experiences with running the course, especially the difficulties experienced with supervising industry-based external students. Furthermore, through the Department a graduate training program is offered for all junior metallurgists at a major South African minerals company. This 2-year program, which is currently on its 12th cohort, offers 1 or 2 week intensive blocks of course work alternating with longer stints where the candidates are based at various operations. Although primarily focussed on minerals processing, it has a significant element of hydrometallurgy in it and in recent years an advanced hydrometallurgy stream has been introduced. The paper reflects on the development of the program over the years, the benefits it has provided to the company as well as some of the challenges that remain. Finally the paper gives an overview of hydrometallurgy related undergraduate and research-only postgraduate MSc and PhD projects at the university. Some emphasis is placed on the recently launched South African Minerals and Metals Research Initiative (SAMMRI), a joint government-industry programme to support university-based research in the area of applied metallurgy.

Jan 1, 2014

By J. Illescas, N. C. Murray

This paper provides an economic comparison and technical evaluation of different approaches for copper recovery from small-scale resources such as historic tails, dumps, pond and pit water as well as acid mine/rock drainage. Factors such as the location, the availability and cost of reagents, power availability and cost and a local market for end product alter the preferred processing technique. A number of scenarios are presented and technologies considered include; solvent extraction, ion exchange, sulphide precipitation, cementation, copper sulphate crystallization, membrane (RO) and copper cathode production.

Jan 1, 2014

By J. H. Ambrose

Introduction The copper smelter of the Hudson Bay Mining and Smelting Company, Limited was constructed to handle the concentrates produced by the concentrator, the residues from the zinc plant, concentrates from Sherritt-Gordon Mines, Limited, and other custom material that might be available. Construction work was started in 1929 and the first concentrates were smelted in November, 1930. From that time until June, 1931, the operations were more or less of an experimental or tuning-up nature. In designing the smelter, it was believed the following tonnages would be available for smelting per day: Copper Tons Content H. B. M. & S. Co. concentrates 331 14.0 per cent H. B. M. & S. Co. zinc plant residues 77 2.5 per cent Sherritt-Gordon concentrates 200 20.0+ per cent Consideration was given to wet-smelting the charge, but, in order to give greater flexibility to the operation, it was finally decided to roast the concentrates before smelting. Briefly, the smelter equipment consists of three Nichols-Herreshoff roasters, one reverberatory furnace, two Peirce-Smith converters, a Walker casting wheel, and a four-unit Cottrell plant, two units' for the roaster gases and two for the converter gases. A general plan of the smelter is shown in Figure 1. Prior to the commencement of smelter operations, a stockpile of about 9,000 tons of concentrates had been built up by the concentrator and the old pilot-mill. The zinc plant was in operation, but the equipment for drying the residues at the smelter had not been completed. Sherritt-Gordon did not commence their shipments of concentrates until April, 1931. The only flux available was barren sand from a pit ten miles south of Flin Flon, adjacent to the railway. Several small deposits of metal-bearing siliceous ore had been discovered in the district, but none of these were sufficiently large to be considered as a source of smelter flux. At the beginning of March, 1931, the entire stockpile of concentrates had been consumed, and available tonnage for smelting was limited to the daily production of the concentrator.

Jan 1, 1935

By G. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment. The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate. The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By Mohamad Sabsabi, André Hamel, André Moreau, Paul Bouchard

"Laser-Induced Breakdown Spectroscopy (LIBS) is an atomic spectroscopy technique used to measure elemental concentrations. It is well-adapted to in-situ and in-line measurements during materials processing in general, and pyrometallurgy in particular. It is an optical non-contact technique and it can measure nearly all elements, including light elements. Our group has developed a mobile prototype system to measure molten metals. The system includes a tube, also called a lance, one end of which is immersed in the molten metal. An inert gas flows in the tube and bubbles out below the surface. The LIBS measurement is made through the tube and onto the bubble’s surface. This is done to avoid measuring contaminants, slag, or fluxes often found at the surface of the melt. An added benefit is that the molten surface is constantly renewed and thus, more representative of the bulk. An alternative to using our lance is to use a tuyère, such as a gas injection tuyère in a converter, as we did several years ago in a nickel matte converter. In this presentation, we will show various applications emphasizing more recent developments. This includes the simultaneous measurement of the concentrations of Cu, Ni, Fe, Co and S in molten matte at 1125 °C. The more obvious industrial applications of the technology include determining the best time to end oxygen blowing in the converter and elemental concentration measurement during alloying.INTRODUCTIONThe mining industry continually faces challenges in optimizing cost and productivity. Because of the large volumes of materials that are being processed, small improvement can have a big impact on benefits. Better real-time information can help improve this optimization."

Jan 1, 2016

By V. L. Mitsopoulos

This paper provides a summary of tailings disposal techniques and the improvements that have been made through the introduction of thickened tailings disposal. The general properties and characteristics of thickened tailings are described, as is a design process for selecting appropriate technologies for thickening, pumping, transporting and storing tailings. The factors affecting the selection of an appropriate disposal site and operational considerations for the effective utilisation of tailings storage areas are also documented.

Jan 1, 2006

By A. M. Cann, C. I. Godwin

"The Kemess porphyry copper-molybdenum deposit occurs in the Intermontane Belt of north-central British Columbia. The deposit is in andesitic to basaltic flows and tuffs which may be correlated with the Savage Mountain Formation of the Upper Triassic Takla Group. Most known chalcopyrite and molybdenite is associated closely with a 500-m-diameter zone of intense quartz-sericite-pyrite alteration. A zone of supergene enrichment, up to 30 m thick, underlies a leached capping about 20 m thick. The age of mineralization and the surrounding granodiorite and quartz monzonite pluton is Early Jurassic. K-Ar and Rb-Sr analyses indicate that the mineralization and alteration is slightly younger (l82±6 Ma) than the granitic intrusion (KAr: about 205±6 Ma; Rb-Sr: 190±4 Ma). The low 87Sr/J6Sr initial ratio for the granodiorite is typical of plutons in the Intermontane Belt.IntroductionKemess is a medium to small porphyry copper-molybdenum deposit with significant gold and silver values (Pilcher and McDougall, 1976). This paper describes the lithologies and alteration at this property; geochronology by Rb-Sr and K-Ar methods defines the ages of mineralization and surrounding plutons to be Early Jurassic.The property, located in the Thutade Lake area of northcentral British Columbia (NTS Map 94E; lat. 57°04'N; long. 126°44'W), is about 425 km northwest of Prince George (Fig. 1). Closest road access is 35 km southeast of Kemess. Final access must be by float plane or helicopter. The British Columbia Railway right of way passes 70 km to the southwest of theproperty.A prominent gossan zone at Kemess was staked in 1967 by Kennco Explorations (Western) Ltd. following detection of geochemical anomalies during stream sampling the previous year. During 1968, 1969and 1971, Kennco completed 232 m of X-ray diamond drilling, conducted geological mapping and carried out geochemical sampling of silts and soils (Stevenson, 1969; B.C. Ministry of Energy, Mines and Petroleum Resources, G.E .M., 1969 and 1971). Getty Mines Ltd. optioned Kemess in 1975and 1976. They remapped the area and diamond drilled 12 BQ and NQ holes, totalling 2065 m (B.C. Ministry of Energy, Mines and Petroleum Resources, Expl. B.C., 1975)."

Jan 1, 1980

By B. C. Jago, H. Derbuch

"The Freightrain kimberlite is located on the Brodeur Peninsula, Baffin Island, Nunavut. Twin Mining is exploring the pipe and adjacent land (79 claims/655 km2) using a combination of airborne geophysics, soil sampling, diamond drilling, trenching and bulk sample processing. The pipe originally was discovered by Cominco Limited in 1975, re-evaluated in 1993 by Lumina Investment Corporation, when it was staked as the Zulu pipe, and subsequently covered by three claims in 1998 by Helix Resources who called it Freightrain.The Freightrain pipe coincides with a strong, ovoid-shaped aeromagnetic anomaly. It is the only surface exposure of kimberlite within a 30 km long linear trend of fourteen aeromagnetic anomalies that are up to 600 m in diameter.The pipe is exposed in the crater facies, near the transition into diatreme facies as indicated by the occurrence of pyroclastic kimberlite characterized by abundant olivine macrocrysts, juvenile lapilli and kimberlite autoliths set in a serpentine-calcite matrix. Olivine, Cr-pyrope garnet and chromite are the most abundant macrocrysts; clinopyroxene, ilmenite and phlogopite mica occur in minor to trace amounts. Garnet and chromite harzburgite, garnet lherzolite, garnet-spinel lherzolite and rare eclogite dominate the xenolith population.Garnet and chromite mineral chemistry indicate encouraging diamond prospectivity and that potentially diamondiferous garnet and chromite harzburgite were the principal sources of diamond in the mantle at the time of kimberlite eruption.Single clinopyroxene grains define an ~42 mW/m2 sub-continental geotherm that is rooted in the diamond stability field. This compares to a slightly hotter geotherm (~48 mW/m2) for adjacent Somerset Island kimberlites with an origin in the graphite stability field. This data accords with the general lack of sub-calcic Cr-pyrope garnet, diamond inclusion chromite and diamond in Somerset Island kimberlites."

Jan 1, 2002

By B. R. Neufeld, M. G. Heximer, S. J. Roach, W. G. Van Luven, D. G. Reynolds

"Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. In the zinc plant, zinc concentrates are roasted to produce calcine, which is then processed in the leaching circuit for zinc recovery. Calcine is first dissolved at pH <2.0. This is followed by a precipitation stage using additional calcine that removes iron as a ferric hydroxide precipitate which is recycled to the lead operations. It is during this pH adjustment that impurities, notably arsenic, antimony and germanium, are co-precipitated with ferric hydroxide which is the primary removal phase for these elements. Recent processing conditions have resulted in lower iron inputs to the leaching circuit and this has resulted in insufficient co-precipitation of key impurities. This paper summarizes the influence of iron concentrations on impurity removal using laboratory and plant scale surveys, and emphasizes key specification limits for the primary iron removal circuit.INTRODUCTIONThe Sulphide Leach Plant (SLP) at Teck Metals Ltd., Trail Operations produces a zinc sulphate electrolyte from three different zinc bearing streams:1. Calcine, primarily containing zinc oxide, from the roasters2. Zinc electrolyte from the Oxide Leach Plant (OLP) is produced by leaching zinc oxide fume from the pyrometallurgical lead smelting operations3. Zinc slurry from the Zinc Pressure Leach (ZPL) autoclaveThe feed sources are blended and introduced to the iron removal process to precipitate iron in the form of a hydrolyzed iron precipitate which is recycled to the lead smelting operation. Along with iron, impurities, namely arsenic, antimony, germanium and silica, also co-precipitate; this process acts as the primary removal step for these elements. Following iron removal, the electrolyte is further processed in the zinc dust purification circuits. Cadmium and copper are removed in the cold stage circuit via zinc dust cementation, followed by cobalt cementation in the hot stage circuit."

Jan 1, 2016