Search Documents

By Jan W. Merks

The objective of metrology in mineral exploration is to derive unbiased confidence limits for masses of metals contained in reserves and resources. Sets of test results for gold and silver determined in pairs of interleaved bulk samples give unbiased confidence limits for the central value of each metal. The same sets of test results show how to verify spatial dependence by applying Fisher?s F-test to the variance of a set and the first variance term of the ordered set. A significant degree of spatial dependence gives a higher degree of precision for the central values of gold and silver. Plotting variance terms of an ordered set against the variance of the set and its lower limits of asymmetric 99% and 95% confidence ranges gives a sampling variogram. Sampling variograms put in plain view where spatial dependence in sampling units or sample spaces dissipates into randomness. The application of statistical methods to test results for sets of ordered core samples within boreholes, and for sets of ordered ore volumes within profiles, plays an important role in defining reserves and resources.

Oct 1, 2009

By Omero Alonso-Gonzalez, Sergio Haro-Rodriguez, Ricardo Solis-Rodriguez, Francisco Alvarado-Hernandez, Juan Antonio Gonzalez-Anaya, Héctor Rene Vega-Carrillo

"Precious metals are currently associated with refractory minerals such as telluride (Calaverite, Sylvanite, etc.) and selenium (Naumannite Ag2Se), which are difficult to dissolve through traditional methods, therefore it is necessary to perform a pretreatment (oxidative or roasting) preceding the process of leaching by cyanidation. In this preliminary work the aim was to study the use of solvent extraction to remove tellurium and selenium ions from a synthetic cyanidation effluent, with the purpose of recycling the cyanide back to the process. For the extraction of these anions, TeO32- and SeO42-, tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (Amine F) were studied as extractants, using nonylphenol as a modifier in the organic phase (trimethylpentane). The results show that it is possible to recover 82% of selenium and 10% of tellurium from synthetic solutions containing either 20 mg/L Se or 20 mg/L of Te, respectively The Se or Te mole ratio to cyanide was 1:4.INTRODUCTION In relation to extraction of precious metals, the cyanidation process has been in use for over a century and despite environmental and toxicological problems it remains the most widely used and economical process available. In the late 90s, there were great efforts to recover gold and silver from refractory ores, which is difficult to do by simple cyanidation. To improve gold recovery from tellurides and selenides that occurs in some new mines, the ores are pretreated by roasting. This is one of the most effective ways of rendering refractory gold ores leachable as well as being a fast pretreatment process compared with bio-oxidation or pressure leaching (Aylmore, 2001). The most important tellurides minerals are Calaverite (AuTe2) and, Silvanite (Au, Ag)2Te4). In the case of selenides, minerals include Naumannite (Ag2Se) and Aguilarite (Ag4SeS) (Ostroumov et al., 1989). Examples of deposits containing telluride include La Bambolla Mine (Sonora, Mexico), Cripple Greek (Colorado, USA), and Kalgoorlie (Western Australia) (Aguayo et al., 1996). The main purpose of this work was to explore the feasibility of using quaternary ammonium salts such as: tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (amine F) to extract tellurium and selenium anions from aqueous synthetic cyanidation effluents, so that the cyanide solution could be recycled back to leaching process. The tests were performed on synthetic solutions similar to those found in a mine: 20 mg/L Te as TeO32-, 20 mg/L Se as SeO42- and mole ratio to cyanide was 1:4. using an alkaline medium with pH ranging from 8 to 12. Two aspects are evaluated in this paper:"

Jan 1, 2017

By Daniel J. Schulze

Abstract-Eclogite is an important source of diamond in the upper mantle, but is more localized than peridotite. Using eclogitic minerals in kimberlite and diamond exploration is also more problematic than using the well-known peridotite-derived indicator minerals Cr-pyrope and magnesiochromite. The problems include color similarities between orange garnets from eclogites, Cr-poor megacrysts, and crustal garnets, chemical similarities with Cr-poor megacryst suite garnets (specifically elevated Na2O contents), and low abundance of eclogite garnet xenocrysts in most known kimberlites. Chemical screens must be used carefully to distinguish between varieties of orange garnets in exploration samples. For example, most orange garnets of crustal origin have >22 wt% FeO, with mantle eclogite garnets having lower values. Na2O-bearing garnets from the Cr-poor megacryst suite can be distinguished from Na2O-bearing garnets from diamondiferous eclogites by the elevated TiO2 contents of the former. The low abundance of eclogite garnet xenocrysts in kimberlites worldwide, however, may dictate that use of eclogite garnets in diamond exploration in most cases be restricted to advanced stages of kimberlite exploration and evaluation of kimberlite diamond potential. Crpyropes, Mg-ilmenites and Cr-rich chromites are more useful than eclogitic garnets in most stages of diamond exploration. If orange garnet xenocrysts are sought in a kimberlite exploration program, those from the Cr-poor megacryst suite will be more useful than eclogite derived garnets, due to the typical great abundance of the former, although they carry no information of the diamond potential of the host kimberlite.

Jan 1, 1997

By Daniel J. Schulze

Eclogite is an important source of diamond in the upper mantle, but is more localized than peridotite. Using eclogitic minerals in kimberlite and diamond exploration is also more problematic than using the well-known peridotite-derived indicator minerals Cr-pyrope and magnesio-chromite. The problems include color similarities between orange garnets from eclogites, Cr-poor megacrysts, and crustal garnets, chemical similarities with Cr-poor megacryst suite garnets (speci?cally elevated Na2O contents), and low abundance of eclogite garnet xenocrysts in most known kimberlites. Chemical screens must be used carefully to distinguish between varieties of orange garnetsin exploration samples. For example, most orange garnets of crustal origin have >22 wt% FeO, with mantle eclogite garnets having lower values. Na2O-bearing garnets from the Cr-poor megacryst suite can be distinguished from Na2O-bearing garnets from diamondiferous eclogites by the elevated TiO2contents of the former. The low abundance of eclogite garnet xenocrysts in kimberlites worldwide, however, may dictate that use of eclogite garnets in diamond exploration in most cases be restricted to advanced stages of kimberlite exploration and evaluation of kimberlite diamond potential. Cr-pyropes, Mg-ilmenites and Cr-rich chromites are more useful than eclogitic garnets in most stages of diamond exploration. If orange garnet xenocrysts are sought in a kimberlite exploration program, those from the Cr-poor megacryst suite will be more useful than eclogite derived garnets, due to the typical great abundance of the former, although they carry no information of the diamond potential of the host kimberlite.

Jan 1, 1997

By Ltd. (CYMCO) Technology Center Yunnan Metallurgical Group Co., S. Jian, T. Song, J. D. Miller

"As sulfide zinc ore deposits become exhausted, nonsulfide zinc ore deposits become the other resource for zinc production. However, flotation for zinc recovery from nonsulfide deposits is much more difficult than the flotation of sphalerite from sulfide deposits and may become an option for zinc production only if a suitable processing technology is developed. In this regard, research efforts are being devoted to the flotation of nonsulfide zinc oxide minerals. Some common methods which have been used for the flotation of zinc oxide minerals include sulfidization-flotation, activation, and direct flotation with anionic and cationic collectors. The traditional flotation techniques have low efficiency and difficulty in separation and recovery of the zinc minerals from gangue minerals, for example, smithsonite (ZnCO3) from other carbonate gangue minerals and hemimorphite (Zn4Si2O7 (OH)2·H2O) from silicate gangue minerals. In this study potassium lauryl phosphate was evaluated as a collector for the flotation of nonsulfide zinc minerals. Results from contact angle and microflotation experiments at pH 6–9 show that hemimorphite (Zn4Si2O7 (OH)2·H2O) can be floated from quartz and that smithsonite (ZnCO3) can be floated from calcite. However, when dodecylamine, which is a common collector reported in literature for the flotation of nonsulfide zinc minerals, was used as collector, no significant difference between nonsulfide zinc minerals and gangue minerals was observed at any pH value. Initial evaluation suggests that potassium lauryl phosphate is effective at low concentration and may be a promising collector for zinc oxide mineral flotation.INTRODUCTIONBefore the twentieth century, zinc was mainly produced from nonsulfide ores (Large, 2001; Gilg, Boni, & Cook, 2008). With the development of differential flotation processes in the late 19th century major production switched from nonsulfide zinc sources to sulfide zinc ores (Hitzman, Reynolds, Sangster, Allen, & Carman, 2003; Gilg et al., 2008). However, as it is becoming more difficult to find new sulfide ores, recovery from nonsulfide deposits is being considered. Nonsulfide flotation for zinc recovery is much more difficult than the flotation recovery of sphalerite from sulfide deposits and may become an option for zinc production if a suitable technology is developed. Zinc and lead oxide ores are difficult to beneficiate ores due to their similar floatability with gangue, high solubility in water, and the influence of slimes (Fa, Miller, Tao, & Li, 2005). In order to improve the performance of oxidized minerals, lots of effort is being devoted to this field of study (Ejtemaei & Mahdi, 2014)."

Jan 1, 2016

By A. Lam

The use of a liquid fed direct methanol fuel cell (DMFC) as a power source for micro and small portable applications is attractive due to its system simplicity, low temperature, etc. The aqueous methanol is directly oxidized and does not require additional fuel processing steps as in reformate based PEM fuel cells. In addition, the use of a liquid fuel is advantageous with respect to humidification, stack cooling and system energy density. The DMFC however, has technological issues that must be addressed before it can be widely adopted, particularly in larger applications such as small utility and transportation. At present, the crossover of methanol from the anode to the cathode is a major limitation on DMFC performance and fuel utilization efficiency. In this paper we discuss the influence of fuel modification on the control of crossover. This involves the use of different fuel additives and concentrations to minimize crossover. This appears to be the first reported case of the use of fuel modification (additives) to reduce methanol crossover. The rate of methanol permeation under passive conditions is discussed with respect to the different conditions.

Jan 1, 2005

Pillars are used in various forms in underground mining. For several decades pillar design has been an issue in both soft and hard rock underground mining. The major use of pillars is in room-and-pillar type mining. Pillars are critical structures in the production levels of block cave mines. With most mines leaning towards the use of block caving for ore extraction today, pillar design has become even more important. Empirical pillar design is popular. The use of numerical modeling is becoming more common in the design of underground mine pillars. A critical review of both the empirical and numerical modeling approaches to the design of underground mine pillars reveal some fundamental flaws. In general, pillar design approaches often assume the pillars are vertical, and are subjected to pure compression. Pillar failure criteria are then based on this assumption. Most papers on numerical modeling for pillar stability assessment use vertical pillars. This paper shows that where pillars are not subjected to pure compression the empirical pillar design approaches are inadequate, and that when using numerical models for the assessment of pillar performance, more care is needed in the determination of the average pillar stresses. The practice of relating field scale pillar strength to laboratory scale intact rock strength determined from conventional laboratory compression tests in empirical design equations is misleading when pillars are inclined or subjected to compressive and shear stresses. New data is added to the hard rock empirical pillar stability chart, and it is shown that it is misleading to conclude that failure of pillars with width to height ratios greater than 2.3 should not be anticipated. New empirical pillar design charts are presented for pillars at various degrees of inclination for different ko-ratios.

Aug 1, 2013

Keeping the sediment on the mine site and out of the water course is essential from the regulatory, environmental and sustainability perspectives. Regulation of this aspect of mining is embedded in environmental legislation and government receiving water quality standards, and government control has apparently been considered to be the most appropriate method to define mine site discharge standards and the environmental implications of sediment in downstream watercourses. A literature search for guidelines for the site specific design and operation of sediment ponds treating mine site runoff to remove total suspended solids, turbidity and flocculant-induced toxicity, revealed little information on the mining industry?s and government?s roles in defining the ?how to achieve? related to sediment pond design. Is there a need or reason for an industry-driven leadership to clearly define the ?how to? keep the sediment on the mine site and out of the water course? Currently, this issue is addressed in Canada by a federal mining regulation for metal mines which specifies discharge quality for sediment. This paper focuses on the method used in British Columbia, Canada, to regulate and provide a scientific methodology to control the discharge of sediment from mine sites. Management plans relative to this topic are discussed and are considered to have value from the exploration, construction, operation and the onset of closure phases. In addition, the balance and linkage between the erosion control management plan and the sediment pond management plan are discussed in terms of how they may be designed to complement each other to lower the risk of exceeding discharge and receiving water quality standards. If there were an industry-driven standard, or guidance document relative to addressing sediment release, it would benefit mining companies by eliminating the repetitive analysis of this topic for each new mine, mine expansion, and mine modification; also, government may often replace certain aspects of permitting with a regulation, if there is a government/industry established standard defining Best Achievable Technology (e.g. the Canadian Metal Mining Effluent Regulations).

Aug 1, 2013

By John Redstone, André R. Laplante

"Le rebroyage des concentrés d'hématite en usine (Sidbec-Normines, Port-Cartier) et en laboratoire a été modélisé selon le modèle de Reid (1965).L'effet du pourcentage solide sur la cinétique de broyage a été étudié en usine. La fonction de sélection corrigée (pour tenir compte de l'effet du pourcentage solide sur le temps de rétention) augmente lorsque le pourcentage solide augmente de 80 à 84 pourcent. Cette amélioration est contrebalancée par une augmentation de la quantité de pulpe court-circuitée, à des pourcentages solides supérieurs a 81%. La densité optimum de broyage se situe à 84 pourcent.Comme alternative au mode d'opération actuel, l'assemblage des broyeurs en série plutôt qu'en parallèle a également été simulée. Le moins 44 µm passe alors de 68.1 à 72.5 pourcent, ce qui correspond à une capacité supplémentaire de 32 tonnes à l'heure par broyeur. Ces résultats doivent toutefois être interprétés avec prudence, car la cinétique de broyage n'est généralement pas linéaire lorsque le taux d'alimentation est plus que doublé.IntroductionL'usine de bouletage de Sidbec-Normines Inc. a été décrite par Morimoto (1977), Lévesque et al. (1979) et Pabst (1979). La section de broyage des concentrés contient six broyeurs à boulets en parallèle et en circuit ouvert, d'un diamètre de 5. 18 mètres et de 10.36 mètres de longueur. Ils contiennent chacun environ 350 tonnes de boulets d'acier forgé de 3.8 cm de diamètre. Le concentré est broyé de 10 pourcent moins 150 µm (100 mailles) à 65-68 pourcent moins 44 µm (325 mailles), à un pourcentage solide de 78 à 80 pourcent. Cette fragmentation poussée exige une consommation d'énergie de 32 kWh/tonne. Cette énergie est surtout libérée sous forme de chaleur, la pulpe étant déchargée a une température de 68-72° C. II en résulte un milieu de broyage corrosif, et une consommation de boulets élevée, de 3.4 à 4.0 kg / tonne broyée."

Jan 1, 1983

By Washington Luiz Mafra

Every year the conventional direct reduction processes ? Midrex and HYL III ? increased their market share in the world steel production, even though they are only economically feasible in countries where natural gas is available at competitive prices. In this context, the new Midrex projects are based on large reactors (Megamod - 1.5 to 1.8 Mt/y of DRI), reduction temperatures of the metallic burden up to 850oC, with bustle gas temperatures between 960oC e 1050oC. Thus, the requirements of metallic burden performance, as well as the evaluating methods, usually based on ISO standards, need to be reviewed. It is well known that the standards usually applied to quality evaluation do not reflect the performance of metallic burden inside the reactors. This paper describes the different methods of evaluating the disintegration under reduction of DR pellets based on ISO 11257 standard. This is the most important method used by pellet producers and customers for evaluating DR feedstocks. The different methodologies tested to evaluate the disintegration under reduction had varying results, evidencing the relevance of the method and the quality of the pellet. Nevertheless, validating the method in an industrial reactor is still fundamental.

May 1, 2007

By J. E. Dutrizac, Alba Sunyer

The factors affecting the precipitation of arsenic-free alunite (KAl3(SO4)2(OH)6) were investigated in a series of laboratory experiments. Although the amount of alunite precipitated increased with increasing retention time, temperature, solution pH and the concentrations of Al(SO4)1.5 or K2SO4, the composition of the products remained nearly constant. The preferred conditions identified for the precipitation of arsenic-free alunite were then used to assess the behaviour As(III) and As(V) during alunite precipitation at 98°C. Increasing additions of As(III), as NaAsO2 or As2O3, resulted in a slight increase in the amount of precipitate formed at pH 2.80. However, X-ray diffraction analysis showed all the precipitates to be alunite, and <0.2% As(III) was detected in the products. In contrast, increasing additions of As(V), as KH2AsO4 or As2O5, resulted in significant increases in the amount of precipitate formed at pH 2.80 or 3.00. Furthermore, the arsenate (AsO43-) contents of the precipitates increased up to 15%, and the sulphate contents decreased, as the As(V) concentration of the synthesis solution increased from 0 to 9 g/L. X-ray diffraction analysis of the products detected only alunite, but there was a progressive expansion of the alunite cell with increasing arsenate content. The implication is that arsenate substitutes for sulphate in the alunite structure. Preliminary observations on the environmental stability of the arsenate-bearing alunite using the TCLP protocol gave solubilities <0.4 mg/L from a precipitate containing 8.5% AsO4 and 7.8 mg/L from a product containing 19.5% AsO4. Thus, it appears that alunites containing less than -10% AsO4 would be an acceptable vehicle for the disposal of arsenic from hydrometallurgical processing solutions.

Jan 1, 2011

By G. P. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Stress-corrosion cracking (SCC) tests were conducted in the near-neutral pH standard solution, NS4, and in an actual soil solution, using four-point bending at high a stress ratio and low frequency conditions very similar to those of operational pipelines. Pitting incubation appeared first and then pitting initiated and grew in both solutions although there were many more pits on the specimen tested in soil purged with 5% CO2 + 95% N2 than in the specimen tested in NS4 solution purged with the same gas. These observations show that samples in soil solution are more susceptible to pitting than those in NS4 solution. When the pit reached a critical size, the increased stress concentration around the pits, resulted in the transition to a crack.

Jan 1, 2005

By Michael Samis

The real option valuation method is often presented as an alternative to the conventional discounted cash flow (DCF) approach because it is able to recognize additional project value due to the presence of management flexibility. However, these two valuation methods can be separated on a more fundamental level by their differences in risk discounting. Real option valuation applies the risk-adjustment to the source of uncertainty in the cash flow while the DCF method adjusts for risk at the aggregate level of net cash flow. This seemingly small difference is the reason why the real option method is able to differentiate between projects according to each project?s unique risk characteristics while the conventional DCF approach cannot. This paper provides an overview of the real options and DCF valuation frameworks and discusses the differences in risk discounting that exist between the two methods. Using grade-school mathematics, this paper clearly demonstrates how, with real options, a unique project risk discount can be calculated which is directly linked to the project?s unique risk profile. It also highlights why the DCF method fails in this regard and shows why a call to ?increase the Risk-Adjusted Discount Rate? is an incomplete solution at best. Finally, a heap-leach project and satellite reserve development project are valued with both techniques and the difference in investment conclusions is explained in terms of the risk-discounting concepts discussed here.

May 1, 2003

By Anoop Sattineni

Over the past decade the use of BIM in the AEC industry has grown several fold and with it the number of standards available for implementing BIM. The ?National BIM Standard? by buildSmart Alliance, the ?Contractor Guide to BIM? by the Associated General Contractors of America, the ?BIM Project Execution Planning Guide and Templates? from Penn State University, the ?BIM Roadmap? by the US Army Corps of Engineers are some of the several BIM guidelines that are currently available to the AEC industry practitioners. Some of these guidelines are as comprehensive as defining BIM and the associated taxonomy while others are meant to be used on an individual project basis. From a contractor?s perspective one of the key benefits of using BIM is for the purpose of collision detection and coordination. This research has found that currently available guidelines do not address these issues adequately. For instance, the currently available guidelines do not allow the subcontractor to quickly communicate issues such as naming conventions and color schemes within the model, to the general contractor. Consequently general contractors and sub-contractors find themselves making changes to their BIM deliverables based on each other?s abilities and levels of adoption, apart from reason?s stemming from use of different software platforms. This paper describes how a group of contractors and subcontractors from Atlanta and Birmingham in the United States came together to create and adopt a ?Coordination Guidelines for Virtual Design and Construction?. These guidelines were specifically created with the purpose of streamlining the construction coordination process using BIM. This paper describes how the guidelines created differ from other guidelines currently available in the industry.

Aug 1, 2013

By Dong-kil Lee

A ventilation improvement index (VII) was developed in an effort to propose an optimal ventilation improvement measure for a designated mine. The index was designed to incorporate both ventilation effectiveness and cost efficiency. To verify the effect of the index, a mine experiencing a ventilation problem was selected, the ventilation assessed and ventilation network analyses were conducted. In the selected mine, four areas with ventilation difficulties were detected and an improvement schemes for each area were proposed. These were simulated through network simulation and evaluated using the ventilation improvement index. As a result, an optimum ventilation improvement scheme was proposed. The improvement scheme with the highest VII value was incorporated in the design.

Aug 1, 2013

By John Hansen

This paper has been written for presentation at the 103rd Annual General Meeting of the Canadian Institute of Mining, Metallurgy, and Petroleum, April 29 to May 02, 2000. The paper addresses blast pattern fragmentation and diggability versus the blasting technique used. RESUME The author is the Vice President for Thunderbird Mining Systems. In this capacity he manages the mine site installation of surface mining mobile equipment monitoring and navigation systems. These systems are onboard instrumentation and software systems designed to: ??measure and log mobile equipments? production and health; and ??direct the equipment operators via onboard displays that show comprehensive maps and engineering instructions. The author is a mining engineering graduate from the Royal School of Mines. His work experience includes front line supervisor and mining engineer for Hudson Bay Mining & Smelting, mining engineer for Teck Corporation, and mining consultant for PriceWaterhouseCoopers.

May 1, 2001

By Leslie S. Weldon

THE Lake Shore mine has been developed by two vertical shafts, with level intervals at 200 feet to the 2200 level and at 125 feet below this horizon. A main cross-cut joins the two shafts on all levels to the bottom of No. 3 shaft, and opening into these cross-cuts are the ore passes and sand passes, which are completed from surface To the 4450 level. In the west part of the mine, additional connections have been made between No. 1 and No. 2 veins, through which the major part of the ore from No. 2 vein west is routed to drifts in No. 1 vein. With the lesser amount of stoping on No. 1 vein, this arrangement permits better haulage to be maintained. The ore passes are driven at 50 degrees from the ends of short cross-cuts off the main ones and are broken through to the levels above at the mouths of the short cross-cuts, to allow for dumping on each level. The passes are controlled at each level by ball-and-chain gates and deliver to crushers and thence to loading pockets, shown in Figure 1. That system is quite flexible in that it is possible to by-pass the crushers at any station and load from either shaft at a number of different pockets. The sand passes are driven from the main cross-cuts at the same inclination as, and parallel to, the ore passes. Each is equipped with a chute and dump hole, so that waste or sand fill may be loaded or dumped at each level. A transfer door, hinged on the bottom, is installed opposite the chute for by-passing fill from one level to the next, and in the closed position protects the opening at the top of the pass. The dump hole situated beside the transfer door is protected by a grizzly with 10-inch spaces. Waste rock may be withdrawn from the system through No. 3 shaft loading pocket at the 2950 level to a waste bin on surface. Levels are developed by drifts in No. 1 and No. 2 veins for their entire lengths. Subsidiary breaks are followed at a later date, when full information has been obtained by exploration, and a considerable amount of development by sub-drifts is carried out in the upper part of the mine, particularly in more or less erratic sections of No. 1 vein.

Jan 1, 1936

By Amir Zavichi

Today, with the necessity of timely, on-budget and high quality completion of projects, proper use of construction equipment is essential to ensure project success. Construction equipment places a large monetary burden on the project and if not utilized efficiently, it can result in economic losses. Cranes are one of the most important and expensive operational devices on construction sites. They play a central role, and often activities that rely on crane services fall on the project?s critical path. Currently, material-handling scheduling is done by the crane operator or by an on-duty superintendent using his/hers personal judgment, making the process manual and timeconsuming. Thus, developing an optimal schedule, which considers different dynamic constraints in construction job site, may not be possible based on the current practice. This leads to longer operation times and a negative impact on project cost. This paper presents the latest results of an ongoing study, which aims to design and implement a nearreal time crane operation decision support system to be utilized directly by the crane operator or as an aid for the superintendent in scheduling optimal operation services. This system has several advantages such as maximizing the efficiency of crane operations, guaranteeing the best operation possible to reduce the crane?s travel time, reducing crews and equipment idle time, and minimizing the dependence on subjective human judgments.

Aug 1, 2013

By Pingchao Ke, Zhihong Liu

"To overcome the problem that scoroditeis not stable in neutral and alkaline solutions, we proposed and investigated a synthesis method of scorodite coated in-situ with hydrated ferric oxide in the Fe(II)-As(V)-H2O system at the initial Fe(III)/As(V) molar ratios larger than 1.0.The synthesis was carried out at 90?,pH 1.5 under atmospheric pressure. During the synthesis, oxygen gas was conducted and bubbled into the system to oxidize Fe(II) ions into Fe(III)ions, and Na2CO3aqueous solution as neutralizing agent was added controllably into the system for keeping the pH constant at 1.5. In this study, three samples of scorodite were synthesized at the controlled initial Fe(II)/As(V) molar ratios of 1.0, 2.0 and 3.0, respectively. The characterizations of the samples by HRTEM, TEM/EDX, and chemical composition indicated that the particle surfaces of scorodite synthesized at the initial Fe(II)/As(V) molar ratio of 2.0 and 3.0 were coated in situ by a film of hydrated ferric oxide with the thickness of several nanometers, while the sample synthesized at the initial Fe(II)/As(V) molar ratio of 1.0 was uncoated scorodite. The TCLP and long-term leaching for the toxicity characteristic of the samples showed that scorodite coated in situ with hydrated ferric oxide was stable in a wide pH range from 3.0 to 10.0, with the arsenic concentrations in the leaching solutions less than 1.0mg/L. Nevertheless, uncoated scorodite was unstable under the conditions from weak acidity to alkalinity, with the arsenic concentrations in the leaching solutions larger than 5.0 mg/L.INTRODUCTIONArsenic pollution is a challenge for environment and health and has been an important issue for scientists (Hopkin, 1989).Arsenicis commonly associated with ores or concentrates of nonferrous metals, mainly as independent arsenic bearing minerals such as arsenopyrite (FeAsS), tennantite(Cu12As4S13), enargite (Cu3AsS4), cobaltite (CoAsS), and gersdorffite (NiAsS), realgar (As2S2), orpiment(As2S3), etc.(Matschullat, 2000; Mandal & Suzuki, 2002; Long & Peng, 2012). In the nonferrous metallurgical processes, arsenic is enriched mainly in such arsenic bearing materials as various flue dusts, residues, and anode slimes, which results in the accumulation of arsenic in the system owing to the circulation of those arsenic-bearing materials back to the system and the pollution to the environment (Harris, et al, 2003).In addition, the utilization of arsenic is limited and has been decreasing owing to its toxicity and carcinogenicity. Therefore, arsenic has to be removed from those arsenic-bearing materials and discarded safely (Dutrizac & Jambor, 1988; Monhemius & Swash, 1999; Drahota & Fillippi, 2009).In this case, how to immobilize arsenic has become a difficult problem which must be solved. Among the methods of immobilizing arsenic which have been proposed and investigated, immobilizing arsenic into a stable mineral to fix it, has been realized as a promising method and becomes a research focus(Dutrizac et al, 1987; Dutrizac & Jambor, 1988; Demopoulos et al, 1995; Fujita et al, 2008a; 2008b).Scorodite has been known as one of the best minerals for immobilizing arsenic, owing to its high stability under weak acidic condition, the arsenic content as high as 32wt%,and good crystallinity benefiting the separation of solid to liquid(Daivid et al, 1999; Zhu & Merkel, 2001). Scorodite can be synthesized from arsenic containing solutions under both hydrothermal and atmospheric conditions, and a lot of work has been done on the synthesis of scorodite and its leaching stability characterization (Filippou & Demopoulos, 1999; Gomez et al, 2011).Two plants for the immobilization of arsenic as scorodite have been putin to operation in Chile and Japan, respectively (Filippou & Demopoulos, 1999; Amir et al, 2016)."

Jan 1, 2017

By A. D. Yell

"Recovery of water is always a major factor in the Beneficiation process. As Preparation Plants become larger the recovery of water for reuse, is a critical cost consideration. Tema Isenmann Inc in conjunction with our sister Company Multotec Manufacturing, has over the years, developed numerous different Screen Panels, Sieve Bends and Static Screens for dewatering. This paper will focus on a new innovation, the TeePee™ Panel which has double the open area of conventional Screen Panels. This results in efficient dewatering (reduced filter cake moistures) which allows for the use of smaller Vibrating Screens or increased capacity on existing Vibrating Screens. A major factor in the efficiency of any Screen Panel, including TeePee™ Panels, is the performance of the Vibrating Screen. If the Vibrating Screen does not have the required gravitational force or screen area to drain it will not dewater efficiently. Therefore a holistic approach has to be taken where the Vibrating Screen needs to operate at an optimal level, in conjunction with the correct Screen Panels, to achieve efficient dewatering. Key performance areas for Vibrating Screens are therefore detailed in this paper with an emphasis on important dewatering criteria. Case studies of different dewatering applications are included, where the use of TeePee™ Panels, has shown a marked improvement over conventional flat Screen Panels in reduction of filter cake moisture content.INTRODUCTION Dewatering can be done in a number of different ways and is largely dependent on the ore type, the particle size distribution and to what extent one needs to dewater will determine the method used. There are a number of different dewatering methods that can be used for particles above 200 micron, including Screen Bowl Centrifuges, Filter Presses, Static Screens, Static Sieve Bends and Vibrating Screens. This paper will focus primarily on Vibrating Dewatering Screens showing improved drainage and a reduction in the filter cake moisture content. KEY PERFORMANCE CRITERIAL FOR VIBRATING DEWATERING SCREENS For clarification the critical key performance criteria for Vibrating Dewatering Screens are set out in this paper. Dewatering Screens Vibrating Dewatering Screens are normally linear motion, either horizontal or inclined at 5 to 7° upwards with a vertical or back sloped plate at 45° to the rest of the screen deck. The back plate will often have screen panels in them to increase the dewatering capability, as shown in Figure 2 below."

Jan 1, 2017